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1. 发明授权

US5608018A .alpha.-olefin polymerization catalyst system and process for producing .alpha.-olefin catalyst 失效
标题翻译： α-烯烃聚合催化剂体系和α-烯烃催化剂生产方法
公开(公告)号：US5608018A
公开(公告)日：1997-03-04
申请号：US350158
申请日：1994-11-30
申请人： Takeshi Ebara , Teruyosi Kiyota , Akio Imai
发明人： Takeshi Ebara , Teruyosi Kiyota , Akio Imai
IPC分类号： C08F4/654 , C08F4/656 , C08F10/00 , C08F4/651
CPC分类号： C08F10/00
摘要： An .alpha.-olefin polymerization catalyst system having so high a catalytic activity and stereoregularity that the catalyst residue and amorphous polymer need not be removed and a process for producing an.alpha.-olefin polymer using the catalyst system, said catalyst system consisting essentially of:(A) a trivalent titanium compound-containing solid catalyst component prepared by reducing a titanium compound, represented by the general formula Ti(OR.sup.1).sub.a X.sub.4-a in which R.sup.1 represents a hydrocarbon group having 1 to 20 carbon atoms; X represents a halogen atom; and a represents a numeral satisfying 0
摘要翻译：具有如此高的催化活性和立构规整性的催化剂残余物和无定形聚合物不需要除去的α-烯烃聚合催化剂体系和使用该催化剂体系生产α-烯烃聚合物的方法，所述催化剂体系基本上由以下组成：（A ）通过还原由通式Ti（OR 1）a X 4-a表示的钛化合物制备的含三价钛化合物的固体催化剂组分，其中R 1表示具有1至20个碳原子的烃基; X表示卤原子; 和a表示满足0

2. 发明申请

US20080015312A1 POLYMER COMPOSITION AND FILM THEREOF 有权
标题翻译：聚合物组合物及其膜
公开(公告)号：US20080015312A1
公开(公告)日：2008-01-17
申请号：US11777427
申请日：2007-07-13
申请人： Hideaki HORI , Takeshi Ebara
发明人： Hideaki HORI , Takeshi Ebara
IPC分类号： C08F8/00
CPC分类号： C08L23/10 , C08J5/18 , C08J2323/02 , C08L23/12 , C08L23/14 , C08L23/142 , C08L23/20 , C08L2205/02 , C08L2205/025 , C08L2205/03 , C08L2205/035 , C08L2666/06 , C08L2666/02
摘要： Disclosed is a polymer composition comprising a copolymer of propylene, a specific amount of α-olefin having 4 or more carbon atoms and optionally a specific amount of ethylene and a specific 1-butene homopolymer or copolymer having a melting point of not lower than 60° C. but lower than 125° C., wherein the polymer composition contains a 20° C. xylene-soluble portion of the polymer composition in an amount of from 5 to 45% by weight and the 20° C. xylene-soluble portion has an intrinsic viscosity of 1.3 dl/g or higher. The polymer composition may optionally contain a specific propylene copolymer and/or a specific propylene homopolymer or copolymer having a melting point of from 150° C. to 170° C.
摘要翻译：公开了一种聚合物组合物，其包含丙烯，特定量的具有4个或更多个碳原子的α-烯烃和任选的特定量的乙烯和特定的1-丁烯均聚物或共聚物的共聚物，其熔点不低于60℃ 但低于125℃，其中聚合物组合物含有5至45重量％的量的聚合物组合物的20℃二甲苯可溶部分，20℃二甲苯可溶部分具有特性粘度为1.3dl / g以上。聚合物组合物可任选地含有特定的丙烯共聚物和/或熔点为150℃至170℃的特定丙烯均聚物或共聚物。

3. 发明授权

US5473021A Process for producing ethylene-propylene block copolymer 失效
标题翻译：生产乙烯 - 丙烯嵌段共聚物的方法
公开(公告)号：US5473021A
公开(公告)日：1995-12-05
申请号：US176917
申请日：1994-01-03
申请人： Hiroyuki Koura , Takeshi Ebara , Kazuki Wakamatsu , Shozo Kawamata , Yoshizumi Sasaki
发明人： Hiroyuki Koura , Takeshi Ebara , Kazuki Wakamatsu , Shozo Kawamata , Yoshizumi Sasaki
IPC分类号： C08F4/658 , C08F4/60 , C08F4/654 , C08F4/80 , C08F210/16 , C08F297/08
CPC分类号： C08F297/083
摘要： A process for producing ethylene-propylene block copolymer which comprises(1) The first step of reacting propylene or a mixture of propylene and ethylene in the presence of a catalyst composed essentially of(A) a solid catalyst component containing magnesium, titanium and a halogen as the indispensable ingredients,(B) an organoaluminum compound, and(C) a silicon compound (1) represented by the formula R.sup.1 R.sup.2 Si(OR.sup.3).sub.2, wherein R.sup.1 is an alicyclic hydrocarbon group of 5-20 carbon atoms and R.sup.2 and R.sup.3 are each independently a hydrocarbon group of 1-20 carbon atoms, to form a propylene homopolymer portion or an ethylene-propylene copolymer portion having an ethylene content of 3% by weight or less, in an amount corresponding to 50-95% by weight of the total block copolymer amount, and(2) the second step of reacting a mixture of ethylene and propylene with the polymer portion obtained in the first step in the presence of the aforesaid catalyst composed essentially of the components (a), (b) and (c) and in the additional presence of a silicon compound (2) represented by the formula R.sup.4.sub.a Si(OR.sup.5).sub.4-a, wherein R.sup.4 and R.sup.5 are each independently a hydrocarbon group of 1-20 carbon atoms and a is a number satisfying the equation 0.ltoreq.a
摘要翻译：一种生产乙烯 - 丙烯嵌段共聚物的方法，其包括（1）在主要由（A）含有镁，钛和卤素的固体催化剂组分的催化剂存在下使丙烯或丙烯与乙烯的混合物反应的第一步骤作为不可或缺的成分，（B）有机铝化合物和（C）由式R 1 R 2 Si（OR 3）2表示的硅化合物（1），其中R 1是5-20个碳原子的脂环族烃基，R 2和R 3是各自独立地是1-20个碳原子的烃基，以形成丙烯均聚物部分或乙烯含量为3重量％以下的乙烯 - 丙烯共聚物部分，其量相当于所述乙烯含量的50-95重量％总共嵌段共聚物量，和（2）在上述主要由组分（a），（b）组成的催化剂存在下，使乙烯和丙烯的混合物与第一步获得的聚合物部分反应的第二步骤，和（c），另外存在由式R4aSi（OR5）4-a表示的硅化合物（2），其中R4和R5各自独立地为1-20个碳原子的烃基，a为满足方程式0 <= a <4，得到乙烯 - 丙烯嵌段共聚物，其含有乙烯含量为至少20重量％的乙烯 - 丙烯共聚物部分，其量相当于5-50重量％总嵌段共聚物量。

4. 发明授权

US5134104A Liquid catalyst component, catalyst system containing said component and process for producing ethylene-.alpha.-olefin copolymer using said catalyst system 失效
标题翻译：液体催化剂组分，含有所述组分的催化剂体系和使用所述催化剂体系生产乙烯-α-烯烃共聚物的方法
公开(公告)号：US5134104A
公开(公告)日：1992-07-28
申请号：US705788
申请日：1991-05-28
申请人： Toshio Sasaki , Hirofumi Jyohouji , Yoshihiro Miyoshi , Takeshi Ebara , Kiyoshi Kawai
发明人： Toshio Sasaki , Hirofumi Jyohouji , Yoshihiro Miyoshi , Takeshi Ebara , Kiyoshi Kawai
IPC分类号： C08F4/64 , C08F210/16
CPC分类号： C08F210/16
摘要： A liquid catalyst component for copolymerization of ethylene with .alpha.-olefin comprising a titanium compound represented by the following general formula:(R.sup.1 R.sup.2 N).sub.4-(m+n) TiX.sub.m Y.sub.nwherein R.sup.1 and R.sup.2 each represents a saturated hydrocarbon group having 8 to 30 carbon atoms; X represents halogen; Y represents an alkoxy group; m represents a number satisfying 1.ltoreq.m.ltoreq.3; n represents a number satisfying 0.ltoreq.n.ltoreq.2; and (m+n) satisfies 1.ltoreq.(m+n).ltoreq.3.Said liquid catalyst component is used in combination with an organoaluminum compound as a catalyst system for copolymerization of ethylene with .alpha.-olefin.
摘要翻译：用于使乙烯与α-烯烃共聚的液体催化剂组分，其包含由以下通式表示的钛化合物：（R1R2N）4-（m + n）TiXmYn其中R1和R2各自表示具有8至30个碳原子的饱和烃基 ; X表示卤素; Y表示烷氧基; m表示满足1≤m≤3的数; n表示满足0≤n≤2的数; 和（m + n）满足1

5. 发明授权

US5039766A Liquid catalyst component, catalyst system containing said component and process for producing ethylene-alpha-olefin copolymer using said catalyst system 失效
标题翻译：液体催化剂组分，含有所述组分的催化剂体系和使用所述催化剂体系生产乙烯-α-烯烃共聚物的方法
公开(公告)号：US5039766A
公开(公告)日：1991-08-13
申请号：US370021
申请日：1989-06-22
申请人： Toshio Sasaki , Hirofumi Jyohouji , Yoshihiro Miyoshi , Takeshi Ebara , Kiyoshi Kawai
发明人： Toshio Sasaki , Hirofumi Jyohouji , Yoshihiro Miyoshi , Takeshi Ebara , Kiyoshi Kawai
IPC分类号： C08F4/60 , C08F4/642 , C08F210/00 , C08F210/16
CPC分类号： C08F210/16 , C08F210/18
摘要： A liquid catalyst component for copolymerization of ethylene with .alpha.-olefin comprising a titanium compound represented by the following general formula:(R.sup.1 R.sup.2 N).sub.4-(m+n) TiX.sub.m Y.sub.nwherein R.sup.1 and R.sup.2 each represents a saturated hydrocarbon group having 8 to 30 carbon atoms; X represents halogen; Y represents an alkoxy group; m represents a number satisfying 1.ltoreq.m.ltoreq.3; n represents a number satisfying 0.ltoreq.n.ltoreq.2; and (m+n) satisfies 1.ltoreq.(m+n).ltoreq.3.Said liquid catalyst component is used in combination with an organoaluminum compound as a catalyst system for copolymerization of ethylene with .alpha.-olefin.

6. 发明授权

US4916099A Solid catalyst component for olefin copolymerization and process for olefin copolymerization using said solid catalyst component 失效
标题翻译：用于烯烃共聚的固体催化剂组分和使用所述固体催化剂组分进行烯烃共聚的方法
公开(公告)号：US4916099A
公开(公告)日：1990-04-10
申请号：US237324
申请日：1988-08-29
申请人： Toshio Sasaki , Yoshihiro Miyoshi , Takeshi Ebara , Kiyoshi Kawai
发明人： Toshio Sasaki , Yoshihiro Miyoshi , Takeshi Ebara , Kiyoshi Kawai
IPC分类号： C08F4/60 , C08F4/64 , C08F4/658 , C08F10/00
CPC分类号： C08F10/00
摘要： A solid catalyst component for olefin copolymerization containing trivalent titanium compound, which is obtained by reducing a titanium compound represented by the general formula Ti(OR.sup.1).sub.n X.sub.4-n (wherein R.sup.1 is a hydrocarbon group of 1 to 20 carbon atoms, X is a halogen atom, and n is a number satisfying 0

7. 发明授权

US06835791B2 Stretched polypropylene film 有权
标题翻译：拉伸聚丙烯薄膜
公开(公告)号：US06835791B2
公开(公告)日：2004-12-28
申请号：US10314132
申请日：2002-12-09
申请人： Takeshi Ebara , Kazuki Wakamatsu
发明人： Takeshi Ebara , Kazuki Wakamatsu
IPC分类号： C08F21006
CPC分类号： C08J5/18 , B29C55/005 , B29C55/143 , B29K2023/12 , C08J2323/14 , C08L23/142 , C08L2205/02 , C08L2666/06
摘要： Disclosed is a stretched film excellent in low-temperature heat sealability after corona treatment as well as that before corona treatment and/or in heat shrinkability, the stretched film being comprised of a layer comprising a copolymer of propylene with &agr;-olefin and/or ethylene such that in measurement of a DSC curve the amount of the heat absorbed in the temperature range of from T−10 (° C.) to T+10 (° C.) accounts for from 15 to 36% of the amount of the heat absorbed in the temperature range of from 53 to 170° C., wherein T denotes a temperature (° C.) at which a maximum endothermic peak appears in the DSC curve.
摘要翻译：公开了一种在电晕处理后以及在电晕处理和/或热收缩之前的低温热封性优异的拉伸膜，拉伸膜由包含丙烯与α-烯烃和/或乙烯的共聚物的层组成使得在DSC曲线的测量中，在T-10（℃）至T + 10（℃）的温度范围内吸收的热量占热量的15至36％在53至170℃的温度范围内吸收，其中T表示在DSC曲线中出现最大吸热峰的温度（℃）。

8. 发明授权

US06639018B2 Polypropylene resin composition and process for producing the same 失效
公开(公告)号：US06639018B2
公开(公告)日：2003-10-28
申请号：US10080705
申请日：2002-02-25
申请人： Shunji Yunoki , Takeshi Ebara , Yoichi Obata
发明人： Shunji Yunoki , Takeshi Ebara , Yoichi Obata
IPC分类号： C08L2300
CPC分类号： C08L23/12 , C08F210/06 , C08L23/142 , C08L2205/02 , C08L2205/025 , C08L2314/02 , C08L2666/04 , C08F210/16 , C08F2500/17 , C08F2500/12 , C08F2500/20 , C08F210/08
摘要： A polypropylene resin composition having a melt flow rate of 0.5 to 20 g/10 min., comprising 20 to 98 parts by weight of a propylene-based polymer (A) having an intrinsic viscosity [&eegr;] measured in tetralin at 135° C. of 2.0 to 5 dl/g and a melting point Tm determined from the peak temperature of the melting curve measured by a differential scanning calorie meter of 140 to 162° C. and 2 to 80 parts by weight of a propylene-based polymer B having an intrinsic viscosity [&eegr;] measured in tetralin at 135° C. of 0.80 to 1.8 dl/g and a melting point Tm determined from the peak temperature of the melting curve measured by a differential scanning calorie meter of 160 to 166° C. and a process for producing the same.

9. 发明授权

US6127303A Process for producing olefin polymers, olefin-polymerizing catalyst and polypropylene for biaxially oriented film produced with said catalyst 失效
标题翻译：用于生产烯烃聚合物，烯烃聚合催化剂和聚丙烯用于由所述催化剂制备的双轴取向膜的方法
公开(公告)号：US6127303A
公开(公告)日：2000-10-03
申请号：US901165
申请日：1997-07-28
申请人： Takeshi Ebara , Koji Mizunuma , Toshio Sasaki , Kazuki Wakamatsu , Junichi Kimura , Yoichi Obata
发明人： Takeshi Ebara , Koji Mizunuma , Toshio Sasaki , Kazuki Wakamatsu , Junichi Kimura , Yoichi Obata
IPC分类号： C08F4/16 , C08F4/645 , C08F4/646 , C08F4/658 , C08F10/06 , C08F110/06 , B01J31/00
CPC分类号： C08F110/06 , C08F4/6465 , C08F10/06
摘要： A catalyst system for polymerizing olefins is obtainable from (A) a solid component containing (A) magnesium, titanium and halogen and an electron donative compound which is an ether or ester; (B) an organoaluminum compound, and (C) at least two electron donative compounds, including an (.alpha.) and (.beta.) compound, wherein the total amount (C) compounds is 0.01 to 1 mole per mole of (B).
摘要翻译：用于聚合烯烃的催化剂体系可从（A）含有（A）镁，钛和卤素的固体组分和作为醚或酯的给电子化合物获得; （B）有机铝化合物，和（C）至少两种给电子化合物，包括（α）和（β）化合物，其中总量（C）化合物为0.01至1摩尔/摩尔（B）。

10. 发明授权

US5258474A Process for producing .alpha.-olefin polymer 失效
公开(公告)号：US5258474A
公开(公告)日：1993-11-02
申请号：US945927
申请日：1992-09-17
申请人： Toshio Sasaki , Hirofumi Jyohouji , Takeshi Ebara , Kiyoshi Kawai
发明人： Toshio Sasaki , Hirofumi Jyohouji , Takeshi Ebara , Kiyoshi Kawai
IPC分类号： C08F4/651 , C08F10/00 , C08F4/654 , C08F4/656
CPC分类号： C08F10/00
摘要： A process for producing an .alpha.-olefin polymer which comprises polymerizing an .alpha.-olefin in the presence of a catalyst system comprising(A) a solid catalyst component containing at least titanium, magnesium, halogen, and electron donor and(B) a sterically hindered aluminum amide compound represented by the general formula ##STR1## wherein, R.sup.1 through R.sup.5 denote each a hydrocarbon group of 1 to 20 carbon atoms, L denotes an alkoxy group of 1 to 20 carbon atoms and/or halogen, l is 2 or 3, x is defined by 0

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