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    • 2. 发明授权
    • Silicone compound, and a makeup containing this compound
    • 硅氧烷化合物和含有该化合物的化妆品
    • US06759031B2
    • 2004-07-06
    • US10136310
    • 2002-05-02
    • Tetsuo NakanishiIchiro OnoToru Shimizu
    • Tetsuo NakanishiIchiro OnoToru Shimizu
    • A61K742
    • A61K8/893A61Q1/02A61Q1/04A61Q1/10C08G77/38C08G77/50
    • This invention relates to a makeup containing a specific modified silicone obtained by an economical manufacturing method not requiring an esterification catalyst, having a high reaction rate and therefore leaving little unreacted material, and in particular relates to a makeup with good skin adhesion, good retention and excellent emulsion stability. A silicone compound represented by the general formula (1): R1aR2bSiO(4-a-b)/2 (in the formula, R1 is at least one substituent group having 1-30 carbon atoms, chosen from alkyaryl, aralkyl, fluorine-substituted alkyl or organopolysiloxanylsilyl, R2 is a carboxylate residue represented by the following general formula (2): R3 is a saturated or unsaturated hydrocarbon group having 2-30 carbon atoms, a is 1.0-2.5, and b is 0.001-1.5.
    • 本发明涉及含有通过不需要酯化催化剂的经济制造方法获得的具有高反应速率并因此留下很少未反应物质的特定改性硅氧烷的组合物,特别涉及具有良好的皮肤粘附性,良好的保留性和 优选的乳液稳定性。由通式(1)表示的硅氧烷化合物:(式中,R 1是至少一个具有1-30个碳原子的取代基,选自烷芳基,芳烷基,氟取代的烷基或有机聚硅氧烷基甲硅烷基 R 2是由以下通式(2)表示的羧酸酯残基:R 3是具有2-30个碳原子的饱和或不饱和烃基,a是1.0-2.5,b是0.001-1.5。
    • 3. 发明授权
    • Silicone compound, a powder surface-treated with this compound, and a makeup containing this powder
    • 硅氧烷化合物,用该化合物表面处理的粉末和含有该粉末的化妆品
    • US06717003B2
    • 2004-04-06
    • US09773671
    • 2001-02-02
    • Tetsuo NakanishiIchiro OnoToru Shimizu
    • Tetsuo NakanishiIchiro OnoToru Shimizu
    • C07F704
    • A61K8/894A61K8/585A61K8/891A61K8/895A61K8/897A61Q1/02A61Q1/10A61Q17/04C08G77/38C08G77/50
    • This invention relates to a powder which is surface-treated by a novel silicone compound, and to a makeup containing this powder. In particular, it relates to a silicone compound which has good compatibility with oils such as ester oils and triglycerides or silicone oils, and to a makeup with a smooth feel, excellent dispersibility and excellent emulsification stability. A silicone compound represented by the general formula (1): R1aR2bR3cSiO(4-a-b-c)/2 (in the formula, R1 is at least one organic group chosen from alkyl having 1-30 carbon atoms, aryl, aralkyl, fluorine-substituted alkyl or organopolysiloxanylsilyl, R2 is a reactive substituent group chosen from hydrogen, hydroxy or alkoxy having 1-6 carbon atoms, or a reactive substituent group in which at least one of carbon, oxygen and silicon are bonded to these reactive substituent groups, R3 is a carboxylate residue represented by the following general formula (2): R4CO2—Q— R4 is a saturated or unsaturated hydrocarbon group having 2-30 carbon atoms, Q is a bivalent hydrocarbon group which may also contain a hetero atom, a is 1.0-2.5. b is 0.001-1.5, and c is 0.001-1.5, a powder surface-treated with this silicone compound, and a makeup containing this powder.
    • 本发明涉及通过新型硅氧烷化合物进行表面处理的粉末以及含有该粉末的化妆品。 特别涉及一种与油类,例如酯油,甘油三酸酯,硅油等相容性好的硅酮化合物,具有平滑感,分散性优异,乳化稳定性优异的化妆品。 1):(式中,R 1是选自具有1-30个碳原子的烷基,芳基,芳烷基,氟取代的烷基或有机聚硅氧烷基甲硅烷基中的至少一个有机基团,R 2是选自 氢,羟基或具有1-6个碳原子的烷氧基,或其中碳,氧和硅中的至少一个与这些反应性取代基键合的反应性取代基,R 3是由以下通式表示的羧酸盐残基 (2):R 4是具有2-30个碳原子的饱和或不饱和烃基,Q是也可以含有杂原子的二价烃基,a是1.0-2.5,b是0.001-1.5,c 为0.001-1.5,粉末表面 用该硅氧烷化合物处理,并含有该粉末的化妆品。
    • 6. 发明授权
    • Silicon compound, and a makeup containing this compound
    • 硅化合物和含有该化合物的化妆品
    • US06479686B2
    • 2002-11-12
    • US09772963
    • 2001-01-31
    • Tetsuo NakanishiIchiro OnoToru Shimizu
    • Tetsuo NakanishiIchiro OnoToru Shimizu
    • C07F708
    • A61K8/893A61Q1/02A61Q1/04A61Q1/10C08G77/38C08G77/50
    • This invention relates to a makeup containing a specific modified silicone obtained by an economical manufacturing method not requiring an esterification catalyst, having a high reaction rate and therefore leaving little unreacted material, and in particular relates to a makeup with good skin adhesion, good retention and excellent emulsion stability. [Composition] A silicone compound represented by the general formula (1): R1aR2bSiO(4-a-b)/2 (in the formula, R1 is at least one substituent group having 1-30 carbon atoms, chosen from alkyaryl, aralkyl, fluorine-substituted alkyl or organopolysiloxanylsilyl, R2 is a carboxylate residue represented by the following general formula (2): R3 is a saturated or unsaturated hydrocarbon group having 2-30 carbon atoms, a is 1.0-2.5, and b is 0.001-1.5.
    • 本发明涉及含有通过不需要酯化催化剂的经济制造方法获得的具有高反应速率并因此留下很少未反应物质的特定改性硅氧烷的组合物,特别涉及具有良好的皮肤粘附性,良好的保留性和 [组成]由通式(1)表示的硅氧烷化合物:(式中,R 1为至少一个具有1-30个碳原子的取代基,选自烷芳基,芳烷基,氟取代的烷基或有机聚硅氧烷基甲硅烷基 R2为由下列通式(2)表示的羧酸盐残基:R3为碳原子数2-30的饱和或不饱和烃基,a为1.0-2.5,b为0.001-1.5。
    • 7. 发明授权
    • Organopolysiloxane-grafted copolymeric compound
    • 有机聚硅氧烷接枝共聚物
    • US06313249B1
    • 2001-11-06
    • US09538262
    • 2000-03-30
    • Tetsuo NakanishiIchiro Ono
    • Tetsuo NakanishiIchiro Ono
    • C08F3008
    • C08G77/442C08F6/02C08F8/42C08F290/148C08F220/00
    • Disclosed is a method for the preparation of an organopolysiloxane-grafted graft copolymer of a carbon-carbon backbone chain structure which is free from the troubles due to emission of an irritative odour and instability in storage. The method comprises the steps of copolymerizing a (meth)acryloxyalkyl-terminated organopolysiloxane compound with (meth)acrylic acid or an alkyl (meth)acrylate, optionally, together with a long chain-alkyl (meth)acrylate and/or a (meth)acryloxy-terminated polyoxyalkylene compound in a solution polymerization process to give a polymer solution and subjecting the polymer solution to a catalytic hydrogenation treatment so as to completely eliminate any unpolymerized acrylic compounds.
    • 公开了一种制备碳 - 碳骨架链结构的有机聚硅氧烷接枝共聚物的方法,该方法由于发出刺激性气味和不稳定性而不会产生故障。 该方法包括以下步骤:(甲基)丙烯酰氧基烷基封端的有机聚硅氧烷化合物与(甲基)丙烯酸或(甲基)丙烯酸烷基酯共聚,任选地与(甲基)丙烯酸长链烷基酯和/或(甲基) 丙烯酰氧基封端的聚氧化烯化合物,得到聚合物溶液,并使聚合物溶液进行催化氢化处理,以完全消除任何未聚合的丙烯酸类化合物。