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1. 发明申请

US20060229403A1 Carbon fiber-containing resin dispersion solution and resin composite material 审中-公开
标题翻译：含碳纤维的树脂分散液和树脂复合材料
公开(公告)号：US20060229403A1
公开(公告)日：2006-10-12
申请号：US10553868
申请日：2004-04-23
申请人： Tatsuhiro Takahashi , Eiji Sato , Toshio Morita
发明人： Tatsuhiro Takahashi , Eiji Sato , Toshio Morita
IPC分类号： C08K3/04
CPC分类号： C08K7/06
摘要： A vapor-grown-carbon-fiber-containing dispersion containing vapor grown carbon fiber having a fiber diameter of and an aspect ration of 5 to 15,000, a resin soluble in an organic solvent, and an organic solvent having an ET value of 45 or less, which value is a solvent parameter calculated from the absorption spectrum of pyridinium-N-phenol betaine, wherein (1) lumps of the carbon fiber are partially disintegrated to thereby allow individual filaments of the carbon fiber to be present as dispersed or (2) the carbon fiber is present such that carbon fiber lumps having a diameter of 40 μm or less and separated individual carbon fiber filaments are intermingled; a production method of the dispersion; vapor-grown-carbon-fiber-containing resin composite material obtained by the method; and electroconductive material and thermal conductive material using the resin composite material. The present invention enables to prepare a resin solution wherein vapor grown carbon fiber is uniformly dispersed and to easily obtain electroconductive material and thermal conductive material from the dispersed solution.
摘要翻译：含有纤维直径为5〜15000的气相生长碳纤维，可溶于有机溶剂的树脂和ET值为45以下的有机溶剂的含有气相生长碳纤维的分散液，其值是由吡啶鎓-N-酚甜菜碱的吸收光谱计算的溶剂参数，其中（1）碳纤维块被部分崩解，从而允许碳纤维的单丝以分散的形式存在，或（2）存在碳纤维使得具有40μm或更小直径的碳纤维块和分离的单个碳纤维长丝混合; 分散体的制造方法; 通过该方法获得的含气态生长碳纤维的树脂复合材料; 导电材料和使用树脂复合材料的导热材料。本发明能够制备其中气相生长的碳纤维均匀分散并且容易地从分散的溶液获得导电材料和导热材料的树脂溶液。

2. 发明申请

US20060235135A1 Resin crystallization promoter and resin composition 审中-公开
标题翻译：树脂结晶促进剂和树脂组合物
公开(公告)号：US20060235135A1
公开(公告)日：2006-10-19
申请号：US10554063
申请日：2004-04-23
申请人： Tatsuhiro Takahashi , Toshio Morita
发明人： Tatsuhiro Takahashi , Toshio Morita
IPC分类号： C08K3/04
CPC分类号： C08K7/06 , C08K2201/016
摘要： The present invention relates to a thermoplastic resin crystallization promoter comprising fine carbon fiber consisting of fiber filaments having a diameter of 0.001 μm to 5 μm and an aspect ratio of 5 to 15,000, a thermoplastic resin composition consisting of the fine carbon fiber and thermoplastic resin and comprising crystallized resin, and a production method thereof. The crystallization promoter comprising the fine carbon fiber of the present invention enables to crystallize even an amorphous resin, which has an irregular molecular structure and therefore is not crystallized, or which exhibits low crystallization degree and therefore is difficult to crystallize by means of a conventional crystallization promoter. The crystallization promoter provides a thermoplastic resin composition, which, when molded, exhibits improved strength and tribological characteristics and is further reinforced when mixed with a filler.
摘要翻译：本发明涉及一种热塑性树脂结晶促进剂，其包含由直径为0.001〜5μm的纤维长丝和5〜15000的纵横比构成的细碳纤维，由细碳纤维和热塑性树脂构成的热塑性树脂组合物和包括结晶树脂及其制备方法。包含本发明的细碳纤维的结晶促进剂甚至能够使具有不规则分子结构的非晶性树脂结晶，因此不结晶，或者结晶度低，因此难以通过常规结晶结晶启动子。结晶促进剂提供了一种热塑性树脂组合物，其在模制时表现出改进的强度和摩擦学特性，并且当与填料混合时进一步增强。

3. 发明授权

US08084121B2 Fine carbon fiber with linearity and resin composite material using the same 有权
标题翻译：细碳纤维与线性和树脂复合材料使用相同
公开(公告)号：US08084121B2
公开(公告)日：2011-12-27
申请号：US10555637
申请日：2004-05-07
申请人： Koichiro Yonetake , Tatsuhiro Takahashi , Ryuji Yamamoto , Toshio Morita
发明人： Koichiro Yonetake , Tatsuhiro Takahashi , Ryuji Yamamoto , Toshio Morita
IPC分类号： B32B18/00 , B32B27/04 , D01F9/12
CPC分类号： B82Y30/00 , B29C70/14 , D01F9/127 , D01F9/1276 , D04H13/00 , Y10T428/249924 , Y10T428/249927 , Y10T428/24994 , Y10T428/249945 , Y10T428/2916 , Y10T428/2918 , Y10T428/2933 , Y10T428/294 , Y10T428/2958 , Y10T428/30
摘要： The fine carbon fiber obtained by pulverizing vapor grown fine carbon fiber, each fiber including a hollow space extending along its axis, and having an outer diameter of 1 to 1,000 nm, an aspect ratio of 5 to 1,000, and a BET specific surface area of 2 to 2,000 m2/g, wherein the average interlayer distance (d002) is 0.345 nm or less, and the ratio of the peak height (Id) of the band (e.g. 1,341 to 1,349 cm−1) in a Raman scattering spectrum to that of the peak height (Ig) of the band (e.g. 1,570 to 1,578 cm−1) (Id/Ig) is 0.1 to 2, a bending angle of 30° or less with respect to the axis; a composite material comprising the fine carbon fiber and a resin serving as a matrix, wherein the fine carbon fiber is oriented in one direction through, application of an external force; and a production method and use thereof. The linear fine carbon fiber of the present invention exhibits excellent dispersibility in a matrix and is readily oriented by application of an external force, and therefore, enables to produce a composite material, wherein merely the carbon fiber is or both the fine carbon fiber and the matrix resin are oriented in one direction.
摘要翻译：通过粉碎气相生长的细碳纤维而获得的细碳纤维，每个纤维包括沿其轴线延伸的中空空间，外径为1至1000nm，纵横比为5至1,000，BET比表面积为 2〜2000m 2 / g，其中平均层间距离（d002）为0.345nm以下，拉曼散射光谱带的峰高（Id）（例如1,341〜1349cm -1）的比例与的带的高度（Ig）（例如1,570-1,578cm-1）（Id / Ig）为0.1〜2，相对于轴的弯曲角为30°以下。包含细碳纤维和用作基质的树脂的复合材料，其中细碳纤维沿一个方向取向，施加外力; 及其制造方法及其用途。本发明的线状细碳纤维在基体中表现出优异的分散性，并且通过施加外力容易取向，因此能够生产复合材料，其中仅碳纤维为细碳纤维或基质树脂在一个方向上取向。

4. 发明申请

US20070042901A1 Porous body, production method thereof and composite material using the porous body 有权
标题翻译：多孔体，其制造方法和使用多孔体的复合材料
公开(公告)号：US20070042901A1
公开(公告)日：2007-02-22
申请号：US10556431
申请日：2004-05-12
申请人： Takashi Kurose , Tatsuhiro Takahashi , Chiaki Sotowa , Toshio Morita
发明人： Takashi Kurose , Tatsuhiro Takahashi , Chiaki Sotowa , Toshio Morita
IPC分类号： B01J21/18
CPC分类号： C08J9/0085 , B01J21/18 , B01J31/06 , B01J31/061 , B01J31/08 , B01J32/00 , B01J35/002 , B01J35/0033 , B01J35/023 , B01J35/026 , B01J35/06 , B01J35/10 , B01J35/1014 , B01J37/32 , B22F2998/10 , C02F1/283 , C02F2303/185 , C04B38/0045 , C04B41/009 , C04B41/48 , C04B41/4888 , C04B41/51 , C04B41/63 , C04B41/69 , C04B41/83 , C04B41/88 , C04B2111/00793 , C04B2111/0081 , C08J9/26 , C08J9/28 , C08J9/40 , C08J2201/038 , C08J2201/048 , C08J2201/0504 , C08J2305/00 , C08J2375/04 , C22C47/08 , H01M4/9083 , H01M4/926 , H01M8/0234 , Y02P70/56 , Y10S977/842 , Y10T428/249927 , Y10T428/24994 , Y10T428/30 , C04B35/52 , C04B38/04 , C04B40/0078 , C04B14/386 , C04B30/02 , C04B38/00 , C04B38/0074 , C04B38/10 , C04B41/457 , C04B41/4523 , C04B35/83 , C22C47/06 , B22F3/114
摘要： A porous material comprising vapor grown carbon fiber in an amount of 10 to 90 mass %, fiber filaments of the carbon fiber forming a three-dimensional network and having a diameter of 1 to 1,000 nm, an aspect ratio of 5 to 15,000, a specific surface area (by BET method) of 2 to 2,000 m2/g, and the ratio of the intensity of the peak at 1,360 cm−1 in a Raman scattering spectrum of the carbon fiber to that of the peak at 1,580 cm−1 in the spectrum(I1360/I1580) is 0.1 to 2.0, wherein the porosity of the porous material (V/V0) is 0.50 to 0.99 and a specific surface area is 5 to 1,000 m2/g; and a production method and use thereof. The vapor grow carbon fiber impregnated in the porous material of the present invention does not contain aggregates and a three-dimensional network is formed between the fiber filaments, wherein length of each of the fiber filaments is maintained. Therefore, the vapor grown carbon fiber enables to readily produce a composite material (porous material), in which even a small amount of addition of vapor grown carbon fiber can exhibit sufficient effect.
摘要翻译： 10.一种多孔材料，其含有10〜90质量％的蒸气生长碳纤维，所述碳纤维的纤维丝形成三维网状物，直径为1〜1000nm，长径比为5〜15000，表面积（BET法）为2〜2000μm2 / g，拉曼散射光谱中1,360cm -1处的峰强度比为在光谱（I 1360/1580℃）中1580cm -1处的峰的碳纤维为0.1〜2.0，其中，多孔材料的孔隙率（V / V 0）为0.50〜0.99，比表面积为5〜1000m 2 / g; 及其制造方法及其用途。浸渍在本发明的多孔材料中的蒸气生长碳纤维不含有聚集体，并且在纤维长丝之间形成三维网络，其中维持每根纤维丝的长度。因此，气相生长碳纤维能够容易地生产即使少量添加气相生长碳纤维也能发挥足够的效果的复合材料（多孔材料）。

5. 发明授权

US08372511B2 Fine carbon fiber with linearity and resin composite material using the same 有权
标题翻译：细碳纤维与线性和树脂复合材料使用相同
公开(公告)号：US08372511B2
公开(公告)日：2013-02-12
申请号：US13312719
申请日：2011-12-06
申请人： Koichiro Yonetake , Tatsuhiro Takahashi , Ryuji Yamamoto , Toshio Morita
发明人： Koichiro Yonetake , Tatsuhiro Takahashi , Ryuji Yamamoto , Toshio Morita
IPC分类号： B32B18/00 , B32B27/04
CPC分类号： B82Y30/00 , B29C70/14 , D01F9/127 , D01F9/1276 , D04H13/00 , Y10T428/249924 , Y10T428/249927 , Y10T428/24994 , Y10T428/249945 , Y10T428/2916 , Y10T428/2918 , Y10T428/2933 , Y10T428/294 , Y10T428/2958 , Y10T428/30
摘要： A fine carbon fiber having linearity, each fiber filament of the carbon fiber having a bending angle of 30° or less with respect to the longitudinal direction of the fiber filament, and including a hollow space extending along its axis, and having an outer diameter of 1 to 1,000 nm, an aspect ratio of 5 to 1,000, and a BET specific surface area of 2 to 2,000 m2/g, wherein the average interlayer distance (d002) of the carbon fiber at a (002) plane is 0.345 nm or less as measured by means of X-ray diffractometry, and the ratio of the peak height (Id) of the band at 1,341 to 1,349 cm−1 in a Raman scattering spectrum of the carbon fiber to that of the peak height (Ig) of the band at 1,570 to 1,578 cm−1 in the spectrum (Id/Ig) is 0.1 to 2. The fiber exhibits excellent dispersibility in a matrix.
摘要翻译：具有线性的细碳纤维，碳纤维的纤维长丝相对于纤维长丝的长度方向具有30°以下的弯曲角度，并且包括沿其轴线延伸的中空空间，并且具有外径 1〜1000nm，长宽比为5〜1000，BET比表面积为2〜2000m 2 / g，其中，（002）面上的碳纤维的平均层间距离（d002）为0.345nm以下如通过X射线衍射法测定的，并且在碳纤维的拉曼散射光谱中，在1,341〜1349cm -1处的条带的峰高（Id）与峰高（Ig）的峰高光谱（Id / Ig）中的1570至1,578cm -1的谱带为0.1至2.该纤维在基质中表现出优异的分散性。

6. 发明授权

US07504153B2 Porous body, production method thereof and composite material using the porous body 有权
标题翻译：多孔体，其制造方法和使用多孔体的复合材料
公开(公告)号：US07504153B2
公开(公告)日：2009-03-17
申请号：US10556431
申请日：2004-05-12
申请人： Takashi Kurose , Tatsuhiro Takahashi , Chiaki Sotowa , Toshio Morita
发明人： Takashi Kurose , Tatsuhiro Takahashi , Chiaki Sotowa , Toshio Morita
IPC分类号： B32B9/00
CPC分类号： C08J9/0085 , B01J21/18 , B01J31/06 , B01J31/061 , B01J31/08 , B01J32/00 , B01J35/002 , B01J35/0033 , B01J35/023 , B01J35/026 , B01J35/06 , B01J35/10 , B01J35/1014 , B01J37/32 , B22F2998/10 , C02F1/283 , C02F2303/185 , C04B38/0045 , C04B41/009 , C04B41/48 , C04B41/4888 , C04B41/51 , C04B41/63 , C04B41/69 , C04B41/83 , C04B41/88 , C04B2111/00793 , C04B2111/0081 , C08J9/26 , C08J9/28 , C08J9/40 , C08J2201/038 , C08J2201/048 , C08J2201/0504 , C08J2305/00 , C08J2375/04 , C22C47/08 , H01M4/9083 , H01M4/926 , H01M8/0234 , Y02P70/56 , Y10S977/842 , Y10T428/249927 , Y10T428/24994 , Y10T428/30 , C04B35/52 , C04B38/04 , C04B40/0078 , C04B14/386 , C04B30/02 , C04B38/00 , C04B38/0074 , C04B38/10 , C04B41/457 , C04B41/4523 , C04B35/83 , C22C47/06 , B22F3/114
摘要： A porous material comprising vapor grown carbon fiber in an amount of 10 to 90 mass %, fiber filaments of the carbon fiber forming a three-dimensional network and having a diameter of 1 to 1,000 nm, an aspect ratio of 5 to 15,000, a specific surface area (by BET method) of 2 to 2,000 m2/g, and the ratio of the intensity of the peak at 1,360 cm−1 in a Raman scattering spectrum of the carbon fiber to that of the peak at 1,580 cm−1 in the spectrum(I1360/I1580) is 0.1 to 2.0, wherein the porosity of the porous material (V/V0) is 0.50 to 0.99 and a specific surface area is 5 to 1,000 m2/g; and a production method and use thereof. The vapor grow carbon fiber impregnated in the porous material of the present invention does not contain aggregates and a three-dimensional network is formed between the fiber filaments, wherein length of each of the fiber filaments is maintained. Therefore, the vapor grown carbon fiber enables to readily produce a composite material (porous material), in which even a small amount of addition of vapor grown carbon fiber can exhibit sufficient effect.
摘要翻译： 10.一种多孔材料，其含有10〜90质量％的蒸气生长碳纤维，所述碳纤维的纤维丝形成三维网状物，直径为1〜1000nm，长径比为5〜15000，表面积（BET法）为2〜2000m 2 / g，碳纤维的拉曼散射光谱中的1,360cm -1处的峰强度与1580cm -1的峰的强度的比例光谱（I1360 / I1580）为0.1〜2.0，其中多孔材料的孔隙率（V / V0）为0.50〜0.99，比表面积为5〜1000m 2 / g; 及其制造方法及其用途。浸渍在本发明的多孔材料中的蒸气生长碳纤维不含有聚集体，并且在纤维长丝之间形成三维网络，其中维持每根纤维丝的长度。因此，气相生长碳纤维能够容易地生产即使少量添加气相生长碳纤维也能发挥足够的效果的复合材料（多孔材料）。

7. 发明授权

US5559180A Polyacetal compositions for use in wear applications 失效
标题翻译：用于磨损应用的聚缩醛组合物
公开(公告)号：US5559180A
公开(公告)日：1996-09-24
申请号：US415869
申请日：1995-04-03
申请人： Tatsuhiro Takahashi , Edmund A. Flexman , Robert J. Kassal
发明人： Tatsuhiro Takahashi , Edmund A. Flexman , Robert J. Kassal
IPC分类号： C08L23/08 , C08L27/18 , C08L59/00 , B29D22/00 , C08L71/00
CPC分类号： C08L59/00 , C08L23/08 , C08L27/18
摘要： A polyacetal composition is provided for use in plastic-plastic wear applications, said composition containing about 85 to 99 weight percent polyacetal, about 0 to 5 weight percent polytetrafluoroethylene fibers, about 0.5 to 5 weight percent ethylene methyl acrylate copolymer, and about 0.5 to 5 weight percent of at least one lubricant. The compositions are particularly useful in forming shaped articles for use especially in conveyor chain applications and gear applications.
摘要翻译：聚缩醛组合物提供用于塑料 - 塑料磨损应用，所述组合物含有约85-99重量％聚缩醛，约0-5重量％聚四氟乙烯纤维，约0.5-5重量％乙烯丙烯酸甲酯共聚物和约0.5-5 至少一种润滑剂的重量百分数。所述组合物特别可用于形成特别用于输送机链应用和齿轮应用中的成形制品。

8. 发明授权

US5969067A Phosphorus-containing fluoromonomers and polymers thereof 失效
标题翻译：含磷含氟单体及其聚合物
公开(公告)号：US5969067A
公开(公告)日：1999-10-19
申请号：US929216
申请日：1997-09-09
申请人： Paul Douglas Brothers , Ming-Hong Hung , Michael Joseph Michalczyk , Tatsuhiro Takahashi
发明人： Paul Douglas Brothers , Ming-Hong Hung , Michael Joseph Michalczyk , Tatsuhiro Takahashi
IPC分类号： C07F9/09 , C07F9/113 , C07F9/14 , C07F9/143 , C07F9/146 , C08F30/02 , C08F214/18 , C08F214/26 , C08F230/02 , C08J7/04 , C09D4/00 , C08F16/24 , C07F9/02
CPC分类号： C07F9/091 , C07F9/113 , C07F9/14 , C07F9/1403 , C08F214/184 , C08F214/262 , C08F30/02 , C08J7/047 , C09D4/00 , C08J2443/00 , Y10T428/3154 , Y10T428/31544 , Y10T428/31663 , Y10T428/31667 , Y10T428/31678 , Y10T428/31692 , Y10T428/31855
摘要： Fluorinated vinyl ethers having phosphorus-containing groups are useful as monomers in making fluoropolymers having functional sites.
摘要翻译：具有含磷基团的氟化乙烯醚可用作制备具有官能位点的含氟聚合物的单体。

9. 发明授权

US5418286A Polyacetal resin composition 失效
标题翻译：聚缩醛树脂组合物
公开(公告)号：US5418286A
公开(公告)日：1995-05-23
申请号：US55173
申请日：1993-04-28
申请人： Tatsuhiro Takahashi , Toshikazu Kobayashi
发明人： Tatsuhiro Takahashi , Toshikazu Kobayashi
IPC分类号： C08L23/02 , C08L25/08 , C08L35/06 , C08L51/00 , C08L59/00 , C08L63/00 , C08L59/02 , C08L59/04
CPC分类号： C08L59/00 , C08L23/02 , C08L25/08 , C08L35/06 , C08L51/00 , C08L63/00
摘要： Incorporation into polyacetal of 0.01-15 weight percent of certain epoxy-containing polymer compounds, oxazolyl-containing monomer and polymer compounds, and/or styrene acrylonitrile graft polymer compounds yields polyacetal compositions having excellent tensile strength after long-term aging and also after long-term aging in grease. The compositions are useful in automotive and electrical/electronic applications.
摘要翻译：含有0.01-15％（重量）某些含环氧基的聚合物化合物，含有恶唑基的单体和聚合物化合物和/或苯乙烯丙烯腈接枝聚合物化合物的聚缩醛的聚缩醛产生长期老化后具有优异拉伸强度的聚缩醛组合物，润滑脂的长期老化。该组合物可用于汽车和电气/电子应用。

10. 发明申请

US20130320268A1 METHOD FOR PRODUCING RESIN FILM USING ELECTROCONDUCTIVE RESIN COMPOSITION 审中-公开
标题翻译：使用电子树脂组合物生产树脂膜的方法
公开(公告)号：US20130320268A1
公开(公告)日：2013-12-05
申请号：US13982687
申请日：2011-11-04
申请人： Kurato Akiba , Kiichiro Matsushita , Tatsuhiro Takahashi , Yumi Takekawa
发明人： Kurato Akiba , Kiichiro Matsushita , Tatsuhiro Takahashi , Yumi Takekawa
IPC分类号： H01B1/12
CPC分类号： H01B1/128
摘要： There is provided a production method for a resin film according to which an application liquid raw material (polyaniline solution) does not gelate over a long period of time and a resin film can be stably produced. A production method for a resin film according to an embodiment of the present invention includes the step of heating and kneading a polyaniline in an emeraldine base state and a protonic acid to prepare a conductive resin composition.
摘要翻译：提供了一种用于树脂膜的制备方法，其中应用液体原料（聚苯胺溶液）不会长时间凝胶化，并且可以稳定地制备树脂膜。根据本发明的实施方案的树脂膜的制造方法包括将翠绿亚胺碱状态的聚苯胺和质子酸进行加热混炼以制备导电性树脂组合物的工序。

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