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    • 3. 发明授权
    • Low-expansion ceramics and method of producing the same
    • 低膨胀陶瓷及其制造方法
    • US4316965A
    • 1982-02-23
    • US152314
    • 1980-05-22
    • Isao OdaTadaaki Matsuhisa
    • Isao OdaTadaaki Matsuhisa
    • C04B35/10C04B35/195C04B35/46C04B35/478C04B35/04C04B35/18C04B35/44
    • C04B35/195C04B35/478
    • The invention relates to low-expansion ceramics, the chemical composition of which consists of 1.2 to 20% by weight of magnesia (MgO), 6.5 to 68% by weight of alumina (Al.sub.2 O.sub.3), 19 to 80% by weight of titanium in terms of titanium oxide (TiO.sub.2), 1 to 20% by weight of silica (SiO.sub.2), and 0.5 to 20% by weight of iron in terms of ferric oxide (Fe.sub.2 O.sub.3); the major component of crystalline phase thereof is a solid solution of magnesium oxide-aluminum oxide-titanium dioxide-silicon oxide-iron oxide; the ceramics have a coefficient of thermal expansion of not more than 20.times.10.sup.-7 (1/.degree.C.) in a temperature range of 25.degree. C. to 800.degree. C., a four-point flexural strength of not smaller than 50 kg/cm.sup.2 at room temperature, and a melting point of not lower than 1,500.degree. C.; and a method of producing low-expansion ceramics comprising the steps of preparing a batch, plasticizing the batch, if necessary, and shaping the batch; drying the body thus shaped; and firing the shaped body at 1,300.degree. C. to 1,700.degree. C., thereby producing ceramics having a coefficient of thermal expansion of not more than 20.times.10.sup.-7 (1/.degree.C.) in a temperature range of 25.degree. C. to 800.degree. C., a four-point flexural strength of not smaller than 50 kg/cm.sup.2 at room temperature, and a melting point of not lower than 1,500.degree. C., and wherein the shape of ceramics is a honeycomb structure.
    • 本发明涉及低膨胀陶瓷,其化学成分由1.2〜20重量%的氧化镁(MgO),6.5〜68重量%的氧化铝(Al 2 O 3),19〜80重量%的钛组成 的二氧化钛(TiO 2),1〜20重量%的二氧化硅(SiO 2)和0.5〜20重量%的以换算成的氧化铁(Fe 2 O 3)计的铁。 其结晶相的主要成分是氧化镁 - 氧化铝 - 二氧化钛 - 氧化硅 - 氧化铁的固溶体; 在25℃〜800℃的温度范围内,陶瓷的热膨胀系数为20×10 -7(1 /℃)以下,四点弯曲强度为50kg / cm2,熔点不低于1500℃。 以及生产低膨胀陶瓷的方法,包括如下步骤:制备批料,如果需要,对批料进行增塑和成型; 干燥身体如此成形; 并将成形体在1300℃〜1700℃下烧成,从而在25℃〜800℃的温度范围内制造热膨胀系数为20×10 -7(1 /℃)以下的陶瓷。 ℃,室温下不低于50kg / cm2的四点弯曲强度,不低于1500℃的熔点,陶瓷的形状是蜂窝结构。
    • 7. 发明授权
    • Low-expansion ceramics and method of producing the same
    • 低膨胀陶瓷及其制造方法
    • US4306909A
    • 1981-12-22
    • US152315
    • 1980-05-22
    • Isao OdaTadaaki Matsuhisa
    • Isao OdaTadaaki Matsuhisa
    • C04B35/10C04B35/46C04B35/478C04B35/04
    • C04B35/478
    • The present invention relates to low-expansion ceramics essentially consisting of 1.5 to 20% by weight of magnesia (MgO), 8 to 68% by weight of alumina (Al.sub.2 O.sub.3), 24 to 80% by weight of titanium in terms of titanium oxide (TiO.sub.2), and 0.5 to 20% by weight of iron in terms of ferric oxide (Fe.sub.2 O.sub.3), that major component of crystalline phase thereof is a solid solution of magnesium oxide-aluminum oxide-titanium dioxide-iron oxide, and that the ceramics has a coefficient of thermal expansion of not more than 20.times.10.sup.-7 (1/.degree. C.) in a temperature range of 25.degree. C. to 800.degree. C. and a melting point of not lower than 1,500.degree. C., said coefficient of thermal expansion being maintained even after exposure 1,100.degree. C. for 1,000 hours, and a method of producing low-expansion ceramics comprising steps of preparing a batch of compounds so as to provide a chemical composition of 1.5 to 20% by weight of magnesia (MgO), 8 to 68% by weight of alumina (Al.sub.2 O.sub.3), 24 to 80% by weight of titanium in terms of titanium oxide, and 0.5 to 20% by weight of iron in terms of ferric oxide (Fe.sub.2 O.sub.3); plasticizing the batch if necessary and shaping the batch; drying the body thus formed and firing the formed body at 1,300.degree. C. to 1,700.degree. C. for 0.5 to 48 hours, thereby having a coefficient of thermal expansion of less than 20.times.10.sup.-7 (1/.degree. C.) in a temperature range of 25.degree. C. to 800.degree. C. and a melting point of not lower than 1,500.degree. C., said coefficient of thermal expansion being maintained even after exposure at 1,100.degree. C. for 1,000 hours, wherein the shape of ceramics is a honeycomb structure.
    • 本发明涉及基本上由氧化镁(MgO)1.5〜20重量%,氧化铝(Al 2 O 3)8〜68重量%,氧化钛换算为24〜80重量%的钛的低膨胀性陶瓷 TiO 2)和0.5〜20重量%的以氧化铁(Fe 2 O 3)计的铁,其结晶相的主要成分是氧化镁 - 氧化铝 - 二氧化钛 - 氧化铁的固溶体,陶瓷具有 在25℃至800℃的温度范围内,热膨胀系数不大于20×10 -7(1 /℃),熔点不低于1500℃,所述热导率 即使在1100℃下曝光1000小时后,也保持膨胀,以及生产低膨胀陶瓷的方法,包括制备一批化合物的步骤,以提供1.5至20重量%的氧化镁(MgO)的化学组成, ,8〜68重量%的氧化铝(Al 2 O 3),24〜80重量%的钛 氧化钛,以氧化铁(Fe 2 O 3)换算为0.5〜20重量%的铁。 必要时对批料进行塑化并成型; 干燥所形成的本体,并将成形体在1300℃至1700℃下焙烧0.5至48小时,从而在温度范围内具有小于20×10 -7(1 /℃)的热膨胀系数 25℃至800℃,熔点不低于1500℃,即使在1100℃下暴露1000小时之后,仍保持热膨胀系数,其中陶瓷的形状为蜂窝状 结构体。