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1. 发明授权

US06200922B1 Catalyst systems of the Ziegler-Natta type 失效
标题翻译：齐格勒 - 纳塔型催化剂系统
公开(公告)号：US06200922B1
公开(公告)日：2001-03-13
申请号：US08869761
申请日：1997-06-05
申请人： Stephan Hüffer , Wolfgang Bidell , Patrik Müller , Ulrich Moll , Roland Hingmann , Günther Schweier
发明人： Stephan Hüffer , Wolfgang Bidell , Patrik Müller , Ulrich Moll , Roland Hingmann , Günther Schweier
IPC分类号： B01J2106
CPC分类号： C08F10/00 , C08F110/06 , C08F4/6465 , C08F4/025 , C08F4/6546 , C08F2500/12 , C08F2500/24
摘要： The catalyst systems comprise as active constituents a) a titanium-containing solid component comprising a compound of titanium, a compound of magnesium, a halogen, an inorganic oxide as support and a carboxylic ester as electron donor compound, and also, as cocatalyst, b) an aluminum compound and c) optionally a further electron donor compound, wherein the inorganic oxide used has a pH of from 1 to 6, an average particle diameter of from 5 to 200 &mgr;m, an average primary particle diameter of from 1 to 20 &mgr;M and voids or channels having an average diameter of from 0.1 to 20 &mgr;m and a macroscopic share of the volume of the overall particle within the range from 5 to 30%.
摘要翻译：催化剂体系包括作为活性成分的含钛固体组分，其包含钛化合物，镁化合物，卤素，作为载体的无机氧化物和作为电子给体化合物的羧酸酯的化合物，以及作为助催化剂的b）铝化合物和任选的另外的电子给体化合物，其中使用的无机氧化物的pH为1至6，平均粒径为5至200μm，平均一次粒径为1至20μm，空隙或平均直径为0.1-20μm的通道，并且整个颗粒的体积的宏观份额在5至30％的范围内。

2. 发明授权

US06524995B2 Catalyst systems of the Ziegler-Natta type 失效
标题翻译：齐格勒 - 纳塔型催化剂系统
公开(公告)号：US06524995B2
公开(公告)日：2003-02-25
申请号：US09750715
申请日：2001-01-02
申请人： Wolf Spaether , Stephan Hüffer , John Lynch , Wolfgang Bidell , Joachim Rösch , Günther Schweier , Roland Hingmann , Alexandre Segul , Rainer Hemmerich , Ingo Treffkorn
发明人： Wolf Spaether , Stephan Hüffer , John Lynch , Wolfgang Bidell , Joachim Rösch , Günther Schweier , Roland Hingmann , Alexandre Segul , Rainer Hemmerich , Ingo Treffkorn
IPC分类号： B01J2302
CPC分类号： C08F10/00 , C08F110/06 , C08F4/025 , C08F4/6546 , C08F2500/12 , C08F2500/24
摘要： Catalyst systems of the Ziegler-Natta type comprise as active constituents a) a solid component comprising a compound of titanium or vanadium, a compound of magnesium, a particulate inorganic oxide as support and an internal electron donor compound, and as cocatalyst b) an aluminum compound and c) if desired, a further, external electron donor compound, wherein the particulate, inorganic oxide used has a specific surface area of from 350 to 1000 m2/g and a mean particle diameter {overscore (D)} in the range from 5 to 60 &mgr;m and comprises particles which are composed of primary particles having a mean particle diameter {overscore (d)} in the range from 1 to 10 &mgr;m and contain voids or channels between the primary particles, where the macroscopic proportion of voids or channels having a diameter of greater than 1 &mgr;m in the particles of the inorganic oxides is in the range from 5 to 30% by volume and the molar ratio of the compound of magnesium to the particulate, inorganic oxide is from 0.5:1 to 2.0:1.
摘要翻译：齐格勒 - 纳塔型的催化剂体系包括作为活性成分的a）包含钛或钒的化合物的固体组分，镁的化合物，作为载体的颗粒状无机氧化物和内部电子给体化合物，以及作为助催化剂）铝化合物和），其中所用的颗粒状无机氧化物的比表面积为350〜1000m2 / g，平均粒径（超芯（D在5〜60μm的范围内）和包含由平均粒径（超芯（d在1-10μm范围内）并且在初级颗粒之间含有空隙或通道的初级颗粒组成的颗粒，其中空隙或通道的宏观比例具有大于1的直径无机氧化物颗粒中的母体在5至30体积％的范围内，镁与颗粒的无机氧化物的摩尔比为0.5:1至 2.0：1。

3. 发明授权

US06589905B1 Method for producing a supported catalyst 有权
标题翻译：负载型催化剂的制造方法
公开(公告)号：US06589905B1
公开(公告)日：2003-07-08
申请号：US09720881
申请日：2001-01-02
申请人： David Fischer , Wolfgang Bidell , Ulrich Moll , Joachim Rösch , Franz Langhauser , Roland Hingmann , Heike Gregorius , Carsten Süling , Günther Schweier
发明人： David Fischer , Wolfgang Bidell , Ulrich Moll , Joachim Rösch , Franz Langhauser , Roland Hingmann , Heike Gregorius , Carsten Süling , Günther Schweier
IPC分类号： B01J2300
CPC分类号： C08F10/06 , C08F4/65904 , C08F4/65912 , C08F4/65927 , C08F110/06 , C08F4/65916 , C08F4/025 , C08F2500/18 , C08F2500/24 , C08F2500/12 , C08F2500/17 , C08F2500/03
摘要： The invention relates to a method for producing a supported catalyst which contains metal, or a supported catalyst constituent which contains metal by impregnating a supporting material with an impregnating solution containing the metal constituent, whereby the impregnating solution flows through the supporting material.
摘要翻译：本发明涉及含有金属的负载型催化剂的制造方法或通过用含有金属成分的浸渍溶液浸渍担载材料而含有金属的负载型催化剂成分，由此浸渍液流过支撑材料。

4. 发明授权

US06812185B2 Preparation of a metal-containing supported catalyst or a supported catalyst component by impregnation of a support material 有权
标题翻译：通过浸渍载体材料制备含金属的负载型催化剂或负载型催化剂组分
公开(公告)号：US06812185B2
公开(公告)日：2004-11-02
申请号：US10402301
申请日：2003-07-30
申请人： David Fischer , Wolfgang Bidell , Ulrich Moll , Joachim Rösch , Franz Langhauser , Roland Hingmann , Heike Gregorius , Carsten Süling , Günther Schweier
发明人： David Fischer , Wolfgang Bidell , Ulrich Moll , Joachim Rösch , Franz Langhauser , Roland Hingmann , Heike Gregorius , Carsten Süling , Günther Schweier
IPC分类号： C08F464
CPC分类号： C08F10/06 , C08F4/65904 , C08F4/65912 , C08F4/65927 , C08F110/06 , C08F4/65916 , C08F4/025 , C08F2500/18 , C08F2500/24 , C08F2500/12 , C08F2500/17 , C08F2500/03
摘要： In a process for preparing a metal-containing supported catalyst or a metal-containing supported catalyst component by impregnation of a support material with an impregnation solution comprising the metal component, the impregnation solution flows through the support material.

5. 发明授权

US06265339B1 Process for preparing carrier-borne transition metal catalysts 失效
标题翻译：制备载体过渡金属催化剂的方法
公开(公告)号：US06265339B1
公开(公告)日：2001-07-24
申请号：US09202534
申请日：1998-12-16
申请人： Wolfgang Bidell , Franz Langhauser , Ulrich Moll , Ian David McKenzie , David Fischer , Roland Hingmann , Günther Schweier , Bernd Lothar Marczinke , Meinolf Kersting , Peter John Vaughan Jones , John Russell Grasmeder
发明人： Wolfgang Bidell , Franz Langhauser , Ulrich Moll , Ian David McKenzie , David Fischer , Roland Hingmann , Günther Schweier , Bernd Lothar Marczinke , Meinolf Kersting , Peter John Vaughan Jones , John Russell Grasmeder
IPC分类号： C08F416
CPC分类号： C08F10/00 , C08F4/61908 , C08F4/61912 , C08F4/61916 , C08F4/6192 , C08F4/61927 , C08F110/06 , Y10S526/943 , C08F2500/12 , C08F2500/17 , C08F2500/03 , C08F2500/24
摘要： A process for preparing a supported transition metal catalyst comprising a particulate organic or inorganic support material, a transition metal complex and a compound capable of forming metallocenium ions comprises the following process steps: a) contacting a solution of a compound capable of forming metallocenium ions with a second solvent in which this compound is only sparingly soluble, in the presence of the support material, b) removing at least part of the solvent from the support material and c) contacting a solution of a mixture of a compound capable of forming metallocenium ions and a transition metal complex with a second solvent in which this mixture is only sparingly soluble, in the presence of the support material obtained as described in a) and b).
摘要翻译：一种制备负载型过渡金属催化剂的方法，其包括颗粒状有机或无机载体材料，过渡金属络合物和能够形成金属茂离子的化合物包括以下工艺步骤：a）使能够形成金属茂离子的化合物的溶液与在载体材料存在下，该化合物只有微溶的第二溶剂，b）从载体材料中除去至少一部分溶剂，和c）使能够形成金属茂离子的化合物的混合物和在如a）和b）中所述获得的载体材料存在下，其中该混合物仅仅是微溶的第二溶剂的过渡金属络合物。

6. 发明授权

US06583253B1 Propene terpolymers with a low extractable portion 有权
标题翻译：具有低可提取部分的丙烯三元共聚物
公开(公告)号：US06583253B1
公开(公告)日：2003-06-24
申请号：US09701943
申请日：2000-12-05
申请人： David Fischer , Peter John Vaughan Jones , Franz Langhauser , Wolfgang Bidell , Roland Hingmann , Günther Schweier , Bernd Lothar Marczinke , Meinolf Kersting , Ulrich Moll
发明人： David Fischer , Peter John Vaughan Jones , Franz Langhauser , Wolfgang Bidell , Roland Hingmann , Günther Schweier , Bernd Lothar Marczinke , Meinolf Kersting , Ulrich Moll
IPC分类号： C08F21000
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65927 , C08F210/06 , Y10S526/904 , Y10S526/943 , C08F4/65916 , C08F210/08 , C08F2500/03 , C08F210/14
摘要： Propene terpolymers consist of from 80 to 99.5 mol % of structural units derived from propene, from 0.1 to 15 mol % of structural units derived from ethene or a C4-C6-1-olefin (I) and from 0.1 to 15 mol % of structural units derived from a further C4-C12-1-olefin (II) which is different from the C4-C6-1-olefin (I), which propene terpolymers have a proportion of regioregular ′1-2′-inserted propene units corresponding to the formula (1) [ ′ ⁢ 1 - 2 ′ ] [ ′ ⁢ 1 - 2 ′ ] + [ ′ ⁢ 2 - 1 ′ ] + [ ′ ⁢ 1 - 3 ′ ] ( 1 ) of more than 0.99, have a melting point (TM), determined from the DSC peak maximum, of less than 135° C. and a weight average molecular weight (MW) of more than 80,000 g/mol and have a xylene-soluble proportion (XS) in % by weight of the propene terpolymer which obeys the following inequality (2) XS≦1411.21 exp(−0.0591 TM[° C.])−0.05 (2).
摘要翻译：丙烯三元共聚物由80至99.5摩尔％的衍生自丙烯的结构单元，0.1至15摩尔％的衍生自乙烯或C 4 -C 6 -1-烯烃（I）的结构单元和0.1至15摩尔％的结构单元组成衍生自不同于C 4 -C 6 -1-烯烃（I）的另外的C 4 -C 12 -1-烯烃（II）的单元，该丙烯三元共聚物具有对应于区域规则'1-2'插入的丙烯单元的比例式（1）大于0.99，由DSC峰值最大值确定的熔点（TM）小于135℃，重均分子量（MW）大于80,000g / mol，具有二甲苯可溶比例（XS）按丙烯三元共聚物的重量百分比计，遵循以下不等式（2）

7. 发明授权

US06562478B1 Sealable multilayer film made of a grafted terpolymer 失效
标题翻译：由可接枝的三元共聚物制成的可密封多层膜
公开(公告)号：US06562478B1
公开(公告)日：2003-05-13
申请号：US09701941
申请日：2000-12-05
申请人： David Fischer , Bernd Lothar Marczinke , Werner Schöne , Franz Langhauser , Wolfgang Bidell , Roland Hingmann , Ulrich Moll , Meinolf Kersting , Günther Schweier , Peter John Vaughan Jones
发明人： David Fischer , Bernd Lothar Marczinke , Werner Schöne , Franz Langhauser , Wolfgang Bidell , Roland Hingmann , Ulrich Moll , Meinolf Kersting , Günther Schweier , Peter John Vaughan Jones
IPC分类号： B32B2732
CPC分类号： B32B27/08 , B29C47/0021 , B29C47/065 , B29C47/145 , B29C55/023 , B29K2995/0022 , B32B27/32 , B32B27/327 , B32B38/0008 , B32B2038/0028 , B32B2310/14 , B32B2553/00 , C08F210/06 , C08F210/16 , Y10T428/2495 , Y10T428/31913 , C08F210/08 , C08F2500/03 , C08F2500/20 , C08F210/14
摘要： A sealable coextruded film is made from at least one outer layer and from at least one base layer, where the outer layer is composed of a propylene terpolymer comprising from 80 to 99.5 mol % of structural units derived from propylene, from 0.2 to 15 mol % of structural units derived from ethene or from a C4-C6 1-olefin (I) and from 0.3 to 15 mol % of structural units derived from another C4-C12 1-olefin (II) different from the C4-C6 1-olefin (I), and where the propylene terpolymer has been prepared using metallocene catalysts.
摘要翻译：可密封的共挤出膜由至少一个外层和至少一个基层制成，其中外层由丙烯三元共聚物组成，丙烯三元共聚物包含80-99.5mol％的衍生自丙烯的结构单元，0.2-15mol％衍生自乙烯或来自C 4 -C 6 1-烯烃（I）的结构单元和0.3至15摩尔％的衍生自不同于C 4 -C 6 1-烯烃的另外的C 4 -C 12 1-烯烃（II）的结构单元（ I），并且其中使用茂金属催化剂制备丙烯三元共聚物。

8. 发明授权

US07022795B1 Highly crystalline propylene homopolymers 失效
标题翻译：高度结晶的丙烯均聚物
公开(公告)号：US07022795B1
公开(公告)日：2006-04-04
申请号：US09041698
申请日：1998-03-13
申请人： Stephan Hüffer , Joachim Rösch , Stefan Seelert , Franz Langhauser , Dieter Lilge , Roland Hingmann , Günther Schweier
发明人： Stephan Hüffer , Joachim Rösch , Stefan Seelert , Franz Langhauser , Dieter Lilge , Roland Hingmann , Günther Schweier
IPC分类号： C08F110/06 , C08F4/646 , C08F4/649
CPC分类号： C08F10/00 , C08F110/06 , C08F4/651 , C08F4/6546 , C08F2500/12
摘要： Propylene homopolymers, wherein, in their separation according to tacticity by first dissolving the polymers in boiling xylene, then cooling the solution to 25° C. at a cooling rate of 10° C./h and then, with ascending temperature, separating the propylene homopolymers into fractions of different tacticity, either one or more of the conditions that i) the fraction of propylene homopolymers which remains undissolved on heating the cooled propylene homopolymer solution to 112° C. is greater than 20% by weight or ii) the fraction of propylene homopolymers which remains undissolved on heating the cooled propylene homopolymer solution to 117° C. is greater than 8% by weight or iii) the fraction of propylene homopolymers which remains undissolved on heating the cooled propylene homopolymer solution to 122° C. is greater than 1% by weight, are satisfied.
摘要翻译：丙烯均聚物，其中通过首先将聚合物溶解在沸腾的二甲苯中，根据立构规整度的分离，然后以10℃/小时的冷却速率将溶液冷却至25℃，然后在升高温度下分离丙烯将均聚物分成不同立构规整度的一个或多个条件，i）在将冷却的丙烯均聚物溶液加热至112℃时保持未溶解的丙烯均聚物的分数大于20重量％或ii）在将冷却的丙烯均聚物溶液加热至117℃时保持未溶解的丙烯均聚物大于8重量％或iii）在将冷却的丙烯均聚物溶液加热至122℃时保持未溶解的丙烯均聚物的分数大于 1重量％。

9. 发明授权

US06593442B2 Semicrystalline propylene polymer compositions with good suitability for producing biaxially oriented films 有权
标题翻译：具有良好适用于生产双轴取向膜的半结晶丙烯聚合物组合物
公开(公告)号：US06593442B2
公开(公告)日：2003-07-15
申请号：US09737848
申请日：2000-12-18
申请人： Wolfgang Bidell , Roland Hingmann , Franz Langhauser , Dieter Lilge , Volker Rauschenberger , Günther Schweier , Florian Stricker , Jürgen Suhm
发明人： Wolfgang Bidell , Roland Hingmann , Franz Langhauser , Dieter Lilge , Volker Rauschenberger , Günther Schweier , Florian Stricker , Jürgen Suhm
IPC分类号： C08F1006
CPC分类号： C08F297/08 , C08F4/65904 , C08F4/65908 , C08F4/65916 , C08F10/06 , C08F110/06 , C08F210/06 , C08L23/14 , C08L2205/02 , C08L2314/06 , Y10S264/901 , Y10S428/91 , Y10S526/905 , C08F4/65927 , C08F2/001 , C08L2666/04 , C08F2500/26 , C08F210/16
摘要： A semicrystalline propylene polymer composition with good suitability for producing biaxially oriented films and prepared by polymerizing propylene, ethylene and/or C4-C18-1-alkenes, where at least 50 mol % of the monomer units present arise from the polymerization of propylene. Also described is the use of the semicrystalline propylene polymer composition for producing films, fibers or moldings, the films, fibers and moldings made from these compositions, biaxially stretched films made from the semicrystalline propylene polymer compositions, and also a method for characterizing the semicrystalline propylene polymer compositions.
摘要翻译：一种半结晶丙烯聚合物组合物，其具有良好的适用于生产双轴取向薄膜并通过聚合丙烯，乙烯和/或C 4 -C 18 -1-烯烃制备，其中存在至少50摩尔％的单体单元来自丙烯的聚合。还描述了使用半结晶丙烯聚合物组合物来生产膜，纤维或模制品，由这些组合物制成的膜，纤维和模制品，由半结晶丙烯聚合物组合物制成的双轴向拉伸膜，以及用于表征半结晶丙烯聚合物组合物。

10. 发明授权

US07196140B2 Highly flowable propylene block copolymers 有权
标题翻译：高流动性丙烯嵌段共聚物
公开(公告)号：US07196140B2
公开(公告)日：2007-03-27
申请号：US10296256
申请日：2001-05-23
申请人： Ulrich Dahn , Wolfgang Bidell , Hans-Jürgen Zimmermann , Roland Hingmann , Joachim Rösch , Günther Schweier , Jürgen Oelze
发明人： Ulrich Dahn , Wolfgang Bidell , Hans-Jürgen Zimmermann , Roland Hingmann , Joachim Rösch , Günther Schweier , Jürgen Oelze
IPC分类号： C08F297/08 , C08F297/00 , C08F4/64 , C08F4/642
CPC分类号： C08F297/08 , C08F10/06 , C08F110/06 , C08F210/06 , C08L53/00 , C08F2/001 , C08F2/34 , C08L2666/02 , C08F2500/12 , C08F2500/17 , C08F210/16
摘要： The invention relates to highly flowable propylene block copolymers that comprise 50 to 80 wt.-% of a propylene homopolymer and 10 to 70 wt.-% of a propylene copolymer having 5 to 50 wt.-% of a C2–C8 alk-1-ene polymerized into it that is different from propylene, and that are obtainable from the gaseous phase by a two-step polymerization by means of a Ziegler-Natta catalyst system. In a first polymerization step, the propylene is polymerized at a pressure of 10 to 50 bar, a temperature of 50 to 100° C. and an average dwelling time of the reaction mixture of 0.3 to 5 hours in the presence of at least 2.0% by volume, based on the total volume, of hydrogen. The propylene homopolymer obtained in said first polymerization step is transferred together with the Ziegler-Natta catalyst system into an intermediate container, expanded for 0.01 to 5 minutes to less than 5 bar and maintained at a temperature of 10 to 80° C. The pressure in the intermediate container is then increased by 5 to 60 bar by introducing under pressure a gaseous mixture, and the propylene homopolymer is then transferred to a second polymerization step together with the Ziegler-Natta catalyst system. In said second polymerization step, a mixture from propylene and a C2–C8 alk-1-ene is polymerized into the propylene homopolymer at a pressure of 10 to 50 bar, a temperature of 50 to 100° C. and an average dwelling time of 0.5 to 5 hours. The weight ratio between the monomers reacted in the first and those reacted in the second polymerization step are adjusted to be in the range of from 4:1 to 1:1.
摘要翻译：本发明涉及高流动性丙烯嵌段共聚物，其包含50至80重量％的丙烯均聚物和10至70重量％的丙烯共聚物，其具有5至50重量％的C 2 其中聚合成与丙烯不同的烷基-1-烯，并且可以通过采用齐格勒 - 纳塔催化剂体系的两步聚合由气相获得。在第一聚合步骤中，丙烯在10至50巴的压力，50至100℃的温度和在至少2.0％的存在下反应混合物的平均停留时间为0.3至5小时的聚合反应，，基于总体积的氢气。将所述第一聚合步骤中获得的丙烯均聚物与齐格勒 - 纳塔催化剂体系一起转移到中间容器中，膨胀0.01至5分钟至小于5巴，并保持在10至80℃的温度。然后通过在压力下引入气体混合物将中间容器增加5至60巴，然后将丙烯均聚物与齐格勒 - 纳塔催化剂体系一起转移到第二聚合步骤。在所述第二聚合步骤中，将丙烯和C 12 -C 13烷-1-烯的混合物在10至50巴的压力下聚合成丙烯均聚物，温度为50〜100℃，平均停留时间为0.5〜5小时。在第一聚合步骤中反应的单体和在第二聚合步骤中反应的单体之间的重量比被调节至4:1至1:1的范围内。

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