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1. 发明授权

US6165550A Symmetrical Polyurea-urethane fertilizer encapsulation 失效
标题翻译：对称聚脲 - 氨酯肥料包封
公开(公告)号：US6165550A
公开(公告)日：2000-12-26
申请号：US121482
申请日：1998-07-23
申请人： Peter H. Markusch , James W. Rosthauser
发明人： Peter H. Markusch , James W. Rosthauser
IPC分类号： C05G3/00 , C08G18/32 , C08G18/76 , C08G18/80 , B05D7/00
CPC分类号： C05G3/0029 , C08G18/3275 , C08G18/7664 , C08G18/8019 , C08G2310/00
摘要： This invention relates to processes for the production of symmetrical polyurea-urethane coated granular fertilizer products, and to the symmetrical polyurea-urethane coated granular fertilizer products produced by these processes. These processes comprise coating fertilizer granules with compounds which react to form urethane coatings which contain terminal isocyanate groups, followed by polymerization of these urethanes to form symmetrical polyurea-urethanes. Suitable compounds comprise a) an organic polyisocyanate component, and b) an alkanolamine component containing at least one tertiary amine group and at least one hydroxyl group. These compounds are present in sufficient quantities that the molar ratio of isocyanate groups to isocyanate-reactive groups is from about 1.6:1.0 up to about 10.0:1.0 in each encapsulating layer. It is necessary that sufficient amounts of these compounds are applied to the fertilizer granules such that the symmetrical polyurea-urethane coated granular fertilizer particles contain from about 0.5 to about 15% by weight of polyurea-urethane, based on the total weight of the encapsulated fertilizer particles.
摘要翻译：本发明涉及用于生产对称聚脲 - 氨基甲酸酯涂覆的颗粒肥料产品的方法以及由这些方法生产的对称聚脲 - 氨基甲酸酯涂覆的颗粒肥料产品。这些方法包括用化合物涂覆化合物颗粒，所述化合物反应形成含有末端异氰酸酯基团的氨基甲酸酯涂料，随后聚合这些聚氨酯以形成对称的聚脲 - 氨基甲酸酯。合适的化合物包括a）有机多异氰酸酯组分，和b）含有至少一个叔胺基团和至少一个羟基的链烷醇胺组分。这些化合物以足够的量存在，每个包封层中异氰酸酯基与异氰酸酯反应性基团的摩尔比为约1.6:1.0至约10.0:1.0。需要将足够量的这些化合物施加到肥料颗粒上，使得对称的聚脲 - 氨基甲酸酯涂覆的颗粒肥料颗粒含有约0.5至约15重量％的聚脲 - 氨基甲酸酯，基于包封的肥料的总重量粒子。

2. 发明授权

US6022444A Modified PMDI for faster press times or lower press temperatures and reduction of MDI from hot presses 失效
标题翻译：改进的PMDI可以更快的压制时间或降低印刷温度，并减少热压机的MDI
公开(公告)号：US6022444A
公开(公告)日：2000-02-08
申请号：US225036
申请日：1994-04-08
申请人： Karl W. Haider , John W. Frink , Heber D. Layton , Peter H. Markusch , James W. Rosthauser , Bonnie L. Lawson , Michael A. Joseph
发明人： Karl W. Haider , John W. Frink , Heber D. Layton , Peter H. Markusch , James W. Rosthauser , Bonnie L. Lawson , Michael A. Joseph
IPC分类号： C08G18/10 , C08G18/76 , C08G18/80 , C08L97/02 , C09J175/04 , C07C271/28 , C08G18/50 , C09J175/08
CPC分类号： C08G18/8019 , C08G18/10 , C08G18/7664 , C08L97/02 , Y10S528/905
摘要： Isocyanate prepolymers which are useful as binders are made from a polyisocyanate mixture and a hydroxyl compound having at least about 1 hydroxyl group. The polyisocyanate mixture is made up of from about 50 to about 60% by weight of polyphenyl polymethylene polyisocyanate and from about 40 to about 50% by weight of an isomeric mixture of diphenylmethane diisocyanate (MDI). The isomeric mixture of MDI is made up of from about 4 to about 30% by weight of the 2,4'-isomer and from about 70 to about 96% by weight of the 4,4'-isomer. The binders of the present invention are advantageous in that they may be used in high moisture, low temperature conditions without a catalyst. Reduced MDI emissions are also achieved when the binders of the present invention are used to make composite materials.
摘要翻译：可用作粘合剂的异氰酸酯预聚物由多异氰酸酯混合物和具有至少约1个羟基的羟基化合物制成。多异氰酸酯混合物由约50至约60重量％的聚苯基多亚甲基多异氰酸酯和约40至约50重量％的二苯基甲烷二异氰酸酯（MDI）的异构体混合物组成。 MDI的异构体混合物由约4至约30重量％的2,4'-异构体和约70至约96重量％的4,4'-异构体组成。本发明的粘合剂的优点在于它们可以在没有催化剂的情况下在高水分，低温条件下使用。当本发明的粘合剂用于制造复合材料时，也可实现减少的MDI排放。

3. 发明授权

US5372875A Aqueous two-component polyurethane-forming compositions and a process for their preparation 失效
标题翻译：水性双组分聚氨酯形成组合物及其制备方法
公开(公告)号：US5372875A
公开(公告)日：1994-12-13
申请号：US14304
申请日：1993-02-05
申请人： Peter H. Markusch , Robin E. Tirpak , James W. Rosthauser
发明人： Peter H. Markusch , Robin E. Tirpak , James W. Rosthauser
IPC分类号： C08K7/14 , B32B27/40 , C08K3/20
CPC分类号： C08K7/14 , Y10T428/31551 , Y10T428/31601 , Y10T442/2992
摘要： The present invention is directed to a process for the preparation of an aqueous two-component polyurethane-forming composition bya) dispersing in water a polyisocyanate which has an isocyanate content of at least 12% by weight andb) also blending with water either before, during or after dispersing the polyisocyanate, a polyhydroxyl compound whichi) has a molecular weight of 62 to 10,000,ii) contains at least two hydroxyl groups,iii) is water soluble or water dispersible,iv) does not contain urea or urethane groups andv) is selected from the group of polyesters, polylactones, polycarbonates, polyethers, polythioethers, polyacetals, polyether esters, polyester amides and polyamides,wherein the equivalent ratio of isocyanate groups to aqueous groups is 0.8:1 to 6:1.The present invention is also directed to the aqueous composition prepared by this process and to its use as a binder for fiberglass.
摘要翻译：本发明涉及一种制备水性双组分聚氨酯形成组合物的方法，该方法是：a）在水中分散异氰酸酯含量为至少12重量％的多异氰酸酯，和b）还可以在水之前与水混合在分散多异氰酸酯之间或之后，分子量为62至10,000的多羟基化合物，ii）至少包含两个羟基，iii）是水溶性的或水分散的，iv）不含脲或氨基甲酸酯基团和v）选自聚酯，聚内酯，聚碳酸酯，聚醚，聚硫醚，聚缩醛，聚醚酯，聚酯酰胺和聚酰胺，其中异氰酸酯基与水基的当量比为0.8:1至6:1。本发明还涉及通过该方法制备的水性组合物及其作为玻璃纤维的粘合剂的用途。

4. 发明授权

US5154950A Rapid curing, light stable, two-component polyurethane coating compositions 失效
标题翻译：快速固化，光稳定，双组分聚氨酯涂料组合物
公开(公告)号：US5154950A
公开(公告)日：1992-10-13
申请号：US447331
申请日：1989-12-07
申请人： James W. Rosthauser , Edward P. Squiller , Peter H. Markusch
发明人： James W. Rosthauser , Edward P. Squiller , Peter H. Markusch
IPC分类号： C08G18/08 , C08G18/18
CPC分类号： C08G18/089 , C08G18/1891 , C08G2150/50
摘要： The present invention is directed to a process for the preparation of a polyurethane coating by a) preparing a coating composition having an improved potlife fromi) a compound containing at least two hydroxyl groups,ii) a polyisocyanate containing aliphatically-, cycloaliphatically- or araliphatically-bound isocyanate groups,iii) about 0.005 to 2.0 to weight percent, based on the weight of components i) and ii), of a tine catalyst andiv) at least about 50 mole percent, based on the tin catalyst, of hydrogen chloride,b) applying the coating composition to a substrate andc) curing the coating composition, optionally in the presence of an amine vapor, to form the polyurethane coating.
摘要翻译：本发明涉及一种制备聚氨酯涂层的方法，该方法是：a）制备具有改善的适用期的涂料组合物，其含有i）含有至少两个羟基的化合物，ii）含有脂族，脂环或芳烃的多异氰酸酯异氰酸酯基团，iii）基于催化剂组分i）和ii）的重量，约0.005至2.0重量％，和iv）基于锡催化剂的至少约50摩尔％的氯化氢 b）将涂料组合物施用到基材上，以及c）任选地在胺蒸气的存在下固化涂料组合物以形成聚氨酯涂层。

5. 发明授权

US6040028A Removable polyurethane adhesives with improved temperature resistance properties 失效
标题翻译：具有改善耐温性能的可拆卸聚氨酯胶粘剂
公开(公告)号：US6040028A
公开(公告)日：2000-03-21
申请号：US6129
申请日：1998-01-13
申请人： Robert L. Cline , James W. Rosthauser , Peter H. Markusch
发明人： Robert L. Cline , James W. Rosthauser , Peter H. Markusch
IPC分类号： C08G18/48 , C08G18/75 , C08L75/08 , C09J7/02 , C09J175/08
CPC分类号： C09J175/08 , C08G18/4812 , C08G18/758 , C09J7/0207 , C08G2170/40 , C08L75/08 , C09J2475/00 , Y02P20/582 , Y10T428/1476 , Y10T428/28 , Y10T428/2896
摘要： The present invention relates to highly elastic polyurethane contact adhesives, a process to coat substrates with these contact adhesives, and the coated substrates produced by this process. This invention requires a) a polyisocyanate with a functionality of less than about 4 and b) a polyol blend comprising 1) about 90 to 100% polyethers with molecular weights from about 1,800 to 12,000 and average functionality from about 1.5 to about 4, and 2) up to about 10% of chain extenders with molecular weights from about 60 to 400 and average functionality from about 1.5 to about 3. The functionalities and amounts of components a) and b) are such that the molecular weight between crosslinks is from about 7,000 to about 16,000 and the equivalent ratio of isocyanate groups to isocyanate-reactive groups is from about 80:100 to about 120:100 and the urethane group content is from about 1 to about 8%. It is preferred that at least one of components a) and b) have a functionality of greater than about 2.2.
摘要翻译：本发明涉及高弹性聚氨酯接触粘合剂，用这些接触粘合剂涂覆基材的方法以及通过该方法生产的涂布基材。本发明要求a）具有小于约4的官能度的多异氰酸酯和b）多元醇共混物，其包含1）约90至100％分子量为约1,800至12,000的聚醚，平均官能度为约1.5至约4，和2 ）至多约10％的分子量为约60至400且平均官能度为约1.5至约3的扩链剂。组分a）和b）的官能度和量使得交联之间的分子量为约7,000 至约16,000，异氰酸酯基与异氰酸酯反应性基团的当量比为约80:100至约120：100，氨基甲酸酯基含量为约1至约8％。组分a）和b）中的至少一种优选具有大于约2.2的官能度。

6. 发明授权

US4788262A Polyisocyanate blends with improved compatibility with coreactants 失效
标题翻译：聚异氰酸酯共混物与共反应物的相容性提高
公开(公告)号：US4788262A
公开(公告)日：1988-11-29
申请号：US938909
申请日：1986-12-08
申请人： Peter H. Markusch , James W. Rosthauser , Michael C. Beatty
发明人： Peter H. Markusch , James W. Rosthauser , Michael C. Beatty
IPC分类号： C08G18/42 , C08G18/72 , C08G18/78 , C08G18/79
CPC分类号： C08G18/792 , C08G18/4208 , C08G18/725 , C08G18/7831 , Y10S524/901
摘要： The present invention is directed to polyisocyanates which have improved compatibility with polyester coreactants and improved solubility in apolar solvents, the polyisocyanates containing, based on solids,(a) about 15 to 85 wt. % of an isocyanurate group-containing polyisocyanate based on hexamethylene diisocynate and(b) about 15 to 85 wt. % of a biuret group-containing polyisocyanate based on hexamethylene diisocyanate.The present invention is additionally directed to two-component polyurethane coating compositions based on the above polyisocyanates and branched polyester polyols. Finally, the present invention is directed to a process for preparing the polyisocyanate.
摘要翻译：本发明涉及具有改善的与聚酯共反应物的相容性和改善在非极性溶剂中的溶解度的多异氰酸酯，多异氰酸酯基于固体含有（a）约15至85wt。％的基于六亚甲基二异氰酸酯的含异氰脲酸酯基的多异氰酸酯和（b）约15至85重量％％的基于六亚甲基二异氰酸酯的含缩二脲基团的多异氰酸酯。本发明另外涉及基于上述多异氰酸酯和支链聚酯多元醇的双组分聚氨酯涂料组合物。最后，本发明涉及一种制备多异氰酸酯的方法。

7. 发明授权

US4501852A Stable, aqueous dispersions of polyurethane-ureas 失效
标题翻译：稳定的聚氨酯 - 脲类水性分散体
公开(公告)号：US4501852A
公开(公告)日：1985-02-26
申请号：US505600
申请日：1983-06-20
申请人： Peter H. Markusch , James W. Rosthauser , Michael C. Beatty
发明人： Peter H. Markusch , James W. Rosthauser , Michael C. Beatty
IPC分类号： C08G18/00 , C08G18/08 , C08G18/10 , C08G18/12 , C08G18/28 , C08G18/44 , C08G18/50 , C08G18/72 , C08G18/78 , C08G18/80 , C08G18/84 , C09D175/00 , C09D175/04 , C08L75/12
CPC分类号： C08G18/84 , C08G18/0819 , C08G18/10 , C08G18/12 , C08G18/2805 , C08G18/5042 , C08G18/721 , C08G18/7818 , C08G18/8064
摘要： The present invention relates to a stable, aqueous dispersion of polyurethane-ureas wherein said polyurethane-ureas contain(i) about 10 to 120 milliequivalents per 100 grams of polyurethane-urea of chemically incorporated anionic groups, and(ii) up to about 10% by weight, based on the weight of the polyurethane-urea, of lateral and/or terminal hydrophilic chains containing ethylene oxide units,wherein the counterions of the anionic groups are a mixture of volatile and non-volatile cations in an equivalent ratio of about 1:4 to 4:1.The present invention is also directed to the coatings and films prepared from these dispersions.
摘要翻译：本发明涉及一种稳定的聚氨酯 - 脲的水分散体，其中所述聚氨酯 - 脲包含（i）每100克化学掺入的阴离子基团的聚氨酯 - 尿素约10至120毫当量，和（ii）至多约10％重量，基于聚氨酯 - 脲的重量，含有环氧乙烷单元的侧面和/或末端亲水链，其中阴离子基团的抗衡离子是挥发性和非挥发性阳离子的混合物，其当量比为约1 ：4到4：1。本发明还涉及由这些分散体制备的涂料和薄膜。

8. 发明授权

US6001147A Unsymmetrical polyureaurethane fertilizer encapsulation 失效
标题翻译：不对称聚脲氨酯肥料封装
公开(公告)号：US6001147A
公开(公告)日：1999-12-14
申请号：US121376
申请日：1998-07-23
申请人： Peter H. Markusch , James W. Rosthauser
发明人： Peter H. Markusch , James W. Rosthauser
IPC分类号： C05G3/00 , C08G18/32 , C09D175/00 , C05G5/00
CPC分类号： C09D175/00 , C05G3/0029 , C08G18/3271 , C08G18/3275
摘要： This invention relates to processes for the production of unsymmetrical polyurea-urethane coated granular fertilizer products, and to the unsymmetrical polyurea-urethane coated granular fertilizer products produced by these processes. These processes comprise coating fertilizer granules with compounds which react to form unsymmetrical polyurea-urethane coatings, then the compounds are polymerized. Suitable compounds comprise a) an organic polyisocyanate component, and b) an alkanolamine component containing at least one primary or secondary amine group and at least one hydroxyl group. These compounds are present in sufficient quantities that the NCO to active hydrogen group is from about 0.5:1.0 up to about 1.5:1.0. It is necessary that sufficient amounts of these compounds are applied to the fertilizer granules such that the unsymmetrical polyurea-urethane coated granular fertilizer particles contain from about 0.5 to about 15% by weight of polyurea-urethane, based on the total weight of the encapsulated fertilizer particles.
摘要翻译：本发明涉及生产不对称聚脲 - 氨基甲酸酯涂覆的颗粒肥料产品的方法以及由这些方法生产的不对称聚脲 - 氨基甲酸酯涂覆的颗粒肥料产品。这些方法包括用化合物包覆肥料颗粒，反应形成不对称的聚脲 - 氨基甲酸酯涂层，然后化合物聚合。合适的化合物包括a）有机多异氰酸酯组分，和b）含有至少一个伯或仲胺基和至少一个羟基的链烷醇胺组分。这些化合物以足够的量存在，使活性氢基团的NCO为约0.5:1.0至约1.5:1.0。需要将足量的这些化合物施加到肥料颗粒上，使得不对称聚脲 - 氨基甲酸酯涂覆的颗粒肥料颗粒含有约0.5至约15重量％的聚脲 - 氨基甲酸酯，基于包封肥料的总重量粒子。

9. 发明授权

US5733966A Polyurethane contact adhesives with improved temperature resistance properties 失效
标题翻译：具有改善耐温性能的聚氨酯接触粘合剂
公开(公告)号：US5733966A
公开(公告)日：1998-03-31
申请号：US787066
申请日：1997-01-22
申请人： Robert L. Cline , James W. Rosthauser , Peter H. Markusch
发明人： Robert L. Cline , James W. Rosthauser , Peter H. Markusch
IPC分类号： C08G18/48 , C08G18/72 , C09J175/08 , C08J3/00 , C08G18/00 , C08K3/20 , C08L75/00
CPC分类号： C08G18/725 , C08G18/4812 , C09J175/08 , C08G2170/40 , Y02P20/582
摘要： The present invention relates to highly elastic polyurethane contact adhesives, a process to coat substrates with these contact adhesives, and the coated substrates produced by this process. This invention requires a) a polyisocyanate with a functionality of less than about 4 and b) a polyol blend comprising 1) about 90 to 100% polyethers with molecular weights from about 1,800 to 12,000 and average functionality from about 1.5 to about 4, and 2) up to about 10% of chain extenders with molecular weights from about 60 to 400 and average functionality from about 1.5 to about 3. The functionalities and amounts of components a) and b) are such that the molecular weight between crosslinks is from about 7,000 to about 16,000 and the equivalent ratio of isocyanate groups to isocyanate-reactive groups is from about 80:100 to about 120:100 and the urethane group content is from about 1 to about 8%. It is preferred that at least one of components a) and b) have a functionality of greater than about 2.2.
摘要翻译：本发明涉及高弹性聚氨酯接触粘合剂，用这些接触粘合剂涂覆基材的方法以及通过该方法生产的涂布基材。本发明要求a）具有小于约4的官能度的多异氰酸酯和b）多元醇共混物，其包含1）约90至100％分子量为约1,800至12,000的聚醚，平均官能度为约1.5至约4，和2 ）至多约10％的分子量为约60至400且平均官能度为约1.5至约3的扩链剂。组分a）和b）的官能度和量使得交联之间的分子量为约7,000 至约16,000，异氰酸酯基与异氰酸酯反应性基团的当量比为约80:100至约120：100，氨基甲酸酯基含量为约1至约8％。组分a）和b）中的至少一种优选具有大于约2.2的官能度。

10. 发明授权

US4826894A Aqueous polyurethane-ureas dispersions and their use for the production of coatings having improved humidity resistance 失效
标题翻译：水性聚氨酯 - 脲分散体及其用于生产具有改善的耐湿性的涂料的用途
公开(公告)号：US4826894A
公开(公告)日：1989-05-02
申请号：US52093
申请日：1987-05-19
申请人： Peter H. Markusch , James W. Rosthauser
发明人： Peter H. Markusch , James W. Rosthauser
IPC分类号： C08G18/58 , C08G18/08 , C08G18/10 , C08G18/70 , C08G18/72 , C09D175/00 , C09D175/04 , C08L63/00 , C08L75/12
CPC分类号： C08G18/10 , C08G18/0819 , C09D175/04
摘要： The present invention is directed to stable, aqueous dispersions of polyurethane-ureas which are formed by dispersing a blend of anionically modified isocyanate terminated prepolymer and epoxy resin in water and chain extending said dispersed blend with a polyamine having an average functionality of about 2.0 to 6.0 in an amount sufficient to provide a ratio of amino groups to isocyanate groups of about 0.6:1.0 to 1.0:1.0.The present invention is also directed to the use of the aqueous polyurethane-urea dispersions for the production of coated substrates having improved humidity resistance.

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