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1. 发明授权

US4032458A Production of 1,4-butanediol 失效
标题翻译：生产1,4-丁二醇
公开(公告)号：US4032458A
公开(公告)日：1977-06-28
申请号：US602993
申请日：1975-08-08
申请人： Stone D. Cooley , Robert P. Arganbright , William G. Bowman , James D. Henery
发明人： Stone D. Cooley , Robert P. Arganbright , William G. Bowman , James D. Henery
IPC分类号： C07C29/17 , C07C67/08 , C07C29/00
CPC分类号： C07C29/177 , C07C67/08
摘要： An improved process is disclosed wherein 1,4-butanediol is produced from a maleic acid-containing solution in a multistep process comprising esterification of maleic acid at elevated temperature and pressure in the presence of a monohydric alcohol to form dialky esters of maleic acid, hydrogenation of the dialkyl esters to 1,4-butanediol in a two-step hydrogenation process, recovery of the 1,4-butanediol substantially free from other close boiling contaminants in an extraction zone and recovering 1,4-butanediol in high purity from a distillation zone operated at reduced pressure.

2. 发明授权

US4172961A Production of 1,4-butanediol 失效
标题翻译：生产1,4-丁二醇
公开(公告)号：US4172961A
公开(公告)日：1979-10-30
申请号：US602992
申请日：1975-08-08
申请人： James D. Henery , Robert P. Arganbright
发明人： James D. Henery , Robert P. Arganbright
IPC分类号： C07C29/149 , C07C29/76 , C07C29/80 , C07C29/86 , C07C31/20
CPC分类号： C07C29/86 , C07C29/149 , C07C29/76 , C07C29/80
摘要： An improved process for the production of 1,4-butanediol is disclosed wherein a dialkyl alkoxy succinate-containing mixture is contacted with hydrogen at elevated temperature and pressure in the presence of a copper chromite hydrogenation catalyst to form a mixture comprising 1,4-butanediol and the corresponding alkanol. In a preferred embodiment, dibutyl butoxy succinate is converted to 1,4-butanediol and n-butanol at high selectivities.
摘要翻译：公开了一种制备1,4-丁二醇的改进方法，其中在亚铬酸铜加氢催化剂存在下，在高温和高压下使含二烷基烷基琥珀酸酯的混合物与氢气接触以形成包含1,4-丁二醇和相应的链烷醇。在优选的实施方案中，琥珀酸二丁酯以高选择性转化为1,4-丁二醇和正丁醇。

3. 发明授权

US4032583A Purification of 1,4-butanediol 失效
标题翻译： 1,4-丁二醇的纯化
公开(公告)号：US4032583A
公开(公告)日：1977-06-28
申请号：US602986
申请日：1975-08-08
申请人： Robert P. Arganbright , William G. Bowman
发明人： Robert P. Arganbright , William G. Bowman
IPC分类号： C07C29/80 , C07C29/24
CPC分类号： C07C29/80 , C07C29/86
摘要： An improved process is disclosed for recovering 1,4-butanediol in high purity from a mixture comprising 1,4-butanediol in admixture with minor amounts of certain impurities which comprises diluting the 1,4-butanediol-containing mixture with water to form an aqueous mixture having from about 5 to about 75 wt. % water and contacting said aqueous mixture in an extraction zone with a hydrocarbon extractant. An aqueous 1,4-butanediol-containing raffinate is obtained as the bottoms product of the extraction zone and is introduced into a distillation zone operated at reduced pressure from which substantially pure 1,4-butanediol is recovered.

4. 发明授权

US06002058A Process for the alkylation of benzene 失效
标题翻译：苯烷基化方法
公开(公告)号：US06002058A
公开(公告)日：1999-12-14
申请号：US184171
申请日：1998-11-02
申请人： Dennis Hearn , Robert P. Arganbright , Lawrence A. Smith, Jr. , John R. Adams
发明人： Dennis Hearn , Robert P. Arganbright , Lawrence A. Smith, Jr. , John R. Adams
IPC分类号： B01D3/34 , B01D3/00 , C07C2/64 , C07C15/02 , C07C15/073 , C07C15/085 , C10G29/20 , C10G35/04 , C10G45/32 , C10G49/00 , C10G65/04 , C10G69/08 , C10G69/12 , C07C1/00 , C07C5/03 , C10G1/00 , C10G45/00
CPC分类号： C10G69/123 , B01D3/009 , C10G29/205 , C10G49/002 , C10G2400/02 , C10G2400/30 , Y10S203/06
摘要： A process for the alkylation of benzene contained in a mixed refinery stream is disclosed wherein the refinery stream is first subjected to hydrogenation of higher olefins prior to alkylation of the benzene with selected types and quantities of lower olefins. Streams containing sulfur compounds may be pretreated by hydrodesulfurization. All of the process steps are advantageously carried out in distillation column reactors to take advantage of that mode of operation.
摘要翻译：公开了一种在混合炼油厂物流中烷基化苯的方法，其中在选择类型和数量的低级烯烃的苯的烷基化之前，首先对炼油厂物流进行高级烯烃的氢化。含有硫化合物的流可以通过加氢脱硫进行预处理。所有的方法步骤有利地在蒸馏塔反应器中进行，以利用这种操作模式。

5. 发明授权

US5243115A Alkylation of organic aromatic compounds 失效
标题翻译：有机芳香化合物的烷基化
公开(公告)号：US5243115A
公开(公告)日：1993-09-07
申请号：US690373
申请日：1991-04-22
申请人： Lawrence A. Smith, Jr. , Robert P. Arganbright , Dennis Hearn
发明人： Lawrence A. Smith, Jr. , Robert P. Arganbright , Dennis Hearn
IPC分类号： B01D3/00 , C07C2/66 , C07C37/14
CPC分类号： C07C37/14 , B01D3/009 , C07C2/66 , Y02P20/127
摘要： Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.
摘要翻译：芳族化合物在催化蒸馏中烷基化，其中催化剂结构还用作蒸馏组分，通过在0.25至50个大气压和80℃的温度下在催化剂床中使芳族化合物与C 2至C 10烯烃接触使用以酸性或酸性阳离子交换树脂为特征的摩尔筛作为催化剂。例如，通过将乙烯输送到催化剂床的中点而制备乙苯，同时方便地通过摩尔过量的回流加入苯与乙烯反应所需的苯，从而使基本上所有的乙烯和回收的苯作为主要塔顶馏出物和乙苯在底部。

6. 发明授权

US4982022A Process for the preparation of tertiary alcohols 失效
标题翻译：叔醇的制备方法
公开(公告)号：US4982022A
公开(公告)日：1991-01-01
申请号：US399259
申请日：1989-08-28
申请人： Lawrence A. Smith, Jr. , Robert P. Arganbright
发明人： Lawrence A. Smith, Jr. , Robert P. Arganbright
IPC分类号： B01J31/10 , C07B61/00 , C07C29/04 , C07C29/80 , C07C31/12 , C07C31/125
CPC分类号： C07C29/04
摘要： A process for the production of tertiary alcohols by the reaction of the corresponding isoolefin and water is disclosed. In particular the production of tertiary butyl alcohol and tertiary amyl alcohol is disclosed. The isoolefin and water are contacted over an acid cation exchange resin catalyst in a distillation column reactor where the products and reactants are separated by fractional distillation. In one embodiment a liquid level is maintained in the catalyst bed.

7. 发明授权

US5446231A Method for removing contaminants from hydrocarbon streams 失效
标题翻译：从烃流中去除污染物的方法
公开(公告)号：US5446231A
公开(公告)日：1995-08-29
申请号：US185121
申请日：1994-01-24
申请人： Robert P. Arganbright , Edward M. Jones, Jr. , Dennis Hearn
发明人： Robert P. Arganbright , Edward M. Jones, Jr. , Dennis Hearn
IPC分类号： C07C7/10 , C10G21/06 , C10G21/16 , C10G21/28 , C07C7/00
CPC分类号： C07C7/10 , C10G21/06 , C10G21/16 , C10G21/28
摘要： The present invention is a method for removing nitrile contaminants from C.sub.5 streams. In particular, a C.sub.5 stream is washed in a countercurrent fashion with a mixture comprising 50% methanol and 50% water to extract the nitriles from the C.sub.5 hydrocarbons into the water-methanol mixture. Propionitrile removal is enhanced by the presence of the methanol in the solvent. An further embodiments include (1) a method for recovering methanol from the extract stream by hydrogenating the nitriles to form amines, converting the amines to ammonium salts by acid treatment and distilling out the methanol and (2) distilling out methanol/nitriles from the extract stream, admixing the methanol/nitriles with an alkane/alkene/ether stream then distilling the methanol out in a azeotrope with the alkane/alkenes while leaving the nitriles in the ether.
摘要翻译：本发明是从C5流中除去腈污染物的方法。特别地，将C5流以包含50％甲醇和50％水的混合物逆流洗涤，以将来自C5烃的腈提取到水 - 甲醇混合物中。通过甲醇在溶剂中的存在来提高丙腈去除效果。另外的实施方案包括（1）通过氢化腈形成胺从萃取物流中回收甲醇的方法，通过酸处理将胺转化成铵盐并蒸馏除去甲醇，和（2）从提取物中蒸出甲醇/腈将甲醇/腈与烷烃/烯烃/醚流混合，然后将甲醇与烷烃/烯烃共沸出，同时将腈离开在乙醚中。

8. 发明授权

US5231234A Two stage production of ether from tertiary alcohol 失效
标题翻译：从三级乙醇生产二级乙醚
公开(公告)号：US5231234A
公开(公告)日：1993-07-27
申请号：US860174
申请日：1992-03-30
申请人： Robert P. Arganbright , Bradley S. Hearn
发明人： Robert P. Arganbright , Bradley S. Hearn
IPC分类号： B01D3/00 , C07C1/24 , C07C41/06 , C07C41/42
CPC分类号： C07C41/42 , B01D3/009 , C07C1/24 , C07C41/06 , C07C2531/08 , Y02P20/127
摘要： An integrated two stage process for the production of isoolefin by the dehydration of isoalcohol and the synthesis of a corresponding ether, for example the production of methyl tertiary butyl ether by (a) feeding tertiary butyl alcohol to a first distillation column reactor into a feed zone; (b) concurrently in said first distillation column reactor (i) contacting said TBA with an acid ion exchange resin catalyst as a component of a distillation structure, at a temperature in the range of 165.degree. to 200.degree. F. to dissociate said tertiary butyl alcohol to the isobutene and water, characterized in that sufficient water is maintained in said distillation reaction zone to inhibit the reaction of the isobutene with itself to form dimers and (ii) separating isobutene and water by fractional distillation; (c) withdrawing isobutene as overheads; (d) withdrawing water and undehydrated isoalcohol as bottoms, and in the second stage feeding the recovered isobutene to a second distillation column reactor with methanol and concurrently reacting methanol and isobutene at the appropriate dilution to form a reaction mixture containing methyl tertiary butyl ether.
摘要翻译：通过脱水异构醇和合成相应的醚来生产异烯烃的综合两阶段方法，例如通过（a）将叔丁醇向第一蒸馏塔反应器中进料到进料区中来生产甲基叔丁基醚 ; （b）在所述第一蒸馏塔反应器（i）中，将所述TBA与作为蒸馏结构的组分的酸性离子交换树脂催化剂接触，在165至200°F的温度下，将所述叔丁基醇到异丁烯和水，其特征在于在所述蒸馏反应区中保持足够的水以抑制异丁烯与其自身的反应以形成二聚体，和（ii）通过分馏分离异丁烯和水; （c）将异丁烯作为塔顶馏出物取出; （d）将水和未脱水的异构醇作为塔底馏出物，在第二阶段中，将回收的异丁烯加入到具有甲醇的第二蒸馏塔反应器中，同时使甲醇和异丁烯以适当的稀释液反应，形成含有甲基叔丁基醚的反应混合物。

9. 发明授权

US5087780A Hydroisomerization process 失效
标题翻译：加氢异构化过程
公开(公告)号：US5087780A
公开(公告)日：1992-02-11
申请号：US701696
申请日：1991-05-14
申请人： Robert P. Arganbright
发明人： Robert P. Arganbright
IPC分类号： C07C5/05 , C07C5/25
CPC分类号： C07C5/05 , C07C5/2512 , C07C2521/04 , C07C2523/44 , Y02P20/127
摘要： A process for the isomerization of butenes in a mixed hydrocarbon stream containing butene-1, butene-2 and small amounts of butadiene in which the mixed hydrocarbon stream is fed to distillation column reactor containing an alumina supported palladium oxide catalyst as a distillation structure. As butene-1 is produced it is distilled off upsetting the equilibrium and allowing for a greater than equilibrium amount of butene-1 to be produced. Additionally, any butadiene in the feed is hydrogenated to butenes. The bottoms, which is rich in butene-2 may be recycled to the reactor column for more complete conversion of butene-2 to butene-1. Alternatively, a portion or essentially all of the bottoms, substantially free of butadiene, may be used for feed to an HF alkylation unit.
摘要翻译：在含有丁烯-1，丁烯-2和少量丁二烯的混合烃流中使丁烯异构化的方法，其中将混合烃流进料到含有氧化铝负载的氧化钯催化剂作为蒸馏结构的蒸馏塔反应器中。当产生丁烯-1时，蒸馏除去平衡的平衡并允许产生大于平衡量的丁烯-1。另外，进料中的任何丁二烯被氢化成丁烯。富含丁烯-2的塔底物可以循环到反应器塔中，以更完全地将丁烯-2转化成丁烯-1。或者，基本上不含丁二烯的部分或基本上全部底部物质可用于进料至HF烷基化单元。

10. 发明授权

US5894076A Process for alkylation of benzene 失效
标题翻译：苯的烷基化方法
公开(公告)号：US5894076A
公开(公告)日：1999-04-13
申请号：US854731
申请日：1997-05-12
申请人： Dennis Hearn , Robert P. Arganbright , Lawrence A. Smith, Jr. , John R. Adams
发明人： Dennis Hearn , Robert P. Arganbright , Lawrence A. Smith, Jr. , John R. Adams
IPC分类号： B01D3/34 , B01D3/00 , C07C2/64 , C07C15/02 , C07C15/073 , C07C15/085 , C10G29/20 , C10G35/04 , C10G45/32 , C10G49/00 , C10G65/04 , C10G69/08 , C10G69/12 , C07C5/02 , C07C2/66 , C07C7/163 , C10G45/00
CPC分类号： C10G69/123 , B01D3/009 , C10G29/205 , C10G49/002 , C10G2400/02 , C10G2400/30 , Y10S203/06
摘要： A process for the alkylation of benzene contained in a mixed refinery stream is disclosed wherein the refinery stream is first subjected to hydrogenation of higher olefins prior to alkylation of the benzene with selected types and quantities of lower olefins. Streams containing sulfur compounds may be pretreated by hydrodesulfurization. All of the process steps are advantageously carried out in distillation column reactors to take advantage of that mode of operation.
摘要翻译：公开了一种在混合炼油厂物流中烷基化苯的方法，其中在选择类型和数量的低级烯烃的苯的烷基化之前，首先对炼油厂物流进行高级烯烃的氢化。含有硫化合物的流可以通过加氢脱硫进行预处理。所有的方法步骤有利地在蒸馏塔反应器中进行，以利用这种操作模式。

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