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1. 发明授权

US5466767A Shaped organosiloxane polycondensates, process for their preparation and use 失效
标题翻译：成型有机硅氧烷缩聚物，其制备和使用过程
公开(公告)号：US5466767A
公开(公告)日：1995-11-14
申请号：US340877
申请日：1994-11-15
申请人： Stefan Wieland , Peter Panster , Horst Grethe
发明人： Stefan Wieland , Peter Panster , Horst Grethe
IPC分类号： C08G77/48 , C08G77/54 , C08G77/58 , C08G77/26 , C08G77/22 , C08G77/30
CPC分类号： C08G77/54 , C08G77/48 , C08G77/58
摘要： Disclosed are shaped organosiloxane polycondensates in the form of macroscopic spherical particles with a diameter of 0.01 to 2.5 mm, a specific surface area of 0.01 to 1000 m.sup.2 /g, a specific pore volume of 0.01 to 5 ml/g, and a bulk density of 50 to 1000 g/l, consisting of units of the formula (I):X--R.sup.1 (I)and/or the formula (II):R.sup.2 --Y--R.sup.3 (II)and the formula (III): ##STR1## as well as optionally, in addition, units of the formula ##STR2## wherein R.sup.1 to R.sup.3 are identical or different and represent a group of the formula (V): ##STR3## R.sup.4 being bonded directly to the X or Y group and representing a linear or branched, fully saturated or unsaturated alkylene group, a cycloalkylene group, a phenylene group or a unit of the formula ##STR4## and M corresponding to a Si, Ti or Zr atom. Also disclosed are a process for preparation and use.
摘要翻译：公开了直径为0.01〜2.5mm，比表面积为0.01〜1000m2 / g，比孔体积为0.01〜5ml / g的宏观球状颗粒形状的成型有机硅氧烷缩聚物，体积密度为由式（I）：X-R1（I）和/或式（II）：R2-Y-R3（Ⅱ）和式（Ⅲ）组成的单位为50〜1000g / （III）的化合物，另外还有式（IV）的单元，其中R 1至R 3相同或不同并且表示式（Ⅴ）的基团：或Y基团，并且表示直链或支链的完全饱和或不饱和的亚烷基，亚环烷基，亚苯基或下式的单元，即对应于Si，Ti或Zr原子的式“IMAGE”或“IMAGE”和M。还公开了一种制备和使用的方法。

2. 发明授权

US4999413A Organosiloxane amine copolycondensates, method of their preparation and use (II) 失效
标题翻译：有机硅氧烷胺共缩聚物，其制备方法及用途（二）
公开(公告)号：US4999413A
公开(公告)日：1991-03-12
申请号：US431220
申请日：1989-11-03
申请人： Peter Panster , Horst Grethe , Peter Kleinschmit
发明人： Peter Panster , Horst Grethe , Peter Kleinschmit
IPC分类号： B01J20/26 , B01J20/22 , C08G77/26 , C08G77/42 , C08G77/44 , C08G77/48 , C08G77/50 , C08G77/54 , C08G77/58
CPC分类号： C08G77/26 , B01J20/22 , C08G77/54 , C08G77/58
摘要： Organosiloxane amine copolycondensates as statistic or block copolycondensates or mixtures thereof consisting of the units ##STR1## andX--R.sup.4 (II)in which R.sup.1 to R.sup.4 is ##STR2## and R.sup.5 is bound directly to the nitrogen atom or the single-bonding X group and is alkylene, cycloalkylene or ##STR3## in which n is 1 to 6 and m 0 to 6. The free valences of the oxygen atoms bound to the silicon atom are saturated by silicon atoms of further groups of formula III, optionally with the inclusion of cross-linking agents, X stands for ##STR4## in which R" is H or alkyl. In addition, preparation methods and the use of the products for the removal of dissolved metals from the liquid phase or for the adsorption of gaseous compounds.
摘要翻译：有机硅氧烷胺共缩聚物作为统计或嵌段共缩聚物或其混合物由其中R 1至R 4为（III）的单元（I）和X-R 4（II）组成，R 5直接键合到氮原子或单键X基并且是亚烷基，亚环烷基或或，其中n为1至6且m 0至6。与硅原子结合的氧原子的自由价饱和为硅原子另外的式III基团，任选地含有交联剂，X代表NH 2，NH（CH 2）2 NH 2，NH（CH 2）2 NH（CH 2）2 NH 2，Cl，Br，I，哪个R“是H或烷基。另外，制备方法和产品用于从液相中除去溶解的金属或用于气态化合物的吸附。

3. 发明授权

US4855470A Organosilanes containing benzoyl thiourea groups and method of preparation 失效
标题翻译：含有苯甲酰硫脲基团的有机硅烷及其制备方法
公开(公告)号：US4855470A
公开(公告)日：1989-08-08
申请号：US154408
申请日：1988-02-10
申请人： Peter Panster , Horst Grethe , Peter Kleinschmit
发明人： Peter Panster , Horst Grethe , Peter Kleinschmit
IPC分类号： B01J20/10 , C07F7/18 , C09K3/00
CPC分类号： C07F7/1836
摘要： R.sup.4 --Si(OR).sub.3R.sup.4 =alkylene, cycloalkylene or an entity of the formula: ##STR2## whereby n=1-6, R=alkyl containing C.sub.1 -C.sub.3 and R.sup.3 =R.sup.2 or H. A method of preparing these compounds is also disclosed.
摘要翻译：其中R 1 =苯基或硝基苯基，R 2是式R 4 -Si（OR）3的实体，R 4 =亚烷基，亚环烷基或下式的实体：其中n = 1-6，R =含有C1-C3和R3 = R2或H的烷基。还公开了制备这些化合物的方法。

4. 发明授权

US4552700A Organopolysiloxanes containing sulphonate groups, method for the production and use thereof 失效
标题翻译：含有磺酸基团的有机聚硅氧烷，其制备方法及其应用
公开(公告)号：US4552700A
公开(公告)日：1985-11-12
申请号：US507200
申请日：1983-06-23
申请人： Peter Panster , Horst Grethe , Peter K. Kleinschmit
发明人： Peter Panster , Horst Grethe , Peter K. Kleinschmit
IPC分类号： B01J39/16 , B01J39/17 , B01J39/18 , C08G77/00 , C08G77/06 , C08G77/28 , C08G77/38 , C08G77/398 , C08G77/50 , C07F7/08 , C07F5/06 , C07F7/28
CPC分类号： C08G77/398 , B01J39/165 , B01J39/18 , C08G77/50
摘要： Organopolysiloxanes are described with the same or different units of the formula:(O.sub.3/2 Si-R.sup.1 -SO.sub.3.sup.-).sub.x M.sup.x+ (1)in which R.sup.1 is alkyl, x is dependent on M and signifies a number from 1 to 4 and M represents hydrogen or a mono- to tetravalent metal ion and the valences of the oxygen atoms are saturated by silicon atoms of other groups of the formula (1), optionally by inserting cross-linking silicon, titanium or aluminum compounds and/or by di-, tri- and tetrasulfide units of the formula: ##STR1## in which the substituents R.sup.1 have the same meaning as in (1) and can be the same or different, wherein the ratio of the sum of silicon atoms in (1) and (2) to the silicon, titanium and aluminum atoms of the cross-linking agent ranges from 1:0 to 1:10. Furthermore, the method of obtaining the organopolysiloxanes containing sulphonate groups and the use thereof as strongly acidic cation exchangers are described.
摘要翻译：有机聚硅氧烷用相同或不同的下式表示：（O 3 / 2Si-R 1 -SO 3 - ）x M x +（1），其中R 1是烷基，x取决于M并且表示1至4的数，M表示氢或一价至四价金属离子，并且氧原子的价数由式（1）的其它基团的硅原子饱和，任选地通过插入交联硅，钛或铝化合物和/或通过二 - ，三 - 和下式（2）中的四硫化物单元，其中取代基R 1具有与（1）中相同的含义并且可以相同或不同，其中（1）中的硅原子和（2）交联剂的硅，钛和铝原子的范围为1:0至1:10。此外，描述了获得含有磺酸盐基团的有机聚硅氧烷的方法及其作为强酸性阳离子交换剂的用途。

5. 发明授权

US5922900A Process for producing carboxylic acid esters and catalysts therefor 失效
标题翻译：制备羧酸酯及其催化剂的方法
公开(公告)号：US5922900A
公开(公告)日：1999-07-13
申请号：US922558
申请日：1997-09-03
申请人： Stefan Wieland , Peter Panster
发明人： Stefan Wieland , Peter Panster
IPC分类号： B01J31/06 , C07B61/00 , C07C67/08 , C07C69/14 , C07C69/80 , C07C67/00 , C08G77/00 , C08G79/00
CPC分类号： C07C67/08
摘要： A process for producing carboxylic acid esters by the following steps:a) preparation of a reaction mixture containing an alcohol and a carboxylic acid and/or a carboxylic anhydride and/or a carboxylic acid ester and or a partially esterified carboxylic acid,b) heating of this mixture to the suitable reaction temperature in the presence of a solid polysiloxane insoluble in the reaction medium and having sulphonic acid groups with intensive thorough mixing accompanied by continuous separation of the reaction water which forms, wherein the polysiloxane used as the catalyst in modified by treatment with a soluble aluminum, titanium or zirconium compound, and the spherical particles thereof have a diameter of 0.01 to 3 mm, a specific surface of 0.1 to 1200 m.sup.2 /g, a specific pore volume of 0.01 to 6.0 ml/g and a bulk density of 50 to 1000 g/l.
摘要翻译：一种通过以下步骤制备羧酸酯的方法：a）制备含有醇和羧酸和/或羧酸酐和/或羧酸酯和/或部分酯化的羧酸的反应混合物，b）加热该混合物在不溶于反应介质的固体聚硅氧烷存在下具有适当的反应温度，并且具有强烈浓缩的磺酸基团，伴随着形成的反应水的连续分离，其中用作催化剂的聚硅氧烷被改性为用可溶性铝，钛或锆化合物处理，其球形颗粒的直径为0.01〜3mm，比表面积为0.1〜1200m2 / g，比孔体积为0.01〜6.0ml / g，体积密度为50〜1000g / l。

6. 发明授权

US5552474A Aqueous solutions of organopolysiloxane-ammonium compounds, methods of their manufacture and use 失效
标题翻译：有机聚硅氧烷 - 铵化合物的水溶液，其制造和使用方法
公开(公告)号：US5552474A
公开(公告)日：1996-09-03
申请号：US400790
申请日：1995-03-03
申请人： Peter Panster , Stefan Wieland
发明人： Peter Panster , Stefan Wieland
IPC分类号： B01J43/00 , C08G77/48 , C08G77/54 , C08L83/14 , C08L83/00
CPC分类号： C08L83/14 , C08G77/54
摘要： Disclosed are aqueous solutions of polymeric organosiloxane-ammonium compounds which possess ion exchange properties and a method for manufacture from solid organopolysiloxanes. The solutions are used in the hydrophobing treatment of inorganic materials and building materials.
摘要翻译：公开了具有离子交换性能的聚合有机硅氧烷 - 铵化合物的水溶液和由固体有机聚硅氧烷制造的方法。该溶液用于无机材料和建筑材料的疏水处理。

7. 发明授权

US5484869A Formed organosiloxane amine copolycondensates, method of their preparation and use 失效
标题翻译：形成有机硅氧烷胺共缩聚物，其制备方法及用途
公开(公告)号：US5484869A
公开(公告)日：1996-01-16
申请号：US427719
申请日：1995-04-21
申请人： Peter Panster , Stefan Wieland
发明人： Peter Panster , Stefan Wieland
IPC分类号： B01D15/00 , B01J20/22 , B01J20/26 , C02F1/62 , C08G77/22 , C08G77/26 , C08G77/28 , C08G77/48 , C08G77/54 , C08G77/58 , C08J3/12 , C08G77/08
CPC分类号： C08G77/58 , B01J20/22 , C08G77/22 , C08G77/54
摘要： Organosiloxane copolycondensates are disclosed and which are optionally cross-linked by means of cross-linking agents containing Si, Ti, Zr and/or Al and contain the units ##STR1## wherein R.sup.1 -R.sup.5 are ##STR2## wherein R.sup.6 is alkylene with C.sub.1 -C.sub.10 bound directly to N or X, cycloalkylene with C.sub.5 -C.sub.8 or ##STR3## X is >N--H, >N--CH.sub.3, >N--C.sub.2 H.sub.5, --S--, --S.sub.2 --, --S.sub.3 --, --S.sub.4 --, ##STR4## wherein R" is H or alkyl with C.sub.1 -C.sub.5. These products are in the form of spherical particles with a diameter of 0.01 to 3.0 mm, a specific surface of up to 1000 m.sup.2 /g, a specific pore volume of up to 6.0 ml/g and a bulk density of 50 to 1000 g/l. Different methods of preparing the formed copolycondensates are disclosed as well as use of certain compositions for removing metals from solutions and/or for the adsorption of gaseous organic compounds and/or of water vapor.
摘要翻译：有机硅氧烷共缩聚物被公开，并且其任选地通过含有Si，Ti，Zr和/或Al的交联剂交联，并且含有单元，其中R 1是具有C1- C10直接键合到N或X上，亚环烷基与C 5 -C 8或X 3或X 3是> NH，> N-CH 3，> N-C 2 H 5，-S-，-S 2 - ，-S 3 - ，-S 4 - ，其中R“为H或C 1 -C 5烷基。这些产品是直径为0.01至3.0mm，比表面积高达1000m 2 / g，比孔容积高达6.0ml / g和体积密度为50至1000g / g的球形颗粒的形式， l。公开了制备形成的共缩聚物的不同方法以及使用某些组合物从溶液中除去金属和/或吸附气态有机化合物和/或水蒸气。

8. 发明授权

US5264514A Metal-containing, shaped organosiloxane amine copolycondensates and methods of their production 失效
标题翻译：含金属的成型有机硅氧烷胺共缩聚物及其制备方法
公开(公告)号：US5264514A
公开(公告)日：1993-11-23
申请号：US860715
申请日：1992-04-01
申请人： Peter Panster , Stefan Wieland
发明人： Peter Panster , Stefan Wieland
IPC分类号： B01J31/06 , B01J31/12 , B01J31/16 , B01J31/18 , C08G77/398 , C08G77/48 , C08G77/54 , C08G77/58 , C08K3/10 , C08L83/04 , C08L83/08 , C08G79/10 , C08G77/26 , C08G77/28
CPC分类号： C08G77/58 , B01J31/124 , B01J31/1675 , B01J31/1805 , C08G77/398 , C08G77/54 , B01J2231/641 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/828
摘要： Shaped organosiloxane amine copolycondensates are described which contain Pd, Pt, Ru and/or Rh, as well as optional promotors and/or moderators. The shaped copolycondensate function as a carrier for metals and are made up of units of: ##STR1## and/or units of Y--R.sup.6. R.sup.2 to R.sup.6 are a group represented by the formula: ##STR2## wherein R.sup.7 is a group bound to N, X, or Y (for example, an alkylene group) and R.sup.1 is R.sup.7 --SiO.sub.3/2, H, CH.sub.3, C.sub.2 H.sub.5, or C.sub.3 H.sub.7. X stands for a double-bonded group such as --S--, --S.sub.2 --, --S.sub.3 --, --S.sub.4 --, --HN--CS--NH-- and Y stands for a monovalent groups such as --CN, --SCN, --SH, --S--CH.sub.3, --NH.sub.2, --NH--(CH.sub.2).sub.2 --NH.sub.2. The carrier substance may be cross-linked with cross-linking agents containing Si, Ti, Zr or Al. The metal-containing product is spherical in form and is defined by the parameters of sphere diameter, specific surface and pore volume as well as bulk density. Methods of production and use of the copolycondensates are also described.
摘要翻译：描述了含有Pd，Pt，Ru和/或Rh的有机硅氧烷胺共缩合物，以及任选的促进剂和/或调节剂。成型的共缩聚物用作金属载体，由以下单元组成：＆lt; IMAGE＆gt;和/或Y-R6单元。 R2至R6是由下式表示的基团：其中R7是与N，X或Y结合的基团（例如亚烷基），R1是R7-SiO3/2，H，CH3 ，C 2 H 5或C 3 H 7。 X表示-S-，-S2-，-S3-，-S4-，-HN-CS-NH-和Y代表一价基团如-CN，-SCN，-SH ，-S-CH 3，-NH 2，-NH-（CH 2）2 -NH 2。载体物质可以与含有Si，Ti，Zr或Al的交联剂交联。含金属产品的形状为球形，由球体直径，比表面积和孔体积以及堆积密度的参数定义。还描述了共缩聚物的生产和使用方法。

9. 发明授权

US5403566A Recovery of hydrogenation catalysts from solutions of hydrogenated nitrile rubber 失效
标题翻译：从氢化丁腈橡胶溶液中回收氢化催化剂
公开(公告)号：US5403566A
公开(公告)日：1995-04-04
申请号：US243535
申请日：1994-05-13
申请人： Peter Panster , Stefan Wieland , Hartmuth Buding , Werner Obrecht
发明人： Peter Panster , Stefan Wieland , Hartmuth Buding , Werner Obrecht
IPC分类号： B01J20/26 , B01J20/22 , B01J20/28 , B01J31/16 , B01J38/00 , C08C2/04 , C08C19/02 , C08F8/04 , B01J31/40
CPC分类号： B01J20/22 , C08C2/04 , Y10T428/2982
摘要： Rhodium and ruthenium catalysts can be recovered from solutions of hydrogenated nitrile rubber by addition onto organosiloxane-based absorbers.
摘要翻译：铑和钌催化剂可以通过加入到有机硅氧烷类吸收剂中从氢化丁腈橡胶的溶液中回收。

10. 发明授权

US5352791A Hydrating or oxidizing process using a metal-containing, shaped organosiloxane amine copolycondensate catalyst 失效
标题翻译：使用含金属的有机硅氧烷胺共缩合催化剂进行保湿或氧化处理
公开(公告)号：US5352791A
公开(公告)日：1994-10-04
申请号：US121580
申请日：1993-09-16
申请人： Peter Panster , Stefan Wieland
发明人： Peter Panster , Stefan Wieland
IPC分类号： B01J31/06 , B01J31/12 , B01J31/16 , B01J31/18 , C08G77/398 , C08G77/48 , C08G77/54 , C08G77/58 , C08K3/10 , C08L83/04 , C08L83/08 , C07D215/06 , C07C53/134 , C08G77/26
CPC分类号： C08G77/58 , B01J31/124 , B01J31/1675 , B01J31/1805 , C08G77/398 , C08G77/54 , B01J2231/641 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/828
摘要： Shaped organosiloxane amine copolycondensates are described which contain Pd, Pt, Ru and/or Rh, as well as optional promotors and/or moderators. The shaped copolycondensate function as a carrier for metals and are made up of units of: ##STR1## and/or units of Y--R.sup.6. R.sup.2 to R.sup.6 are a group represented by the formula: ##STR2## wherein R.sup.7 is a group bound to N, X, or Y (for example, an alkylene group) and R.sup.1 is R.sup.7 --SiO.sub.3/2, H, CH.sub.3, C.sub.2 H.sub.5, or C.sub.3 H.sub.7. X stands for a double-bonded group such as --S--, --S.sub.2 --, --S.sub.3 --, --S.sub.4 --, --HN--CS--NH-- and Y stands for a monovalent groups such as --CN, --SCN, --SH, --S--CH.sub.3, --NH.sub.2, --NH--(CH.sub.2).sub.2 --NH.sub.2. The carrier substance may be cross-linked with cross-linking agents containing Si, Ti, Zr or Al. The metal-containing product is spherical in form and is defined by the parameters of sphere diameter, specific surface and pore volume as well as bulk density. Methods of production and use of the copolycondensates are also described.
摘要翻译：描述了含有Pd，Pt，Ru和/或Rh的有机硅氧烷胺共缩合物，以及任选的促进剂和/或调节剂。成型的共缩聚物用作金属载体，由以下单元组成：＆lt; IMAGE＆gt;和/或Y-R6单元。 R2至R6是由下式表示的基团：其中R7是与N，X或Y结合的基团（例如亚烷基），R1是R7-SiO3/2，H，CH3 ，C 2 H 5或C 3 H 7。 X表示-S-，-S2-，-S3-，-S4-，-HN-CS-NH-和Y代表一价基团如-CN，-SCN，-SH ，-S-CH 3，-NH 2，-NH-（CH 2）2 -NH 2。载体物质可以与含有Si，Ti，Zr或Al的交联剂交联。含金属产品的形状为球形，由球体直径，比表面积和孔体积以及堆积密度的参数定义。还描述了共缩聚物的生产和使用方法。

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