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1. 发明授权

US4581433A Elastomer polyurethane-polyurea coatings based on bis(4-isocyanatocyclohexyl)methane 失效
标题翻译：基于双（4-异氰酸根合环己基）甲烷的弹性体聚氨酯 - 聚脲涂料
公开(公告)号：US4581433A
公开(公告)日：1986-04-08
申请号：US728124
申请日：1985-04-29
申请人： Terry A. Potter , Peter H. Markusch , David J. Prepelka
发明人： Terry A. Potter , Peter H. Markusch , David J. Prepelka
IPC分类号： C08G18/10 , C08G18/48 , C08G18/75
CPC分类号： C08G18/758 , C08G18/10 , C08G18/4825 , C08G18/4829
摘要： The present invention relates to coating compositions comprising (i) an isocyanate prepolymer based on bis(4-isocyanatocyclohexyl)methane and polyalkylene ether polyols having hydroxyl functionalities of 2 to 3 and (ii) at least one diprimary aromatic diamine having at least one alkyl substituent in an ortho-position to one amino group and two alkyl substituents in both ortho-positions to the other amino group.
摘要翻译：本发明涉及涂料组合物，其包含（i）基于双（4-异氰酸根合环己基）甲烷的异氰酸酯预聚物和羟基官能度为2至3的聚亚烷基醚多元醇和（ii）至少一种具有至少一个烷基取代基的二原子芳族二胺在与另一个氨基的两个邻位的一个氨基和两个烷基取代基的邻位。

2. 发明授权

US4413111A Isocyanate-terminated prepolymers with low free monomer contents 失效
标题翻译：具有低游离单体含量的异氰酸酯封端的预聚物
公开(公告)号：US4413111A
公开(公告)日：1983-11-01
申请号：US426301
申请日：1982-09-29
申请人： Peter H. Markusch , Terry A. Potter
发明人： Peter H. Markusch , Terry A. Potter
IPC分类号： C08G18/00 , C08G18/10 , C08G18/65 , C08G18/75
CPC分类号： C08G18/758 , C08G18/10
摘要： The present invention is directed to a process for the preparation of an isocyanate-terminated prepolymer having a content of unreacted diisocyanate of less than about 2% by weight, preferably less than about 1% by weight, based on the weight of the isocyanate-terminated prepolymer, and containing internal urethane groups based on 4,4'-diisocyanato-dicyclohexyl-methane by(a) preparing an OH-terminated prepolymer from(i) a high molecular weight polyol component, and/or(ii) a low molecular weight isocyanate-reactive component, and(iii) a polyisocyanate component comprising 4,4'-diisocyanato-dicyclohexyl-methane at an NCO/OH equivalent ratio of about 0.5:1 to 0.9:1;(b) forming the isocyanate-terminated prepolymer by reacting the OH-terminated prepolymer with a polyisocyanate other than 4,4'-diisocyanato-dicyclohexyl-methane containing aromatically-, aliphatically- and/or cycloaliphatically-bound isocyanate groups at an NCO:OH equivalent ratio, based on the free -OH groups of component (a), of about 1.6:1 to 15:1, and(c) reducing the amount of unreacted diisocyanate to less than about 2% by weight, based on the weight of the isocyanate-terminated prepolymer.The present invention is also directed to the products prepared by this process and their use in one-component, moisture-cure systems or as the isocyanate component in two-component polyurethanes.
摘要翻译：本发明涉及一种制备异氰酸酯封端的预聚物的方法，所述预聚物的异氰酸酯封端的预聚物的含量基于异氰酸酯封端的重量计小于约2重量％，优选小于约1重量％预聚物，并且通过（a）由（i）高分子量多元醇组分制备OH-封端的预聚物和/或（ii）低分子量的，由4,4'-二异氰酸根合二环己基甲烷形成的内部氨基甲酸酯基团异氰酸酯反应性组分，和（iii）包含NCO / OH当量比为约0.5:1至0.9:1的4,4'-二异氰酸根合二环己基甲烷的多异氰酸酯组分; （b）通过使羟基封端的预聚物与除NCO:OH之间含有芳香，脂族和/或环脂键结合的异氰酸酯基团的4,4'-二异氰酸根合二环己基甲烷以外的多异氰酸酯反应形成异氰酸酯封端的预聚物基于组分（a）的游离-OH基团的当量比为约1.6：1至15：1，和（c）将未反应的二异氰酸酯的量减少至小于约2重量％，基于异氰酸酯封端的预聚物。本发明还涉及通过该方法制备的产品及其在单组分，湿固化体系中的用途或作为双组分聚氨酯中的异氰酸酯组分的用途。

3. 发明授权

US4383070A Storage stable polyurethane compositions 失效
标题翻译：储存稳定的聚氨酯组合物
公开(公告)号：US4383070A
公开(公告)日：1983-05-10
申请号：US382509
申请日：1982-05-27
申请人： Peter H. Markusch , Terry A. Potter , Kenneth P. Yonek , James W. Rosthauser
发明人： Peter H. Markusch , Terry A. Potter , Kenneth P. Yonek , James W. Rosthauser
IPC分类号： C08G18/10 , C08G18/50
CPC分类号： C08G18/5021 , C08G18/10
摘要： The present invention is directed to an organic polyurethane composition having a solids content of about 10 to 100 weight percent which comprises(1) isocyanate-terminated prepolymers which are prepared by reacting reaction products of the phosgenation of aniline-formaldehyde condensates containing specific ratios of isomers and homologues with polyether polyols containing at least two hydroxyl groups and at least one tertiary nitrogen atom and, optionally, an additional polyol which does not contain a tertiary nitrogen atom and optionally,(2) a monoisocyanate comprising a member selected from para-toluenesulfonyl isocyanate and the reaction product of 2,4- or 2,6-toluene diisocyanate or mixtures thereof with specific monoalcohols.The present invention is also directed to the coatings produced from the polyurethane compositions, optionally containing pigments.
摘要翻译：本发明涉及固体含量为约10至100重量％的有机聚氨酯组合物，其包含（1）异氰酸酯封端的预聚物，其通过使含有特定比例异构体的苯胺 - 甲醛缩合物的光气化反应产物和含有至少两个羟基和至少一个叔氮原子的聚醚多元醇的同系物，以及任选地，不含叔氮原子的另外的多元醇，和任选地，（2）包含选自对甲苯磺酰基异氰酸酯的成员的单异氰酸酯以及2,4-或2,6-甲苯二异氰酸酯或其混合物与特定一元醇的反应产物。本发明还涉及由聚氨酯组合物制备的涂层，任选地含有颜料。

4. 发明授权

US6103849A Storage stable, heat curable polyurethane compositions 失效
标题翻译：储存稳定的，可热固化的聚氨酯组合物
公开(公告)号：US6103849A
公开(公告)日：2000-08-15
申请号：US266290
申请日：1994-06-27
申请人： Edward P. Squiller , James W. Rosthauser , Peter H. Markusch , Terry A. Potter
发明人： Edward P. Squiller , James W. Rosthauser , Peter H. Markusch , Terry A. Potter
IPC分类号： C08G18/10 , C09D175/04 , C08G18/80
CPC分类号： C08G18/10 , C09D175/04 , C08G2190/00
摘要： Storage-stable, one-component polyurethane compositions which cure at elevated temperature are made up of (a) an isocyanate which has been blocked with a phenol or an oxime, (b) at least one compound selected from polyketimines, polyenamines and oxazolidines, and (c) a compound which generates water at elevated temperature. Components (a), (b) and (c) are used in amounts such that the equivalent ratio of a:b:c is from about 1.0:0.1:0.5 to about 1:2:2.
摘要翻译：在高温下固化的储存稳定的单组分聚氨酯组合物由以下物质组成：（a）已用苯酚或肟封端的异氰酸酯，（b）至少一种选自聚酮亚胺，多烯胺和恶唑烷的化合物，以及（c）在高温下产生水的化合物。组分（a），（b）和（c）的用量使得a:b:c的当量比为约1.0:0.1:0.5至约1:2:2。

5. 发明授权

US5389718A Two-component aqueous polyurethane dispersions 失效
标题翻译：双组分水性聚氨酯分散体
公开(公告)号：US5389718A
公开(公告)日：1995-02-14
申请号：US249486
申请日：1994-05-26
申请人： Terry A. Potter , Patricia B. Jacobs , Peter H. Markusch , James W. Rosthauser
发明人： Terry A. Potter , Patricia B. Jacobs , Peter H. Markusch , James W. Rosthauser
IPC分类号： C08G18/08 , C08G18/10 , C08G18/28 , C08G18/50 , C08G18/79 , C08L75/04
CPC分类号： C08G18/792 , C08G18/0819 , C08G18/10 , C08G18/283 , C08G18/5042 , Y10S524/906
摘要： The present invention relates to a two-component, aqueous polyurethane coating composition which may be cured at ambient temperature and which containsI) a first component based on an aqueously dispersed polyurethane wherein the polyurethane hasa) an average hydroxy functionality of at least 1.8b) a total content of urethane and urea groups, calculated as --NH--C--O--, of 9 to 20% by weight, based on the weight of the polyurethane, andc) sufficient chemically incorporated anionic groups andd) ethylene oxide units incorporated within terminal and/or lateral polyether chainsto maintain the polyurethane stably dispersed in water, andII) a second component based on a water dispersible polyisocyanate wherein the polyisocyanate hasa) an isocyanate content of 2 to 30% by weight, based on the weight of the polyisocyanate,b) an average functionality of at least 1.8 andc) sufficient chemically incorporated anionic groups andd) ethylene oxide units incorporated within terminal and/or lateral polyether chainsto maintain the polyisocyanate stably dispersed in water, and components I and II are present in an amount sufficient to provide an equivalent ratio of isocyanate groups to hydroxyl groups of 0.8:1 to 6:1.The present invention is also directed to the coatings prepared from these coating compositions.
摘要翻译：本发明涉及双组分水性聚氨酯涂料组合物，其可以在环境温度下固化，并且其包含I）基于高分散聚氨酯的第一组分，其中所述聚氨酯具有a）至少1.8b的平均羟基官能度）基于聚氨酯的重量计，氨基甲酸酯和尿素基团的总含量（以-NH-CO-计算）为9至20重量％，以及c）足够的化学引入的阴离子基团和d）掺入到其中的环氧乙烷单元末端和/或侧面聚醚链以保持聚氨酯稳定地分散在水中，和II）基于水分散性多异氰酸酯的第二组分，其中多异氰酸酯的a）异氰酸酯含量为2-30重量％，基于多异氰酸酯，b）至少1.8的平均官能度，和c）足够化学引入的阴离子基团，和d）结合在末端和/或之后的环氧乙烷单元以保持多异氰酸酯稳定地分散在水中，并且组分I和II以足以提供异氰酸酯基与羟基的当量比为0.8:1至6:1的量存在。本发明还涉及由这些涂料组合物制备的涂料。

6. 发明授权

US06364925B1 Polyurethane encapsulated fertilizer having improved slow-release properties 失效
标题翻译：具有改善缓释性能的聚氨酯包封肥料
公开(公告)号：US06364925B1
公开(公告)日：2002-04-02
申请号：US09458818
申请日：1999-12-10
申请人： Peter H. Markusch , Robert L. Cline , Ashok M. Sarpeshkar , Robert P. Yeater
发明人： Peter H. Markusch , Robert L. Cline , Ashok M. Sarpeshkar , Robert P. Yeater
IPC分类号： C05G500
CPC分类号： C09D175/04 , C08G18/4891 , C08G18/6696
摘要： The present invention relates to polyurethane encapsulated fertilizer particles which exhibit slow-release properties and to a process for their production. The process comprises applying an isocyanate-reactive component to fertilizer particles, to form fertilizer particles coated with an isocyanate-reactive component, applying a polyisocyanate component onto the coated fertilizer particles to form polyurethane encapsulated fertilizer particles, and, optionally, repeating these steps as many times as necessary to form the polyurethane encapsulated fertilizer particles that contain about 2 to 20% by weight of polyurethane, based on the total weight of the encapsulated fertilizer particles. Suitable isocyanate-reactive components include polyesterether polyols that comprise either a blend of or the reaction product of (i) castor oil having an OH number of about 160 to about 170, a viscosity of about 500 to about 900 mPa.s at 25° C., and a water content of less than 0.5% by weight; and (ii) a polyether polyol having an OH number of from 28 to 700, a functionality of from 3 to 8, and a molecular weight of about 240 to about 6,000, and a viscosity of from about 50 to 35,000 mPa.s at 25° C. The polyether polyol must be prepared from a suitable initiator compound and an alkylene oxide comprising at least 70% by weight of propylene oxide.
摘要翻译：本发明涉及具有缓释特性的聚氨酯包封肥料颗粒及其生产方法。该方法包括将异氰酸酯反应性组分施用于肥料颗粒，以形成涂覆有异氰酸酯反应性组分的肥料颗粒，将多异氰酸酯组分施加到涂覆的肥料颗粒上以形成聚氨酯包封的肥料颗粒，以及任选地重复这些步骤以形成包含约2至20重量％的聚氨酯的聚氨酯包封的肥料颗粒，基于包封的肥料颗粒的总重量。合适的异氰酸酯反应性组分包括聚异戊二烯多元醇，其包含（i）OH值为约160至约170的蓖麻油，25℃下约500至约900mPa.s的粘度的混合物或其反应产物含水量小于0.5重量％; 和（ii）OH值为28至700，官能度为3至8，分子量为约240至约6,000，粘度为约50至35,000mPa.s在25的聚醚多元醇聚醚多元醇必须由合适的引发剂化合物和包含至少70重量％环氧丙烷的烯化氧制备。

7. 发明授权

US06358296B1 Slow-release polyurethane encapsulated fertilizer using oleo polyols 失效
标题翻译：使用油脂多元醇缓释聚氨酯包封肥料
公开(公告)号：US06358296B1
公开(公告)日：2002-03-19
申请号：US09613680
申请日：2000-07-11
申请人： Peter H. Markusch , Robert L. Cline , Ashok M. Sarpeshkar
发明人： Peter H. Markusch , Robert L. Cline , Ashok M. Sarpeshkar
IPC分类号： C05G500
CPC分类号： C08G18/36 , C05G3/0029 , C08G18/7664
摘要： This invention relates to polyurethane encapsulated fertilizer particles which exhibit slow-release properties and to a process for their production. The process comprises (1) applying an isocyanate-reactive component or a polyisocyanate component to fertilizer particles, to form coated fertilizer particles, followed by (2) applying a polyisocyanate component or an isocyanate-reactive component onto the coated fertilizer particles to form polyurethane encapsulated fertilizer particles, and, optionally, repeating these steps as many times as necessary to form the polyurethane encapsulated fertilizer particles that contain about 2 to 20% by weight of polyurethane, based on the total weight of the encapsulated fertilizer particles. Alternatively, the isocyanate-reactive component and the polyisocyanate component can be premixed prior to being applied to the fertilizer particles to form polyurethane encapsulated fertilizer particles. Suitable isocyanate-reactive components comprise oleo polyols.
摘要翻译：本发明涉及具有缓释特性的聚氨酯包封的肥料颗粒及其生产方法。该方法包括（1）将异氰酸酯反应性组分或多异氰酸酯组分施用于肥料颗粒，以形成包覆的肥料颗粒，随后将（2）将多异氰酸酯组分或异氰酸酯反应性组分施加到涂覆的肥料颗粒上以形成聚氨酯包封肥料颗粒，并且任选地重复这些步骤，以根据包封的肥料颗粒的总重量形成含有约2至20重量％聚氨酯的聚氨酯包封的肥料颗粒。或者，异氰酸酯反应性组分和多异氰酸酯组分可以在施用于肥料颗粒之前预混合以形成聚氨酯包封的肥料颗粒。合适的异氰酸酯反应性组分包括油醇多元醇。

8. 发明授权

US6165550A Symmetrical Polyurea-urethane fertilizer encapsulation 失效
标题翻译：对称聚脲 - 氨酯肥料包封
公开(公告)号：US6165550A
公开(公告)日：2000-12-26
申请号：US121482
申请日：1998-07-23
申请人： Peter H. Markusch , James W. Rosthauser
发明人： Peter H. Markusch , James W. Rosthauser
IPC分类号： C05G3/00 , C08G18/32 , C08G18/76 , C08G18/80 , B05D7/00
CPC分类号： C05G3/0029 , C08G18/3275 , C08G18/7664 , C08G18/8019 , C08G2310/00
摘要： This invention relates to processes for the production of symmetrical polyurea-urethane coated granular fertilizer products, and to the symmetrical polyurea-urethane coated granular fertilizer products produced by these processes. These processes comprise coating fertilizer granules with compounds which react to form urethane coatings which contain terminal isocyanate groups, followed by polymerization of these urethanes to form symmetrical polyurea-urethanes. Suitable compounds comprise a) an organic polyisocyanate component, and b) an alkanolamine component containing at least one tertiary amine group and at least one hydroxyl group. These compounds are present in sufficient quantities that the molar ratio of isocyanate groups to isocyanate-reactive groups is from about 1.6:1.0 up to about 10.0:1.0 in each encapsulating layer. It is necessary that sufficient amounts of these compounds are applied to the fertilizer granules such that the symmetrical polyurea-urethane coated granular fertilizer particles contain from about 0.5 to about 15% by weight of polyurea-urethane, based on the total weight of the encapsulated fertilizer particles.
摘要翻译：本发明涉及用于生产对称聚脲 - 氨基甲酸酯涂覆的颗粒肥料产品的方法以及由这些方法生产的对称聚脲 - 氨基甲酸酯涂覆的颗粒肥料产品。这些方法包括用化合物涂覆化合物颗粒，所述化合物反应形成含有末端异氰酸酯基团的氨基甲酸酯涂料，随后聚合这些聚氨酯以形成对称的聚脲 - 氨基甲酸酯。合适的化合物包括a）有机多异氰酸酯组分，和b）含有至少一个叔胺基团和至少一个羟基的链烷醇胺组分。这些化合物以足够的量存在，每个包封层中异氰酸酯基与异氰酸酯反应性基团的摩尔比为约1.6:1.0至约10.0:1.0。需要将足够量的这些化合物施加到肥料颗粒上，使得对称的聚脲 - 氨基甲酸酯涂覆的颗粒肥料颗粒含有约0.5至约15重量％的聚脲 - 氨基甲酸酯，基于包封的肥料的总重量粒子。

9. 发明授权

US6152981A Sulfur containing isocyanate compositions 有权
标题翻译：含硫异氰酸酯组合物
公开(公告)号：US6152981A
公开(公告)日：2000-11-28
申请号：US255285
申请日：1999-02-22
申请人： Peter H. Markusch , Donald MacNaughtan, Jr. , William G. Crabtree , Robert L. Cline
发明人： Peter H. Markusch , Donald MacNaughtan, Jr. , William G. Crabtree , Robert L. Cline
IPC分类号： C05G3/00 , C08G18/32 , C08G18/76 , C08K3/06 , A01N25/00 , A01N27/00 , A01N31/00
CPC分类号： C05G3/0023 , C05G3/0029 , C08G18/3206 , C08G18/7664 , C08K3/06 , C08G2230/00
摘要： This invention relates to an isocyanate composition comprising a) at least one isocyanate and b) from 1 to 50% by weight, based on the total weight of component a), of sulfur. These isocyanate compositions are suitable for the preparation of polyurethane/polyurea encapsulated fertilizers. Accordingly, the present invention also relates to an improved process for the production of a polyurea/polyurethane encapsulated fertilizer comprising applying at least one isocyanate-reactive component to the fertilizer particles and applying the isocyanate compositions of the present invention to the fertilizer particles, to form these polyurea/polyurethane encapsulated fertilizers.
摘要翻译：本发明涉及异氰酸酯组合物，其包含a）至少一种异氰酸酯和b）基于组分a）的总重量为1至50重量％的硫。这些异氰酸酯组合物适用于制备聚氨酯/聚脲包封肥料。因此，本发明还涉及用于生产聚脲/聚氨酯包封的肥料的改进方法，包括将至少一种异氰酸酯反应性组分施用于肥料颗粒并将本发明的异氰酸酯组合物施用于肥料颗粒，以形成这些聚脲/聚氨酯包封肥料。

10. 发明授权

US6022444A Modified PMDI for faster press times or lower press temperatures and reduction of MDI from hot presses 失效
标题翻译：改进的PMDI可以更快的压制时间或降低印刷温度，并减少热压机的MDI
公开(公告)号：US6022444A
公开(公告)日：2000-02-08
申请号：US225036
申请日：1994-04-08
申请人： Karl W. Haider , John W. Frink , Heber D. Layton , Peter H. Markusch , James W. Rosthauser , Bonnie L. Lawson , Michael A. Joseph
发明人： Karl W. Haider , John W. Frink , Heber D. Layton , Peter H. Markusch , James W. Rosthauser , Bonnie L. Lawson , Michael A. Joseph
IPC分类号： C08G18/10 , C08G18/76 , C08G18/80 , C08L97/02 , C09J175/04 , C07C271/28 , C08G18/50 , C09J175/08
CPC分类号： C08G18/8019 , C08G18/10 , C08G18/7664 , C08L97/02 , Y10S528/905
摘要： Isocyanate prepolymers which are useful as binders are made from a polyisocyanate mixture and a hydroxyl compound having at least about 1 hydroxyl group. The polyisocyanate mixture is made up of from about 50 to about 60% by weight of polyphenyl polymethylene polyisocyanate and from about 40 to about 50% by weight of an isomeric mixture of diphenylmethane diisocyanate (MDI). The isomeric mixture of MDI is made up of from about 4 to about 30% by weight of the 2,4'-isomer and from about 70 to about 96% by weight of the 4,4'-isomer. The binders of the present invention are advantageous in that they may be used in high moisture, low temperature conditions without a catalyst. Reduced MDI emissions are also achieved when the binders of the present invention are used to make composite materials.
摘要翻译：可用作粘合剂的异氰酸酯预聚物由多异氰酸酯混合物和具有至少约1个羟基的羟基化合物制成。多异氰酸酯混合物由约50至约60重量％的聚苯基多亚甲基多异氰酸酯和约40至约50重量％的二苯基甲烷二异氰酸酯（MDI）的异构体混合物组成。 MDI的异构体混合物由约4至约30重量％的2,4'-异构体和约70至约96重量％的4,4'-异构体组成。本发明的粘合剂的优点在于它们可以在没有催化剂的情况下在高水分，低温条件下使用。当本发明的粘合剂用于制造复合材料时，也可实现减少的MDI排放。

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