专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US07083775B2 Process for the autothermal catalytic steam reforming of hydrocarbons 有权
公开(公告)号：US07083775B2
公开(公告)日：2006-08-01
申请号：US09853902
申请日：2001-05-14
申请人： Stefan Wieland , Frank Baumann , Rainer Ahlborn
发明人： Stefan Wieland , Frank Baumann , Rainer Ahlborn
IPC分类号： C01B3/26
CPC分类号： B01J23/63 , C01B3/382 , C01B3/40 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , C01B2203/1094 , C01B2203/142 , C01B2203/82 , Y02P20/52
摘要： A process for autothermal catalytic steam reforming of hydrocarbons by passing a reactant mixture of hydrocarbons, oxygen and water or water vapor, heated to a preheating temperature, over a catalyst. The process is operated adiabatically and the catalyst has a coating of a catalyst material on a support structure, the catalyst material containing at least one platinum group metal on an oxidic support material which can be aluminum oxide, silicon dioxide, titanium dioxide or mixed oxides thereof and zeolites.

2. 发明授权

US06649559B2 Supported metal membrane, a process for its preparation and use 失效
公开(公告)号：US06649559B2
公开(公告)日：2003-11-18
申请号：US09912439
申请日：2001-07-26
申请人： Ernst Drost , Werner Kuhn , Meike Roos , Stefan Wieland , Bernd Kempf
发明人： Ernst Drost , Werner Kuhn , Meike Roos , Stefan Wieland , Bernd Kempf
IPC分类号： B01J2118
CPC分类号： B01D67/0069 , B01D53/228 , B01D67/0072 , B01D69/105 , B01D71/022 , B01D2325/04 , B01D2325/10 , C01B3/505 , C01B2203/041 , C01B2203/0475 , C01B2203/0485 , H01M8/0687 , Y02P70/56 , Y10T428/12063 , Y10T428/12479 , Y10T428/24149 , Y10T428/24997 , Y10T428/24999
摘要： The invention provides a supported metal membrane which contains a metal membrane on a support surface of a porous membrane support. The supported metal membrane is obtainable by applying the metal membrane to the support surface of the membrane support, wherein the pores in the membrane support are sealed, at least in the region of the support surface, prior to applying the metal membrane and are opened by removing the auxiliary substance only after applying the metal membrane.

3. 发明授权

US5808123A Continuous method of producing .gamma.-aminopropyltrialkoxysilanes 失效
标题翻译：连续生产γ-氨基丙基三烷氧基硅烷的方法
公开(公告)号：US5808123A
公开(公告)日：1998-09-15
申请号：US990730
申请日：1997-12-15
申请人： Torsten Balduf , Stefan Wieland , Wolfgang Lortz , Joachim Pohlisch , Thomas Gobel , Horst Grethe
发明人： Torsten Balduf , Stefan Wieland , Wolfgang Lortz , Joachim Pohlisch , Thomas Gobel , Horst Grethe
IPC分类号： C07F7/18 , C07F7/10
CPC分类号： C07F7/1892
摘要： A continuous method of producing .gamma.-aminopropyltrialkoxysilanes as well as mixtures of primary and secondary aminosilanes by reacting .gamma.-chloropropyltrialkoxysilane with ammonia is disclosed. The steps are: a) .gamma.-chloropropyltrialkoxysilane and ammonia are first mixed in the desired amount ratio, b) this mixture is heated to the reaction temperature, c) allowed to run through a pressure reactor with a dwell time sufficient for the complete reaction, during which the mixture can run through several temperature zones, d) the reaction mixture is subsequently cooled off, e) the product (.gamma.-aminopropyltrialkoxysilanes or the mixtures) is separated out of a two-phase mixture and f) the ammoniacal phase returned into the reactor.
摘要翻译：公开了通过使γ-氯丙基三烷氧基硅烷与氨反应产生γ-氨基丙基三烷氧基硅烷以及伯和仲氨基硅烷的混合物的连续方法。步骤是：a）首先以所需量的比例混合γ-氯丙基三烷氧基硅烷和氨，b）将该混合物加热至反应温度，c）允许经过足以进行完全反应的停留时间的压力反应器，在此期间，混合物可以穿过几个温度区域，d）随后将反应混合物冷却，e）将产物（γ-氨基丙基三烷氧基硅烷或其混合物）从两相混合物中分离出来，并且f）将氨酸返回到反应堆。

4. 发明授权

US5789628A Production of 2,2'-bis (4-hydroxyphenyl) propanes in the presence of organopolysiloxanes containing sulphonate and mercapto groups 失效
标题翻译：在含有磺酸盐和巯基的有机聚硅氧烷的存在下制备2,2'-双（4-羟基苯基）丙烷
公开(公告)号：US5789628A
公开(公告)日：1998-08-04
申请号：US710756
申请日：1996-09-20
申请人： Emmanuel Auer , Stefan Wieland , Hans Lansink-Rotgerink , Hauke Jacobsen , Heike Riedemann
发明人： Emmanuel Auer , Stefan Wieland , Hans Lansink-Rotgerink , Hauke Jacobsen , Heike Riedemann
IPC分类号： C07C37/11 , C07C37/20 , C07C39/16 , C07C39/12
CPC分类号： C07C37/20
摘要： A process for the production of 2,2'-bis(4-hydroxyphenyl)propanes by reacting the corresponding phenols and carbonyl compounds in the presence of organopolysiloxanes containing sulphonate and mercapto groups and acting as a catalyst, consisting of units of the formula �O.sub.3/2 --Si--R.sup.1 --SO.sub.3 --!.sub.x M.sup.x+ (I), wherein R.sup.1 is a linear or branched alkylene group having 1 to 12 C atoms, a cycloalkylene group having 5 to 8 C atoms or a unit of the formulae ##STR1## and units of the formula O.sub.3/2 --Si--R.sup.2 --SH (III)
摘要翻译：在含有磺酸盐和巯基的有机聚硅氧烷和作为催化剂的存在下，通过使相应的酚和羰基化合物反应生成2,2'-双（4-羟基苯基）丙烷的方法，由式[O 3 / 2-Si-R1-SO3-] xMx +（I），其中R1是具有1至12个C原子的直链或支链亚烷基，具有5至8个碳原子的亚环烷基或式“IMAGE”（ II）＆lt; IMAGE＆gt;和式O3 / 2-Si-R2-SH（III）的单元

5. 发明授权

US5734070A Hardening of unsaturated fats, fatty acids or fatty acid esters 失效
标题翻译：不饱和脂肪，脂肪酸或脂肪酸酯的硬化
公开(公告)号：US5734070A
公开(公告)日：1998-03-31
申请号：US689836
申请日：1996-08-14
申请人： Thomas Tacke , Stefan Wieland , Peter Panster , Martin Bankmann , Reinhold Brand , Hendrik Magerlein
发明人： Thomas Tacke , Stefan Wieland , Peter Panster , Martin Bankmann , Reinhold Brand , Hendrik Magerlein
IPC分类号： B01J3/00 , C07C51/36 , C07C67/303 , C11C3/12 , C07C31/56
CPC分类号： C11C3/126 , B01J3/008 , C07C51/36 , C07C67/303 , Y02P20/544
摘要： A process is disclosed for continuously hydrogenating unsaturated fats, fatty acids or fatty acid esters on a shaped catalyst in a solid bed. The reactants flow over the catalyst in the presence of a medium or solvent mixture in supercritical conditions. This leads to considerably improved activity and selectivity of the hydrogenation reaction compared with conventional trickle bed hydrogenation processes.
摘要翻译：公开了用于在固体床中的成形催化剂上连续氢化不饱和脂肪，脂肪酸或脂肪酸酯的方法。反应物在超临界条件下在介质或溶剂混合物存在下流过催化剂。与常规滴流床氢化方法相比，这导致氢化反应的活性和选择性显着提高。

6. 发明授权

US5721016A Process for the treatment of mineral building materials 失效
标题翻译：矿物建筑材料处理工艺
公开(公告)号：US5721016A
公开(公告)日：1998-02-24
申请号：US650347
申请日：1996-05-20
申请人： Peter Panster , Thomas Goebel , Stefan Wieland , Marion Langen , Klaus Zinsmeister , Ute Werner , Christian Brandes
发明人： Peter Panster , Thomas Goebel , Stefan Wieland , Marion Langen , Klaus Zinsmeister , Ute Werner , Christian Brandes
IPC分类号： C04B41/49 , C04B41/64 , C09D183/04 , B05D1/34 , B05D1/36
CPC分类号： C04B41/009 , C04B41/4905 , C04B2103/0087 , C04B2111/00491 , C04B2111/20 , C04B2111/21
摘要： A process for the impregnating and priming treatment of mineral building materials of synthetic or natural origin using aqueous suspensions or solutions which contain at least one silicon-containing ion exchanger of the formula �(YO).sub.3 Si(CH.sub.2).sub.x !.sub.n EX (I) or an oligomer of this compound, wherein x signifies an integer of 1 to 12, n signifies an integer of 1 to 3, depending on E Y signifies H, Na, K, Mg, Ca, Ba E signifies a cation-exchanging or anion-exchanging group, and X signifies H.sup.+ or an alkali cation or alkaline earth cation or OH.sup.- or an anion, in a quantity of from 0.1 to 70% by weight, particularly from 10 to 30% by weight, based on the total quantity of the solution or suspension, with the treatment being carried out in a single stage or in multiple stages, optionally combined with a treatment with aqueous or organic emulsions or solutions containing hydrolyzable silanes and/or siloxanes.
摘要翻译：使用含有至少一种式[（YO）3 Si（CH 2）x] nEX（I）的含硅离子交换剂的含水悬浮液或溶液浸渍和起始处理合成或天然来源的矿物建筑材料的方法或该化合物的低聚物，其中x表示1〜12的整数，n表示1〜3的整数，根据EY表示H，Na，K，Mg，Ca，Ba，E表示阳离子交换或阴离子交换基团，X表示H +或碱性阳离子或碱土金属阳离子或OH-或阴离子，其量为0.1至70重量％，特别是10至30重量％，基于溶液的总量或悬浮液，其处理在单一阶段或多个阶段进行，任选地与含有水性或有机乳剂或含有可水解硅烷和/或硅氧烷的溶液的处理组合。

7. 发明授权

US5237019A Metal-containing, shaped polymeric, tertiary and/or secondary organosiloxane amine compounds, method of their production and use 失效
标题翻译：含金属，形状的聚合物，仲胺和/或次生有机硅氧烷化合物，其生产和使用方法
公开(公告)号：US5237019A
公开(公告)日：1993-08-17
申请号：US858415
申请日：1992-03-27
申请人： Stefan Wieland , Peter Panster , Bertrand Despeyroux , Klaus Deller
发明人： Stefan Wieland , Peter Panster , Bertrand Despeyroux , Klaus Deller
IPC分类号： B01J31/06 , B01J31/16 , B01J31/18 , C08G77/38 , C08G77/398 , C08G77/54 , C08G77/58 , C08K3/10 , C08L83/04 , C08L83/08
CPC分类号： C08G77/58 , B01J31/1675 , B01J31/1805 , C08G77/398 , C08G77/54 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/828
摘要： Metal-containing, shaped, polymeric, tertiary and/or secondary organosiloxane amine compounds are introduced which contain the metals Pd, Pt, Ru, Rh individually or in combination as well as optional promotors and/or moderators. The organosiloxane amine functioning as carrier for the metals contains the units ##STR1## and/or units ##STR2## in which R.sup.1 to R.sup.5 are a group ##STR3## with R.sup.6 as a double-bonded group bound to N and Si (e.g. an alkylene group) and X is an amine group such as The carrier substance can be cross-linked with cross-linking agents containing Si, Ti, Zr or Al. The metal-containing product is spherical in form and is defined by the parameters of sphere diameter, specific surface and pore volume as well as bulk density. A method of production is disclosed which can be carried out in several variants as well as the use of the metal-containing product as catalyst for hydrogenation reactions and oxidation reactions.
摘要翻译：引入含金属，成型，聚合，叔和/或次级有机硅氧烷胺化合物，其单独或组合地含有金属Pd，Pt，Ru，Rh以及任选的促进剂和/或调节剂。有机硅氧烷胺作为载体发挥功能的金属包含单元和/或单元（II）其中R 1至R 5是一组（III）与R6如与N-双键基团和Si（例如亚烷基），X是胺基，例如载体物质可以与含有Si，Ti，Zr或Al的交联剂交联。含金属产品的形状为球形，由球体直径，比表面积和孔体积以及堆积密度的参数定义。公开了一种生产方法，其可以在几种变体中进行，以及使用含金属的产物作为氢化反应和氧化反应的催化剂。

8. 发明授权

US5093451A Formed organosiloxane amine copolycondensates method of their preparation and use 失效
标题翻译：形成的有机硅氧烷共聚物其制备和使用方法
公开(公告)号：US5093451A
公开(公告)日：1992-03-03
申请号：US556720
申请日：1990-07-25
申请人： Peter Panster , Stefan Wieland
发明人： Peter Panster , Stefan Wieland
IPC分类号： C08G77/28 , B01J20/22 , B01J20/26 , C02F1/62 , C02F5/00 , C02F5/08 , C02F5/10 , C08G77/22 , C08G77/26 , C08G77/48 , C08G77/54 , C08G77/58 , C08J3/12
CPC分类号： B01J20/22 , C08G77/22 , C08G77/54 , C08G77/58
摘要： Organosiloxane copolycondensates which are optionally cross-linked by means of cross-linking agents containing Si, Ti, Zr and/or Al and comprised of the units ##STR1## and X--R.sup.4, wherein ##STR2## wherein R.sup.5 =alkylene with C.sub.1 -C.sub.10 bound directly to N or X, or cycloalkylene with C.sub.5 -C.sub.8 or ##STR3## X=--NH.sub.2, --NH--(CH.sub.2).sub.2 --NH.sub.2, --N(CH.sub.3).sub.2, --N(C.sub.2 H.sub.5).sub.2 --NH--(CH.sub.2).sub.2 --NH--(CH.sub.2).sub.2 --NH.sub.2, --Cl, --Br, --I, --SH, --P(C.sub.6 H.sub.5).sub.2, ##STR4## wherein R"=H or alkyl with C1-C5 in the form of spherical particles with a diameter of 0.01 to 3.0 mm, a specific surface of up to 1000 m.sup.2 /g, a specific pore volume of up to 6.0 ml/g and a bulk density of 50 to 1000 g/l. The formed copolycondensates can be used for removing metals from solutions and/or for the adsorption of gaseous organic compounds and/or of water vapor.
摘要翻译：有机硅氧烷共缩聚物，其任选地通过含有Si，Ti，Zr和/或Al的交联剂交联，并由单元X和R 4组成，其中R 5 =亚烷基与C 1 -C 10 X = -NH 2，-NH-（CH 2）2 -NH 2，-N（CH 3）2，-N（C 2 H 5）2 -NH），或（C 1 -C 6）烷基， - （CH 2）2 -NH-（CH 2）2 -NH 2，-Cl，-Br，-I，-SH，-P（C 6 H 5）2，其中R“= H或具有C 1 -C5，直径为0.01〜3.0mm，比表面积为1000m2 / g，比孔容积达6.0ml / g，堆积密度为50〜1000g / l 。形成的共缩聚物可用于从溶液中除去金属和/或用于气态有机化合物和/或水蒸气的吸附。

9. 发明授权

US06156933A Supercritical hydrogenation 有权
标题翻译：超临界氢化
公开(公告)号：US06156933A
公开(公告)日：2000-12-05
申请号：US155660
申请日：1999-02-18
申请人： Martyn Poliakoff , Thomas M. Swan , Thomas Tacke , Martin G. Hitzler , Stephen K. Ross , Stefan Wieland
发明人： Martyn Poliakoff , Thomas M. Swan , Thomas Tacke , Martin G. Hitzler , Stephen K. Ross , Stefan Wieland
IPC分类号： B01J3/00 , C07B35/02 , C07B43/04 , C07B61/00 , C07C29/132 , C07C29/141 , C07C29/145 , C07C29/20 , C07C45/58 , C07C209/36 , C07D317/66 , C07C209/00 , C07C5/00 , C07C37/00
CPC分类号： C07C29/145 , B01J3/008 , C07B35/02 , C07B43/04 , C07C209/36 , C07C29/132 , C07C29/141 , C07C29/20 , C07C45/58 , C07D317/66 , C07C2101/14 , Y02P20/544
摘要： Process for the selective hydrogenation of alphatic or aromatic substrates under supercritical or near critical conditions. Hydrogenation is effected using a heterogeneous catalyst in a continuous flow reactor containing a supercritical or near critical reaction medium and selectively of product formation is achieved by varying one or more of the temperature, pressure, catalyst and flow rate.
摘要翻译： PCT No.PCT / GB97 / 01014 Sec。 371日期1999年2月18日 102（e）1999年2月18日PCT 1997年4月11日PCT PCT。出版物WO97 / 38955 日期1997年10月23日在超临界或接近临界条件下选择性氢化脂肪或芳香族底物的方法。在包含超临界或近临界反应介质的连续流动反应器中使用非均相催化剂进行氢化，并且通过改变一种或多种温度，压力，催化剂和流速来实现产物形成的选择性。

10. 发明授权

US5922900A Process for producing carboxylic acid esters and catalysts therefor 失效
标题翻译：制备羧酸酯及其催化剂的方法
公开(公告)号：US5922900A
公开(公告)日：1999-07-13
申请号：US922558
申请日：1997-09-03
申请人： Stefan Wieland , Peter Panster
发明人： Stefan Wieland , Peter Panster
IPC分类号： B01J31/06 , C07B61/00 , C07C67/08 , C07C69/14 , C07C69/80 , C07C67/00 , C08G77/00 , C08G79/00
CPC分类号： C07C67/08
摘要： A process for producing carboxylic acid esters by the following steps:a) preparation of a reaction mixture containing an alcohol and a carboxylic acid and/or a carboxylic anhydride and/or a carboxylic acid ester and or a partially esterified carboxylic acid,b) heating of this mixture to the suitable reaction temperature in the presence of a solid polysiloxane insoluble in the reaction medium and having sulphonic acid groups with intensive thorough mixing accompanied by continuous separation of the reaction water which forms, wherein the polysiloxane used as the catalyst in modified by treatment with a soluble aluminum, titanium or zirconium compound, and the spherical particles thereof have a diameter of 0.01 to 3 mm, a specific surface of 0.1 to 1200 m.sup.2 /g, a specific pore volume of 0.01 to 6.0 ml/g and a bulk density of 50 to 1000 g/l.
摘要翻译：一种通过以下步骤制备羧酸酯的方法：a）制备含有醇和羧酸和/或羧酸酐和/或羧酸酯和/或部分酯化的羧酸的反应混合物，b）加热该混合物在不溶于反应介质的固体聚硅氧烷存在下具有适当的反应温度，并且具有强烈浓缩的磺酸基团，伴随着形成的反应水的连续分离，其中用作催化剂的聚硅氧烷被改性为用可溶性铝，钛或锆化合物处理，其球形颗粒的直径为0.01〜3mm，比表面积为0.1〜1200m2 / g，比孔体积为0.01〜6.0ml / g，体积密度为50〜1000g / l。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式