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    • 3. 发明授权
    • Optical semiconductor sealing material
    • 光学半导体密封材料
    • US08648160B2
    • 2014-02-11
    • US13587250
    • 2012-08-16
    • Tomoaki TakebeTsuyoshi OtaYutaka ObataHiroyuki Higuchi
    • Tomoaki TakebeTsuyoshi OtaYutaka ObataHiroyuki Higuchi
    • C08F220/10C08F220/28
    • C08F220/10C08F220/18C08F220/28C09J133/14H01L31/0203
    • The present invention provides an optical semiconductor sealing material comprising a radically polymerized polymer of a methacrylate ester having an alicyclic hydrocarbon group containing 7 or more carbon atoms, e.g. an adamantyl group, a norbornyl group, or a dicyclopentanyl group; and an optical semiconductor sealing material comprising a radically polymerized polymer of 50 to 97 mass % of the methacrylate ester and 3 to 50 mass % of acrylate ester having a hydroxyl group. The optical semiconductor sealing material of the present invention is highly transparent and stable to UV light and thus does not undergo yellowing. In addition, the material exhibits excellent compatibility between heat resistance and refractive index, does not undergo deformation or cracking during heating processes such as reflow soldering, and shows high processability. The material can be preferably used as a sealing material for light-emitting elements and light-receiving elements of optical semiconductor devices (semiconductor light-emitting devices).
    • 本发明提供一种光学半导体密封材料,其包含具有含有7个或更多个碳原子的脂环族烃基的甲基丙烯酸酯的自由基聚合的聚合物, 金刚烷基,降冰片基或二环戊基; 以及包含50〜97质量%的甲基丙烯酸酯的自由基聚合物和3〜50质量%的具有羟基的丙烯酸酯的光学半导体密封材料。 本发明的光半导体密封材料高度透明,对紫外光稳定,因此不会发黄。 此外,该材料在耐热性和折射率之间表现出优异的相容性,在诸如回流焊接的加热过程中不会发生变形或开裂,并且显示出高加工性。 该材料可以优选用作光半导体器件(半导体发光器件)的发光元件和光接收元件的密封材料。
    • 6. 发明授权
    • Propylene/ethylene block copolymer
    • 丙烯/乙烯嵌段共聚物
    • US06201090B1
    • 2001-03-13
    • US09463983
    • 2000-02-16
    • Takashi SumitomoSueto MiyazakiTsuyoshi OtaKazuo Sato
    • Takashi SumitomoSueto MiyazakiTsuyoshi OtaKazuo Sato
    • C08F21000
    • C08F297/083
    • Provided are propylene-ethylene block copolymers having the advantage of well-balanced physical properties of rigidity, impact resistance, etc. The propylene-ethylene block copolymers are characterized by (a), (b), (c1), (c2) and (c3): (a) The melt flow rate falls between 0.01 and 1000 g/10 min. (b) The room-temperature xylene-insoluble component has an [mmmm] fraction of not smaller than 98.9%. (cl) The amount of the room-temperature xylene-soluble component falls between 3 and 50% by weight. (c2) The T1 relaxation time component in pulse NMR is of a single relaxation component. (c3) The ethylene content, x % by weight, as measured through 13C-NMR, and the T1 relaxation time satisfy y≦0.0014x3−0.0897x2−1.0593x +231.6. The block copolymers may be characterized by (a), (b), (c1) and (c4): (a) The melt flow rate falls between 0.01 and 1000 g/10 min. (b) The room-temperature xylene-insoluble component has an [mmmm] fraction of not smaller than 98.9%. (c1) The amount of the room-temperature xylene-soluble component falls between 3 and 50 % by weight. (c4) The ethylene content, x% by weight, and the ratio by weight of the crystalline polyethylene segments to the total of the ethylene-propylene copolymer segments and the crystalline polyethylene segments, z (%), as obtained from the TEM (transmission electron microscope) image of the propylene-ethylene block copolymers, satisfy 2≦0.016x2−0.069x−1.34.
    • 丙烯 - 乙烯嵌段共聚物的特征在于(a),(b),(c1),(c2)和(c2)和 c3):(a)熔体流动速率为0.01-1000g / 10min。 (b)室温二甲苯不溶成分的[mmmm]分数不小于98.9%。 (c1)室温二甲苯可溶成分的量为3〜50重量%。 (c2)脉冲NMR中的T1弛豫时间分量是单个弛豫分量。 (c3)通过13 C-NMR测量的乙烯含量,x重量%,以及T1弛豫时间满足y <= 0.0014×3-0.0897x2-1.0593x + 231.6。嵌段共聚物的特征可以是(a), (b),(c1)和(c4):(a)熔体流动速率为0.01-1000g / 10min。 (b)室温二甲苯不溶成分的[mmmm]分数不小于98.9%。 (c1)室温二甲苯可溶成分的量为3〜50重量%。 (c4)从TEM(透射率)获得的乙烯含量,x重量%以及结晶聚乙烯链段的重量比与乙烯 - 丙烯共聚物链段和结晶聚乙烯链段的总和z(%) 电子显微镜)图像的丙烯 - 乙烯嵌段共聚物满足2 <= 0.016x2-0.069x-1.34。
    • 7. 发明授权
    • (Meth)acrylate copolymer for syrup and resin composition thereof
    • (甲基)丙烯酸酯共聚物和其树脂组合物
    • US08138287B2
    • 2012-03-20
    • US12515757
    • 2007-11-19
    • Tsuyoshi OtaShinichi YukimasaYutaka ObataTomoaki Takebe
    • Tsuyoshi OtaShinichi YukimasaYutaka ObataTomoaki Takebe
    • C08F230/08C08F220/10C08F220/26
    • C08F265/04C08F220/10C08F220/26C08F265/06C08F285/00C08F290/06C08F290/061C08F290/068C08L51/003C08F220/16C08L2666/02
    • The present invention provides a copolymer for syrup, characterized by being formed from (A) 1 to 60 mass % of at least one (meth)acrylate compound selected from among a (meth)acrylate-modified silicone oil, an alkyl(meth)acrylate, a monoalkylene glycol(meth)acrylate, and a polyalkylene glycol(meth)acrylate, and (B) 99 to 40 mass % of a (meth)acrylate compound having a C≧6 alicyclic hydrocarbon group bonded thereto via an ester bond; a (meth)acrylate composition containing a (meth)acrylate monomer and 1 to 60 mass % of the (meth)acrylate copolymer for syrup; and a cured product of the composition. The (meth)acrylate copolymer for syrup of the present invention has excellent solubility, particularly in a (meth)acrylate compound having an alicyclic ester substituent, and a (meth)acrylate resin composition containing the copolymer provides a stable cured product having high transparency and high resistance to UV rays and heat. Thus, the cured product is suitably used as a material for lenses, illumination devices, automobiles, displays, optical-semiconductors, etc.
    • 本发明提供一种用于糖浆的共聚物,其特征在于由(A)1至60质量%的至少一种(甲基)丙烯酸酯改性硅油,(甲基)丙烯酸烷基酯 ,(甲基)丙烯酸单亚烷基二醇酯,(甲基)丙烯酸聚亚烷基二醇酯,(B)99〜40质量%的具有通过酯键与C键6的脂肪族烃基结合的(甲基)丙烯酸酯化合物; 含有(甲基)丙烯酸酯单体和1〜60质量%的(甲基)丙烯酸酯共聚物的(甲基)丙烯酸酯组合物, 和该组合物的固化产物。 本发明的用于糖浆的(甲基)丙烯酸酯共聚物具有优异的溶解性,特别是在具有脂环族酯取代基的(甲基)丙烯酸酯化合物中,含有共聚物的(甲基)丙烯酸酯树脂组合物提供了具有高透明度的稳定的固化产物, 高耐紫外线和热量。 因此,固化物适合用作透镜,照明装置,汽车,显示器,光学半导体等的材料。
    • 8. 发明申请
    • OPTICAL SEMICONDUCTOR ENCAPSULATING MATERIAL
    • 光学半导体封装材料
    • US20100234527A1
    • 2010-09-16
    • US12299015
    • 2007-04-19
    • Tsuyoshi OtaShinichi YukimasaYutaka ObataTomoaki Takebe
    • Tsuyoshi OtaShinichi YukimasaYutaka ObataTomoaki Takebe
    • C08F2/38
    • C08F290/02C08F220/18C08F222/1006C08L2312/00C09D133/14H01L31/0203H01L33/56
    • The present invention provides a sealant material for an optical semiconductor containing (A) one or more kinds of a (meth)acrylic compound selected from a (meth)acrylate-modified silicone oil, a long chain alkyl (meth)acrylate, and a polylakylene glycol (meth)acrylate having the number average molecular weight of 400 or more, (B) a (meth)acrylate compound having an ester bond with an alicyclic hydrocarbon group having 6 or more carbon atoms, and (C) a radical polymerization initiator; and an optoelectronic conversion element and an optoelectronic conversion device using thereof. The sealant material for an optical semiconductor of the present invention provides a cured product having excellent characteristics in transparency, stability to UV light and heat, yellowing resistance, and adhesion performance, and thus may be suitably used as a sealant material for a light emitting element, a light receiving element and the like in an optical semiconductor device (semiconductor light emitting device), especially as a transparent sealant material for optical semiconductors such as LED and the like.
    • 本发明提供一种光学半导体用密封材料,其含有(A)一种或多种选自(甲基)丙烯酸酯改性硅油,长链烷基(甲基)丙烯酸酯和聚亚芳基 数均分子量为400以上的(甲基)丙烯酸乙二醇酯,(B)具有碳原子数6以上的脂环式烃基具有酯键的(甲基)丙烯酸酯化合物,(C)自由基聚合引发剂; 以及光电转换元件及其使用的光电转换元件。 本发明的光学半导体用密封剂材料提供了透明性,紫外线稳定性和耐热性,耐黄变性和粘合性能优异的固化物,因此可以适合用作发光元件用密封材料 ,光半导体装置(半导体发光装置)中的受光元件等,特别是作为用于诸如LED等的光半导体的透明密封剂材料。