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    • 3. 发明授权
    • Semielectroconductive polyimide resin belt and process for producing semielectroconductive polyimide resin belt
    • 半导电聚酰亚胺树脂带和半导电聚酰亚胺树脂带的制造方法
    • US08506848B2
    • 2013-08-13
    • US12734874
    • 2008-11-27
    • Akira IchinoNaoki NishiuraTakashi Kuraoka
    • Akira IchinoNaoki NishiuraTakashi Kuraoka
    • H01B1/04H01B1/24G03G15/00
    • C08G73/1046C08G73/105C08G73/1064C08G73/1067C08G73/1071C08K3/04C08L79/08G03G15/162G03G2215/1623
    • A semiconductive polyimide resin belt that exhibits excellent electrical properties, including the ability to achieve accurate image transfer in a color image-forming unit, and the ability to prevent variations in resistance due to the transfer voltage, enabling high-quality transfer images to be stably produced over an extended period of time; and excellent physical properties, including resistance to deterioration in flatness due to plastic deformation caused by loads applied in the width direction of the belt, excellent durability, and stable operation even after extended use; and an intermediate transfer belt made of the semiconductive polyimide resin belt. The semiconductive polyimide resin belt comprises carbon black and a polyimide resin. The polyimide resin is obtained by imidization of terphenyl-3,3′,4,4′-tetracarboxylic dianhydride and an aromatic diamine component containing 50 mol % or more of an aromatic diamine having 3 and/or 4 aromatic rings based on a total amount of the aromatic diamine component.
    • 具有优异的电性能的半导体聚酰亚胺树脂带,包括在彩色图像形成单元中实现精确图像转印的能力以及防止由于转印电压引起的电阻变化的能力,使得高质量的转印图像能够稳定 长时间生产; 具有优异的物理性能,包括由于在带的宽度方向上施加的载荷引起的塑性变形而导致的平坦度劣化,耐久性优异,即使在长时间使用后也能稳定运行; 和由半导电聚酰亚胺树脂带制成的中间转印带。 半导电性聚酰亚胺树脂带包含炭黑和聚酰亚胺树脂。 聚酰亚胺树脂通过三联苯-3,3',4,4'-四羧酸二酐和含有50mol%以上芳香族二胺的芳族二胺组分的酰亚胺化而得到,所述芳族二胺具有3和/或4个芳环,基于总量 的芳族二胺组分。
    • 5. 发明申请
    • SEMIELECTROCONDUCTIVE POLYIMIDE RESIN BELT AND PROCESS FOR PRODUCING SEMIELECTROCONDUCTIVE POLYIMIDE RESIN BELT
    • 半导体聚酰亚胺树脂带和生产半导体聚酰亚胺树脂带的方法
    • US20100329751A1
    • 2010-12-30
    • US12734874
    • 2008-11-27
    • Akira IchinoNaoki NishiuraTakashi Kuraoka
    • Akira IchinoNaoki NishiuraTakashi Kuraoka
    • G03G15/14B29C39/08H01B1/24
    • C08G73/1046C08G73/105C08G73/1064C08G73/1067C08G73/1071C08K3/04C08L79/08G03G15/162G03G2215/1623
    • An object of the present invention is to provide a semiconductive polyimide resin belt that exhibits electrical properties, including the ability to achieve accurate image transfer in a color image-forming unit, and the ability to prevent variations in resistance due to the transfer voltage, enabling high-quality transfer images to be stably produced over an extended period of time; and physical properties, including resistance to deterioration in flatness due to plastic deformation caused by loads applied in the width direction of the belt, excellent durability, and stable operation even after extended use; and more particularly, to provide an intermediate transfer belt made of the semiconductive polyimide resin belt. The semiconductive polyimide resin belt comprises carbon black and a polyimide resin. The polyimide resin is obtained by imidization of terphenyl-3,3′,4,4′-tetracarboxylic dianhydride and an aromatic diamine component, the aromatic diamine component containing 50 mol % or more of an aromatic diamine having 3 and/or 4 aromatic rings based on a total amount of the aromatic diamine component.
    • 本发明的目的是提供一种具有电性能的半导电聚酰亚胺树脂带,其包括在彩色图像形成单元中实现精确的图像转印的能力,以及防止由于转印电压引起的电阻变化的能力,使得能够 高质量的传输图像能够在长时间内稳定地生产; 物理性能,包括由于在带的宽度方向上施加的载荷引起的塑性变形导致的平坦度劣化,耐久性优异,即使在长时间使用后也能够稳定地工作; 并且更具体地,提供由半导电聚酰亚胺树脂带制成的中间转印带。 半导电性聚酰亚胺树脂带包含炭黑和聚酰亚胺树脂。 聚酰亚胺树脂通过三联苯-3,3',4,4'-四羧酸二酐和芳族二胺组分的酰亚胺化获得,芳族二胺组分含有50mol%或更多具有3个和/或4个芳环的芳族二胺 基于芳族二胺组分的总量。
    • 8. 发明授权
    • Carbon black-dispersed polyamic acid solution composition, and process for producing semiconductive polyimide resin belt therewith
    • 炭黑分散聚酰胺酸溶液组合物及其半导体聚酰亚胺树脂带的制造方法
    • US08303852B2
    • 2012-11-06
    • US12441980
    • 2007-09-18
    • Naoki NishiuraTakashi KuraokaToru Murakami
    • Naoki NishiuraTakashi KuraokaToru Murakami
    • H01B1/06H01B1/24
    • B29C41/04G03G15/162
    • A carbon black-dispersed polyamic acid solution composition that utilizes carbon black excelling in safety and environmental adaptability and excels in the dispersion stability and fluidity of carbon black dispersed in polyamic acid solution, and that realizes high solid content and high carbon black content. An intermediate transfer belt of polyimide, which produces a transfer image of high quality in a color image-forming apparatus, produced from the polyamic acid solution composition. In particular, a carbon black-dispersed polyamic acid solution composition containing a polyamic acid solution obtained by reaction of approximately equimolar amounts of biphenyltetracarboxylic acid dianhydride and an aromatic diamine, and containing a carbon black of 2 to 6% volatile content produced by oil furnace process, wherein the solid content of the solution composition is 23 wt. % or more and wherein the carbon black content of the solid is in the range of 20 to 30 wt. %.
    • 炭黑分散的聚酰胺酸溶液组合物,其利用安全性和环境适应性优异的炭黑,并且分散在聚酰胺酸溶液中的炭黑的分散稳定性和流动性优异,并且实现高固含量和高炭黑含量。 一种聚酰亚胺的中间转印带,其由聚酰胺酸溶液组合物制成,其在彩色成像装置中产生高质量的转印图像。 特别是含有通过大约等摩尔量的联苯四羧酸二酐与芳香族二胺反应而得到的聚酰胺酸溶液并含有通过油炉法制造的挥发分含量为2〜6%的炭黑的炭黑分散聚酰胺酸溶液组合物 ,其中所述溶液组合物的固体含量为23重量%。 %以上,其中固体的炭黑含量在20〜30重量%的范围内。 %。
    • 10. 发明授权
    • Electrically-semiconductive poly(amic acid) liquid compositions and their use
    • 电半导体聚(酰胺酸)液体组合物及其用途
    • US06303054B1
    • 2001-10-16
    • US09638343
    • 2000-08-14
    • Junya KanetakeTsutomu YoshidaNaoki NishiuraTsuneo MiyamotoTakashi Kuraoka
    • Junya KanetakeTsutomu YoshidaNaoki NishiuraTsuneo MiyamotoTakashi Kuraoka
    • H01B124
    • H01B1/24
    • The present invention provides an electrically-semiconductive poly(amic acid) liquid composition and a use thereof. An electrically-semiconductive poly(amic acid) (polyimide precursor) liquid composition whose electrical semiconductivity is applied by comprising an electrically-conductive carbon black. Change in an electrical resistivity of the liquid composition after being stored for 180 days at a temperature of 23° C. and in an atmosphere of a RH of 65% is 7% or less based on the electrical resistivity immediately after the preparation of the liquid composition. The electrically-semiconductive poly(amic acid) liquid composition is obtainable by mixing 5-40 parts by weight of a poly(amic acid), 95-60 parts by weight of an organic polar solvent and 10-40% by weight based on the poly(amic acid) of an electrically-conductive carbon black having a volatile content of 5-20%, a specific surface area of 100-300 m2/g and a pH of 2-4. The electrically-semiconductive poly(amic acid) liquid composition is used for molding an electrically-semiconductive seamless tubular polyimide film, for example, which is usable as an intermediate belt member for fixation and transfer of toner in a copying machine.
    • 本发明提供一种电半导体聚(酰胺酸)液体组合物及其用途。 通过包含导电炭黑施加电半导电性的电半导体聚(酰胺酸)(聚酰亚胺前体)液体组合物。 在液体组合物在23℃的温度下和RH的65%的气氛中储存180天后的电阻率的变化基于在制备液体之后的电阻率为7%以下 组成。 电半导体聚(酰胺酸)液体组合物可通过将5-40重量份的聚(酰胺酸),95-60重量份的有机极性溶剂和10-40重量%的混合物 挥发物含量为5-20%,比表面积为100-300m2 / g,pH为2-4的导电性炭黑的聚(酰胺酸)。 电半导体聚(酰胺酸)液体组合物用于模制例如可用作在复印机中定影和转印调色剂的中间带构件的电半导体无缝管状聚酰亚胺膜。