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    • 2. 发明授权
    • High-pressure phase boron nitride base sinter
    • 高压相氮化硼基烧结矿
    • US6008153A
    • 1999-12-28
    • US101742
    • 1998-07-16
    • Satoru KukinoTetsuo NakaiJunichi ShiraishiTomohiro FukayaShinya Uesaka
    • Satoru KukinoTetsuo NakaiJunichi ShiraishiTomohiro FukayaShinya Uesaka
    • C04B35/5831C04B35/5835
    • C04B35/5831
    • A high-pressure phase boron nitride-based high-hardness high-strength sintered body for cutting tools represented by a milling tool and an end mill etc., which is improved in wear resistance and chipping resistance, is obtained. The high-pressure phase boron nitride-based sintered body according to the present invention comprises a plurality of grains (1) of high-pressure phase boron nitride and a binder phase (2, 3), and the content of the aforementioned grains (1) is at least 20.0 volume % and not more than 99.7 volume %. The aforementioned binder phase (2, 3) includes a first binder phase (2) enclosing the aforementioned grains (1) and a second binder phase (3) other than that. The first binder phase (2) consists of the form of at least either a nitride of at least one of Ti, TiAl, Zr and Hf or a solid solution thereof. The aforementioned second binder phase (3) includes a grain growth suppressive binder phase (4) between a plurality of the aforementioned grains (1) enclosed with the aforementioned first binder phase (2).
    • PCT No.PCT / JP97 / 04410 Sec。 371日期:1998年7月16日 102(e)日期1998年7月16日PCT 1997年12月3日PCT PCT。 出版物WO98 / 24736 日期1998年6月11日获得了耐磨性和耐崩裂性提高的用于切削工具的高压相氮化硼系高硬度高强度烧结体。 根据本发明的高压相氮化硼基烧结体包括多个高压相氮化硼颗粒(1)和粘结相(2,3),并且上述颗粒(1)的含量 )为20.0体积%以上且99.7体积%以下。 上述粘合剂相(2,3)包括包围上述颗粒(1)的第一粘结相(2)和除此之外的第二粘结相(3)。 第一粘合剂相(2)由至少一种Ti,TiAl,Zr和Hf的氮化物或其固溶体的形式组成。 上述第二粘结相(3)包括在由上述第一粘结相(2)包围的多个上述颗粒(1)之间的晶粒生长抑制粘合剂相(4)。
    • 3. 发明授权
    • Hard and tough sintered body
    • 坚硬坚韧的烧结体
    • US6001758A
    • 1999-12-14
    • US960773
    • 1997-10-30
    • Tomohiro FukayaTetsuo NakaiJunichi ShiraishiSatoru KukinoShinya Uesaka
    • Tomohiro FukayaTetsuo NakaiJunichi ShiraishiSatoru KukinoShinya Uesaka
    • C04B35/5831C04B35/5835
    • C04B35/5831
    • A sintered body consists of high-pressure phase boron nitride, a residual binder phase and an unavoidable impurity, and contains high-pressure phase boron nitride powder which is previously coated with a binder before sintering. The coating binder consists of an element belonging to the group 4a, 5a or 6a of the periodic table or the like, and has an average thickness of 5 to 300 nm. Binder powder other than the coating binder consists of an element belonging to the group 4a, 5a or 6a of the periodic table or the like, and a contact ratio of high-pressure phase boron nitride particles in surface-to-surface contact with each other is at least 20% and less than 50%. The resulting high-pressure phase boron nitride-based hard and tough sintered body for a cutting tool is improved in wear resistance and chipping resistance.
    • 烧结体由高压相氮化硼,残余粘结相和不可避免的杂质组成,并且包含预先在烧结之前用粘合剂涂覆的高压相氮化硼粉末。 涂层粘合剂由属于周期表等的4a,5a或6a族元素组成,平均厚度为5〜300nm。 涂层粘合剂以外的粘合剂粉末由属于周期表等的4a,5a或6a族的元素组成,高压相氮化硼颗粒在表面与表面之间接触的接触比 至少为20%且小于50%。 所得到的用于切削工具的高压相氮化硼基硬坚韧烧结体的耐磨性和耐崩裂性提高。
    • 6. 发明授权
    • High strength sintered impact having excellent resistance to cratering
    • 高强度烧结冲击具有优异的耐火蚀性
    • US06635593B1
    • 2003-10-21
    • US09913265
    • 2001-08-10
    • Satoru KukinoTomohiro FukayaJunichi ShiraishiTetsuo Nakai
    • Satoru KukinoTomohiro FukayaJunichi ShiraishiTetsuo Nakai
    • C04B355831
    • C04B35/5831Y10T407/27
    • A sintered material containing high-pressure phase-type boron nitride and a binder is provided. The high-pressure phase-type boron nitride is contained in an amount of from 50% to 78% by volume, and the balance is a binder phase. The binder phase comprises at least one selected from the group consisting of nitride, carbide, carbonitride, and boride of Ti, nitride, boride and oxide of Al, carbide and boride of W, nitride, carbide, carbonitride and boride of Co, and carbide and boride of Ni, or a mutual solid solution thereof. The binder phase forms a binder phase which is continuous in a sintered material texture. The weight of metal components Al, W, Co and Ni which are present as compounds in the sintered material is from 3% to 20% based on the sintered material. The sintered material is excellent in crater resistance and capable of realizing a long tool life, even under the condition that the temperature of the cutting edge becomes high and the impact is large, as in high-speed interrupted cutting of hardened steel where the cutting speed V becomes at least 150 m/min.
    • 提供含有高压相型氮化硼和粘合剂的烧结材料。 高压相型氮化硼的含量为50〜78体积%,余量为粘结相。 粘结相包括选自Ti,氮化物,硼化物和Al的氧化物的氮化物,碳化物,碳氮化物和硼化物中的至少一种,W,氮化物,碳化物,碳氮化物和Co的硼化物的碳化物和硼化物,以及碳化物 和Ni的硼化物或其相互固溶体。 粘结相形成在烧结材料结构中连续的粘结相。 烧结材料中作为化合物存在的金属成分Al,W,Co,Ni的重量相对于烧结体为3〜20%。 该烧结材料即使在切削刃的温度高,冲击大的条件下也能够实现长的刀具寿命,因为在切削速度高的淬火钢的高速切断切削中 V变为至少150m / min。
    • 8. 发明授权
    • Sintered body for high-hardness tools
    • 烧结体用于高硬度工具
    • US5596156A
    • 1997-01-21
    • US529639
    • 1995-09-18
    • Tomohiro FukayaTetsuo Nakai
    • Tomohiro FukayaTetsuo Nakai
    • C22C29/16B01J3/06B22F3/14B22F3/15C22C1/05C22C26/00C22C29/04
    • C22C26/00B01J3/062B01J2203/0645B01J2203/066B01J2203/0685C22C2026/005
    • The invention provides a sintered body for high-hardness tools which, when used for cutting work of cast irons where the cutting edge undergoes high temperature and abrupt impact, holds high chip-off and abrasion resistances and exhibits good cutting performance. The sintered body for high-hardness tools is obtained by sintering 60 to 75% by volume of cubic boron nitride powder and remaining part of a binder powder under a superhigh pressure, the binder comprising 5 to 15% by weight of Al, and the remaining part comprising a compound represented by (Hf.sub.X Ti.sub.y M.sub.1-x-y)(C.sub.Z N.sub.1-z).sub..alpha. (where M denotes an element belonging to IVa, Va or VIa group in the periodic table except Ti and Hf, and where 0.1.ltoreq.x.ltoreq.0.5, 0.5.ltoreq.y.ltoreq.0.9, 0.7.ltoreq.z.ltoreq.0.9, and 0.6.ltoreq..alpha..ltoreq.0.8) or a mixture of a plurality of compounds that totally results in the aforementioned composition.
    • 本发明提供一种用于高硬度工具的烧结体,当用于切割边缘经受高温和突然冲击的铸铁的切割工作时,其具有高的切屑和耐磨性,并且具有良好的切削性能。 用于高硬度工具的烧结体通过在超高压下烧结60至75体积%的立方氮化硼粉末和剩余部分粘合剂粉末而获得,粘合剂包含5至15重量%的Al,剩余的 部分包括由(HfX y y 1-xy)(CZN 1-z)α表示的化合物(其中M表示除了Ti和Hf之外的元素周期表中属于IVa,Va或VIa基团的元素,其中0.1 < 0.5,0.5≤y≤0.9,0.7≤z≤0.9,0.6≤α≤0.8)或多个化合物的混合物,其总体上导致上述组成。