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1. 发明申请

US20180319931A1 FUNCTIONALIZATION OF DIELS-ALDER POLYPHENYLENE POLYMERS 审中-公开
公开(公告)号：US20180319931A1
公开(公告)日：2018-11-08
申请号：US16039153
申请日：2018-07-18
申请人： National Technology & Engineering Solutions of Sandia, LLC
发明人： Cy Fujimoto
IPC分类号： C08G61/10 , C08L65/00
CPC分类号： C08G61/10 , C08G2261/11 , C08G2261/146 , C08G2261/148 , C08G2261/312 , C08G2261/46 , C08G2261/516 , C08G2261/72 , C08G2261/722 , C08G2261/728 , C08J5/2287 , C08J2365/02 , C08L65/00 , H01M8/1023 , H01M8/1039
摘要： The present invention relates to functionalized polymers including a poly(phenylene) structure. The structure can include any useful modifications, such as the inclusion of one or more reactive handles having an aryl group. Methods and uses of such structures and polymers are also described herein.

2. 发明申请

US20110201756A1 NOVEL AMPHIPHILIC BLOCK COPOLYMER, METHOD FOR MANUFACTURING THE SAME, AND POLYMER ELECTROLYTE MEMBRANE USING THE SAME 有权
标题翻译：新型嵌段共聚物，其制造方法和使用该聚合物的聚合物电解质膜
公开(公告)号：US20110201756A1
公开(公告)日：2011-08-18
申请号：US12885841
申请日：2010-09-20
申请人： Won Ho Jo , Tae-ann Kim , In Chul Hwang , Nak Hyun Kwon
发明人： Won Ho Jo , Tae-ann Kim , In Chul Hwang , Nak Hyun Kwon
IPC分类号： C08F293/00
CPC分类号： H01M8/1023 , C08F8/36 , C08F293/00 , C08G65/48 , C08G75/23 , C08G2261/722 , C08G2650/40 , C08L71/00 , C08L2205/05 , H01M8/1025 , H01M8/1027 , H01M8/1044 , H01M8/1072 , H01M2300/0082 , Y02P70/56 , C08L25/06 , C08L25/04 , C08F293/005
摘要： The present invention provides an amphiphilic block copolymer, a method for manufacturing the same, and a fuel cell membrane using the same. According to preferred embodiments, the amphiphilic block copolymer may contain poly(arylene sulfone ether ketone) (PSEK) as a hydrophobic component and poly(sulfonated styrene-co-acrylonitrile) (PSSAN) as a hydrophilic component. According to other preferred embodiments, polymer electrolyte membrane manufactured using the amphiphilic block copolymer has certain advantages in that the hydrogen ion conductivity is not reduced even at a high temperature of more than 100° C. but is rather increased and the thermal and chemical dimensional stability is excellent.
摘要翻译：本发明提供两亲性嵌段共聚物，其制造方法以及使用其的燃料电池膜。根据优选的实施方案，两亲嵌段共聚物可以含有作为疏水组分的聚（亚芳基砜醚酮）（PSEK）和作为亲水组分的聚（磺化苯乙烯 - 共 - 丙烯腈）（PSSAN）。根据其它优选实施方案，使用两亲性嵌段共聚物制造的聚合物电解质膜具有某些优点，即即使在高于100℃的高温下，氢离子传导性也不降低，但是相当增加，并且热和化学尺寸稳定性很好

3. 发明授权

US10053535B2 Poly(phenylene)-based anion exchange polymers and methods thereof 有权
公开(公告)号：US10053535B2
公开(公告)日：2018-08-21
申请号：US15398547
申请日：2017-01-04
申请人： NATIONAL TECHNOLOGY & ENGINEERING SOLUTIONS OF SANDIA, LLC , LOS ALAMOS NATIONAL SECURITY, LLC
发明人： Yu Seung Kim , Kwan-Soo Lee , Cy Fujimoto
IPC分类号： B01J49/00 , C08G61/10 , C08J5/22 , B01J41/13 , C08L65/00
CPC分类号： C08G61/10 , C08G2261/11 , C08G2261/312 , C08G2261/46 , C08G2261/516 , C08G2261/722 , C08J5/2256 , C08J2365/00 , C08J2365/02 , C08L65/00 , H01M8/1023 , H01M8/1039
摘要： The present invention relates to anionic exchange polymers including a poly(phenylene) structure. The structure can include any useful cationic moiety. Methods and uses of such structures and polymers are also described herein. In one instance, such polymers are employed to form a solid membrane.

4. 发明申请

US20140054509A1 SULFONATION OF CONDUCTING POLYMERS AND OLED, PHOTOVOLTAIC, AND ESD DEVICES 有权
标题翻译：导电聚合物和OLED，光伏和ESD器件的降解
公开(公告)号：US20140054509A1
公开(公告)日：2014-02-27
申请号：US13768967
申请日：2013-02-15
申请人： Plextronics, Inc.
发明人： Venkataramanan Seshadri , Brian Woodworth , Christopher Greco , Darin Laird , Mathew Mathai
IPC分类号： H01L51/00
CPC分类号： H01L51/0036 , C08G61/126 , C08G2261/1424 , C08G2261/1452 , C08G2261/18 , C08G2261/212 , C08G2261/3223 , C08G2261/43 , C08G2261/512 , C08G2261/722 , C08G2261/79 , C08G2261/95 , C08L65/00 , C09D165/00 , H01G9/028 , H01G11/48 , H01G11/56 , H01L51/006 , H01L51/0081 , H01L51/5048 , H01L51/5088 , Y02E10/549 , Y02E60/13 , Y10T428/31504 , Y10T428/31533 , Y10T428/31678 , C08L2666/02
摘要： Conducting polymer systems for hole injection or transport layer applications including a composition comprising: a water soluble or water dispersible regioregular polythiophene comprising (i) at least one organic substituent, and (ii) at least one sulfonate substituent comprising sulfonate sulfur bonding directly to the polythiophene backbone. The polythiophene can be water soluble, water dispersible, or water swellable. They can be self-doped. The organic substituent can be an alkoxy substituent, or an alkyl substituent. OLED, PLED, SMOLED, PV, and ESD applications can be used.
摘要翻译：用于空穴注入或传输层应用的导电聚合物体系包括包含以下组合物的组合物：水溶性或水分散性区域性聚噻吩，其包含（i）至少一种有机取代基，和（ii）至少一种磺酸盐取代基，其包含与所述聚噻吩直接结合的磺酸盐骨干。聚噻吩可以是水溶性的，水分散的或水可溶胀的。它们可以是自掺杂的。有机取代基可以是烷氧基取代基或烷基取代基。可以使用OLED，PLED，SMOLED，PV和ESD应用。

5. 发明申请

US20140014881A1 CONDUCTIVE POLYMER FOR SOLID ELECTROLYTE CAPACITOR 有权
标题翻译：固体电解电容器的导电聚合物
公开(公告)号：US20140014881A1
公开(公告)日：2014-01-16
申请号：US13903864
申请日：2013-05-28
申请人： Plextronics, Inc.
发明人： Takuma Takeda , Koichi Mori , Bunpei Yoshida
IPC分类号： H01G9/042
CPC分类号： H01G9/042 , C08G61/126 , C08G2261/1424 , C08G2261/1452 , C08G2261/3223 , C08G2261/516 , C08G2261/722 , C08G2261/90 , C08L65/00 , H01B1/122 , H01B1/127 , H01G9/028 , H01G9/15
摘要： [Problem] To provide a conductive polymer for solid electrolyte capacitor having outstanding solubility in solvents or dispersibility in solvents and which can produce a capacitor having outstanding capacitor characteristics in high-temperature environments.[Means Used to Resolve the Problem] A conductive polymer (A) for solid electrolyte capacitor containing substituted polythiophene (P) having thiophene repeating units (D) substituted by a least one type of group (s) selected from a group made up of a polyether group (a) indicated in general formula (1); an alkoxy group (b) having 1 to 15 carbon atoms; an alkoxy alkyl group (c) indicated in general formula (2); an alkyl group (d) having 1 to 15 carbon atoms; and a group (e) indicated in general formula (3); as well as thiophene repeating units (E) wherein the hydrogen atoms at position 3 and position 4 on the thiophene ring have been substituted by group (s) and sulfo group (—SO3H) (f). —(OR1)k—OR2 (1) —R3—OR4 (2) —R5—(OR6)m—OR7 (3)
摘要翻译：为了提供在溶剂中具有优异的溶解性或在溶剂中的分散性的固体电解质电容器的导电性高分子，能够在高温环境下制造出具有优异电容特性的电容器。 [用于解决问题的手段]一种含有具有噻吩重复单元（D）的取代聚噻吩（P）的固体电解电容器用导电性聚合物（A），其由选自由以下组成的组中的至少一种基团取代：通式（1）表示的聚醚基（a）; 具有1至15个碳原子的烷氧基（b）; 通式（2）表示的烷氧基烷基（c）; 具有1至15个碳原子的烷基（d）; 和通式（3）表示的基团（e）。以及其中噻吩环上第3位和第4位上的氢原子已经被一个或多个基团和磺基（-SO 3 H）（f）取代的噻吩重复单元（E）。 - （OR1）k-OR2（1）-R3-OR4（2）-R5-（OR6）m-OR7（3）

6. 发明申请

US20120097898A1 REPLACING AQUEOUS WITH NON-AQUEOUS SOLVENT 审中-公开
标题翻译：用非水溶剂替代水
公开(公告)号：US20120097898A1
公开(公告)日：2012-04-26
申请号：US13265523
申请日：2010-04-30
申请人： Venkataramanan Seshadri , Edward Yang
发明人： Venkataramanan Seshadri , Edward Yang
IPC分类号： H01B1/00 , C08K5/06 , C08K5/41 , C08K5/20 , C08L41/00 , C08K5/3415
CPC分类号： H01L51/0007 , C08G2261/1424 , C08G2261/1452 , C08G2261/3223 , C08G2261/63 , C08G2261/722 , C08J3/09 , C08J2365/00 , C08L25/02 , C08L39/04 , C08L65/00 , C08L81/06 , C09D11/52 , H01L51/0036 , C08L2666/22
摘要： Disclosed are methods of dispersing sulfonated polythiophenes in a non-aqueous solvent including replacing water for organic solvent without precipitation of the polythiophene. Once dispersed in a non-aqueous solvent, the sulfonated polythiophene can be mixed with a matrix polymer. The materials can be used in organic electronic devices including OLEDs and OPVs. The solvent processes can improve the viscosity properties. Sulfonated regioregular polythiophenes can be used. A benefit is improved solvent compatibility in building organic electronic devices and improved ability to formulate with matrix materials.
摘要翻译：公开了将磺化聚噻吩分散在非水溶剂中的方法，包括将水替换为有机溶剂而不沉淀聚噻吩。一旦分散在非水溶剂中，可将磺化聚噻吩与基质聚合物混合。这些材料可以用于包括OLED和OPV在内的有机电子器件中。溶剂工艺可以改善粘度性能。可以使用磺化的区域性聚噻吩。改善溶剂在构建有机电子器件中的相容性以及改进配合基质材料的能力的优点。

7. 发明申请

US20110136041A1 SULFONATED POLY(ARYLENE ETHER) COPOLYMERS AND RELATED POLYMER ELECTROLYTE MEMBRANES AND FUEL CELLS 有权
公开(公告)号：US20110136041A1
公开(公告)日：2011-06-09
申请号：US12917772
申请日：2010-11-02
申请人： Ju Ho Lee , Dong Il Kim , Nak Hyun Kwon , Inchul Hwang
发明人： Ju Ho Lee , Dong Il Kim , Nak Hyun Kwon , Inchul Hwang
IPC分类号： H01M8/10 , C08J5/20 , B01J39/20
CPC分类号： H01M8/1025 , C08G65/4012 , C08G65/48 , C08G75/23 , C08G2261/722 , C08J5/2256 , C08J2371/12 , C08J2481/06 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1044 , H01M8/1048 , H01M8/1051 , H01M8/1072 , H01M2300/0082 , H01M2300/0091 , Y02P70/56
摘要： The present invention relates to a sulfonated poly(arylene ether) copolymer, a manufacturing method thereof and a polymer electrolyte membrane for fuel cell using the same.

8. 发明申请

US20110136016A1 POLYMER BLEND PROTON EXCHANGE MEMBRANE AND METHOD FOR MANUFACTURING THE SAME 有权
标题翻译：聚合物共混物交换膜及其制造方法
公开(公告)号：US20110136016A1
公开(公告)日：2011-06-09
申请号：US12821961
申请日：2010-06-23
申请人： Mianyan HUANG , Yanling ZHAO , Linlin LI
发明人： Mianyan HUANG , Yanling ZHAO , Linlin LI
IPC分类号： H01M10/0565 , C08J5/22 , H01M8/10
CPC分类号： H01M8/20 , C08G65/48 , C08G2261/722 , C08J5/2275 , C08J2381/06 , C08L71/00 , C08L81/06 , H01M8/1011 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1044 , H01M8/1081 , H01M8/188 , Y02E60/523 , Y02P70/56
摘要： The present invention relates to a polymer blend proton exchange membrane comprising a soluble polymer and a sulfonated polymer, wherein the soluble polymer is at least one polymer selected from the group consisting of polysulfone, polyethersulfone and polyvinylidene fluoride, the sulfonated polymer is at least one polymer selected from the group consisting of sulfonated poly(ether-ether-ketone), sulfonated poly(ether-ketone-ether-ketone-ketone), sulfonated poly(phthalazinone ether keton), sulfonated phenolphthalein poly(ether sulfone), sulfonated polyimides, sulfonated polyphosphazene and sulfonated polybenzimidazole, and wherein the degree of sulfonation of the sulfonated polymer is in the range of 96% to 118%. The present invention further relates to a method for manufacturing the polymer blend proton exchange membrane.
摘要翻译：本发明涉及包含可溶性聚合物和磺化聚合物的聚合物共混物质子交换膜，其中可溶性聚合物是选自聚砜，聚醚砜和聚偏二氟乙烯中的至少一种聚合物，磺化聚合物是至少一种聚合物选自磺化聚（醚 - 醚 - 酮），磺化聚（醚 - 酮 - 醚 - 酮 - 酮），磺化聚（酞嗪酮醚酮），磺化酚酞聚（醚砜），磺化聚酰亚胺，磺化聚磷腈和磺化聚苯并咪唑，并且其中磺化聚合物的磺化度在96％至118％的范围内。本发明还涉及一种制造聚合物共混质子交换膜的方法。

9. 发明申请

US20190031821A1 POLY(PHENYLENE)-BASED ANION EXCHANGE POLYMERS AND METHODS THEREOF 审中-公开
公开(公告)号：US20190031821A1
公开(公告)日：2019-01-31
申请号：US16039158
申请日：2018-07-18
申请人： National Technology & Engineering Solutions of Sandia, LLC , Los Alamos National Security, LLC
发明人： Yu Seung Kim , Kwan-Soo Lee , Cy Fujimoto
IPC分类号： C08G61/10 , C08J5/22 , C08L65/00 , H01M8/1023 , H01M8/1039
CPC分类号： C08G61/10 , C08G2261/11 , C08G2261/312 , C08G2261/46 , C08G2261/516 , C08G2261/722 , C08J5/2256 , C08J2365/00 , C08J2365/02 , C08L65/00 , H01M8/1023 , H01M8/1039
摘要： The present invention relates to anionic exchange polymers including a poly(phenylene) structure. The structure can include any useful cationic moiety. Methods and uses of such structures and polymers are also described herein. In one instance, such polymers are employed to form a solid membrane.

10. 发明授权

US10053534B2 Functionalization of Diels-Alder polyphenylene polymers 有权
公开(公告)号：US10053534B2
公开(公告)日：2018-08-21
申请号：US15398545
申请日：2017-01-04
申请人： National Technology & Engineering Solutions of Sandia, LLC
发明人： Cy Fujimoto
IPC分类号： B01J49/00 , C08G61/10 , C08L65/00
CPC分类号： C08G61/10 , C08G2261/11 , C08G2261/146 , C08G2261/148 , C08G2261/312 , C08G2261/46 , C08G2261/516 , C08G2261/72 , C08G2261/722 , C08G2261/728 , C08J5/2287 , C08J2365/02 , C08L65/00 , H01M8/1023 , H01M8/1039
摘要： The present invention relates to functionalized polymers including a poly(phenylene) structure. The structure can include any useful modifications, such as the inclusion of one or more reactive handles having an aryl group. Methods and uses of such structures and polymers are also described herein.

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