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    • 1. 发明授权
    • Photographic light-sensitive material
    • 摄影感光材料
    • US4600687A
    • 1986-07-15
    • US725684
    • 1985-04-22
    • Taku NakamuraMitsunori HiranoMasasi OgawaKunio Ishigaki
    • Taku NakamuraMitsunori HiranoMasasi OgawaKunio Ishigaki
    • G03C1/04C07C67/00C07C313/00C07C317/04C07C317/18C07C317/28C07C317/44C07C317/46C08L7/00C08L21/00C08L23/00C08L33/00C08L33/02C08L89/00C08L101/00G03C1/053G03C1/30G03C1/85G03C1/89G03C7/00G03C8/08G03C8/26G03C8/56G03C1/76G03C1/86
    • G03C1/89G03C1/053G03C1/307G03C8/56Y10S430/142
    • A photographic light-sensitive material having at least one layer containing a polymer having a repeating unit of the formula (I): ##STR1## wherein A is a monomer unit prepared by copolymerizing copolymerizable ethylenically unsaturated monomers; R.sub.1 is hydrogen or a lower alkyl group having 1 to 6 carbon atoms; Q is ##STR2## (wherein R.sub.1 is the same as defined above) or an arylene group having 6 to 10 carbon atoms; L is a divalent group having 3 to 15 carbon atoms and containing at least one linking group selected from the members consisting of ##STR3## (wherein R.sub.1 is the same as defined above) or a divalent group having 1 to 12 carbon atoms and containing at least one linking group selected from the members consisting of ##STR4## (wherein R.sub.1 is the same as defined above); R.sub.2 is --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 X (wherein X is a group capable of being substituted with a nucleophilic group or a group capable of being released in the form of HX upon a base; and x and y each represents molar percent, x being between 0 and 99 and y being between 1 and 100. The polymer has a vinylsulfone group or a functional group which is a precursor of a vinylsulfone group fixed in a specific layer of the photographic light-sensitive material and can be used as a mordant, an antistatic agent or other various photographic additives.
    • 具有至少一层含有具有式(I)的重复单元的聚合物的摄影感光材料:其中A是通过共聚合可烯化不饱和单体制备的单体单元; R1是氢或具有1-6个碳原子的低级烷基; Q是(其中R1与上述定义相同)或具有6至10个碳原子的亚芳基; L是具有3至15个碳原子的二价基团,并且含有至少一个选自由下列成员组成的连接基团:其中R 1与上述定义相同或含有1至12个碳原子的二价基团, 从由 + TR (其中R1与上述定义相同)的成员中选择的至少一个连接基团; R2是-CH = CH2或-CH2CH2X(其中X是能够被亲核基团取代的基团或能够在碱基上以HX形式释放的基团; x和y各自表示摩尔百分比,x为 0至99之间,y为1至100.聚合物具有乙烯基砜基团或官能团,其是固定在照相感光材料的特定层中的乙烯基砜基团的前体,并且可用作媒染剂, 抗静电剂或其他各种照相添加剂。
    • 5. 发明授权
    • Method of hardening gelatin and photographic materials produced thereby
    • 硬化明胶和由此生产的照相材料的方法
    • US4444926A
    • 1984-04-24
    • US320028
    • 1981-11-10
    • Masasi OgawaKunio IshigakiKiyotaka Hori
    • Masasi OgawaKunio IshigakiKiyotaka Hori
    • C08L89/00C09H7/00G03C1/053G03C1/30B01J13/02
    • G03C1/053G03C1/307
    • A method of hardening gelatin is described which uses (1) a polymer containing at least 0.01 mol % of a repeating unit represented by formula (I) ##STR1## wherein R represents a hydrogen atom, an alkyl group having from 1 to 6 carbon atoms, or a halogen atom, M represents a hydrogen atom, an alkali metal atom, an alkaline earth metal atom, or an organic base, X represents an alkyl group having from 1 to 6 carbon atoms, an alkoxy group having from 1 to 6 carbon atoms, an alkylamino group having from 1 to 6 carbon atoms, or a halogen atom, m represents 0, 1 or 2, and n represents 1 or 2, (2) a polyvalent alcohol having at least two hydroxy groups, and (3) a hardener having an active vinyl group.The method has advantages in that the rate of hardening the gelatin is fast, the so-called post hardening property is small, and the gelatin composition is hardely influenced by the conditions of temperature and humidity during storage.
    • 描述了一种硬化明胶的方法,其使用(1)含有至少0.01mol%由式(I)表示的重复单元的聚合物其中R表示氢原子,具有1〜 6个碳原子或卤素原子,M表示氢原子,碱金属原子,碱土金属原子或有机碱,X表示碳原子数1〜6的烷基,烷氧基含1个 至6个碳原子,具有1至6个碳原子的烷基氨基或卤素原子,m表示0,1或2,n表示1或2,(2)具有至少两个羟基的多元醇,以及 (3)具有活性乙烯基的固化剂。 该方法的优点在于明胶硬化速度快,所谓的后固化性能小,明胶组合物在储存期间受温度和湿度条件的影响很大。