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1. 发明申请

US20110065009A1 IRON-AIR ACCUMULATOR WITH LITHIUM MEDIATOR 有权
标题翻译：带空气介质的铁空气累加器
公开(公告)号：US20110065009A1
公开(公告)日：2011-03-17
申请号：US12992279
申请日：2009-11-11
申请人： Stephane Lascaud , Philippe Stevens
发明人： Stephane Lascaud , Philippe Stevens
IPC分类号： H01M8/22
CPC分类号： H01M4/74 , H01M2/1606 , H01M2/162 , H01M2/1646 , H01M2/1686 , H01M4/0445 , H01M4/049 , H01M4/24 , H01M4/521 , H01M12/08 , H01M2300/0014 , Y02E60/124 , Y02E60/128 , Y02P70/54
摘要： The invention relates to a half-cell including an electrode formed of an electron collector containing one or more transition metals from groups 4 to 12 of the Period Table of the Elements, and of an electrochemically active material present on the surface of the electron collector in the form of a nanostructured conversion film containing nanoparticles having an average diameter of between 1 nm and 1000 nm. The electrochemically active material contains at least one compound of the transition metal or the transition metals present in the electron collector. The invention further includes a continuous film of a lithium-ion conductive, solid electrolyte that is water- and air-impermeable and that is deposited directly onto, covering totally, the surface of the nanostructured active material of the electrode. The continuous film of solid electrolyte having a thickness of between 1 μm and 50 μm.
摘要翻译：本发明涉及一种半电池，包括由含有元素周期表第4至12族中的一种或多种过渡金属的电子收集体形成的电极，以及存在于电子收集器表面上的电化学活性材料包含平均直径在1nm和1000nm之间的纳米颗粒的纳米结构转化膜的形式。电化学活性材料含有至少一种过渡金属化合物或存在于电子收集器中的过渡金属。本发明还包括一种锂离子传导性固体电解质的连续膜，其是水不透气且直接沉积在电极的纳米结构的活性材料的表面上。固体电解质的连续薄膜的厚度为1μm〜50μm。

2. 发明授权

US09136539B2 Iron-air accumulator with lithium mediator 有权
标题翻译：带锂介质的铁空气蓄能器
公开(公告)号：US09136539B2
公开(公告)日：2015-09-15
申请号：US12992279
申请日：2009-11-11
申请人： Stephane Lascaud , Philippe Stevens
发明人： Stephane Lascaud , Philippe Stevens
IPC分类号： H01M2/16 , H01M4/74 , H01M4/04 , H01M4/24 , H01M4/52 , H01M12/08
CPC分类号： H01M4/74 , H01M2/1606 , H01M2/162 , H01M2/1646 , H01M2/1686 , H01M4/0445 , H01M4/049 , H01M4/24 , H01M4/521 , H01M12/08 , H01M2300/0014 , Y02E60/124 , Y02E60/128 , Y02P70/54
摘要： The invention relates to a half-cell including an electrode formed of an electron collector containing one or more transition metals from groups 4 to 12 of the Period Table of the Elements, and of an electrochemically active material present on the surface of the electron collector in the form of a nanostructured conversion film containing nanoparticles having an average diameter of between 1 nm and 1000 nm. The electrochemically active material contains at least one compound of the transition metal or the transition metals present in the electron collector. The invention further includes a continuous film of a lithium-ion conductive, solid electrolyte that is water- and air-impermeable and that is deposited directly onto, covering totally, the surface of the nanostructured active material of the electrode. The continuous film of solid electrolyte having a thickness of between 1 μm and 50 μm.
摘要翻译：本发明涉及一种半电池，包括由含有元素周期表第4至12族中的一种或多种过渡金属的电子收集体形成的电极，以及存在于电子收集器表面上的电化学活性材料包含平均直径在1nm和1000nm之间的纳米颗粒的纳米结构转化膜的形式。电化学活性材料含有至少一种过渡金属化合物或存在于电子收集器中的过渡金属。本发明还包括一种锂离子传导性固体电解质的连续膜，其是水不透气且直接沉积在电极的纳米结构的活性材料的表面上。固体电解质的连续薄膜的厚度为1μm〜50μm。

3. 发明授权

US07572532B2 Oxide material and a fuel cell electrode containing said material 有权
标题翻译：氧化物材料和含有所述材料的燃料电池电极
公开(公告)号：US07572532B2
公开(公告)日：2009-08-11
申请号：US10599132
申请日：2005-03-21
申请人： Philippe Stevens , Emmanuelle Boehm , Jean-Marc Basset , Fabrice Mauvy , Jean-Claude Grenier
发明人： Philippe Stevens , Emmanuelle Boehm , Jean-Marc Basset , Fabrice Mauvy , Jean-Claude Grenier
IPC分类号： C01F17/00 , H01M4/86
CPC分类号： H01M4/9025 , C01G1/00 , C01G3/006 , C01G37/006 , C01G45/1264 , C01G49/0054 , C01G51/40 , C01G51/70 , C01G53/40 , C01G53/70 , C01P2006/40 , H01M4/9016 , H01M2008/1293
摘要： The invention relates to an oxide material of general formula (I) A2−x−yA′XA″yM1−z M′Z04+δ, wherein A and A′ are independently a metal cation of a group formed by lanthanides and/or alkalis and/or alkaline earths, A″ is a cationic gap, i.e. a cation vacancy A and/or A′, M and M′ are independently a metal of a group formed by transition metals such as 0
摘要翻译：本发明涉及通式（Ⅰ）A2-x-yA'A''yM1-zM'Z04 +δ的氧化物材料，其中A和A'独立地是由镧系元素形成的基团的金属阳离子和/或碱和/或碱土金属，A“是阳离子间隙，即阳离子空位A和/或A'，M和M'独立地是由过渡金属如0

4. 发明授权

US09236642B2 Rigid negative compartment for a metal-air battery and method of manufacturing said compartment 有权
标题翻译：用于金属空气电池的刚性负隔室和制造所述隔室的方法
公开(公告)号：US09236642B2
公开(公告)日：2016-01-12
申请号：US13498649
申请日：2010-09-22
申请人： Gwenaelle Toussaint , Philippe Stevens , Georges Caillon , Patrick Viaud , Christophe Cantau , Philippe Vinatier
发明人： Gwenaelle Toussaint , Philippe Stevens , Georges Caillon , Patrick Viaud , Christophe Cantau , Philippe Vinatier
IPC分类号： H01M10/0562 , H01M12/08 , H01M2/02 , H01M2/30 , H01M4/04 , H01M4/13 , H01M4/1395 , H01M4/70 , H01M4/72 , H01M10/052
CPC分类号： H01M12/08 , H01M2/0207 , H01M2/0277 , H01M2/30 , H01M4/0438 , H01M4/13 , H01M4/134 , H01M4/1395 , H01M4/70 , H01M4/72 , H01M10/052 , H01M10/0562 , Y02E60/122 , Y02E60/128 , Y02P70/54
摘要： The present invention relates to a precursor of a negative electrode compartment for rechargeable metal-air batteries, comprising a rigid casing (1), at least one solid electrolyte membrane (2), a protective covering (5), completely covering the inside face of the solid electrolyte membrane (2), a metallic current collector (3) applied against the inside face of the protective covering (5), preferably also a block (4) of elastic material applied against the current collector and essentially filling the entire internal space defined by the walls of the rigid casing and the solid electrolyte (2), and a flexible electronic conductor (6) passing in a sealed manner through one of the walls of the rigid casing. The present invention also relates to a negative electrode compartment having a rigid casing obtained from said precursor and to a battery containing such a negative electrode compartment.
摘要翻译：本发明涉及一种用于可再充电金属 - 空气电池的负极隔室的前体，包括刚性壳体（1），至少一个固体电解质膜（2），保护覆盖物（5），其完全覆盖固体电解质膜（2），施加在保护罩（5）的内表面上的金属集电体（3），优选地还包括施加在集电器上的基本上填充整个内部空间的弹性材料块（4）由刚性壳体和固体电解质（2）的壁限定，以及柔性电子导体（6），其以密封方式通过刚性壳体的一个壁。本发明还涉及具有由所述前体获得的刚性壳体和包含这种负极隔室的电池的负极隔室。

5. 发明申请

US20120058413A1 INTERPENETRATING NETWORK OF ANION-EXCHANGE POLYMERS, PRODUCTION METHOD THEREOF AND USE OF SAME 有权
标题翻译：阴离子交换聚合物的交联网络及其生产方法及其使用
公开(公告)号：US20120058413A1
公开(公告)日：2012-03-08
申请号：US13318497
申请日：2010-05-04
申请人： Philippe Stevens , Fouad Ghamous , Odile Fichet , Christian Sarrazin
发明人： Philippe Stevens , Fouad Ghamous , Odile Fichet , Christian Sarrazin
IPC分类号： H01M4/86 , H01M8/08 , C08J5/22 , H01M8/10
CPC分类号： H01M8/1044 , C08J3/246 , C08J5/2275 , C08J2300/208 , C08L71/03 , H01M8/083 , H01M12/02 , H01M12/06 , H01M2008/1095 , H01M2300/0082 , Y02E60/50 , Y02P70/56 , C08L2666/04 , C08L2666/06
摘要： The invention relates to a method for producing an anion-exchange polymer material having an IPN or semi-IPN structure, said method consisting in: (A) preparing a homogeneous reaction solution containing, in a suitable organic solvent, (a) at least one organic polymer bearing reactive halogen groups, (b) at least one tertiary diamine, (c) at least one monomer comprising an ethylenic unsaturation polymerizable by free radical polymerization, (d) optionally at least one cross-linking agent including at least two ethylenic unsaturations polymerizable by free radical polymerization, and e) at least one free radical polymerization initiator; and (B) heating the prepared solution to a temperature and for a duration that are sufficient to allow both a nucleophilic substitution reaction between components (a) and (b) and a free radical copolymerization reaction of components (c) and optionally (d) initiated by component (e). The invention also relates to the resulting IPN or semi-IPN material and to the use thereof in electrochemical devices, in direct contact with an air electrode.
摘要翻译：本发明涉及一种具有IPN或半IPN结构的阴离子交换聚合物材料的制备方法，所述方法包括：（A）制备均匀的反应溶液，该溶液含有在合适的有机溶剂中，（a）至少一种带有反应性卤素基团的有机聚合物，（b）至少一种叔胺，（c）至少一种包含通过自由基聚合可聚合的烯属不饱和度的单体，（d）任选至少一种包含至少两个烯属不饱和键的交联剂可通过自由基聚合反应，和e）至少一种自由基聚合引发剂; 和（B）将制备的溶液加热到足以允许组分（a）和（b）之间的亲核取代反应和组分（c）和任选（d）的自由基共聚反应的温度和持续时间，由组件（e）启动。本发明还涉及所得到的IPN或半IPN材料及其在与空气电极直接接触的电化学装置中的用途。

6. 发明申请

US20070098905A1 Method for preparing metal oxide layers 审中-公开
标题翻译：制备金属氧化物层的方法
公开(公告)号：US20070098905A1
公开(公告)日：2007-05-03
申请号：US10561581
申请日：2004-06-17
申请人： Manuel Gaudon , Christel Laberty-Robert , Florence Ansart , Philippe Stevens
发明人： Manuel Gaudon , Christel Laberty-Robert , Florence Ansart , Philippe Stevens
IPC分类号： B01J23/10 , B05D1/18 , B05D1/12 , B05D3/02
CPC分类号： C23C18/1283 , C23C18/1216 , C23C18/1241 , C23C18/1245 , H01M4/9066
摘要： Method of preparing a metal oxide layer on a substrate, in which the following successive steps are carried out: a) a metal oxide powder is dispersed in a liquid medium comprising a dispersion solvent and a dispersant, the said liquid medium containing neither plasticizer nor binder, by means of which a suspension A of the said metal oxide powder in the said liquid medium is obtained; b) a solution of at least one polymer in a solvent is added to the said suspension A, by means of which a suspension B is obtained; c) suspension B is deposited on the substrate by a dip coating method, by means of which a green layer is obtained; d) the green layer obtained in step c) is dried; and e) the dried layer obtained in step d) is calcined.
摘要翻译：在基材上制备金属氧化物层的方法，其中进行以下连续步骤：a）将金属氧化物粉末分散在包含分散溶剂和分散剂的液体介质中，所述液体介质既不含增塑剂也不含粘合剂通过其获得所述液体介质中的所述金属氧化物粉末的悬浮液A; b）将至少一种聚合物在溶剂中的溶液加入到所述悬浮液A中，借此获得悬浮液B. c）通过浸涂法将悬浮液B沉积在基底上，通过该方法获得绿色层; d）将步骤c）中获得的生坯层干燥; 和e）将步骤d）中获得的干燥层煅烧。

7. 发明授权

US09911999B2 Interpenetrating network of anion-exchange polymers, production method thereof and use of same 有权
公开(公告)号：US09911999B2
公开(公告)日：2018-03-06
申请号：US14851216
申请日：2015-09-11
申请人： Philippe Stevens , Fouad Ghamouss , Odile Fichet , Christian Sarrazin
发明人： Philippe Stevens , Fouad Ghamouss , Odile Fichet , Christian Sarrazin
IPC分类号： H01M8/10 , H01M8/1044 , C08J3/24 , C08J5/22 , C08L71/03 , H01M8/083 , H01M12/06 , H01M12/02 , H01M8/1018
CPC分类号： H01M8/1044 , C08J3/246 , C08J5/2275 , C08J2300/208 , C08L71/03 , H01M8/083 , H01M12/02 , H01M12/06 , H01M2008/1095 , H01M2300/0082 , Y02E60/50 , Y02P70/56 , C08L2666/04 , C08L2666/06
摘要： The invention relates to a method for producing an anion-exchange polymer material having an IPN or semi-IPN structure, said method consisting in: (A) preparing a homogeneous reaction solution containing, in a suitable organic solvent, (a) at least one organic polymer bearing reactive halogen groups, (b) at least one tertiary diamine, (c) at least one monomer comprising an ethylenic unsaturation polymerizable by free radical polymerization, (d) optionally at least one cross-linking agent including at least two ethylenic unsaturations polymerizable by free radical polymerization, and e) at least one free radical polymerization initiator; and (B) heating the prepared solution to a temperature and for a duration that are sufficient to allow both a nucleophilic substitution reaction between components (a) and (b) and a free radical copolymerization reaction of components (c) and optionally (d) initiated by component (e). The invention also relates to the resulting IPN or semi-IPN material and to the use thereof in electrochemical devices, in direct contact with an air electrode.

8. 发明授权

US09136550B2 Interpenetrating network of anion-exchange polymers, production method thereof and use of same 有权
标题翻译：阴离子交换聚合物的互穿网络及其制备方法及用途
公开(公告)号：US09136550B2
公开(公告)日：2015-09-15
申请号：US13318497
申请日：2010-05-04
申请人： Philippe Stevens , Fouad Ghamouss , Odile Fichet , Christian Sarrazin
发明人： Philippe Stevens , Fouad Ghamouss , Odile Fichet , Christian Sarrazin
IPC分类号： H01M4/86 , H01M8/08 , C08J3/24 , C08J5/22 , C08L71/03 , H01M12/06
CPC分类号： H01M8/1044 , C08J3/246 , C08J5/2275 , C08J2300/208 , C08L71/03 , H01M8/083 , H01M12/02 , H01M12/06 , H01M2008/1095 , H01M2300/0082 , Y02E60/50 , Y02P70/56 , C08L2666/04 , C08L2666/06
摘要： The invention relates to a method for producing an anion-exchange polymer material having an IPN or semi-IPN structure, said method consisting in: (A) preparing a homogeneous reaction solution containing, in a suitable organic solvent, (a) at least one organic polymer bearing reactive halogen groups, (b) at least one tertiary diamine, (c) at least one monomer comprising an ethylenic unsaturation polymerizable by free radical polymerization, (d) optionally at least one cross-linking agent including at least two ethylenic unsaturations polymerizable by free radical polymerization, and e) at least one free radical polymerization initiator; and (B) heating the prepared solution to a temperature and for a duration that are sufficient to allow both a nucleophilic substitution reaction between components (a) and (b) and a free radical copolymerization reaction of components (c) and optionally (d) initiated by component (e). The invention also relates to the resulting IPN or semi-IPN material and to the use thereof in electrochemical devices, in direct contact with an air electrode.
摘要翻译：本发明涉及一种具有IPN或半IPN结构的阴离子交换聚合物材料的制备方法，所述方法包括：（A）制备均匀的反应溶液，该溶液含有在合适的有机溶剂中，（a）至少一种带有反应性卤素基团的有机聚合物，（b）至少一种叔胺，（c）至少一种包含通过自由基聚合可聚合的烯属不饱和度的单体，（d）任选的至少一种包含至少两个烯属不饱和键的交联剂可通过自由基聚合反应，和e）至少一种自由基聚合引发剂; 和（B）将制备的溶液加热到足以允许组分（a）和（b）之间的亲核取代反应和组分（c）和任选（d）的自由基共聚反应的温度和持续时间，由组件（e）启动。本发明还涉及所得到的IPN或半IPN材料及其在与空气电极直接接触的电化学装置中的用途。

9. 发明申请

US20080011604A1 Process and Device for Water Electrolysis Comprising a Special Oxide Electrode Material 审中-公开
标题翻译：包含特殊氧化物电极材料的水电解工艺和装置
公开(公告)号：US20080011604A1
公开(公告)日：2008-01-17
申请号：US11570859
申请日：2005-06-21
申请人： Philippe Stevens , Cecile Lalane , Jean-Marc Bassat , Fabrice Mauvy , Jean-Claude Grenier
发明人： Philippe Stevens , Cecile Lalane , Jean-Marc Bassat , Fabrice Mauvy , Jean-Claude Grenier
IPC分类号： C25B11/04 , C25B1/06 , C25B9/00
CPC分类号： C25B1/04 , C25B11/0452 , H01M4/9025 , Y02E60/366
摘要： The invention relates to a method for water electrolysis consisting in using an electrode containing at least one type of oxide material of general formula A2−x−yA′xA″yM1−zM′zO4+δ, wherein A is a lanthanide and/or alkaline and/or alkaline earth metal cation, A′ is at least one lanthanide and/or alkaline and/or alkaline earth metal cation, A″ is a cation gap, M is a transition metal element, M′ is at least one type of transition metal element, wherein said metal is such that 0
摘要翻译：本发明涉及一种水电解方法，其包括使用含有至少一种类型的通式为A-2-xy A'x A'的氧化物材料的电极，其中A是镧系元素和/或碱性和/或碱土金属离子， /或碱土金属阳离子，A'是至少一种镧系元素和/或碱土金属和/或碱土金属阳离子，A“是阳离子间隙，M是过渡金属元素，M'是至少一种过渡类型金属元素，其中所述金属使得0

10. 发明授权

US09293757B2 Metal-air accumulator with air electrode protection device 有权
标题翻译：金属空气蓄电池带空气电极保护装置
公开(公告)号：US09293757B2
公开(公告)日：2016-03-22
申请号：US14117527
申请日：2012-05-15
申请人： Gwenaelle Toussaint , Philippe Stevens , Bernard Toussaint
发明人： Gwenaelle Toussaint , Philippe Stevens , Bernard Toussaint
IPC分类号： H02J7/00 , H01M2/34 , H01M10/42 , H01M10/44 , H01M10/48 , H01M12/08
CPC分类号： H01M2/34 , H01M10/425 , H01M10/44 , H01M10/48 , H01M12/08 , H02J7/0068 , Y02E60/128
摘要： The present invention relates to a rechargeable accumulator comprising one or more metal-air cells, each cell comprising a metallic negative electrode, a first positive electrode for releasing oxygen, a second positive electrode which is a porous air electrode containing at least one oxygen reducing catalyst, and an automatic device for protecting the air electrode during the charging and discharging phases of the accumulator. The invention also relates to a method for storing and releasing electrical energy using such an accumulator.
摘要翻译：本发明涉及包含一个或多个金属空气电池的可充电蓄电池，每个电池包括金属负极，用于释放氧的第一正电极，第二正电极，其是含有至少一种氧还原催化剂的多孔空气电极以及在蓄电池的充放电阶段保护空气极的自动装置。本发明还涉及使用这种蓄能器来储存和释放电能的方法。

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