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1. 发明授权

US4694094A Cyclic diphosphonites 失效
标题翻译：环状二膦酸盐
公开(公告)号：US4694094A
公开(公告)日：1987-09-15
申请号：US736447
申请日：1985-05-21
申请人： Sylvain Juge , Yvonne Legras
发明人： Sylvain Juge , Yvonne Legras
IPC分类号： C07F9/32 , C07F9/48 , C07F9/6571 , C07F9/6574 , C07F9/6584 , C07F9/15
CPC分类号： C07F9/65719 , C07F9/3235 , C07F9/485 , C07F9/6584 , C07F9/65842
摘要： New organic compounds containing a phosphorus heterocycle of the phosphonite type, in which the phosphorus atom is connected on the one hand to an oxygen atom and on the other hand to an oxygen, sulphur or nitrogen atom, characterized by comprising two of such heterocycles, the two phosphorus atoms being connected by a hydrocarbon group. Preparation of these diphosphonites by the action of a tetrahalogeno- or tetraminodiphosphine upon a diol or an alcohol carrying a phenol, thiol, enol, acid or amine function.
摘要翻译：含有亚磷酸盐类型的磷杂环的新的有机化合物，其中磷原子一方面连接到氧原子，另一方面连接到氧，硫或氮原子上，其特征在于包含两个这样的杂环，两个磷原子被烃基连接。通过四卤代 - 或四马来二膦的作用制备这些二膦酸酯在二醇或含有苯酚，硫醇，烯醇，酸或胺官能团的醇上。

2. 发明授权

US4952740A Cyclic phosphonites 失效
标题翻译：环状亚膦酸酯
公开(公告)号：US4952740A
公开(公告)日：1990-08-28
申请号：US407702
申请日：1989-09-12
申请人： Sylvain Juge , Yvonne Legras
发明人： Sylvain Juge , Yvonne Legras
IPC分类号： C07F9/24 , C07F9/22 , C07F9/32 , C07F9/38 , C07F9/40 , C07F9/48 , C07F9/53 , C07F9/6571 , C07F9/6574 , C07F9/6578 , C07F9/6584 , C07F17/00 , C07G99/00
CPC分类号： C07F9/65719 , C07F9/3264 , C07F9/3276 , C07F9/5325 , C07F9/657181
摘要： New cyclic phosphonites, in which one of the oxygen atoms of the ring can be replaced by an atom of sulphur or nitrogen; the molecule has an asymmetry due to at least two carbon atoms, one or more nitrogen and/or oxygen atoms or several of these elements together.Preparation of these phosphonites by the reaction of a dihalogeno-phosphine with a compound having two active H atoms, in the presence of a hydracid acceptor.Application of the new phosphonites to the production of the corresponding phosphinates and phosphine oxides.
摘要翻译：新的环状亚膦酸酯，其中一个氧原子可以被硫或氮原子取代; 该分子由于至少两个碳原子，一个或多个氮原子和/或氧原子或这些元素中的几个一起具有不对称性。在氢酸受体存在下，通过二卤代膦与具有两个活性H原子的化合物的反应来制备这些亚膦酸酯。应用新的亚膦酸盐生产相应的次膦酸盐和氧化膦。

3. 发明授权

US5264602A Chiral phosphinite-boranes, their preparation and uses 失效
标题翻译：手性膦 - 硼烷，其制备和用途
公开(公告)号：US5264602A
公开(公告)日：1993-11-23
申请号：US817802
申请日：1992-01-09
申请人： Sylvain Juge , Jean-Pierre Genet , Jean-Alex Laffitte , Massoud Stephan
发明人： Sylvain Juge , Jean-Pierre Genet , Jean-Alex Laffitte , Massoud Stephan
IPC分类号： C07F9/46 , C07F9/50 , C07F5/02 , C07F7/08
CPC分类号： C07F9/46 , C07F9/5027 , C07F9/5045
摘要： This invention is concerned with new chiral diphosphinite-borane compound of the formula ##STR1## wherein R.sup.1 and R.sup.2, identical or different, represent each a C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.18 cycloalkyl, C.sub.7 -C.sub.18 aralkyl or C.sub.6 -C.sub.14 aryl group which can bear functional groups,R.sup.3 represents a C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.18 cycloalkyl, C.sub.7 -C.sub.18 aralkyl, C.sub.6 -C.sub.14 aryl, C.sub.1 -C.sub.18 alkoxy, C.sub.5 -C.sub.18 cycloalkyloxy, C.sub.7 -C.sub.18 aralkyloxy or C.sub.6 -C.sub.14 aryloxy group,Z represents a bridge linking the two phosphinite P atoms, said bridge being (i) a hydrocarbon chain having from 1 to 12 catenary C atoms or (ii) a heterohydrocarbon chain comprising from 1 to 12 catenary C atoms and at least one catenary heteroatom selected from the group consisting of O, S, Si, P and N.These chiral compounds are useful in the manufacture of chiral diphosphine compounds.
摘要翻译：本发明涉及式（I）（Iobis）的新型手性二膦 - 硼烷化合物，其中R 1和R 2相同或不同，表示C1-C18烷基，C5-C18环烷基，C7- C18芳烷基或C6-C14芳基，R3表示C1-C18烷基，C5-C18环烷基，C7-C18芳烷基，C6-C14芳基，C1-C18烷氧基，C5-C18环烷基氧基，C7-C18 芳烷氧基或C 6 -C 14芳氧基，Z表示连接两个磷化物P原子的桥，所述桥是（i）具有1至12个链C原子的烃链或（ii）包含1至12个链C的杂烃链原子和至少一个选自O，S，Si，P和N的链状杂原子。这些手性化合物可用于制造手性二膦化合物。

4. 发明授权

US4983768A Process of preparation of phosphinamides applications and new products 失效
标题翻译：膦酰胺应用和新产品的制备工艺
公开(公告)号：US4983768A
公开(公告)日：1991-01-08
申请号：US754956
申请日：1985-07-15
申请人： Sylvain Juge
发明人： Sylvain Juge
IPC分类号： C07F9/32 , C07F9/36 , C07F9/6584
CPC分类号： C07F9/65844 , C07F9/32 , C07F9/36
摘要： Phosphinamides are prepared by the action of an organic halide on an oxazaphospholidine. Depending upon the configuration desired for the stereoisomer to be obtained, an oxazaphospholidine is utilized which has been derived from a (+) or (-) optically-active amino-alcohol. These phosphinamides are useful for the preparation of phosphinates, in particular optically-active phosphinates of known absolute configuration; for this, the phosphinamide is subjected to alcoholysis.
摘要翻译：膦酰胺通过有机卤化物在氧氮杂磷杂环丁烷的作用下制备。根据所获得的立体异构体所需的构型，使用衍生自（+）或（ - ）光学活性氨基醇的氧氮杂磷杂环丁烷。这些次膦酰胺可用于制备已知绝对构型的次膦酸盐，特别是光学活性膦酸盐; 为此，将膦酰胺进行醇解。

5. 发明授权

US5614641A Process for enantioselective hydrogenation of the oxo C.dbd.O double bond 失效
标题翻译：氧代C = O双键的对映选择性氢化方法
公开(公告)号：US5614641A
公开(公告)日：1997-03-25
申请号：US362557
申请日：1995-03-09
申请人： Jean-Pierre Genet , Sylvain Juge , Jean-Alex Laffitte , Catherine Pinel , Serge Mallart
发明人： Jean-Pierre Genet , Sylvain Juge , Jean-Alex Laffitte , Catherine Pinel , Serge Mallart
IPC分类号： B01J31/24 , C07B53/00 , C07C67/31 , C07D307/33 , C07D307/32 , C07C27/00 , C07C35/08 , C07C64/76
CPC分类号： B01J31/2452 , B01J31/24 , B01J31/2409 , B01J31/2414 , C07B53/00 , C07C67/31 , C07D307/33 , B01J2231/643 , B01J2531/0266 , B01J2531/821
摘要： The present invention concerns a process for enantioselective catalytic hydrogenation of the ketone C.dbd.O double bond to a secondary alcohol function, said process using a neutral ruthenium complex as the catalyst and a compound containing a C.dbd.O group as the substrate to be hydrogenated, characterised in that it comprises hydrogenation of the substrate using a diallyl (diphosphino) ruthenium compound with formula ##STR1## where al preferably represents CH.sub.2 CH.dbd.CH.sub.2 or CH.sub.2 C(CH.sub.3).dbd.CH.sub.2,Q represents a hydrocarbon bridge containing at least two catenary carbon atoms and which can contain one to four catenary heteroatoms selected from O, S, N and Si,R.sup.1 to R.sup.4 may be identical or different and each represents a C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.7 cycloalkyl or C.sub.6 -C.sub.12 aryl group.
摘要翻译： PCT No.PCT / FR93 / 00663 Sec。 371日期：1995年3月5日 102（e）1995年3月9日PCT PCT 1993年6月30日PCT公布。第WO94 / 01390号公报日本1994年1月20日本发明涉及酮C = O双键对仲醇官能团的对映体选择性催化氢化的方法，所述使用中性钌络合物作为催化剂的方法和含有C = O基团的化合物作为底物被氢化，其特征在于它包括使用式（I）的二烯丙基（二膦）钌化合物氢化底物，其中a1优选代表CH 2 CH = CH 2或CH 2 C（CH 3）= CH 2，Q代表烃桥含有至少两个链状碳原子并且可以含有一至四个选自O，S，N和Si的链状杂原子，R 1至R 4可以相同或不同，并且各自表示C1-C18烷基，C5-C7环烷基或C6- C12芳基。

6. 发明授权

US5043465A Organic phosphorus compounds complexed to boron, their preparation and applications 失效
标题翻译：有机磷化合物与硼络合，其制备和应用
公开(公告)号：US5043465A
公开(公告)日：1991-08-27
申请号：US458496
申请日：1989-12-28
申请人： Sylvain Juge , Jean-Pierre Genet
发明人： Sylvain Juge , Jean-Pierre Genet
IPC分类号： C07F9/50 , C07F9/52 , C07F9/6571 , C07F9/6584
CPC分类号： C07F9/52 , C07F9/5045 , C07F9/6571 , C07F9/6584
摘要： New organic phosphorus compounds, comprised of hetero-phosphacycloalkanes whose phosphorus atom forms a complex with a borane. They can be prepared by the action of a borane on a hetero-phosphacycloalkane, within a solvent, at temperatures ranging from -20.degree. to +60.degree. C. Their transformation into other derivatives, phosphinites or phosphines in particular, can be carried out without any modification in the chirality of the initial complex. An especially useful application is their conversion into highly optically active phosphines, used in particular as catalysts in various reactions.
摘要翻译：新的有机磷化合物，其磷原子与硼烷形成络合物的杂 - 磷杂环烷烃组成。它们可以通过硼烷在杂 - 磷杂环烷烃的溶剂中，在-20℃至+ 60℃的温度范围内的作用而制备。它们可以在不进行其它衍生物，亚磷酸盐或膦的转化的情况下进行，任何修改手段的初步复杂。特别有用的应用是将其转化为高度光学活性的膦，特别是在各种反应中用作催化剂。

7. 发明授权

US5166389A Process for preparation of derivatives of phosphinous acid 失效
标题翻译：膦酸衍生物的制备方法
公开(公告)号：US5166389A
公开(公告)日：1992-11-24
申请号：US737339
申请日：1991-07-29
申请人： Sylvain Juge , Jean-Pierre Genet
发明人： Sylvain Juge , Jean-Pierre Genet
IPC分类号： C07F9/46 , C07F9/50 , C07F9/52 , C07F9/53 , C07F11/00
CPC分类号： C07F9/52 , C07F11/005 , C07F9/46 , C07F9/505 , C07F9/5325
摘要： New chemical product, constituted by an organic phosphorus compound of the structure ##STR1## where Q is an N or O atom, T is an alkylene or arylene, possibly carrying substituents, or not existing, while R.sup.1 to R.sup.7, the same or different, are H or aliphatic, cycloaliphatic and/or arylic hydrocarbon radicals, possibly substituted, R.sup.3 not existing when Q is oxygen. This product is used as an intermediate in the preparation of different derivatives of phosphinous acid.
摘要翻译：新化学产品由结构为“IMAGE”的有机磷化合物构成，其中Q为N或O原子，T为亚烷基或亚芳基，可能带有取代基或不存在，而R1至R7相同或不同，是当Q是氧时不存在的H或脂族，脂环族和/或芳基烃基，可能被取代。该产品用作制备不同亚磷酸衍生物的中间体。

8. 发明授权

US5068425A Process of preparation of phosphinamides, applications and new products 失效
标题翻译：磷酰胺，应用和新产品的制备方法
公开(公告)号：US5068425A
公开(公告)日：1991-11-26
申请号：US598927
申请日：1990-10-17
申请人： Sylvain Juge
发明人： Sylvain Juge
IPC分类号： C07F9/32 , C07F9/36 , C07F9/6584
CPC分类号： C07F9/65844 , C07F9/32 , C07F9/36
摘要： Phosphinamides are prepared by the action of an organic halide on an oxazaphospholidine. Depending upon the configuration desired for the stereoisomer to be obtained, an oxazaphospholidine is utilized which has been derived from a (+) or (-) optically-active amino-alcohol. These phosphinamides are useful for the preparation of phosphinates, in particular optically-active phosphinates of known absolute configuration; for this, the phosphinamide is subjected to alcoholysis.

9. 发明授权

US4952728A Process for preparation of derivatives of phosphinous acid and intermediate product used to that effect 失效
标题翻译：用于制备次膦酸衍生物和中间产物的方法
公开(公告)号：US4952728A
公开(公告)日：1990-08-28
申请号：US089592
申请日：1987-08-26
申请人： Sylvain Juge , Jean-Pierre Genet
发明人： Sylvain Juge , Jean-Pierre Genet
IPC分类号： C07F9/28 , C07F9/46 , C07F9/50 , C07F9/52 , C07F9/53 , C07F9/6574 , C07F9/6584 , C07F11/00
CPC分类号： C07F9/5325 , C07F11/005 , C07F9/46 , C07F9/505 , C07F9/52
摘要： New chemical product, constituted by an organic phosphorus compound of the structure ##STR1## where Q is an N or O atom, T is an alkylene or arylene, possibly carrying substituents, or not existing, while R.sup.1 to R.sup.7, the same or different, are H or aliphatic, cycloaliphatic and/or arylic hydrocarbon radicals, possibly substituted, R.sup.3 not existing when Q is oxygen.This product is used as an intermediate in the preparation of different derivatives of phosphinous acid.
摘要翻译：新化学产品由结构为“IMAGE”的有机磷化合物构成，其中Q为N或O原子，T为亚烷基或亚芳基，可能带有取代基或不存在，而R1至R7相同或不同，是当Q是氧时不存在的H或脂族，脂环族和/或芳基烃基，可能被取代。该产品用作制备不同亚磷酸衍生物的中间体。

10. 发明授权

US5434285A Chiral phosphinite-boranes and their preparation and use 失效
标题翻译：手性膦 - 硼烷及其制备与应用
公开(公告)号：US5434285A
公开(公告)日：1995-07-18
申请号：US104023
申请日：1993-10-07
申请人： Jean A. Laffitte , Sylvain Juge , Jean P. Genet , Massoud Stephan
发明人： Jean A. Laffitte , Sylvain Juge , Jean P. Genet , Massoud Stephan
IPC分类号： C07F9/46 , C07F9/50 , C07F7/02
CPC分类号： C07F9/46 , C07F9/5027 , C07F9/5045
摘要： The present invention relates, by way of novel industrial products, to the phosphinite-borane compounds of the general formula ##STR1## in which R.sup.1 and R.sup.2, which are identical or different, are each a C.sub.1 -C.sub.18 -alkyl group, a C.sub.5 -C.sub.18 -cycloalkyl group, a C.sub.7 -C.sub.18 -aralkyl group or a C.sub.6 -C.sub.14 -aryl group, it being possible for each of these groups to carry functional groups, and F is a silicon containing bridging group.These products are useful in the syntheses of chiral compounds.
摘要翻译： PCT No.PCT / FR92 / 00143 Sec。 371日期：1993年10月7日 102（e）日期1993年10月7日PCT提交1992年2月13日PCT公布。公开号WO92 / 14538 本发明是通过新工业产品涉及通式为（X）的膦 - 硼烷化合物，其中相同或不同的R 1和R 2各自为 C 1 -C 18烷基，C 5 -C 18环烷基，C 7 -C 18芳烷基或C 6 -C 14 - 芳基，这些基团中的每一个可以携带官能团，F是含硅桥接组。这些产物可用于合成手性化合物。

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