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1. 发明申请

US20090018348A1 Heterocyclic Fused Selenophene Monomers 有权
公开(公告)号：US20090018348A1
公开(公告)日：2009-01-15
申请号：US11777362
申请日：2007-07-13
申请人： Steffen Zahn , Carrie A. Costello , Mark McLaws
发明人： Steffen Zahn , Carrie A. Costello , Mark McLaws
IPC分类号： C07D495/04 , C07D345/00
CPC分类号： C07D517/04 , C07D333/28 , C07D345/00
摘要： A heterocyclic fused selenophenes and a method of making a heterocyclic fused selenophenes of formula (1): wherein X is S or Se, Y is S or Se, wherein one or both of X and Y is Se, R is a substituent group. The monomer being capable of polymerization to form an electrically conductive polymer or oligomer.

2. 发明授权

US07432340B2 Fluorinated alkyl substituted-thieno[3,4-]thiophene monomers and polymers therefrom 有权
标题翻译：氟化烷基取代噻吩并[3,4-b]噻吩单体及其聚合物
公开(公告)号：US07432340B2
公开(公告)日：2008-10-07
申请号：US11128538
申请日：2005-05-13
申请人： Steffen Zahn , Gauri Sankar Lal , William Franklin Burgoyne, Jr. , Kristen Elaine Minnich , Andrew Francis Nordquist , Lloyd Mahlon Robeson , Francis Joseph Waller
发明人： Steffen Zahn , Gauri Sankar Lal , William Franklin Burgoyne, Jr. , Kristen Elaine Minnich , Andrew Francis Nordquist , Lloyd Mahlon Robeson , Francis Joseph Waller
IPC分类号： C08G73/24 , C08F4/80 , C08G75/00
CPC分类号： C08G61/123 , C08G61/126
摘要： Partially and fully fluorinated alkyl substituted thienothiophene monomers (and polymers thereof) wherein the monomers are represented by the formula: wherein R is a partially or fully fluorinated primary, secondary or tertiary alkyl having from 1 to 8 carbon atoms; and X and X′ are independently selected from the group consisting of H, F, Cl, Br, I, MgCl, MgBr, Mgl, Sn(R′)3, CH═CHR″, —OR″, —COOR″, —S—COR″, —B(OR″)2, —COR″, —C≡CH, and a polymerizable cyclic pi-conjugated carbon-ring structure optionally comprising S, N or O heteroatoms; wherein R′ is a primary, secondary or tertiary alkyl having from 1 to 6 carbon atoms, and R″ is H or a primary, secondary or tertiary alkyl having from 1 to 6 carbon atoms.
摘要翻译：部分和完全氟化的烷基取代的噻吩并噻吩单体（及其聚合物），其中单体由下式表示：其中R是具有1至8个碳原子的部分或完全氟化的伯，仲或叔烷基; 并且X和X'独立地选自H，F，Cl，Br，I，MgCl，MgBr，MgI，Sn（R'）3，CH-CHR“， - OR“，-COOR”，-S-COR“，-B（OR”）2，-COR“，-C≡CH和可聚合的环状π-共轭碳任选地包含S，N或O杂原子的环结构; 其中R'是具有1至6个碳原子的伯，仲或叔烷基，R“是H或具有1至6个碳原子的伯，仲或叔烷基。

3. 发明申请

US20060208233A1 Pentafluorosulfanyl-substituted thienothiophene monomers and conducting polymers 失效
标题翻译：五氟硫烷基取代的噻吩并噻吩单体和导电聚合物
公开(公告)号：US20060208233A1
公开(公告)日：2006-09-21
申请号：US11439553
申请日：2006-05-23
申请人： Steffen Zahn , Andrew Nordquist , Kristen Minnich , Guari Lal , William Burgoyne , Axel Klauck-Jacobs
发明人： Steffen Zahn , Andrew Nordquist , Kristen Minnich , Guari Lal , William Burgoyne , Axel Klauck-Jacobs
IPC分类号： H01B1/12
CPC分类号： C07D495/04 , C07D333/28 , C08G61/126 , H01G11/48 , Y02E60/13
摘要： Thienothiophene monomers having an SF5 group and conducting oligomers and polymers formed by the polymerization of such monomers and their use as hole injection materials, charge transport materials, or as semiconductors. The compound may be of the formula: where X and X′ are independently H, halogen atoms (e.g., F, Cl, Br, and 1), MgCl, MgBr, Mgl, Sn(R′)3, where R′ comprises C1-6 alkyl or —OC16 alkyl, boronic acid, boronic ester, -CH=CHR″ (where R″ comprises H or C1-6 alkyl), —OC1-6 alkyl, —COOC1-6 alkyl, —S—COR′″ and —COR ″ (where R ″ comprises H or c1-6 alkyl), —C≡CH, or polymerizable aromatic rings (such as phenyl, naphthalene, pyrrole, dithiophene, thienothiophene, thiophene and so forth).
摘要翻译：具有SF 5 N基团的噻吩并噻吩单体和通过这些单体的聚合形成的导电低聚物和聚合物及其作为空穴注入材料，电荷传输材料或半导体的用途。化合物可以具有下式：其中X和X'独立地为H，卤素原子（例如F，Cl，Br和1），MgCl，MgBr，Mg1，Sn（R'）3 >，其中R'包含C 1-6烷基或-OC 1 - 亚烷基，硼酸，硼酸酯，-CH = CHR' '（其中R“包括H或C 1-6烷基），-OC 1-6烷基，-COOC 1-6烷基，-S-COR“和-COR”（其中R“包括H或C 1-6烷基），-C≡CH或可聚合芳环（例如苯基，萘，吡咯，二噻吩，噻吩并噻吩，噻吩等）。

4. 发明授权

US07981323B2 Selenium containing electrically conductive copolymers 有权
标题翻译：含硒导电共聚物
公开(公告)号：US07981323B2
公开(公告)日：2011-07-19
申请号：US11777386
申请日：2007-07-13
申请人： Steffen Zahn
发明人： Steffen Zahn
IPC分类号： H01B1/12
CPC分类号： C07D517/04 , C08L25/18 , C08L65/00 , H01B1/127 , H01G11/48 , H01G11/56 , H01L51/0036 , H01L51/0062 , H01L51/0069 , Y02E60/13 , C08L2666/06
摘要： Monomeric, oligomeric and polymeric electrically conductive compounds and methods of making the compounds having a repeating unit having formula P1, as follows: where X is S or Se, Y is S or Se, wherein one or both of X and Y is Se, R is a substituent group capable of bonding to the ring structure. R may include hydrogen or isotopes thereof, hydroxyl, alkyl, including C1 to C20 primary, secondary or tertiary alkyl groups, arylalkyl, alkenyl, perfluoroalkyl, perfluororaryl, aryl, alkoxy, cycloalkyl, cycloalkenyl, alkanoyl, alkylthio, aryloxy, alkylthioalkyl, alkynyl, alkylaryl, arylalkyl, amido, alkylsulfinyl, alkoxyalkyl, alkylsulfonyl, aryl, arylamino, diarylamino, alkylamino, dialkylamino, arylarylamino, arylthio, heteroaryl, arylsulfinyl, alkoxycarbonyl, arylsulfonyl, carboxyl, halogen, nitro, cyano, sulfonic acid, or alkyl or phenyl substituted with one or more sulfonic acid, phosphoric acid, carboxylic acid, halo, amino, nitro, hydroxyl, cyano or epoxy moieties. Electrical devices utilizing the electrically conductive polymers is also disclosed.
摘要翻译：单体，低聚物和聚合物导电化合物和制备具有式P1重复单元的化合物的方法如下：其中X是S或Se，Y是S或Se，其中X和Y中的一个或两个是Se，R 是能够与环结构键合的取代基。 R可包括氢或其同位素，羟基，烷基，包括C1至C20伯，仲或叔烷基，芳基烷基，烯基，全氟烷基，全氟芳基，芳基，烷氧基，环烷基，环烯基，烷酰基，烷硫基，芳氧基，烷硫基烷基，炔基，烷基芳基，芳基烷基，酰胺基，烷基亚磺酰基，烷氧基烷基，烷基磺酰基，芳基，芳基氨基，二芳基氨基，烷基氨基，二烷基氨基，芳基芳基氨基，芳硫基，杂芳基，芳基亚硫酰基，烷氧基羰基，芳基磺酰基，羧基，卤素，硝基，氰基，磺酸或烷基或苯基取代与一个或多个磺酸，磷酸，羧酸，卤素，氨基，硝基，羟基，氰基或环氧部分。还公开了利用导电聚合物的电气装置。

5. 发明申请

US20070238854A1 Heterocyclic Fused Isothiazole and Isoselenazole Monomers and Conducting Polymers 审中-公开
标题翻译：杂环稠合异噻唑和异丝烯唑单体和导电聚合物
公开(公告)号：US20070238854A1
公开(公告)日：2007-10-11
申请号：US11733335
申请日：2007-04-10
申请人： Steffen Zahn , Michael Ford , Joanne Cunningham
发明人： Steffen Zahn , Michael Ford , Joanne Cunningham
IPC分类号： C07D498/02 , C08G75/32
CPC分类号： C07D513/04 , C07D517/04 , C08G61/123 , C08G61/124 , C08G61/125 , C08G61/126
摘要： A composition of matter having the following structure: where X is S or Se; and Y is NH, O, S, or Se; and R is an H, a C1-8F3-17 primary, secondary, or tertiary fluoroalkyl, a C1-20 primary, secondary or tertiary alkyl, or a halogen atom, and a composition of matter comprising polymerized units having the following structure: where X is S or Se; and Y is NH, O, S, or Se; and R is an H, a C1-8F3-17 primary, secondary, or tertiary fluoroalkyl, a C1-20 primary, secondary or tertiary alkyl, or a halogen atom.
摘要翻译：具有以下结构的物质组合物：其中X是S或Se; Y是NH，O，S或Se; 并且R是H，一个C 1〜8个C 3〜17个伯，仲或叔氟代烷基，C 1-120〜，仲或叔烷基或卤素原子，以及包含具有以下结构的聚合单元的物质组合物：其中X是S或Se; Y是NH，O，S或Se; 并且R是H，一个C 1〜8个C 3〜17个伯，仲或叔氟代烷基，C 1-120〜仲或叔烷基或卤素原子。

6. 发明授权

US07041910B2 Emissive, high charge transport polymers 失效
标题翻译：发射，高电荷输送聚合物
公开(公告)号：US07041910B2
公开(公告)日：2006-05-09
申请号：US10621041
申请日：2003-07-15
申请人： Timothy M. Swager , Steffen Zahn
发明人： Timothy M. Swager , Steffen Zahn
IPC分类号： H01B7/00
CPC分类号： C09K11/06 , C08G61/02 , C09K9/02 , C09K2211/1416 , C09K2211/1425 , H01L51/0035 , H01L51/0043 , H01L51/0052 , H01L51/42 , H01L51/50 , Y02E10/549
摘要： The present invention generally relates to stable emissive aggregates of polymers. The aggregates are composed of various polymer molecules arranged in such a way as to allow extended electronic couplings between nearby polymer molecules, enhancing exciton transport, while minimizing the effects of quenching due to interchain interactions. For example, the polymer molecules may be arranged in a non-aligned, electronically-communicative manner (for example, at an oblique angle), stabilized by various methods such as chemical linkages or physical interactions. Within the aggregate, electronic interactions along the polymer molecule may extend to nearby polymer molecules, which may be observed as a shift in the absorption spectra relative to a random dispersion. Light emitted from the aggregate may be polarized in some cases, for example, linearly or circularly, which may be caused by chiral arrangements of polymers within the aggregate (the polymers themselves may or may not be chiral). These aggregates may find widespread use, for example, in enantiomeric detectors, electrochemical devices, photodetectors, organic diodes, sensors, light sources, or photovoltaic devices.
摘要翻译：本发明一般涉及聚合物的稳定发射聚集体。聚集体由各种聚合物分子组成，这些聚合物分子以允许附近聚合物分子之间的扩展电子耦合方式排列，增强激子传输，同时最小化由于链间相互作用引起的猝灭的影响。例如，聚合物分子可以以不对准的电子通信方式（例如，以倾斜角度）排列，通过诸如化学键或物理相互作用的各种方法来稳定。在聚合物中，沿着聚合物分子的电子相互作用可以延伸到附近的聚合物分子，这可以作为相对于随机分散体的吸收光谱的偏移而被观察到。从聚集体发射的光可能在某些情况下极化，例如线性或圆形，这可能由聚合物内的聚合物的手性排列引起（聚合物本身可能是或可能不是手性的）。这些聚集体可以广泛用于例如对映体检测器，电化学装置，光电检测器，有机二极管，传感器，光源或光伏器件中。

7. 发明授权

US08268195B2 Electrically conductive films formed from dispersions comprising polythiophenes and ether containing polymers 有权
标题翻译：由包含聚噻吩和含醚聚合物的分散体形成的导电膜
公开(公告)号：US08268195B2
公开(公告)日：2012-09-18
申请号：US12388862
申请日：2009-02-19
申请人： Shiying Zheng , Steffen Zahn , Gang Chris Han-Adebekun
发明人： Shiying Zheng , Steffen Zahn , Gang Chris Han-Adebekun
IPC分类号： H01B1/00 , C08G75/00 , C08G73/00 , C08G73/06
CPC分类号： C09D5/24 , C08G2261/1424 , C08G2261/3223 , C08G2261/3243 , C08G2261/722 , C08G2261/794 , C08L71/00 , C08L79/02 , C08L81/06 , C09D7/65 , C09D11/52 , C09D165/00 , C09D179/04 , H01B1/127 , H01B1/128 , H01L51/0037 , H01L51/105 , H01L51/5203 , Y02E10/549 , C08L81/00 , C08L2666/22 , C08L71/126
摘要： An aqueous dispersion and a method for making an aqueous dispersion. The dispersion including at least one conductive polymer such as a polythienothiophene, at least one ether containing polymer and optionally at least one colloid-forming polymeric acid and one non-fluorinated polymeric acid. Devices utilizing layers formed of the inventive dispersions are also disclosed.
摘要翻译：水性分散体和水分散体的制造方法。该分散体包括至少一种导电聚合物如聚噻吩并噻吩，至少一种含醚聚合物和任选的至少一种胶体形成聚合酸和一种非氟化聚合酸。还公开了利用由本发明分散体形成的层的装置。

8. 发明申请

US20100081007A1 Electrically Conductive Films Formed From Dispersions Comprising Polythiophenes and Ether Containing Polymers 有权
标题翻译：由包含聚噻吩和含醚聚合物的分散体形成的导电膜
公开(公告)号：US20100081007A1
公开(公告)日：2010-04-01
申请号：US12388862
申请日：2009-02-19
申请人： Shiying Zheng , Steffen Zahn , Gang Chris Han-Adebekun
发明人： Shiying Zheng , Steffen Zahn , Gang Chris Han-Adebekun
IPC分类号： H01B1/12 , B32B27/00
CPC分类号： C09D5/24 , C08G2261/1424 , C08G2261/3223 , C08G2261/3243 , C08G2261/722 , C08G2261/794 , C08L71/00 , C08L79/02 , C08L81/06 , C09D7/65 , C09D11/52 , C09D165/00 , C09D179/04 , H01B1/127 , H01B1/128 , H01L51/0037 , H01L51/105 , H01L51/5203 , Y02E10/549 , C08L81/00 , C08L2666/22 , C08L71/126
摘要： An aqueous dispersion and a method for making an aqueous dispersion. The dispersion including at least one conductive polymer such as a polythienothiophene, at least one ether containing polymer and optionally at least one colloid-forming polymeric acid and one non-fluorinated polymeric acid. Devices utilizing layers formed of the inventive dispersions are also disclosed.
摘要翻译：水性分散体和水分散体的制造方法。该分散体包括至少一种导电聚合物如聚噻吩并噻吩，至少一种含醚聚合物和任选的至少一种胶体形成聚合酸和一种非氟化聚合酸。还公开了利用由本发明分散体形成的层的装置。

9. 发明授权

US07241904B2 Pentafluorosulfanyl-substituted thienothiophene monomers and conducting polymers 失效
标题翻译：五氟硫烷基取代的噻吩并噻吩单体和导电聚合物
公开(公告)号：US07241904B2
公开(公告)日：2007-07-10
申请号：US11439553
申请日：2006-05-23
申请人： Steffen Zahn , Andrew Francis Nordquist , Kristen Elaine Minnich , Guari Sankar Lal , William Franklin Burgoyne, Jr. , Axel Klauck-Jacobs
发明人： Steffen Zahn , Andrew Francis Nordquist , Kristen Elaine Minnich , Guari Sankar Lal , William Franklin Burgoyne, Jr. , Axel Klauck-Jacobs
IPC分类号： C07D333/04
CPC分类号： C07D495/04 , C07D333/28 , C08G61/126 , H01G11/48 , Y02E60/13
摘要： Disclosed are monomers of the formula:
摘要翻译：公开了下式的单体：

10. 发明授权

US07060846B2 Pentafluorosulfanyl-substituted thienothiophene monomers and conducting polymers 有权
标题翻译：五氟硫烷基取代的噻吩并噻吩单体和导电聚合物
公开(公告)号：US07060846B2
公开(公告)日：2006-06-13
申请号：US11229516
申请日：2005-09-20
申请人： Steffen Zahn , Andrew Francis Nordquist , Kristen Elaine Minnich , Guari Sankar Lal , William Franklin Burgoyne, Jr. , Axel Klauck-Jacobs
发明人： Steffen Zahn , Andrew Francis Nordquist , Kristen Elaine Minnich , Guari Sankar Lal , William Franklin Burgoyne, Jr. , Axel Klauck-Jacobs
IPC分类号： C07D333/04
CPC分类号： C07D495/04 , C07D333/28 , C08G61/126 , H01G11/48 , Y02E60/13
摘要： Thienothiophene monomers having an SF5 group and conducting oligomers and polymers formed by the polymerization of such monomers and their use as hole injection materials, charge transport materials, or as semiconductors. The compound may be of the formula: where X and X′ are independently H, halogen atoms (e.g., F, Cl, Br, and I), MgCl, MgBr, Mgl, Sn(R′)3, where R′ comprises C1-6 alkyl or —OC1-6 alkyl, boronic acid, boronic ester, —CH═CHR″ (where R″ comprises H or C1-6 alkyl), —OC1-6 alkyl, —COOC1-6 alkyl, —S—COR′″ and —COR′″ (where R′″ comprises H or C1-6 alkyl), —C≡CH, or polymerizable aromatic rings (such as phenyl, naphthalene, pyrrole, dithiophene, thienothiophene, thiophene and so forth).
摘要翻译：具有SF 5 N基团的噻吩并噻吩单体和通过这些单体的聚合形成的导电低聚物和聚合物及其作为空穴注入材料，电荷传输材料或半导体的用途。化合物可以具有下式：其中X和X'独立地为H，卤素原子（例如F，Cl，Br和I），MgCl，MgBr，Mg1，Sn（R'）3 >，其中R'包含C 1-6烷基或-OC 1-6 - 烷基，硼酸，硼酸酯，-CH-CHR“（其中R” 包括H或C 1-6烷基），-OC 1-6烷基，-COOC 1-6烷基，-S-COR' '和-COR'''（其中R“'包括H或C 1-6烷基），-C≡CH或可聚合的芳环（例如苯基，萘，吡咯，二噻吩噻吩并噻吩，噻吩等）。

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