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1. 发明授权

US4455368A Silver halide photographic light-sensitive material containing a UV absorbing polymer latex 失效
标题翻译：含有紫外线吸收聚合物胶乳的卤化银照相感光材料
公开(公告)号：US4455368A
公开(公告)日：1984-06-19
申请号：US484813
申请日：1983-04-14
申请人： Tetsuro Kojima , Shingo Ishimaru , Naohiko Sugimoto , Tadashi Ikeda
发明人： Tetsuro Kojima , Shingo Ishimaru , Naohiko Sugimoto , Tadashi Ikeda
IPC分类号： G03C7/26 , C07C67/00 , C07C229/30 , C07C253/00 , C07C255/30 , C07C313/00 , C07C317/28 , C07C317/44 , C07C317/48 , C08F12/00 , C08F12/06 , C08F20/00 , C08F20/10 , C08F20/26 , C08F20/34 , C08F20/38 , C08F20/52 , C08F20/54 , C08F22/32 , C08F36/00 , C08F36/04 , C09K3/00 , G03C1/04 , G03C1/06 , G03C1/815 , G03C1/78
CPC分类号： G03C1/815 , Y10S430/132
摘要： A silver halide photographic light-sensitive material comprising a support having thereon at least one light-sensitive silver halide emulsion and at least one light-insensitive layer is disclosed. One or more of the layers of the material contains an ultraviolet ray absorbing polymer latex which comprises a homopolymer or copolymer having a repeating unit derived from a monomer represented by the general formula (II) in which one or more ultraviolet ray absorbing compounds represented by the general formula (I) is loaded: ##STR1## the substituents within the general formula are defined within the specification. The material has excellent absorption characteristics in the 300 to 400 nm range and does not cause static marks caused by ultraviolet rays or undergo deterioration of color reproduction. In addition, the material has good film strength and reduced layer thickness and provides a color image having improved sharpness which is free from fading or discoloration due to light.
摘要翻译：公开了一种卤化银照相感光材料，其包含其上具有至少一种感光卤化银乳剂和至少一种不透光层的载体。材料的一层或多层包含一种紫外线吸收聚合物胶乳，其包含具有衍生自由通式（II）表示的单体的重复单元的均聚物或共聚物，其中一个或多个由通式（I）被加载：通式（II）中的取代基在本说明书中定义。该材料在300〜400nm的范围内具有优异的吸收特性，不会引起紫外线引起的静电痕迹或颜色再现的劣化。此外，该材料具有良好的膜强度和降低的层厚度，并且提供了一种具有改善的清晰度的彩色图像，其不会因光而褪色或变色。

2. 发明授权

US4443534A Silver halide photographic elements containing polymers which filter UV light 失效
标题翻译：含有过滤紫外光的聚合物的卤化银照相元件
公开(公告)号：US4443534A
公开(公告)日：1984-04-17
申请号：US484331
申请日：1983-04-12
申请人： Tetsuro Kojima , Shingo Ishimaru , Naohiko Sugimoto , Tadashi Ikeda
发明人： Tetsuro Kojima , Shingo Ishimaru , Naohiko Sugimoto , Tadashi Ikeda
IPC分类号： G03C7/26 , C07C67/00 , C07C225/14 , C07C225/16 , C07C229/30 , C07C253/00 , C07C255/30 , C07C313/00 , C07C317/28 , C07C317/48 , C07D211/46 , C07D417/12 , C08F12/00 , C08F12/06 , C08F20/00 , C08F20/10 , C08F20/26 , C08F20/34 , C08F20/38 , C08F20/52 , C08F20/54 , C08F20/60 , C08F36/04 , C08F220/00 , C08F220/10 , C08F236/00 , C08F236/04 , G03C1/053 , G03C1/06 , G03C1/815 , G03C1/84
CPC分类号： G03C1/053 , C08F20/60 , G03C1/815 , Y10S430/132
摘要： A silver halide photographic light-sensitive material is disclosed. The material is comprised of a support having thereon a light-sensitive silver halide layer and a light-insensitive layer. The material may also contain other layers and one or more layers contains an ultraviolet ray absorbing polymer latex. The polymer latex is comprised of a homopolymer or a copolymer having a repeating unit derived from a monomer represented by the following general formula (I): ##STR1## within the general formula (I) the Q represents an ultraviolet ray absorbing group represented by the general formula (II): ##STR2## the substituents within the general formulae (I) and (II) are defined in a specification. The photographic light-sensitive material has excellent absorbing characteristic in the 300 to 400 nm range and does not cause static marks caused by ultraviolet layer. Furthermore, the material does not undergo discoloration. In addition, the photographic material has good film strength and a reduced layer thickness and provides a color image having an improved sharpness and which is free from fading and discoloration caused by light.
摘要翻译：公开了一种卤化银照相感光材料。该材料由其上具有感光卤化银层和不透光层的支撑体构成。该材料还可以含有其它层，一层或多层含有紫外线吸收聚合物胶乳。聚合物胶乳由均聚物或具有衍生自下列通式（I）表示的单体的重复单元的共聚物构成：通式（I）中的I（I）中，Q表示紫外线吸收组由通式（II）表示：通式（I）和（II）中的取代基在说明书中定义。照相感光材料在300〜400nm范围内具有优异的吸收特性，不会引起紫外线层引起的静电痕迹。此外，该材料不会变色。此外，照相材料具有良好的膜强度和降低的层厚度，并且提供了具有改善的清晰度并且没有由光引起的褪色和变色的彩色图像。

3. 发明授权

US4431726A Silver halide photographic light-sensitive element containing a u.v. absorbing layer 失效
公开(公告)号：US4431726A
公开(公告)日：1984-02-14
申请号：US453657
申请日：1982-12-27
申请人： Tetsuro Kojima , Tadashi Ikeda , Shingo Ishimaru , Naohiko Sugimoto
发明人： Tetsuro Kojima , Tadashi Ikeda , Shingo Ishimaru , Naohiko Sugimoto
IPC分类号： G03C7/26 , C08F20/00 , C08F20/12 , C08F20/34 , C08F20/52 , C08F20/54 , C08F22/00 , C08F22/32 , G03C1/04 , G03C1/06 , G03C1/815 , G03C1/78
CPC分类号： G03C1/815 , C08F20/12 , C08F20/54 , Y10S430/114
摘要： A silver halide photographic light-sensitive material is disclosed. The material is comprised of one or more light-sensitive silver emulsion layers and one or more light-insensitive layers. The silver halide layers or light-insensitive layers contain an ultraviolet ray absorbing polymer latex. The polymer latex is comprised of a homopolymer or copolymer having a repeating unit derived from monomers represented by the following general formula (I): ##STR1## wherein the substituents within a general formula (I) are defined within the specification. The polymer latex (I) contains a substituents Q which represents an ultraviolet ray absorbing group represented by the general formula (II): ##STR2## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 each represents a hydrogen atom, a halogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an aryloxy group having 6 to 20 carbon atoms, an alkylthio group having 1 to 20 carbon atoms, an arylthio group having 6 to 20 carbon atoms, an amino group, an alkylamino group having 1 to 20 carbon atoms, an arylamino group having 6 to 20 carbon atoms, a hydroxyl group, a cyano group, a nitro group, an acylamino group, a carbamoyl group, a sulfonyl group, a sulfamoyl group, a sulfonamide group, an acyloxy group or an oxycarbonyl group, and R.sub.1 and R.sub.2, R.sub.2 and R.sub.3, R.sub.3 and R.sub.4 or R.sub.4 and R.sub.5 may form a 5 to 6 member ring by ring closure; R.sub.6 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms; R.sub.7 represents a cyano group, --COOR.sub.9, --CONHR.sub.9, --COR.sub.9 or --SO.sub.2 R.sub.9 ; and R.sub.8 represents a cyano group, --COOR.sub.10, --CONHR.sub.10, --COR.sub.10 or --SO.sub.2 R.sub.10 ; wherein R.sub.9 and R.sub.10 each represents an alkyl group having 1 to 20 carbon atoms or an aryl group having 6 to 20 carbon atoms; wherein one of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 bonds to the vinyl group through the linking group. The photographic material which includes the polymer latex of the invention has excellent absorption characteristics in the 300 to 400 nm range and does not cause static marks caused by ultraviolet rays. Furthermore, the material does not undergo deterioration of color reproduction and fading or discoloration of color images caused by light.

4. 发明授权

US4645735A Silver halide photographic light-sensitive material containing ultraviolet ray absorbing polymer latex 失效
标题翻译：含有紫外线吸收聚合物胶乳的卤化银照相感光材料
公开(公告)号：US4645735A
公开(公告)日：1987-02-24
申请号：US712314
申请日：1985-03-13
申请人： Naohiko Sugimoto , Tetsuro Kojima , Shingo Ishimaru
发明人： Naohiko Sugimoto , Tetsuro Kojima , Shingo Ishimaru
IPC分类号： G03C1/85 , G03C1/04 , G03C1/06 , G03C1/76 , G03C1/815 , G03C1/84
CPC分类号： G03C1/8155 , Y10S430/132
摘要： A silver halide photographic light-sensitive material is disclosed. The material is comprised of a support base having positioned thereon a light-sensitive silver halide emulsion layer, a light-insensitive layer and ultraviolet ray absorbing polymer latex of a polymer having a repeating unit derived from a monomer represented by the general formula (I): ##STR1## within general formula (I) the substituents are defined within the specification. The Q represents an ultraviolet ray absorbing group represented by a general formula (II) or (III): ##STR2## The substituents within the general formulae given above are defined in the specification. By including the particular ultraviolet ray absorbing polymer latex of the invention the resulting photographic material has improved antistatic properties and the photographic characteristics of the material are not deteriorated by the presence of the latex.
摘要翻译：公开了一种卤化银照相感光材料。该材料包括其上定位有感光卤化银乳剂层的支撑基底，具有衍生自由通式（I）表示的单体的重复单元）的聚合物的光不敏感层和紫外线吸收聚合物胶乳，：通式（I）中的取代基在说明书中定义。 Q表示由通式（II）或（III）表示的紫外线吸收基团：上述通式中的取代基在说明书中定义。通过包括本发明的特定的紫外线吸收聚合物胶乳，所得的照相材料具有改善的抗静电性能，并且材料的照相特性不会因胶乳的存在而劣化。

5. 发明授权

US4464462A Silver halide photographic light-sensitive material 失效
标题翻译：卤化银照相感光材料
公开(公告)号：US4464462A
公开(公告)日：1984-08-07
申请号：US518721
申请日：1983-07-29
申请人： Naohiko Sugimoto , Tetsuro Kojima , Yasuo Mukunoki
发明人： Naohiko Sugimoto , Tetsuro Kojima , Yasuo Mukunoki
IPC分类号： G03C1/34 , C09K3/16 , G03C1/76 , G03C1/85 , G03C7/396 , G03C1/84
CPC分类号： G03C7/396 , Y10S430/162
摘要： A silver halide photographic light-sensitive material having improved antistatic properties is disclosed. The material is comprised of a support having thereon a light-senstive silver halide emulsion layer and a light-insensitive layer. The material includes (A) a flourine containing cationic surface active agent and (B) an ultraviolet ray absorbing polymer latex which comprises a polymer or a copolymer having a repeating unit derived from a monomer represented by the following general formula (I): ##STR1## within the formula (I) the Q is an ultraviolet ray absorbing group represented by the following general formula (II) or (III): ##STR2## the substituents within the formulae shown are defined within the specification. The ultraviolet ray absorbing polymer latex is present in the material in an amount in the range of 10 to 2,000 mg/m.sup.2 of the material. The material which contains a combination of the ultraviolet ray absorbing polymer latex and the fluorine containing cationic surface active agent has excellent antistatic properties and does not result in the occurrence of pressure marks.
摘要翻译：公开了具有改善的抗静电性能的卤化银照相感光材料。该材料由其上具有光敏卤化银乳剂层和不透光层的载体组成。该材料包括（A）含有阳离子表面活性剂的粉末和（B）包含聚合物或共聚物的紫外线吸收聚合物胶乳，所述聚合物或共聚物具有源自由以下通式（I）表示的单体的重复单元：

6. 发明授权

US4551420A Silver halide photographic light-sensitive material 失效
标题翻译：卤化银照相感光材料
公开(公告)号：US4551420A
公开(公告)日：1985-11-05
申请号：US698251
申请日：1985-02-01
申请人： Naohiko Sugimoto , Tetsuro Kojima
发明人： Naohiko Sugimoto , Tetsuro Kojima
IPC分类号： G03C1/85 , G03C1/04 , G03C1/06 , G03C1/815 , G03C1/89 , G03C1/78
CPC分类号： C07C255/00 , G03C1/8155 , G03C1/89 , Y10S430/132
摘要： A silver halide photographic light-sensitive material is disclosed which is comprised of a support base having thereon a light-sensitive silver halide emulsion layer and a light-insensitive layer. The material also includes an ultraviolet ray absorbing polymer latex and a fine grained silver halide having a diameter of 0.2 microns or less. The ultraviolet ray absorbing polymer latex is a polymer or copolymer having a repeating unit derived from a monomer represented by the general formula (I): ##STR1## the substituents are defined within the specification. By utilizing the polymer latex of general formula (I) the occurance of static marks is almost completely prevented without causing undesirable effects on other film properties.
摘要翻译：公开了一种卤化银照相感光材料，其由其上具有感光卤化银乳剂层和不透光层的支撑基底组成。该材料还包括紫外线吸收聚合物胶乳和直径为0.2微米或更小的细粒状卤化银。紫外线吸收聚合物胶乳是具有衍生自由通式（I）表示的单体的重复单元的聚合物或共聚物：取代基在说明书中定义。通过使用通式（I）的聚合物胶乳几乎完全防止了静电痕迹的出现，而不会对其它膜性质产生不期望的影响。

7. 发明授权

US4675278A Silver halide photographic light-sensitive materials 失效
标题翻译：卤化银照相感光材料
公开(公告)号：US4675278A
公开(公告)日：1987-06-23
申请号：US918642
申请日：1986-10-10
申请人： Naohiko Sugimoto , Kunio Ishigaki
发明人： Naohiko Sugimoto , Kunio Ishigaki
IPC分类号： G03C1/06 , G03C1/32 , G03C1/76
CPC分类号： G03C1/7614 , Y10S430/151 , Y10S430/162
摘要： In silver halide photographic light-sensitive materials comprising at least one silver halide photographic emulsion layer on one side of a base and an emulsion protective layer thereon, and a hydrophilic colloid backing layer on the other side of the base, the improvement wherein said backing layer contains a polymer matting agent having an average particle size of 3.0 .mu.m or more and said emulsion protective layer contains at least one of a polyoxyethylene type surface active agent, and a silicone type slipping agent.
摘要翻译：在卤化银照相感光材料中，在基材的一侧上包含至少一个卤化银照相乳剂层和其上的乳液保护层，以及在该基材的另一侧上的亲水胶体背衬层，其中所述背衬层含有平均粒径为3.0μm以上的聚合物消光剂，所述乳液保护层含有聚氧乙烯型表面活性剂和硅酮型滑爽剂中的至少一种。

8. 发明授权

US4474873A Silver halide photographic light-sensitive materials containing fluorinated compounds 失效
标题翻译：含氟化合物的卤化银照相感光材料
公开(公告)号：US4474873A
公开(公告)日：1984-10-02
申请号：US495878
申请日：1983-05-18
申请人： Yukio Maekawa , Yasuo Mukunoki , Naohiko Sugimoto
发明人： Yukio Maekawa , Yasuo Mukunoki , Naohiko Sugimoto
IPC分类号： G03C1/38 , G03C1/85 , G03C1/78
CPC分类号： G03C1/385 , Y10S430/136
摘要： A silver halide photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer wherein the photographic light-sensitive material contains a compound represented by the following general formula (I): ##STR1## wherein Rf represents a saturated or unsaturated hydrocarbon group having from 3 to 20 carbon atoms wherein all or a part of the hydrogen atoms are substituted with fluorine atoms; A and B each represents a divalent linking group; R.sub.1 represents a hydrogen atom or an alkyl group; R.sub.2, R.sub.3 and R.sub.4 each represents an alkyl group and at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represents an alkyl group substituted with a monovalent group, and X represents an anion.The photographic light-sensitive material containing the compound represented by the general formula (I) provides improved antistatic properties without adversely affecting the photographic properties and can be prepared without problems during coating such as formation of "comets" and "repelling".
摘要翻译：一种卤化银照相感光材料，其包含其上具有至少一个卤化银乳剂层的载体，其中所述照相感光材料含有由以下通式（I）表示的化合物：其中R f表示具有3至20个碳原子的饱和或不饱和烃基，其中全部或一部分氢原子被氟原子取代; A和B各自表示二价连接基团; R1表示氢原子或烷基; R 2，R 3和R 4各自表示烷基，R 1，R 2，R 3和R 4中的至少一个表示被一价基团取代的烷基，X表示阴离子。含有由通式（I）表示的化合物的照相感光材料提供了改进的抗静电性能，而不会不利地影响照相性能，并且可以在涂布过程中没有问题地制备，例如形成“彗星”和“排斥”。

9. 发明授权

US4267265A Photographic light-sensitive material 失效
标题翻译：摄影感光材料
公开(公告)号：US4267265A
公开(公告)日：1981-05-12
申请号：US974460
申请日：1978-12-29
申请人： Naohiko Sugimoto , Ikutaro Horie , Kameji Nagao , Masakazu Yoneyama , Yasuhiro Nakayama , Nobuo Yamamoto
发明人： Naohiko Sugimoto , Ikutaro Horie , Kameji Nagao , Masakazu Yoneyama , Yasuhiro Nakayama , Nobuo Yamamoto
IPC分类号： C10M105/72 , C10M105/54 , C10M105/58 , C10N40/36 , G03C1/76 , G03C1/85 , G03C1/31
CPC分类号： G03C1/7614 , Y10S430/162
摘要： A silver halide photographic light-sensitive material comprising a support having thereon at least one light-sensitive silver halide emulsion layer and a surface layer thereof containing an organic fluoro-compound and a carboxy group-containing compound, resulting in an improvement in the physical characteristics of the surface.
摘要翻译：一种卤化银照相感光材料，其包含其上具有至少一个感光卤化银乳剂层的支撑体及其含有有机氟化合物和含羧基化合物的表面层，导致物理特性的改善的表面。

10. 发明授权

US3938999A Antistatic photographic sensitive materials 失效
标题翻译：抗静电感光材料
公开(公告)号：US3938999A
公开(公告)日：1976-02-17
申请号：US563904
申请日：1975-03-31
申请人： Masakazu Yoneyama , Nobuo Yamamoto , Naohiko Sugimoto , Ikutaro Horie , Yasuhiro Nakayama
发明人： Masakazu Yoneyama , Nobuo Yamamoto , Naohiko Sugimoto , Ikutaro Horie , Yasuhiro Nakayama
IPC分类号： C09K3/16 , C08F8/00 , C08F8/14 , G03C1/85 , G03C1/89 , G03C1/84 , G03C1/82
CPC分类号： G03C1/89 , Y10S430/131 , Y10S430/16
摘要： An antistatic photographic sensitive material comprising a support having thereon at least one silver halide emulsion layer, wherein a surface active copolymer containing in the main chain a repeating unit represented by the formula (I) ##EQU1## wherein Y represents an organic residue having 4 to 22 carbon atoms; n represents the average number of ethyleneoxy units and is 1 to 100; and M represents a hydrogen atom, an alkali metal atom, an alkaline earth metal atom, an ammonium group or an alkylammonium group is present in at least one of a surface of the support and a photographic layer.
摘要翻译：一种防静电感光材料，包括其上具有至少一个卤化银乳剂层的载体，其中在主链中含有由式（I）-CHCH- | Y-表示的重复单元的表面活性共聚物， CH 2 CH 2 O n CC-OM（I）并行对苯二甲酸乙酯其中Y代表具有4-22个碳原子的有机残基; n表示乙烯氧基单元的平均数，为1〜100; M表示氢原子，碱金属原子，碱土金属原子，铵基或烷基铵基存在于载体表面和照相层中的至少一个中。

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