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1. 发明申请

US20100018580A1 Method for the Manufacture of a Solar Cell and the Resulting Solar Cell 审中-公开
标题翻译：太阳能电池的制造方法和太阳能电池的制造方法
公开(公告)号：US20100018580A1
公开(公告)日：2010-01-28
申请号：US12554410
申请日：2009-09-04
申请人： Dirk Habermann , Patrik Müller
发明人： Dirk Habermann , Patrik Müller
IPC分类号： H01L31/00 , H01L31/18
CPC分类号： H01L31/02168 , H01L31/022425 , Y02E10/50
摘要： In a method for the manufacture of a solar cell from a silicon substrate to the front and back surfaces are firstly applied a first antireflection coating with an optical refractive index n between 3.6 and 3.9. To the latter is applied a second antireflection with an optical refractive index n between 1.94 and 2.1. The antireflection coatings are separated down to the underlying silicon substrate in order to introduce metal contacts to the silicon substrate into the antireflection coatings.
摘要翻译：在从硅衬底到前表面和后表面的太阳能电池的制造方法中首先应用光折射率n在3.6和3.9之间的第一抗反射涂层。对光纤折射率n在1.94与2.1之间的第二次抗反射应用于后者。将抗反射涂层分离到下面的硅衬底，以便将金属接触引入硅衬底进入抗反射涂层。

2. 发明授权

US07358381B2 Racemoselective preparation of bridged metallocene complexes having unsubstituted or 2-substituted indenyl ligands 有权
标题翻译：具有未取代或2-取代茚基配体的桥连茂金属络合物的外消旋选择性制备
公开(公告)号：US07358381B2
公开(公告)日：2008-04-15
申请号：US10532522
申请日：2003-10-22
申请人： Hans-Robert-Hellmuth Damrau , Patrik Müller , Valerie Garcia , Christian Sidot , Christian Tellier , Jean-François Lelong , Eric Huriez
发明人： Hans-Robert-Hellmuth Damrau , Patrik Müller , Valerie Garcia , Christian Sidot , Christian Tellier , Jean-François Lelong , Eric Huriez
IPC分类号： C07F17/00 , B01J31/00 , C08F4/44
CPC分类号： C07F17/00 , C08F10/00 , Y10S526/943 , C08F4/65927
摘要： The invention relates to a process for preparing racemic metallocene complexes by reacting transition metal complexes with cyclopentadienyl derivatives of alkali metals or alkaline earth metals and heating the reaction mixture obtained in this way to a temperature in the range from −78 to 250° C., to the corresponding metallocene complexes themselves and to their use as catalysts or as constituents of catalysts for the polymerization of olefinically unsaturated compounds or as reagents or catalysts in stereoselective synthesis.
摘要翻译：本发明涉及一种通过使过渡金属络合物与碱金属或碱土金属的环戊二烯基衍生物反应制备外消旋茂金属络合物的方法，并将以这种方式获得的反应混合物加热至-78至250℃的温度，相应的茂金属络合物本身以及它们作为催化剂或用作烯属不饱和化合物的聚合催化剂或作为立体选择性合成中的试剂或催化剂的成分的用途。

3. 发明授权

US07053160B1 Metallocene monohalogenides 有权
标题翻译：茂金属一卤化物
公开(公告)号：US07053160B1
公开(公告)日：2006-05-30
申请号：US09701658
申请日：1999-11-18
申请人： Carsten Bingel , Hans-Herbert Brintzinger , Hans-Robert-Hellmuth Damrau , Patrik Müller , Jürgen Suhm
发明人： Carsten Bingel , Hans-Herbert Brintzinger , Hans-Robert-Hellmuth Damrau , Patrik Müller , Jürgen Suhm
IPC分类号： C08F4/76 , C08F4/52 , C07F17/00
CPC分类号： C08F10/00 , C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/06 , C08F110/06 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F2500/15
摘要： Novel metallocene monohalides can be used in the polymerization of olefins.
摘要翻译：新型茂金属一卤化物可用于烯烃聚合。

4. 发明授权

US07193099B2 Racemoselective preparation of isolable ansa-metallocene biphenoxide complexes 有权
标题翻译：可分离的安全 - 金属茂双氧化物配合物的外消旋选择性制备
公开(公告)号：US07193099B2
公开(公告)日：2007-03-20
申请号：US10532570
申请日：2003-10-22
申请人： Hans-Robert-Hellmuth Damrau , Patrik Müller , Valerie Garcia , Christian Sidot , Christian Tellier , Jean-François Lelong
发明人： Hans-Robert-Hellmuth Damrau , Patrik Müller , Valerie Garcia , Christian Sidot , Christian Tellier , Jean-François Lelong
IPC分类号： C07F17/00 , B01J31/00 , C08F4/44
CPC分类号： C07F17/00
摘要： The invention relates to a process for preparing racemic metallocene biphenoxide complexes by reacting bridged transition metal complexes with cyclopentadienyl derivatives of alkali metals or alkaline earth metals and heating the reaction mixture obtained in this way to a temperature in the range from −78 to 250° C., to the corresponding metallocene biphenoxide complexes and to their use as catalysts or as constituents of catalysts for the polymerization of olefinically unsaturated compounds or as reagents or catalysts in stereoselective synthesis.
摘要翻译：本发明涉及一种通过使桥连过渡金属配合物与碱金属或碱土金属的环戊二烯基衍生物反应来制备外消旋茂金属二氧化物络合物的方法，并将以这种方式获得的反应混合物加热至-78至250℃ 相应的金属茂双氧化物配合物，以及它们作为催化剂或用作烯属不饱和化合物的聚合催化剂或作为立体选择性合成中的试剂或催化剂的成分的用途。

5. 发明授权

US06992204B2 Method for the selective production of racemic metallocene complexes 有权
标题翻译：选择性生产外消旋茂金属络合物的方法
公开(公告)号：US06992204B2
公开(公告)日：2006-01-31
申请号：US10312359
申请日：2001-06-28
申请人： Robert Damrau , Patrik Müller , Eva Royo , Hans-Herbert Brintzinger
发明人： Robert Damrau , Patrik Müller , Eva Royo , Hans-Herbert Brintzinger
IPC分类号： C07F17/00 , B01J31/00 , C08F4/44
CPC分类号： C08F10/00 , C07B53/00 , C07F17/00 , Y10S526/943 , C08F4/65927 , C08F4/64079
摘要： The invention relates to a method for producing racemic metallocene complexes by reacting bridged or non-bridged transition metal complexes with cyclopentadienyl derivatives of alkaline or alkaline earth metals and optionally, subsequently substituting the phenolate ligands.
摘要翻译：本发明涉及一种通过使桥连或非桥连的过渡金属络合物与碱金属或碱土金属的环戊二烯基衍生物反应制备外消旋金属茂络合物的方法，任选地随后用酚盐配体取代。

6. 发明申请

US20100274035A1 Process for Recycling Cyclopentadienyl Derivatives and Preparing Metallocenes From Recycled, Substituted Cyclopentadienyl Derivatives 有权
标题翻译：回收环戊二烯基衍生物的方法和从再循环的取代的环戊二烯基衍生物制备金属茂
公开(公告)号：US20100274035A1
公开(公告)日：2010-10-28
申请号：US12086711
申请日：2006-12-19
申请人： Patrik Müller , Robert L. Jones , Reynald Chevalier , Christian Sidot , Valerie Garcia
发明人： Patrik Müller , Robert L. Jones , Reynald Chevalier , Christian Sidot , Valerie Garcia
IPC分类号： C07F17/00 , C07C7/12
CPC分类号： C07F17/00 , C07C7/12 , C07F7/0832 , C07C13/465
摘要： The present invention relates to a process for recycling cyclopentadienyl derivatives of the formulae (I) and (I′), a process for preparing metallocenes of the formula (III) from cyclopentadienyl derivatives of the formulae (I) and (I′) or from bridged biscyclopentadienyl derivatives of the formula (II), in which the cyclopentadienyl derivatives of the formulae (I), (I′) or (II) which are used have been at least partly recovered and purified by means of liquid-solid chromatography, and the use of liquid-solid chromatography for purifying substituted, recovered cyclopentadienyl derivatives of the formulae (I), (I′) or (II).
摘要翻译：本发明涉及用于回收式（I）和（I'）的环戊二烯基衍生物的方法，由式（I）和（I'）的环戊二烯基衍生物制备式（III）的金属茂的方法或式（II）的桥连双环戊二烯基衍生物，其中使用的式（I），（I'）或（II）的环戊二烯基衍生物已经通过液固色谱至少部分回收和纯化，以及使用液 - 固色谱来纯化式（I），（I'）或（II）的取代的回收的环戊二烯基衍生物。

7. 发明授权

US07671223B2 Process for the racemoselective preparation of ansa-metallocenes 有权
公开(公告)号：US07671223B2
公开(公告)日：2010-03-02
申请号：US11579526
申请日：2005-05-04
申请人： Valerie Garcia , Patrik Müller , Christian Sidot , Christian Tellier , Ludovic Delancray , Reynald Chevalier
发明人： Valerie Garcia , Patrik Müller , Christian Sidot , Christian Tellier , Ludovic Delancray , Reynald Chevalier
IPC分类号： C07F17/00 , C07F7/00
CPC分类号： C07F17/00
摘要： The present invention relates to a process for the racemoselective preparation of ansa-metallocene complexes of the formula (I) which comprises reacting a ligand starting compound of the formula (II) with a transition metal compound of the formula (III) (LB)yM1(NR3R4)Xx-1 (III) where R1, R1′ are identical or different and are each hydrogen or an organic radical having from 1 to 40 carbon atoms, R2, R2′ are identical or different and are each hydrogen or an organic radical having from 1 to 40 carbon atoms, R3 is an organic radical having from 1 to 40 carbon atoms, R4 is hydrogen or an organic radical having from 1 to 40 carbon atoms, T, T′ are identical or different and are each a divalent organic group which has from 1 to 40 carbon atoms and together with the cyclopentadienyl ring forms at least one further saturated or unsaturated, substituted or unsubstituted ring system which has a ring size of from 5 to 12 atoms, where T and T′ may contain the heteroatoms Si, Ge, N, P, As, Sb, O, S, Se or Te within the ring system fused to the cyclopentadienyl ring, A is a bridge consisting of a divalent atom or a divalent group, M1 is an element of group 3, 4, 5 or 6 of the Periodic Table of the Elements or the lanthanides, the radicals X are identical or different and are each an organic or inorganic radical which can be substituted by a cyclopentadienyl anion, x is a natural number from 3 to 6, M2 is an alkali metal, an alkaline earth metal or a magnesium monohalide fragment, p is 1 in the case of doubly positively charged metal ions or is 2 in the case of singly positively charged metal ions or metal ion fragments, LB is an uncharged Lewis-base ligand and y is a natural number from 0 to 6, and also a further process for the racemoselective preparation of ansa-metallocene complexes of the formula (IV) starting from the metallocene complexes of the formula (I) prepared by the first process, the use of transition metal compounds of the formula (III) for preparing metallocenes and also specific transition metal compounds of the formula (III).

8. 发明授权

US07951970B2 Process for recycling cyclopentadienyl derivatives and preparing metallocenes from recycled, substituted cyclopentadienyl derivatives 有权
标题翻译：回收环戊二烯基衍生物的方法和从循环的取代的环戊二烯基衍生物制备金属茂的方法
公开(公告)号：US07951970B2
公开(公告)日：2011-05-31
申请号：US12086711
申请日：2006-12-19
申请人： Patrik Müller , Robert L. Jones , Reynald Chevalier , Christian Sidot , Valerie Garcia
发明人： Patrik Müller , Robert L. Jones , Reynald Chevalier , Christian Sidot , Valerie Garcia
IPC分类号： C07F7/00 , C07F17/00 , C07C7/12
CPC分类号： C07F17/00 , C07C7/12 , C07F7/0832 , C07C13/465
摘要： The present invention relates to a process for recycling cyclopentadienyl derivatives of the formulae (I) and (I′), a process for preparing metallocenes of the formula (III) from cyclopentadienyl derivatives of the formulae (I) and (I′) or from bridged biscyclopentadienyl derivatives of the formula (II), in which the cyclopentadienyl derivatives of the formulae (I), (I′) or (II) which are used have been at least partly recovered and purified by means of liquid-solid chromatography, and the use of liquid-solid chromatography for purifying substituted, recovered cyclopentadienyl derivatives of the formulae (I), (I′) or (II).
摘要翻译：本发明涉及用于回收式（I）和（I'）的环戊二烯基衍生物的方法，由式（I）和（I'）的环戊二烯基衍生物制备式（III）的金属茂的方法或式（II）的桥连双环戊二烯基衍生物，其中使用的式（I），（I'）或（II）的环戊二烯基衍生物已经通过液固色谱至少部分回收和纯化，以及使用液 - 固色谱来纯化式（I），（I'）或（II）的取代的回收的环戊二烯基衍生物。

9. 发明授权

US07635783B2 Meso-selective synthesis of ansa-metallocenes 有权
公开(公告)号：US07635783B2
公开(公告)日：2009-12-22
申请号：US10583574
申请日：2004-12-15
申请人： Reynald Chevalier , Patrik Müller , Christian Sidot , Christian Tellier , Valerie Garcia , Ludovic Delancray
发明人： Reynald Chevalier , Patrik Müller , Christian Sidot , Christian Tellier , Valerie Garcia , Ludovic Delancray
IPC分类号： C07F17/00 , B01J31/00
CPC分类号： C07F17/00 , C08F10/00 , C08F110/06 , Y10S526/943 , C08F4/65927
摘要： The present invention relates to a process for the meso-selective preparation of ansa-metallocene complexes of the formula (I), which comprises reacting a ligand starting compound of the formula (II) with a transition metal compound of the formula III, where R1, R1 are identical or different and are each hydrogen or an organic radical having from 1 to 40 carbon atoms, R2, R2 are identical or different and are each hydrogen or an organic radical having from 1 to 40 carbon atoms, R3 is a bulky organic radical which has at least 3 carbon atoms, is bound to the oxygen atom via a nonaromatic carbon or silicon atom and may be substituted by halogen atoms or further organic radicals having from 1 to 20 carbon atoms and may also contain heteroatoms selected from the group consisting of Si, N, P, O and S, T, T′ are identical or different and are each a divalent organic group which has from 1 to 40 carbon atoms and together with the cyclopentadienyl ring forms at least one further saturated or unsaturated, substituted or unsubstituted ring system having a ring size of from 5 to 12 atoms, where T and T′ may contain the heteroatoms Si, Ge, N, P, As, Sb, O, S, Se or Te within the ring system fused to the cyclopentadienyl ring, A is a bridge consisting of a divalent atom or a divalent group, M1 is an element of group 3, 4, 5 or 6 of the Periodic Table of the Elements or the lanthanides, the radicals X are identical or different and are each an organic or inorganic radical which is able to be replaced by a cyclopentadienyl anion, x is a natural number from 1 to 4, M2 is an alkali metal, an alkaline earth metal or a magnesium monohalide fragment, p is 1 in the case of doubly positively charged metal ions or 2 in the case of singly positively charged metal ions or metal ion fragments, LB is an uncharged Lewis base ligand, and y is a natural number from 0 to 6, and also the subsequent reaction of these complexes to form ansa-metallocenes of the formula (IV), the use of transition metal compounds of the formula (III) for preparing metallocenes and also transition metal compounds of the formula (III), ansa-metallocene complexes of the formula (I) and the use of these as constituents of catalyst systems for the polymerization of olefines.

10. 发明授权

US07619106B2 Preparation of partially hydrogenated rac-ansa-metallocene complexes 有权
标题翻译：部分氢化的外消旋 - 茂金属络合物的制备
公开(公告)号：US07619106B2
公开(公告)日：2009-11-17
申请号：US10532523
申请日：2003-10-22
申请人： Hans-Robert-Hellmuth Damrau , Patrik Müller , Valerie Garcia , Christian Sidot , Christian Tellier , Stéphanie Duchiron , Jean-Francois Lelong
发明人： Hans-Robert-Hellmuth Damrau , Patrik Müller , Valerie Garcia , Christian Sidot , Christian Tellier , Stéphanie Duchiron , Jean-Francois Lelong
IPC分类号： C07F17/00 , B01J31/00 , C08F4/44
CPC分类号： B01J31/2234 , B01J31/2295 , B01J2531/30 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/56 , B01J2531/57 , B01J2531/58 , B01J2531/60 , C07B53/00 , C07F17/00 , C08F10/00 , Y10S526/943 , C08F4/65927
摘要： The invention relates to a process for preparing hydrogenated or partially hydrogenated, racemic ansa-metallocene complexes by reacting bridged or unbridged transition metal complexes with alkali metal compounds or alkaline earth metal compounds, heating the resulting reaction mixture to a temperature in the range from −78 to 250° C. and at least partially hydrogenating the reaction products in the presence of a suitable catalyst, to the corresponding hydrogenated or partially hydrogenated metallocenes and to their use as catalysts or as a constituent of catalysts for the polymerization of olefinically unsaturated compounds or as reagents or catalysts in stereoselective synthesis.
摘要翻译：本发明涉及一种通过使桥联或未桥连的过渡金属络合物与碱金属化合物或碱土金属化合物反应制备氢化或部分氢化的外消旋的仲茂金属络合物的方法，将得到的反应混合物加热至-78℃ 至250℃，并在合适的催化剂存在下将反应产物至少部分氢化为相应的氢化或部分氢化的金属茂，并将其用作催化剂或用作烯属不饱和化合物聚合的催化剂或作为试剂或催化剂在立体选择性合成中。

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