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    • 3. 发明授权
    • Silver halide photographic light-sensitive material
    • 卤化银照相感光材料
    • US4304852A
    • 1981-12-08
    • US188783
    • 1980-09-19
    • Naohiko SugimotoShinzo KishimotoKatsumi RyokeMasakazu YoneyamaNobuhisa Sekiguchi
    • Naohiko SugimotoShinzo KishimotoKatsumi RyokeMasakazu YoneyamaNobuhisa Sekiguchi
    • C09K3/16G03C1/85G03C1/89G03C1/78
    • G03C1/89Y10S430/162
    • A silver halide photographic light-sensitive material is described containinga film-forming water-soluble polymer derived from a monomer including a carboxylic acid group;a compound of the formula (I) ##STR1## wherein A is ##STR2## or a chemical bond; R is a saturated or unsaturated hydrocarbon group having from 8 to 22 carbon atoms when A is a chemical bond, and a saturated or unsaturated hydrocarbon group having from 7 to 21 carbon atoms whenA is ##STR3## R.sub.5 is hydrogen, a methyl group, or an ethyl group; B is --COO.sup..crclbar. or --SO.sub.3.sup..crclbar. ; R.sub.1 and R.sub.2 are each an alkyl group or hydroxyalkyl group having from 1 to 18 carbon atoms, or a polyalkylene oxide chain group; R.sub.3 and R.sub.4 are each hydrogen or an alkyl group having from 1 to 4 carbon atoms; n is an integer of from 2 to 8; and x is 0 or 1; anda compound of the formula (II) ##STR4## wherein A, B, R.sub.1, R.sub.2, R.sub.3, R.sub.4 and x can have the same meanings as defined for formula (I) above; Rf is a perfluoroalkyl group having from 8 to 22 carbon atoms when A is a chemical bond, and a perfluoroalkyl group having from 7 to 21 carbon atoms when A is ##STR5##
    • 描述了一种卤化银照相感光材料,其包含衍生自包含羧酸基团的单体的成膜水溶性聚合物; 式(I)化合物其中A为化学键或化学键; 当A为化学键时,R为碳原子数为8〜22的饱和或不饱和烃基,A为R5时为碳原子数为7〜21的饱和或不饱和烃基为氢,甲基, 或乙基; B是-COO( - )或-SO 3( - ); R1和R2各自为具有1至18个碳原子的烷基或羟烷基,或聚环氧烷链基; R 3和R 4各自为氢或具有1至4个碳原子的烷基; n为2〜8的整数, x为0或1; 和式(II)化合物其中A,B,R 1,R 2,R 3,R 4和x可以具有与上述式(I)所定义相同的含义; 当A为化学键时,Rf为碳原子数为8〜22的全氟烷基,A为碳原子数为7〜21的全氟烷基时,
    • 5. 发明授权
    • Silver halide photographic light-sensitive materials containing
fluorinated compounds
    • 含氟化合物的卤化银照相感光材料
    • US4474873A
    • 1984-10-02
    • US495878
    • 1983-05-18
    • Yukio MaekawaYasuo MukunokiNaohiko Sugimoto
    • Yukio MaekawaYasuo MukunokiNaohiko Sugimoto
    • G03C1/38G03C1/85G03C1/78
    • G03C1/385Y10S430/136
    • A silver halide photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer wherein the photographic light-sensitive material contains a compound represented by the following general formula (I): ##STR1## wherein Rf represents a saturated or unsaturated hydrocarbon group having from 3 to 20 carbon atoms wherein all or a part of the hydrogen atoms are substituted with fluorine atoms; A and B each represents a divalent linking group; R.sub.1 represents a hydrogen atom or an alkyl group; R.sub.2, R.sub.3 and R.sub.4 each represents an alkyl group and at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represents an alkyl group substituted with a monovalent group, and X represents an anion.The photographic light-sensitive material containing the compound represented by the general formula (I) provides improved antistatic properties without adversely affecting the photographic properties and can be prepared without problems during coating such as formation of "comets" and "repelling".
    • 一种卤化银照相感光材料,其包含其上具有至少一个卤化银乳剂层的载体,其中所述照相感光材料含有由以下通式(I)表示的化合物:其中R f表示 具有3至20个碳原子的饱和或不饱和烃基,其中全部或一部分氢原子被氟原子取代; A和B各自表示二价连接基团; R1表示氢原子或烷基; R 2,R 3和R 4各自表示烷基,R 1,R 2,R 3和R 4中的至少一个表示被一价基团取代的烷基,X表示阴离子。 含有由通式(I)表示的化合物的照相感光材料提供了改进的抗静电性能,而不会不利地影响照相性能,并且可以在涂布过程中没有问题地制备,例如形成“彗星”和“排斥”。
    • 8. 发明授权
    • Silver halide photographic light-sensitive material
    • 卤化银照相感光材料
    • US4464462A
    • 1984-08-07
    • US518721
    • 1983-07-29
    • Naohiko SugimotoTetsuro KojimaYasuo Mukunoki
    • Naohiko SugimotoTetsuro KojimaYasuo Mukunoki
    • G03C1/34C09K3/16G03C1/76G03C1/85G03C7/396G03C1/84
    • G03C7/396Y10S430/162
    • A silver halide photographic light-sensitive material having improved antistatic properties is disclosed. The material is comprised of a support having thereon a light-senstive silver halide emulsion layer and a light-insensitive layer. The material includes (A) a flourine containing cationic surface active agent and (B) an ultraviolet ray absorbing polymer latex which comprises a polymer or a copolymer having a repeating unit derived from a monomer represented by the following general formula (I): ##STR1## within the formula (I) the Q is an ultraviolet ray absorbing group represented by the following general formula (II) or (III): ##STR2## the substituents within the formulae shown are defined within the specification. The ultraviolet ray absorbing polymer latex is present in the material in an amount in the range of 10 to 2,000 mg/m.sup.2 of the material. The material which contains a combination of the ultraviolet ray absorbing polymer latex and the fluorine containing cationic surface active agent has excellent antistatic properties and does not result in the occurrence of pressure marks.
    • 公开了具有改善的抗静电性能的卤化银照相感光材料。 该材料由其上具有光敏卤化银乳剂层和不透光层的载体组成。 该材料包括(A)含有阳离子表面活性剂的粉末和(B)包含聚合物或共聚物的紫外线吸收聚合物胶乳,所述聚合物或共聚物具有源自由以下通式(I)表示的单体的重复单元: