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1. 发明授权

US6004478A Silacyclohexane compounds, preparation thereof, liquid crystal compositions comprising the same, and liquid crystal devices comprising the composition 失效
标题翻译：硅环己烷化合物，其制备方法，含有它们的液晶组合物和包含该组合物的液晶装置
公开(公告)号：US6004478A
公开(公告)日：1999-12-21
申请号：US616384
申请日：1996-03-15
申请人： Takaaki Shimizu , Tsutomu Ogihara , Tatsushi Kaneko , Kazuyuki Asakura , Takeshi Kinsho , Mutsuo Nakashima
发明人： Takaaki Shimizu , Tsutomu Ogihara , Tatsushi Kaneko , Kazuyuki Asakura , Takeshi Kinsho , Mutsuo Nakashima
IPC分类号： C07F7/08 , C07F7/12 , C09K19/40 , C09K19/42 , C09K19/34 , C09K19/30
CPC分类号： C09K19/406 , C07F7/0818 , C07F7/0896 , C07F7/12 , C09K19/42
摘要： A silacyclohexane compound of the formulas (I) ##STR1## wherein R represents an organic residue, ##STR2## represents an unsubstituted or substituted silicon-containing cyclohexylene group or a 1,4-cyclohexylene group, ##STR3## represents an unsubstituted or substituted phenylene, an unsubstituted or substituted silicon-containing cyclohexylene group or trans-4-sila-1,4-cyclohexylene group, or a 1,4-cyclohexylene group provided that at least one of these residues represents a silicon-containing cyclohexylene group, j, k and l are, respectively, 0 or 1, L.sub.1 and L.sub.2, respectively, represent H or F, m and n are, respectively, 0, 1 or 2 provided that m+n=2, 3 or 4, and X represents H, F or Cl. A liquid crystal composition comprising the silacyclohexane compound of the above formula is also described, along with a liquid crystal device comprising the composition.
摘要翻译：式（I）的硅环己烷化合物，其中R表示有机残基，表示未取代或取代的含硅亚环己基或1,4-亚环己基，表示未取代或取代的亚苯基，未取代或取代的含硅亚环己基基团或反式-4-硅烷-1,4-亚环己基或1,4-亚环己基，条件是这些残基中的至少一个表示含硅的亚环己基，j，k和l分别为0或 1，L1和L2分别表示H或F，m和n分别为0,1或2，条件是m + n = 2,3或4，X表示H，F或Cl。还描述了包含上式的硅环己烷化合物的液晶组合物以及包含该组合物的液晶装置。

2. 发明授权

US5762826A Liquid crystal composition and a liquid crystal display element which contains it 失效
标题翻译：液晶组合物和含有它的液晶显示元件
公开(公告)号：US5762826A
公开(公告)日：1998-06-09
申请号：US576319
申请日：1995-12-21
申请人： Takaaki Shimizu , Tatsushi Kaneko , Tsutomu Ogihara , Takeshi Kinsho , Kazuyuki Asakura , Mutsuo Nakashima
发明人： Takaaki Shimizu , Tatsushi Kaneko , Tsutomu Ogihara , Takeshi Kinsho , Kazuyuki Asakura , Mutsuo Nakashima
IPC分类号： C09K19/40 , C09K19/34 , C09K19/30
CPC分类号： C09K19/406
摘要： A liquid crystal composition comprising one or more types compounds represented by general formula II: ##STR1## and one or more types of compounds selected from the group consisting of: ##STR2## wherein R, rings A and B, X, Y1, Y2, Y3, Y4 and m are defined herein.
摘要翻译：一种液晶组合物，其包含一种或多种由通式II表示的化合物：（II）和一种或多种选自以下的化合物：图像（I）图像（III）（IV）其中R，环A和B，X，Y 1，Y 2，Y 3，Y 4和m如本文所定义。

3. 发明授权

US5679746A Silacyclohexane compound, a method of preparing it and a liquid crystal composition containing it 失效
标题翻译：硅环己烷化合物，其制备方法和含有它的液晶组合物
公开(公告)号：US5679746A
公开(公告)日：1997-10-21
申请号：US576619
申请日：1995-12-21
申请人： Takaaki Shimizu , Tsutomu Ogihara , Kazuyuki Asakura , Takeshi Kinsho , Tatsushi Kaneko , Mutsuo Nakashima
发明人： Takaaki Shimizu , Tsutomu Ogihara , Kazuyuki Asakura , Takeshi Kinsho , Tatsushi Kaneko , Mutsuo Nakashima
IPC分类号： C07F7/08 , C07F7/12 , C09K19/40 , C09K19/34
CPC分类号： C07F7/0818 , C07F7/0896 , C07F7/12 , C09K19/406
摘要： A silacyclohexane compound represented by the following general formula (I): ##STR1## wherein R denotes a mono- or di-fluoroalkyl group with 1-10 carbons: ##STR2## denotes a trans-1-silacyclohexylene or a trans-4-silacyclohexylene group whose silicon at position 1 or position 4 has a substitutional group of H, F, Cl or CH.sub.3 ; X denotes a CN, F, Cl, CF.sub.3, CF.sub.2 Cl, CHFCl, OCF.sub.3, OCHF.sub.2, OCF.sub.2 Cl, OCHFCl, (O).sub.3 CY.sub.1 .dbd.CX.sub.1 X.sub.2 (X.sub.1 and Y.sub.1 denote H, F or Cl, and X.sub.2 denotes F or Cl) (O).sub.3 C.sub.p H.sub.q F.sub.r (p denotes 2, 3 or 4, and q and r are integers which satisfy the equation q+r=2p+1, and s denotes 0 or 1), the aforementioned R, or an alkyl or alkoxy group with 1-5 carbons; Y denotes H or F; and Z denotes H or F; and process of manufacturing same.
摘要翻译：由以下通式（I）表示的硅环己烷化合物：其中R表示具有1-10个碳的单 - 或二 - 氟烷基：表示反式-1-硅杂环己烯或反式-4-硅杂环己烯其位置1或位置4的硅具有H，F，Cl或CH 3的取代基; X表示CN，F，Cl，CF 3，CF 2 Cl，CHFCl，OCF 3，OCHF 2，OCF 2 Cl，OCHFCl，（O）3CY 1 = CX 1 X 2（X 1和Y 1表示H，F或Cl，X2表示F或Cl）（O） 3CpHqFr（p表示2,3或4，q和r是满足方程式q + r = 2p + 1，s表示0或1的整数），上述R 1或具有1-5个碳原子的烷基或烷氧基碳; Y表示H或F; Z表示H或F; 和制造过程相同。

4. 发明授权

US5665271A Silacyclohexane compounds, preparation thereof, liquid crystal compositions comprising the same, and liquid crystal devices comprising the compositions 失效
标题翻译：硅环己烷化合物，其制备方法，含有它们的液晶组合物和包含该组合物的液晶装置
公开(公告)号：US5665271A
公开(公告)日：1997-09-09
申请号：US598595
申请日：1996-02-12
申请人： Tsutomu Ogihara , Takaaki Shimizu , Takeshi Kinsho , Tatsushi Kaneko , Kazuyuki Asakura , Mutsuo Nakashima
发明人： Tsutomu Ogihara , Takaaki Shimizu , Takeshi Kinsho , Tatsushi Kaneko , Kazuyuki Asakura , Mutsuo Nakashima
IPC分类号： C07F7/08 , C07F7/12 , C09K19/40 , C09K19/34
CPC分类号： C07F7/12 , C07F7/0818 , C07F7/0896 , C09K19/406
摘要： Silacyclohexane compounds of the following formula (I) or (II) along with intermediate compounds therefor are described ##STR1## wherein R is an organic residue, one of ##STR2## represents a trans-1-sila-1,4-cyclohexylene group or trans-4-sila-1,4-cyclohexylene group having a substituent of H, F, Cl or CH.sub.3, and the other represents a trans-1,4-cyclohexylene group, or such a trans-1-sila-1,4-cyclohexylene group or trans-4-sila-1,4-cyclohexylene group as defined above, n is 0 or 1, L.sub.1 represents H or F, L.sub.2 represents H, F or Cl, and Z represents CN, F, Cl or an organic residue, and ##STR3## The processes for preparing the compounds (I) and (II) are also described along with liquid crystal compositions comprising the compounds and the liquid crystal devices comprising the compositions.
摘要翻译：描述下式（I）或（II）的硅环己烷化合物及其中间体化合物描述：其中R是有机残基，其中一个表示反式-1-硅烷-1,4-二醇，具有H，F，Cl或CH 3的取代基的亚环己基或反式-4-硅烷-1,4-亚环己基，另一个表示反式-1,4-亚环己基或反式-1-硅烷基， 1,4-亚环己基或反式-4-硅烷-1,4-亚环己基，n为0或1，L 1表示H或F，L 2表示H，F或Cl，Z表示CN，F， Cl或有机残基，以及包含化合物的液晶组合物和包含该组合物的液晶装置也描述了（I）和（II）。

5. 发明授权

US5641430A Silacyclohexane compounds, preparation thereof, liquid crystal compositions comprising the same, and liquid crystal devices comprising the compositions 失效
标题翻译：硅环己烷化合物，其制备方法，含有它们的液晶组合物和包含该组合物的液晶装置
公开(公告)号：US5641430A
公开(公告)日：1997-06-24
申请号：US566392
申请日：1995-12-01
申请人： Mutsuo Nakashima , Takaaki Shimizu , Tsutomu Ogihara , Takeshi Kinsho , Tatsushi Kaneko , Kazuyuki Asakura , Hideshi Kurihara
发明人： Mutsuo Nakashima , Takaaki Shimizu , Tsutomu Ogihara , Takeshi Kinsho , Tatsushi Kaneko , Kazuyuki Asakura , Hideshi Kurihara
IPC分类号： C07F7/08 , C07F7/12 , C09K19/40 , C09K19/34 , C09K19/30
CPC分类号： C07F7/0818 , C07F7/0896 , C07F7/12 , C09K19/406
摘要： A silacyclohexane compound of the following formula (I) or (II) ##STR1## wherein R is an organic residue, ##STR2## represents an unsubstituted or substituted trans-1-sila-1,4-cyclohexylene group or trans-4-sila-1,4-cyclohexylene group, L.sub.1 and L.sub.2 independently represent H, F, Cl or CH.sub.3 ; and X represents an organic residue, CN, F or Cl, or ##STR3## wherein R, L.sub.1, L.sub.2 and X are, respectively, as defined above, and at least one of ##STR4## represents an unsubstituted or substituted trans-1-sila-1,4-cyclohexylene group or trans-4-sila-1,4-cyclohexylene group, and the other may be a trans-1,4-cyclohexylene group. The preparation of these compounds is described along with a composition comprising the compound (I) and/or (II) and a display device comprising the composition.
摘要翻译：下式（I）或（II）的硅环己烷化合物其中R是有机残基，IMAGE表示未取代或取代的反式-1-硅烷-1,4-亚环己基或反式-1- 4-硅烷-1,4-亚环己基，L1和L2独立地表示H，F，Cl或CH3; 和X表示有机残基，CN，F或Cl，或如上所定义，并且所述反式-1-硅烷-1,4-亚环己基或反式-4-硅烷-1,4-亚环己基中的至少一种，另一个可以是反式-1,4-亚环己基。这些化合物的制备与包含化合物（I）和/或（II）的组合物以及包含该组合物的显示装置一起被描述。

6. 发明授权

US5641431A Silacyclohexanone compound and a method of preparing a silacyclohexane-type liquid crystal composition containing it 失效
标题翻译：硅环己酮化合物和含有它的硅烷环己烷型液晶组合物的制备方法
公开(公告)号：US5641431A
公开(公告)日：1997-06-24
申请号：US408961
申请日：1995-03-23
申请人： Takeshi Kinsho , Takaaki Shimizu , Tsutomu Ogihara , Ryuichi Saito , Kazuyuki Asakura , Mutsuo Nakashima
发明人： Takeshi Kinsho , Takaaki Shimizu , Tsutomu Ogihara , Ryuichi Saito , Kazuyuki Asakura , Mutsuo Nakashima
IPC分类号： C07F7/08 , C09K19/40 , C09K19/30
CPC分类号： C07F7/0896 , C07F7/0818 , C09K19/406
摘要： A silacyclohexanone compound represented by the following general formula (I). ##STR1## wherein Ar denotes a phenyl group or a tolyl group. R denotes a tolyl group, a linear-chain alkyl group with a carbon number of 2-10, a mono- or di-fluoroalkyl group with a carbon number of 1-10, a branched-chain alkyl group with a carbon number of 3-8 or an alkoxyalkyl group with a carbon number of 2-7. Also, a method of manufacturing silacyclohexane-type liquid crystal compounds represented by the general formula (II) ##STR2## and the general formula (III) ##STR3## which are derived from this compound.
摘要翻译：由以下通式（I）表示的硅环己酮化合物。（I）其中Ar表示苯基或甲苯基。 R表示甲苯基，碳数为2-10的直链烷基，碳数为1〜10的单 - 或二 - 氟烷基，碳数为3的支链烷基 -8或碳数为2-7的烷氧基烷基。另外，由该化合物衍生的由通式（II）表示的硅环己烷型液晶化合物的制造方法（II）和通式（III）的化合物（III）。

7. 发明授权

US5725797A Silacyclohexane compound, a process for producing the same, and a liquid crystal composition comprising the same 失效
标题翻译：硅环己烷化合物，其制造方法以及含有它们的液晶组合物
公开(公告)号：US5725797A
公开(公告)日：1998-03-10
申请号：US742626
申请日：1996-10-31
申请人： Kazuyuki Asakura , Takanobu Takeda , Takaaki Shimizu , Tsutomu Ogihara , Tatsushi Kaneko
发明人： Kazuyuki Asakura , Takanobu Takeda , Takaaki Shimizu , Tsutomu Ogihara , Tatsushi Kaneko
IPC分类号： C07F7/08 , C07F7/12 , C09K19/40 , C09K19/34 , C09K19/30 , G02F1/13
CPC分类号： C07F7/0896 , C07F7/0818 , C07F7/12 , C09K19/406
摘要： For the purpose of improving the characteristics of a liquid crystal substance, there is provided a silacyclohexane compound represented by the general formula (I): ##STR1## wherein R represents a specific straight-chain alkyl group, mono or difluoro alkyl group, branched-chain alkyl group, alkoxyalkyl group, and alkenyl group; at least one of rings A and B represent a trans-1-sila-1,4-cyclohexylene group or a trans-4-sila-1,4-cyclohexylene group both having a substituent group H, F, Cl, CH.sub.3 or Ar (Ar stands for a phenyl or tolyl group) on silicon at the 1 or 4 position, and the other group, if any, represents a trans-1,4-cyclohexylene group or ##STR2## Z represents CN, F, Cl, CF.sub.3, CClF.sub.2, CHClF, OCF.sub.3, OCClF.sub.2, OCHF.sub.2, OCHClF, R, or OR; L.sub.1 represents H, F or Cl; L.sub.2 and L.sub.3 stand independently for H or F; i represents an integer of 0 to 2; m is 1 or 2; n is 0 or 1; and if m is 2, the two rings may be the same or different.
摘要翻译：为了改善液晶物质的特性，提供了由通式（I）表示的硅环己烷化合物：其中R表示特定的直链烷基，单或二氟烷基，支链烷基，烷氧基烷基和烯基; 环A和B中的至少一个表示具有取代基H，F，Cl，CH 3或Ar的反式-1-硅烷-1,4-亚环己基或反式-4-硅烷-1,4-亚环己基（Ar表示苯基或甲苯基），另一组（如果有的话）表示反式-1,4-亚环己基或Z表示CN，F，Cl，CF 3 ，CClF 2，CHClF，OCF 3，OCClF 2，OCHF 2，OCHClF，R或OR; L 1表示H，F或Cl; L2和L3独立地用于H或F; i表示0〜2的整数， m为1或2; n为0或1; 如果m为2，则两个环可以相同或不同。

8. 发明申请

US20080011257A1 DECOMPRESSION APPARATUS AND INTERNAL COMBUSTION ENGINE HAVING THE SAME 有权
标题翻译：拆装装置和内燃机
公开(公告)号：US20080011257A1
公开(公告)日：2008-01-17
申请号：US11774901
申请日：2007-07-09
申请人： Toshikazu IWAMA , Kazuyuki Asakura , Hideyuki Tawara , Akira Tokito
发明人： Toshikazu IWAMA , Kazuyuki Asakura , Hideyuki Tawara , Akira Tokito
IPC分类号： F01L1/047
CPC分类号： F01L1/053 , F01L13/085
摘要： A decompression apparatus includes a plunger and a decompression shaft. The plunger is provided in a plunger hole formed in a cam shaft which is configured to move an engine valve of an internal combustion engine. The plunger is movable in the plunger hole between a decompression position in which the plunger opens the engine valve and a decompression cancel position in which the plunger does not open the engine valve. The plunger hole has a first opening which partially locates on a cam surface of a valve cam which is provided on the cam shaft. A first end portion of the plunger protrudes from the first opening to open the engine valve in the decompression position. The decompression shaft is provided in the cam shaft and configured to move the plunger between the decompression position and the decompression cancel position.
摘要翻译：减压装置包括柱塞和减压轴。柱塞设置在形成在凸轮轴中的柱塞孔中，凸轮轴构造成移动内燃机的发动机气门。柱塞可在活塞孔中在活塞打开发动机气门的减压位置和减压取消位置之间移动，其中柱塞不打开发动机气门。柱塞孔具有部分地位于设置在凸轮轴上的阀凸轮的凸轮表面上的第一开口。柱塞的第一端部从第一开口突出，以将发动机气门打开在减压位置。减压轴设置在凸轮轴中，并且构造成使柱塞在减压位置和减压取消位置之间移动。

9. 发明授权

US07621247B2 Decompression apparatus and internal combustion engine having the same 有权
标题翻译：减压装置和具有该减压装置的内燃机
公开(公告)号：US07621247B2
公开(公告)日：2009-11-24
申请号：US11774901
申请日：2007-07-09
申请人： Toshikazu Iwama , Kazuyuki Asakura , Hideyuki Tawara , Akira Tokito
发明人： Toshikazu Iwama , Kazuyuki Asakura , Hideyuki Tawara , Akira Tokito
IPC分类号： F01L13/08
CPC分类号： F01L1/053 , F01L13/085
摘要： A decompression apparatus includes a plunger and a decompression shaft. The plunger is provided in a plunger hole formed in a cam shaft which is configured to move an engine valve of an internal combustion engine. The plunger is movable in the plunger hole between a decompression position in which the plunger opens the engine valve and a decompression cancel position in which the plunger does not open the engine valve. The plunger hole has a first opening which partially locates on a cam surface of a valve cam which is provided on the cam shaft. A first end portion of the plunger protrudes from the first opening to open the engine valve in the decompression position. The decompression shaft is provided in the cam shaft and configured to move the plunger between the decompression position and the decompression cancel position.
摘要翻译：减压装置包括柱塞和减压轴。柱塞设置在形成在凸轮轴中的柱塞孔中，凸轮轴构造成移动内燃机的发动机气门。柱塞可在活塞孔中在活塞打开发动机气门的减压位置和减压取消位置之间移动，其中柱塞不打开发动机气门。柱塞孔具有部分地位于设置在凸轮轴上的阀凸轮的凸轮表面上的第一开口。柱塞的第一端部从第一开口突出，以将发动机气门打开在减压位置。减压轴设置在凸轮轴中，并且构造成使柱塞在减压位置和减压取消位置之间移动。

10. 发明授权

US5461166A Chemically adsorbed ultrathin film and its material, and method of manufacturing the same 失效
标题翻译：化学吸附超薄膜及其材料及其制造方法
公开(公告)号：US5461166A
公开(公告)日：1995-10-24
申请号：US384594
申请日：1995-02-03
申请人： Norihisa Mino , Kazufumi Ogawa , Toshinobu Ishihara , Mikio Endo , Tohru Kubota , Kazuyuki Asakura
发明人： Norihisa Mino , Kazufumi Ogawa , Toshinobu Ishihara , Mikio Endo , Tohru Kubota , Kazuyuki Asakura
IPC分类号： C07B61/00 , B01J23/42 , B05D1/18 , C07F7/08 , C07F7/12 , C07F7/18 , C09K3/00 , G03F7/075 , C07D333/02 , C08G77/08 , C08F28/06
CPC分类号： B82Y30/00 , B05D1/185 , B82Y10/00 , B82Y40/00 , C07F7/12 , C07F7/182 , C07F7/1836 , C07F7/1868
摘要： Disclosed are a conductive thienyl derivative monomolecular film covalently bonded to a substrate surface and method of manufacturing the same, and a silicon compound comprising 3-thienyl groups (thiophene derivative) used for forming the conductive monomolecular film and a method of manufacturing the same. A monomolecular ultrathin film comprising 3-thienyl groups and silicon groups is formed in the invention. The silicon compound used for forming the film is provided by reacting .omega.-(3-thienyl)-1-alkene compound to a monosilane derivative compound, in which three out of four hydrogen atoms of monosilane are replaced with halogen or alkoxy groups, in the presence of a transition metal catalyst. A substrate is dipped and held in a nonaqueous solution of the above-noted compound, thus chemically bonding the monomolecular film to the substrate surface. Furthermore, a thienyl derivative ultrathin film is formed by the electrolytic or catalytic polymerization of the monomolecular film.
摘要翻译：公开了共价结合到基板表面的导电噻吩基衍生物单分子膜及其制造方法，以及包含用于形成导电性单分子膜的3-噻吩基（噻吩衍生物）的硅化合物及其制造方法。在本发明中形成包含3-噻吩基和硅基团的单分子超薄膜。用于形成膜的硅化合物是通过使ω-（3-噻吩基）-1-烯烃化合物与甲硅烷衍生物化合物反应而得到的，其中甲硅烷中四分之三的氢原子被卤素或烷氧基取代，过渡金属催化剂的存在。将基材浸渍并保持在上述化合物的非水溶液中，从而将单分子膜化学键合到基材表面。此外，通过单分子膜的电解或催化聚合形成噻吩衍生物超薄膜。

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