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    • 1. 发明申请
    • INTERMEDIATE TRANSFER BELT
    • 中间转移带
    • US20120128953A1
    • 2012-05-24
    • US13388784
    • 2010-08-04
    • Takashi KuraokaSatoshi MitsuiYuuki Matsumura
    • Takashi KuraokaSatoshi MitsuiYuuki Matsumura
    • B32B25/08B32B38/18
    • B32B5/145B32B7/02B32B7/12B32B27/08B32B27/20B32B27/281B32B27/304B32B27/40B32B2250/03B32B2250/04B32B2250/24B32B2264/102B32B2264/104B32B2264/108B32B2274/00B32B2305/30B32B2307/536B32B2307/54B32B2307/554B32B2413/00B32B2559/00G03G15/162G03G15/1685Y10T428/24967
    • A main object of the present invention is to provide an intermediate transfer belt for image-forming devices and a method for producing the intermediate transfer belt, the intermediate transfer belt having excellent image transfer to rough paper and resistance to abrasion and being free from problems such as filming, by forming a surface layer that has excellent resistance to abrasion and in which defects such as pinholes are not likely to occur even when the surface layer is thinned.An intermediate transfer belt for image-forming devices and a method for producing the same, the intermediate transfer belt comprising at least the following three layers laminated in the described order: (a) a base layer formed from resin, (b) a rubber-elastic layer formed from a rubber or elastomer, having a thickness of 200 to 400 μm and (c) a surface layer formed from resin, having a thickness of 0.5 to 6 μm, wherein the intermediate transfer belt has the following properties: (i) the dynamic ultramicro hardness (ISO14577-1) measured from the surface layer side is 2.5 to 4.5 N/mm2 at the indentation depth of 2 μm, and 1.0 N/mm2 or less at the indentation depth of 10 μm, and/or (ii) the rubber-elastic layer contains a filler in a proportion of 0.4 to 4.0 vol. %, and the ratio (M1/M3) of the mass concentration M1 of the filler in the region from the interface between the surface layer and the rubber-elastic layer toward the base layer to a depth of 20 μm, to the mass concentration M3 of the filler in the region from 120 μm to 140 μm in depth from the interface between the surface layer and the rubber-elastic layer toward the base layer is 1.3 or higher.
    • 本发明的主要目的在于提供一种用于成像装置的中间转印带和中间转印带的制造方法,该中间转印带具有优异的图像转印到粗糙纸和耐磨性,并且没有这样的问题 作为成膜,通过形成具有优异的耐磨性的表面层,即使表面层变薄也不易发生诸如针孔的缺陷。 一种用于成像装置的中间转印带及其制造方法,所述中间转印带至少包括以下顺序层叠的三层:(a)由树脂形成的基层,(b)橡胶 - 弹性层由厚度为200〜400μm的橡胶或弹性体形成,(c)由树脂形成的表层,厚度为0.5〜6μm,其中中间转印带具有以下性质:(i) 表面层侧的动态超微硬度(ISO14577-1)在压痕深度为2μm时为2.5〜4.5N / mm 2,在压痕深度为10μm时为1.0N / mm2以下,和/或(ii )橡胶弹性层含有比例为0.4〜4.0体积%的填料。 %,以及从表面层和橡胶弹性层之间的界面朝向基底层到20μm的深度的区域中填料的质量浓度M1与质量浓度M3的比(M1 / M3) 在表面层和橡胶弹性层之间的界面朝向基底层的深度为120μm至140μm的区域中的填料为1.3或更高。
    • 5. 发明授权
    • Semielectroconductive polyimide resin belt and process for producing semielectroconductive polyimide resin belt
    • 半导电聚酰亚胺树脂带和半导电聚酰亚胺树脂带的制造方法
    • US08506848B2
    • 2013-08-13
    • US12734874
    • 2008-11-27
    • Akira IchinoNaoki NishiuraTakashi Kuraoka
    • Akira IchinoNaoki NishiuraTakashi Kuraoka
    • H01B1/04H01B1/24G03G15/00
    • C08G73/1046C08G73/105C08G73/1064C08G73/1067C08G73/1071C08K3/04C08L79/08G03G15/162G03G2215/1623
    • A semiconductive polyimide resin belt that exhibits excellent electrical properties, including the ability to achieve accurate image transfer in a color image-forming unit, and the ability to prevent variations in resistance due to the transfer voltage, enabling high-quality transfer images to be stably produced over an extended period of time; and excellent physical properties, including resistance to deterioration in flatness due to plastic deformation caused by loads applied in the width direction of the belt, excellent durability, and stable operation even after extended use; and an intermediate transfer belt made of the semiconductive polyimide resin belt. The semiconductive polyimide resin belt comprises carbon black and a polyimide resin. The polyimide resin is obtained by imidization of terphenyl-3,3′,4,4′-tetracarboxylic dianhydride and an aromatic diamine component containing 50 mol % or more of an aromatic diamine having 3 and/or 4 aromatic rings based on a total amount of the aromatic diamine component.
    • 具有优异的电性能的半导体聚酰亚胺树脂带,包括在彩色图像形成单元中实现精确图像转印的能力以及防止由于转印电压引起的电阻变化的能力,使得高质量的转印图像能够稳定 长时间生产; 具有优异的物理性能,包括由于在带的宽度方向上施加的载荷引起的塑性变形而导致的平坦度劣化,耐久性优异,即使在长时间使用后也能稳定运行; 和由半导电聚酰亚胺树脂带制成的中间转印带。 半导电性聚酰亚胺树脂带包含炭黑和聚酰亚胺树脂。 聚酰亚胺树脂通过三联苯-3,3',4,4'-四羧酸二酐和含有50mol%以上芳香族二胺的芳族二胺组分的酰亚胺化而得到,所述芳族二胺具有3和/或4个芳环,基于总量 的芳族二胺组分。
    • 6. 发明申请
    • SEMIELECTROCONDUCTIVE POLYIMIDE RESIN BELT AND PROCESS FOR PRODUCING SEMIELECTROCONDUCTIVE POLYIMIDE RESIN BELT
    • 半导体聚酰亚胺树脂带和生产半导体聚酰亚胺树脂带的方法
    • US20100329751A1
    • 2010-12-30
    • US12734874
    • 2008-11-27
    • Akira IchinoNaoki NishiuraTakashi Kuraoka
    • Akira IchinoNaoki NishiuraTakashi Kuraoka
    • G03G15/14B29C39/08H01B1/24
    • C08G73/1046C08G73/105C08G73/1064C08G73/1067C08G73/1071C08K3/04C08L79/08G03G15/162G03G2215/1623
    • An object of the present invention is to provide a semiconductive polyimide resin belt that exhibits electrical properties, including the ability to achieve accurate image transfer in a color image-forming unit, and the ability to prevent variations in resistance due to the transfer voltage, enabling high-quality transfer images to be stably produced over an extended period of time; and physical properties, including resistance to deterioration in flatness due to plastic deformation caused by loads applied in the width direction of the belt, excellent durability, and stable operation even after extended use; and more particularly, to provide an intermediate transfer belt made of the semiconductive polyimide resin belt. The semiconductive polyimide resin belt comprises carbon black and a polyimide resin. The polyimide resin is obtained by imidization of terphenyl-3,3′,4,4′-tetracarboxylic dianhydride and an aromatic diamine component, the aromatic diamine component containing 50 mol % or more of an aromatic diamine having 3 and/or 4 aromatic rings based on a total amount of the aromatic diamine component.
    • 本发明的目的是提供一种具有电性能的半导电聚酰亚胺树脂带,其包括在彩色图像形成单元中实现精确的图像转印的能力,以及防止由于转印电压引起的电阻变化的能力,使得能够 高质量的传输图像能够在长时间内稳定地生产; 物理性能,包括由于在带的宽度方向上施加的载荷引起的塑性变形导致的平坦度劣化,耐久性优异,即使在长时间使用后也能够稳定地工作; 并且更具体地,提供由半导电聚酰亚胺树脂带制成的中间转印带。 半导电性聚酰亚胺树脂带包含炭黑和聚酰亚胺树脂。 聚酰亚胺树脂通过三联苯-3,3',4,4'-四羧酸二酐和芳族二胺组分的酰亚胺化获得,芳族二胺组分含有50mol%或更多具有3个和/或4个芳环的芳族二胺 基于芳族二胺组分的总量。
    • 9. 发明授权
    • Carbon black-dispersed polyamic acid solution composition, and process for producing semiconductive polyimide resin belt therewith
    • 炭黑分散聚酰胺酸溶液组合物及其半导体聚酰亚胺树脂带的制造方法
    • US08303852B2
    • 2012-11-06
    • US12441980
    • 2007-09-18
    • Naoki NishiuraTakashi KuraokaToru Murakami
    • Naoki NishiuraTakashi KuraokaToru Murakami
    • H01B1/06H01B1/24
    • B29C41/04G03G15/162
    • A carbon black-dispersed polyamic acid solution composition that utilizes carbon black excelling in safety and environmental adaptability and excels in the dispersion stability and fluidity of carbon black dispersed in polyamic acid solution, and that realizes high solid content and high carbon black content. An intermediate transfer belt of polyimide, which produces a transfer image of high quality in a color image-forming apparatus, produced from the polyamic acid solution composition. In particular, a carbon black-dispersed polyamic acid solution composition containing a polyamic acid solution obtained by reaction of approximately equimolar amounts of biphenyltetracarboxylic acid dianhydride and an aromatic diamine, and containing a carbon black of 2 to 6% volatile content produced by oil furnace process, wherein the solid content of the solution composition is 23 wt. % or more and wherein the carbon black content of the solid is in the range of 20 to 30 wt. %.
    • 炭黑分散的聚酰胺酸溶液组合物,其利用安全性和环境适应性优异的炭黑,并且分散在聚酰胺酸溶液中的炭黑的分散稳定性和流动性优异,并且实现高固含量和高炭黑含量。 一种聚酰亚胺的中间转印带,其由聚酰胺酸溶液组合物制成,其在彩色成像装置中产生高质量的转印图像。 特别是含有通过大约等摩尔量的联苯四羧酸二酐与芳香族二胺反应而得到的聚酰胺酸溶液并含有通过油炉法制造的挥发分含量为2〜6%的炭黑的炭黑分散聚酰胺酸溶液组合物 ,其中所述溶液组合物的固体含量为23重量%。 %以上,其中固体的炭黑含量在20〜30重量%的范围内。 %。