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    • 3. 发明授权
    • Method of production of dielectric ceramic composition and method of production of electronic device containing dielectric layers
    • 电介质陶瓷组合物的制造方法和含有电介质层的电子器件的制造方法
    • US06800270B2
    • 2004-10-05
    • US09932023
    • 2001-08-20
    • Takeshi NomuraShigeki Sato
    • Takeshi NomuraShigeki Sato
    • C01G2300
    • C04B35/468H01G4/1227Y10T29/417
    • A method of production of a dielectric ceramic composition having at least a main component of Ba2TiO3, a second subcomponent including at least one compound selected from SiO2, MO (where M is at least one element selected from Ba, Ca, Sr, and Mg), Li2O, and B2O3, and other subcomponents, comprising the step of: mixing in said main component at least part of other subcomponents except for said second subcomponent to prepare a pre-calcination powder, calcining the pre-calcination powder to prepare a calcined powder, and mixing at least said second subcomponent in said calcined powder to obtain the dielectric ceramic composition having molar ratios of the subcomponents to the main component of predetermined ratios. As the other subcomponents, there is a third subcomponent including at least one compound selected from V2O5, MoO3, and WO3. A ratio of the third subcomponent to 100 moles of the main component is preferably 0.01 to 0.1 mole.
    • 一种制备具有至少主要成分为Ba2TiO3的电介质陶瓷组合物的方法,包括至少一种选自SiO 2,MO(其中M为选自Ba,Ca,Sr和Mg中的至少一种元素)的第二副成分的方法, ,Li 2 O和B 2 O 3以及其它副成分的方法,包括以下步骤:在所述主成分中除了所述第二副成分以外的至少一部分其他副成分混合以制备预煅烧粉末,煅烧所述预煅烧粉末以制备煅烧粉末 ,并将所述第二副成分混合在所述煅烧粉末中,得到具有预定比例的副成分与主成分的摩尔比的电介质陶瓷组合物。 作为其它副成分,存在包含至少一种选自V 2 O 5,MoO 3和WO 3的化合物的第三副成分。 第三副成分与主成分100摩尔的比优选为0.01〜0.1摩尔。
    • 6. 发明授权
    • Dielectric ceramic composition and electronic device
    • 介电陶瓷组合物和电子器件
    • US06226172B1
    • 2001-05-01
    • US09361311
    • 1999-07-27
    • Shigeki SatoTakeshi NomuraAkira Sato
    • Shigeki SatoTakeshi NomuraAkira Sato
    • H01G412
    • H01G4/1227
    • A dielectric ceramic composition having at least a main component of BaTiO3, a first subcomponent including at least one compound selected from MgO, CaO, BaO, SrO and Cr2O3, a second subcomponent of (Ba, Ca)x,SiO2+x(where, x=0.8 to 1.2), a third subcomponent including at least one compound selected from V2O5, MoO3, and WO3, and a fourth subcomponent including an oxide of R1 (where R1 is at least one element selected from Sc, Er, Tm, Yb, and Lu), wherein the ratios of the subcomponents to 100 moles of the main component of BaTiO3 are as follows: first subcomponent: 0.1 to 3 moles, second subcomponent: 2 to 10 moles, third subcomponent: 0.01 to 0.5 mole, and fourth subcomponent: 0.5 to 7 moles (where the number of moles of the fourth subcomponent is the ratio of R1 alone). The dielectric ceramic composition has a high relative dielectric constant, has a capacity-temperature characteristic satisfying the X8R characteristic of the EIA standard (−55 to 150° C., &Dgr;C =±15% or less), enables sintering in a reducing atmosphere, has a small change in the capacity under a direct current electric field along with time, and further has a long lifetime of the insulation resistance.
    • 具有BaTiO 3的至少主要成分的电介质陶瓷组合物,包含选自MgO,CaO,BaO,SrO和Cr 2 O 3中的至少一种化合物的第一副成分,(Ba,Ca)x,SiO 2 + x的第二副成分(其中, x = 0.8〜1.2),包含至少一种选自V 2 O 5,MoO 3和WO 3的化合物的第三副成分和包含R1的氧化物的第四副成分(其中,R 1为选自Sc,Er,Tm,Yb中的至少一种元素 和Lu),其中副成分与100摩尔BaTiO 3的主要成分的比例如下:第一副成分:0.1〜3摩尔,第2副成分:2〜10摩尔,第3副成分:0.01〜0.5摩尔,第4次 副成分:0.5〜7摩尔(第四副成分的摩尔数为单独的R1的比例)。 电介质陶瓷组合物具有高相对介电常数,具有满足EIA标准(-55〜150℃,DELTAC =±15%以下)的X8R特性的容量 - 温度特性,能够在还原气氛中进行烧结, 随着时间的推移,直流电场下的容量变化很小,绝缘电阻的寿命也较长。
    • 8. 发明授权
    • Method of manufacturing dielectric ceramic composition and electronic device containing dielectric layer
    • 制造介电陶瓷组合物的方法和含有电介质层的电子器件
    • US06485672B1
    • 2002-11-26
    • US09673957
    • 2000-10-24
    • Takeshi NomuraShigeki Sato
    • Takeshi NomuraShigeki Sato
    • C04B35468
    • C04B35/4682H01G4/1227
    • A method of manufacturing a dielectric ceramic composition comprising at least a main component of BaTiO3, a second subcomponent as represented by (Ba, Ca)xSiO2+x (where, x=0.8 to 1.2), and other subcomponents. The main component and at least part of the subcomponents except the second subcomponent are mixed to prepare a pre-calcination powder and the pre-calcination powder is calcined to prepare a calcined powder. The second subcomponent is at least mixed in the calcined powder to obtain a dielectric ceramic composition having a ratio of each subcomponent to the main component of BaTiO3 of a predetermined molar ratio. It is therefore possible to obtain an electronic device containing a dielectric layer such as a multi-layer ceramic capacitor able to satisfy both of the capacity-temperature characteristics of the X7R characteristic (EIA standard) and the B characteristic (EIAJ standard), even when the dielectric layer is a superthin one of not more than 4 &mgr;m and having a small change in the capacity under a DC electric field along with time and further having a long accelerated lifetime of the insulation resistance and a small drop in capacity under a DC bias.
    • 一种电介质陶瓷组合物的制造方法,其至少包含BaTiO 3的主要成分,由(Ba,Ca)xSiO 2 + x(其中x = 0.8〜1.2)表示的第二副成分,以及其他亚成分。 混合除了第二副成分以外的主成分和副成分的至少一部分,制备预煅烧粉末,并煅烧预煅烧粉末以制备煅烧粉末。 将第二副成分至少在煅烧粉末中混合,得到具有预定摩尔比的BaTiO 3的每个副成分与主要成分的比例的电介质陶瓷组合物。 因此,即使是能够满足X7R特性(EIA标准)和B特性(EIAJ标准)的容量 - 温度特性两者的多层陶瓷电容器的电介质层,也能够得到电子装置, 电介质层是不超过4μm的超导体,并且随着时间的推移在DC电场下的容量变化很小,并且还具有绝缘电阻的长加速寿命和在DC偏压下的容量的小的下降 。
    • 10. 发明授权
    • Conductive paste for a multi-layered ceramic electronic component and a method for manufacturing a multi-layered unit for a multi-layered ceramic electronic component
    • 多层陶瓷电子部件用导电性糊剂及多层陶瓷电子部件用多层单元的制造方法
    • US07537713B2
    • 2009-05-26
    • US10590683
    • 2005-02-23
    • Shigeki SatouTakeshi Nomura
    • Shigeki SatouTakeshi Nomura
    • H01B1/22B05D5/12H01G4/12H01G4/30
    • H01B1/22H01G4/008H01G4/0085H01G4/12H01G4/30
    • It is an object of the present invention to provide a method for manufacturing a multi-layered unit for a multi-layered ceramic electronic component which can reliably prevent short circuit failure from occurring in a multi-layered ceramic electronic component and form an electrode layer in a desired manner.A method for manufacturing a multi-layered ceramic electronic component includes a step of printing a conductive paste containing a binder containing ethyl cellulose having a weight average molecular weight of MWL and ethyl cellulose having a weight average molecular weight of MWH at a weight ratio of X:(1−X), where MWL, MWH and X are selected so that X*MWL+(1−X)*MWH falls within a range of 145,000 to 215,000 and at least one solvent selected from the group consisting of isobornyl acetate, dihydroterpinyl methyl ether, terpinyl methyl ether, α-terpinyl acetate, I-dihydrocarvyl acetate, I-menthone, I-menthyl acetate, I-perillyl acetate and I-carvyl acetate on a ceramic green sheet containing a butyral system resin as a binder in a predetermined pattern, thereby forming an electrode layer.
    • 本发明的目的是提供一种用于制造多层陶瓷电子部件的多层单元的方法,其可以可靠地防止在多层陶瓷电子部件中发生短路故障并形成电极层 一种理想的方式。 一种多层陶瓷电子部件的制造方法包括:将含有重均分子量为MWL的乙基纤维素和重均分子量为MWH的乙基纤维素的重量比为X的导电糊的印刷工序 :(1-X),其中选择MWL,MWH和X,使得X * MWL +(1-X)* MWH在145,000至215,000的范围内,并且至少一种溶剂选自乙酸异冰片酯,二氢萜烯 甲基醚,萜品烯甲基醚,乙酸萜品酯,乙酸1-二氢乙酰酯,1-薄荷酮,乙酸1-乙烯酯,乙酸1-乙烯酯和乙酸1-乙酰酯在含有缩丁醛树脂作为粘合剂的陶瓷生片上 从而形成电极层。