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1. 发明授权

US06812185B2 Preparation of a metal-containing supported catalyst or a supported catalyst component by impregnation of a support material 有权
标题翻译：通过浸渍载体材料制备含金属的负载型催化剂或负载型催化剂组分
公开(公告)号：US06812185B2
公开(公告)日：2004-11-02
申请号：US10402301
申请日：2003-07-30
申请人： David Fischer , Wolfgang Bidell , Ulrich Moll , Joachim Rösch , Franz Langhauser , Roland Hingmann , Heike Gregorius , Carsten Süling , Günther Schweier
发明人： David Fischer , Wolfgang Bidell , Ulrich Moll , Joachim Rösch , Franz Langhauser , Roland Hingmann , Heike Gregorius , Carsten Süling , Günther Schweier
IPC分类号： C08F464
CPC分类号： C08F10/06 , C08F4/65904 , C08F4/65912 , C08F4/65927 , C08F110/06 , C08F4/65916 , C08F4/025 , C08F2500/18 , C08F2500/24 , C08F2500/12 , C08F2500/17 , C08F2500/03
摘要： In a process for preparing a metal-containing supported catalyst or a metal-containing supported catalyst component by impregnation of a support material with an impregnation solution comprising the metal component, the impregnation solution flows through the support material.

2. 发明授权

US06746981B2 Particulate group 4 metallocene-aluminoxane catalyst compositions devoid of preformed support, and their preparation and their use 失效
标题翻译：没有预形成载体的颗粒组4茂金属 - 铝氧烷催化剂组合物及其制备及其应用
公开(公告)号：US06746981B2
公开(公告)日：2004-06-08
申请号：US10323171
申请日：2002-12-18
申请人： Steven P. Diefenbach
发明人： Steven P. Diefenbach
IPC分类号： C08F464
CPC分类号： C08F10/02 , C08F4/65927 , C08F110/02 , Y10S526/943 , C08F4/65912 , C08F2500/24
摘要： Described are solid olefin polymerization catalysts that have, inter alia, very high productivities (at least 18,000 grams of polyethylene per gram of catalyst in one hour) as shown by a standard test procedure for measuring this property or characteristic. Such particulate catalysts can be prepared by prepolymerizing vinylolefin with a Group 4 metallocene-aluminoxane solution, using proportions of vinylolefin (most preferably, ethylene) in the range of about 150 to about 1500, and preferably in the range of about 175 to about 1000, moles per mole of Group 4 metallocene used in forming the solution. The atom ratio of aluminum to Group 4 metal in the solution is in the range of about 150:1 to about 1500:1, and preferably in the range of about 175:1 to about 1000:1. In addition, the Group 4 metallocene ingredient used in forming these highly productive catalysts has in its molecular structure at least one polymerizable olefinic substituent. These particulate catalysts do not contain, and thus are not produced in the presence of, a preformed support such as an inorganic compound (silica or etc.) or a preformed particulate polymeric support.
摘要翻译：描述的是固体烯烃聚合催化剂，其特别是具有非常高的生产率（在1小时内每克催化剂至少18,000克聚乙烯），如用于测量该性质或特性的标准测试程序所示。这样的颗粒催化剂可以通过将乙烯基烯烃与第4族茂金属 - 铝氧烷溶液预聚合来制备，使用在约150至约1500范围内，优选在约175至约1000范围内的乙烯（优选乙烯）摩尔每摩尔用于形成溶液的4族茂金属。溶液中铝与第4族金属的原子比在约150:1至约1500:1的范围内，优选在约175:1至约1000:1的范围内。此外，用于形成这些高产率催化剂的4族金属茂成分在其分子结构中具有至少一个可聚合的烯属取代基。这些颗粒催化剂不含预先形成的载体例如无机化合物（二氧化硅等）或预成型颗粒状聚合物载体，因此不会生成。

3. 发明授权

US06734266B2 Catalyst for olefin polymerization 有权
标题翻译：烯烃聚合催化剂
公开(公告)号：US06734266B2
公开(公告)日：2004-05-11
申请号：US10074662
申请日：2002-02-13
申请人： Xiaoliang Gao , P. Scott Chisholm , Matthew Gerald Kowalchuk , Robert D. Donaldson
发明人： Xiaoliang Gao , P. Scott Chisholm , Matthew Gerald Kowalchuk , Robert D. Donaldson
IPC分类号： C08F464
CPC分类号： C08F10/02 , C08F4/6592 , C08F4/65925 , C08F110/02 , C08F210/16 , C08F4/65916 , C08F210/14
摘要： A supported catalyst for olefin polymerization comprises a combination of a sulfated metal oxide support, an aluminoxane and an organometallic complex of a group 4 metal. The sulfated metal oxide may be quickly and conveniently prepared by, for example, contacting the precursor metal oxide with a sulfuric acid. The supported catalyst of this invention is highly active for olefin polymerization in comparison to conventional catalysts which are prepared with non-sulfated supports.
摘要翻译：用于烯烃聚合的负载催化剂包括硫酸化金属氧化物载体，铝氧烷和第4族金属的有机金属络合物的组合。硫酸化金属氧化物可以通过例如使前体金属氧化物与硫酸接触来快速和方便地制备。与用非硫酸化载体制备的常规催化剂相比，本发明的负载型催化剂对烯烃聚合具有高度的活性。

4. 发明授权

US06689829B2 Process for imparting improved whiteness to polyolefin resins 失效
标题翻译：赋予聚烯烃树脂改善白度的方法
公开(公告)号：US06689829B2
公开(公告)日：2004-02-10
申请号：US10348034
申请日：2003-01-21
申请人： Mark K. Russell
发明人： Mark K. Russell
IPC分类号： C08F464
CPC分类号： C08K5/17 , C08L23/02
摘要： Hydroxyalkylamines can, in addition to imparting antistatic properties, significantly improve the color, i.e., the whiteness, of polyolefin resins produced with chromium-based catalysts and metallocene catalysts. Additionally, such compounds can impart improved whiteness at a loading significantly lower than that required to impart antistatic properties. Surprisingly, the discovered improvement in whiteness is not, however, observed in resins produced using other types of catalysts.
摘要翻译：除了赋予抗静电性之外，羟烷基胺可以显着改善用铬基催化剂和茂金属催化剂生产的聚烯烃树脂的颜色，即白度。此外，这样的化合物可以在负载下赋予改善的白度，显着低于赋予抗静电性能所需的白度。令人惊奇的是，在使用其他类型催化剂制备的树脂中，观察到白度的改善并不是观察到的。

5. 发明授权

US06649712B2 Process for the polymerization of alpha olefins 失效
标题翻译： α-烯烃聚合方法
公开(公告)号：US06649712B2
公开(公告)日：2003-11-18
申请号：US10045875
申请日：2001-11-07
申请人： John A. Ewen
发明人： John A. Ewen
IPC分类号： C08F464
CPC分类号： C08F10/00 , C07F17/00 , C08F4/63912 , C08F4/63927 , C08F4/65912 , C08F110/02 , C08F110/06 , Y10S526/943 , C08F4/65927 , C08F2500/17 , C08F2500/03 , C08F2500/15
摘要： The present invention provides a method for varying the melting points and molecular weights of polyolefins by changing the structure of the catalyst used in the polymerization. The catalysts that are useful in the present invention are chiral, stereorigid metallocene catalyst of the formula R″(C5R″m)2MeQ. The catalysts include a bridge structure between the (C5R′m) groups and may contain substituents on the groups. It has been discovered that the melting points and molecular weights of the polymers produced by such catalysts are influenced by the bridge and substituents added to the (C5R′m) groups. Thus, the present invention provides a method for varying the melting points of the polymer product and a method of varying the molecular weights of the product by changing the components and structure of the metallocene catalysts. The present invention also provides a process for polymerizing olefins in which the melting points and/or molecular weights of the product may be controlled. Also included in the invention is the discovery that the melting points of the products are controlled by the number of inversions in the xylene insoluble fraction of the polymer.
摘要翻译：本发明提供了通过改变聚合中使用的催化剂的结构来改变聚烯烃的熔点和分子量的方法。可用于本发明的催化剂是式R“（C5R''m）2MeQ的手性，立体刚性茂金属催化剂。催化剂包括（C5R'm）基团之间的桥结构，并且可以在基团上含有取代基。已经发现，由这些催化剂制备的聚合物的熔点和分子量受加入（C5R'm）基团的桥和取代基的影响。因此，本发明提供了改变聚合物产物的熔点的方法和通过改变茂金属催化剂的组分和结构来改变产物分子量的方法。本发明还提供了可以控制产物的熔点和/或分子量的烯烃聚合方法。本发明还包括以下发现：产物的熔点由聚合物的二甲苯不溶部分的反转次数控制。

6. 发明授权

US06646071B1 Metal complexes containing bridging heteroatom for olefin-polymerization-process 有权
标题翻译：含有桥连杂原子的金属络合物用于烯烃聚合方法
公开(公告)号：US06646071B1
公开(公告)日：2003-11-11
申请号：US09936120
申请日：2001-09-06
申请人： Jerzy Klosin , Peter N. Nickias
发明人： Jerzy Klosin , Peter N. Nickias
IPC分类号： C08F464
CPC分类号： C07F17/00 , C08F4/65908 , C08F10/00 , C08F210/16 , Y10S526/943 , C08F4/6592 , C08F210/14
摘要： Metal complexes comprising an oxygen, sulfur, or nitrogen containing bridging group which are useful as catalyst components for the polymerization of olefins.
摘要翻译：包含可用作烯烃聚合的催化剂组分的含氧，硫或含氮桥连基团的金属络合物。

7. 发明授权

US06555631B1 Manufacture of polyethylenes 有权
标题翻译：聚乙烯的制造
公开(公告)号：US06555631B1
公开(公告)日：2003-04-29
申请号：US09672612
申请日：2000-09-28
申请人： Lin Wang , Maria Spinu , Joel David Citron
发明人： Lin Wang , Maria Spinu , Joel David Citron
IPC分类号： C08F464
CPC分类号： C08F10/02 , C08F4/61904 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F10/00 , C08F110/02 , C08L23/0815 , C08L2205/02 , C08L2314/06 , C08F4/025 , C08L2666/04 , C08F2500/10 , C08F2500/04 , C08F4/7042
摘要： Blends of two or more polyethylenes are made by reacting ethylene with an oligomerization catalyst that forms &agr;-olefins, and two polymerization catalysts, one of which under the process conditions copolymerizes ethylene and &agr;-olefins, and the other of which under process conditions does not readily copolymerize ethylene and &agr;-olefins. The blends may have improved physical properties and/or processing characteristics.
摘要翻译：两种或更多种聚乙烯的共混物是通过乙烯与形成α-烯烃的低聚催化剂反应制得的，两种聚合催化剂，其中一种在工艺条件下共聚乙烯和α-烯烃，另一种在工艺条件下不是容易使乙烯和α-烯烃共聚。共混物可具有改善的物理性能和/或加工特性。

8. 发明授权

US06544922B1 Cyclopentadienyl-containing low-valent early transition metal olefin polymerization catalysts 失效
标题翻译：含环戊二烯基的低价早期过渡金属烯烃聚合催化剂
公开(公告)号：US06544922B1
公开(公告)日：2003-04-08
申请号：US10198241
申请日：2002-07-18
申请人： Tobin J. Marks , Lubin Luo , Sung Cheol Yoon
发明人： Tobin J. Marks , Lubin Luo , Sung Cheol Yoon
IPC分类号： C08F464
CPC分类号： C08F220/14 , B01J31/2295 , B01J2231/12 , B01J2531/46 , C08F4/6192 , C08F4/65908 , C08F4/6592 , C08F10/00 , C08F12/08 , C08F212/08 , Y10S526/943
摘要： A catalyst system useful to polymerize and co-polymerize polar and non-polar olefin monomers is formed by in situ reduction with a reducing agent of a catalyst precursor comprising {Cp*MRR′n}+{A}− wherein Cp* is a cyclopentadienyl or substituted cyclopentadienyl moiety; M is an early transition metal; R is a C1-C20 hydrocarbyl; R′ are independently selected from hydride, C1-C20 hydrocarbyl, SiR″3, NR″2, OR″, SR″, GeR″3, and SnR″3 containing groups (R″=C1-C10 hydrocarbyl); n is an integer selected to balance the oxidation state of M; and A is a suitable non-coordinating anionic cocatalyst or precursor. This catalyst system may form stereoregular olefin polymers including syndiotactic polymers of styrene and methylmethacrylate and isotactic copolymers of polar and nonpolar olefin monomers such as methylmethacrylate and styrene.
摘要翻译：通过用包含Cp *是环戊二烯基或取代的环戊二烯基部分的催化剂前体的还原剂进行原位还原来形成可用于聚合和共聚极性和非极性烯烃单体的催化剂体系; M是早期过渡金属; R是C1-C20烃基; R'独立地选自氢化物，C 1 -C 20烃基，SiR''3，NR''2，OR“，SR”，GeR'3和含SnR'3的基团（R“= C1- C10烃基）; n是选择以平衡M的氧化态的整数; 而A是合适的非配位阴离子助催化剂或前体。该催化剂体系可以形成包含苯乙烯和甲基丙烯酸甲酯的间同立构聚合物的立构规环烯烃聚合物，以及极性和非极性烯烃单体如甲基丙烯酸甲酯和苯乙烯的全同立构共聚物。

9. 发明授权

US06492292B2 Gelatinous compositions formed from hydroxyaluminoxane, solid compositions formed therefrom, and the use of such compositions as catalyst components 失效
公开(公告)号：US06492292B2
公开(公告)日：2002-12-10
申请号：US09946976
申请日：2001-09-05
申请人： Feng-Jung Wu , Larry S. Simeral
发明人： Feng-Jung Wu , Larry S. Simeral
IPC分类号： C08F464
CPC分类号： B01J31/143 , B01J31/2295 , B01J31/38 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07F5/066 , C07F17/00 , C08F4/65916 , C08F4/65922 , C08F4/65927 , C08F10/00 , C08F110/02 , C08F110/06 , Y10S526/943 , C08F4/65912 , C08F2500/12 , C08F2500/18 , C08F2500/03 , C08F2500/15
摘要： Gelatinous compositions of matter which are useful as polymerization catalyst components and are highly stable in terms of OH-decay rate, as well as similarly stable solid compositions of matter formed from such gelatinous compositions, are described. The gelatinous and solid compositions are formed from hydroxyaluminoxane. Also disclosed is a process comprising converting a hydroxyaluminoxane into a gelatinous composition of matter, whereby the rate of OH-decay for the composition is reduced as compared to that of the hydroxyaluminoxane. Olefin polymerization processes and catalysts formed from these novel compositions of matter also are disclosed.

10. 发明授权

US06462149B1 Control of resin split in single-reactor manufacture of bimodal polyolefins 有权
标题翻译：双模聚烯烃单反应器制造中树脂分离的控制
公开(公告)号：US06462149B1
公开(公告)日：2002-10-08
申请号：US09668232
申请日：2000-09-22
申请人： Michael W. Tilston , Vinayak Maheshwari , Mark Bradley Davis
发明人： Michael W. Tilston , Vinayak Maheshwari , Mark Bradley Davis
IPC分类号： C08F464
CPC分类号： C08F10/00 , C08F4/65916 , C08F4/65925 , C08F110/02 , C08F2400/02 , Y10S526/943 , C08F4/65904 , C08F2/00 , C08F4/6557 , C08F4/68 , C08F2500/05
摘要： Bimodal resin products are produced in a single reactor by using two bicomponent catalyst compositions, each having a high molecular weight and a low molecular weight component, in different ratios. The HMW/LMW split of the final resin product is controlled accurately by controlling the ratio of the feed of the two bicomponent catalyst compositions. Bimodal or polymodal effects are also achieved for properties or characteristics other than molecular weight. More complex results can be achieved with more than two components. The invention is applicable to a wide variety of polymer products, particularly polyolefins and polyethylene.
摘要翻译：通过使用两种具有不同比例的高分子量和低分子量组分的双组分催化剂组合物，在单个反应器中制备双峰树脂产物。通过控制两种双组分催化剂组合物的进料比例，精确控制最终树脂产品的HMW / LMW裂缝。对于分子量以外的性质或特性，也可实现双峰或多模态效应。可以通过两个以上的组件实现更复杂的结果。本发明适用于各种聚合物产品，特别是聚烯烃和聚乙烯。

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