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    • 3. 发明授权
    • Composite hollow fiber-type separation membranes, processes for the
preparation thereof and their use
    • 复合中空纤维型分离膜,其制备方法及其应用
    • US4664669A
    • 1987-05-12
    • US584321
    • 1984-02-28
    • Shuzo OhyabuSyuji KawaiTakehiko OkamotoTakao Migaki
    • Shuzo OhyabuSyuji KawaiTakehiko OkamotoTakao Migaki
    • D01F8/04B01D69/02B01D69/08B01D69/12B01D71/68B01D71/70D06M15/643D06M101/00D06M101/16D06M101/30A61F2/00
    • B01D69/08B01D69/02B01D69/12Y10S623/92Y10T428/249953
    • A composite hollow fiber type separation membrane which has three layers comprising a selective separation layer, an ultra-microporous layer and a porous layer, said selective separation layer, said ultra-microporous layer, said porous layer being arranged in said order commencing from the inner surface of said hollow fiber membrane;wherein said selective separation layer is formed on said ultra-microporous layer without penetrating into said ultra-microporous layer and has a non-porous, dense structure, the average thickness of said layer being 0.01-2.mu., and the coefficient of variation in thickness thereof being less than or equal to 25%;wherein said ultra-microporous layer has a surface in which the presence of pores cannot be confirmed by 24,000 .times. scanning electron microscopy, but which has a fluid permeability at least 10 times that of said selective separation layer, the thickness of said layer being less than or equal to 0.08.mu.; andwherein said porous layer is a sponge structure comprising pores having a pore diameter of 0.1-1.mu. except for macro-voids and having a porosity of at least 50%, the thickness of said layer being 10-500.mu..
    • 一种复合中空纤维型分离膜,其具有包括选择性分离层,超微孔层和多孔层的三层,所述选择性分离层,所述超微孔层,所述多孔层以从所述内层 所述中空纤维膜的表面; 其中所述选择性分离层形成在所述超微孔层上,而不会渗入所述超微孔层并具有无孔,致密结构,所述层的平均厚度为0.01-2μm,厚度变化系数 小于或等于25%; 其特征在于,所述超微孔层具有不能通过24000×扫描电子显微镜确认孔的存在的表面,但是其流体渗透率为所述选择性分离层的至少10倍,所述层的厚度小于 或等于0.08亩; 并且其中所述多孔层是海绵结构,其包含孔径为0.1-1μm的孔,除了大孔隙,并且孔隙率为至少50%,所述层的厚度为10-500μm。
    • 6. 发明授权
    • Method for producing impact resistant thermoplastic resin by continuous
bulk polymerization
    • 通过连续本体聚合制备耐冲击热塑性树脂的方法
    • US3981944A
    • 1976-09-21
    • US478535
    • 1974-06-12
    • Takehiko OkamotoAkihiko KishimotoIkuo NagaiHiroshi SatoHotsuma OkasakaMasakazu Inoue
    • Takehiko OkamotoAkihiko KishimotoIkuo NagaiHiroshi SatoHotsuma OkasakaMasakazu Inoue
    • C08F2/02C08F279/02C08F285/00C08L9/02C08L9/06
    • C08F285/00C08F279/02
    • A method is provided for continuously manufacturing high impact strength thermoplastic resins comprised of the sequential steps of (a) bulk-polymerizing a monomer solution, which contains a diene type rubber polymer or a graft polymer obtained by extracting the rubber polymer particle or vinyl monomer grafted polymer particle in latex with vinyl monomers which contain 5-20 percent by weight of water at a temperature of 85.degree.-135.degree.C, while continuously stirring the solution, vaporizing the volatile components, condensing the volatile component and recycling them back to reaction mixture, until the solid content in the reaction mixture reaches 40-75 percent by weight, and thereafter (b) bulk polymerizing the resulting prepolymer solution under the condition that plug-flowing can be attained with a temperature gradient 100.degree.-170.degree.C at the top of the reaction vessel and 170.degree.-270.degree.C at the bottom thereof, while the volatile component of the mixture are evaporated off, condensed and recycled to the reaction mixture, until the solid content is at least 90 percent by weight.
    • 提供一种用于连续制造高冲击强度热塑性树脂的方法,其包括以下顺序步骤:(a)将含有二烯型橡胶聚合物的单体溶液本体聚合或通过萃取橡胶聚合物颗粒或乙烯基单体接枝而获得的接枝聚合物 乙烯基单体的聚合物颗粒在85℃-135℃的温度下含有5-20重量%的水,同时连续搅拌该溶液,蒸发挥发性组分,将挥发性组分冷凝并回收到反应混合物中 直到反应混合物中的固体含量达到40-75重量%,然后(b)在100-170℃的温度梯度下,在可以实现堵塞流动的条件下将所得预聚物溶液本体聚合 反应容器的顶部和底部为170℃-270℃,同时将混合物的挥发性组分蒸发掉 并将其再循环到反应混合物中,直到固体含量为至少90重量%。
    • 7. 发明授权
    • Filtration apparatus using hollow fiber membrane
    • 中空纤维膜过滤装置
    • US4547289A
    • 1985-10-15
    • US584118
    • 1984-02-27
    • Yoshihiro OkanoTakehiko OkamotoAkio Ohmory
    • Yoshihiro OkanoTakehiko OkamotoAkio Ohmory
    • B01D63/02B01D65/10B01D31/00
    • B01D65/102B01D63/024B01D2313/21
    • A filtration apparatus for removing undesirable components from a solution to be treated, comprises a module in which a number of hollow fibers are fixed at one end thereof by cast-molding materials, and is opened at the end portion above described and closed at another end portion thereof, in which said solution to be treated can be kept from leaking out of a mechanically sealed portion. Any defect in the sealed portion can be detected from the outside by the provision of an opening which leads the leaked solution to the outside of the apparatus, instead of allowing it to combine with the filtrate. The apparatus is preferably used for the manufacture of purified water which is free from bacteria, pyrogene, and the like. Ultra-purified water of remarkably high purity can be obtained when the apparatus is used as a check filter in a process for manufacturing ultra-purified water.
    • 用于从待处理溶液中除去不希望的组分的过滤装置包括其中多个中空纤维在其一端通过铸塑材料固定的模块,并且在另一端的上述端部处封闭 其中所述待处理溶液可以防止从机械密封部分泄漏。 通过设置将泄漏溶液引导到设备外部的开口,可以从外部检测密封部分中的任何缺陷,而不是允许其与滤液结合。 该装置优选用于制造不含细菌,焦炉等的净化水。 当在超纯水制造过程中将该装置用作检查过滤器时,可以获得非常高纯度的超纯水。