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    • 1. 发明授权
    • Monoazo compounds containing long-chain alkyl radicals
    • 含有长链烷基的单偶氮化合物
    • US4997920A
    • 1991-03-05
    • US405612
    • 1989-09-11
    • Stefan HariOlof WallquistJost von der Crone
    • Stefan HariOlof WallquistJost von der Crone
    • C07D239/88C07C245/06C07C245/10C07C255/65C07D235/26C07D263/58C07D265/36C07D277/82C08K5/00C08K5/23C08K5/34C08K5/35C08K5/46C09B29/01C09B29/20C09B29/33C09B67/20
    • C08K5/23C08K5/0041C09B29/0003C09B29/20C09B29/337C09B29/338
    • Compounds of the formulae I and II ##STR1## in which A is a radical of the formulae III, IV or V ##STR2## R.sub.1 and R.sub.4 are --H or --Cl, R.sub.2 and R.sub.5 are --H, halogen, --NO.sub.2, --CN, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 alkoxy, --CF.sub.3 or phenyloxy which is unsubstituted or substituted by one or two chlorine atoms and/or one or two methyl or methoxy groups, and R.sub.3 is alkyl having at least 10 C atoms, X is a radical of the formulae --NH--, --O--, ##STR3## n is the number 1 or 2, Y is the radical of the formulae --COO--, --OOC--, --CONH-- or --NHCO-- or a radical of the formulae ##STR4## in which R.sub.1 and R.sub.2 are as defined above, D is an aromatic heterocyclic 5- or 6-membered ring, in which the ring contains 1 or 2 N atoms and may additionally contain an O atom or S atom, Z is --H, --Br, --OCH.sub.3, --CN or --NO.sub.2 and X.sub.1 and X.sub.2, independently of one another, are --H, halogen, --CH.sub.3, --OCH.sub.3, --OC.sub.2 H.sub.5 or --NO.sub.2 and X.sub.3 is --H, --NHCO--C.sub.1 -C.sub.4 alkyl, benzoylamino or phenylcarboxamide which are each unsubstituted or substituted on the phenyl ring by one or two chlorine atoms and/or one or two methyl or methoxy groups or an --NHCO--C.sub.1 -C.sub.4 alkyl group, or X.sub.2 and X.sub.3 together with the carbon atom to which they are bound are an aromatic carbocyclic 6-membered ring or an aromatic heterocyclic 5- or 6-membered ring, in which the heterocyclic ring contains 1 or 2 N atoms and can additionally have an O atom or S atom, and Y.sub.1 is --H, --OCH.sub.3, --OC.sub.2 H.sub.5 or --NHCOCH.sub.3, with the proviso that X.sub.3 must not be H, if X is --O-- or --NH--, are highly suitable for the mass coloration of plastics, in particular of polyolefins.
    • 其中A是式III,IV或V的基团,其中A是式(I)的化合物,其中A是式III,IV或V的基团(III) (V)R 1和R 4是-H或-Cl,R 2和R 5是-H,卤素,-NO 2,-CN,C 1 -C 4 - 烷基,C 1 -C 4烷氧基,-CF 3或苯氧基,其未被取代或被 一个或两个氯原子和/或一个或两个甲基或甲氧基,并且R 3是具有至少10个C原子的烷基,X是式-NH-,-O-, 的基团 > + TR n是数字1或2,Y是式-COO-,-OOC-,-CONH-或-NHCO-的基团或式(IMAGE)+ TR 其中R1和R2如上定义,D是芳族杂环的5或6元环,其中环含有1或2个N原子,并且可以另外含有O原子或S原子,Z是-H, - Br,-OCH 3,-CN或-NO 2,X 1和X 2彼此独立地是-H,卤素,-CH 3,-OCH 3,-OC 2 H 5或-NO 2,X 3是-H,-NHCO-C 1 -C 4烷基, 苯甲酰氨基或苯基 甲酰胺,其各自未被取代或在苯环上被一个或两个氯原子和/或一个或两个甲基或甲氧基或-NHCO-C 1 -C 4烷基取代,或X 2和X 3与它们所在的碳原子一起 结合的是芳族碳环6元环或芳族杂环5或6元环,其中杂环含有1或2个N原子,并且可以另外具有O原子或S原子,Y 1是-H, - OCH 3,-OC 2 H 5或-NHCOCH 3,条件是如果X为-O-或-NH-,则X3不能为H,高度适用于塑料,特别是聚烯烃的大量着色。
    • 2. 发明授权
    • Disazo compounds containing long-chain alkyl ester radicals or
alkylamide radicals
    • 含有长链氨基酸酯或碱性氨基酸的灭菌化合物
    • US5071967A
    • 1991-12-10
    • US654140
    • 1991-02-11
    • Stefan HariJost von der Crone
    • Stefan HariJost von der Crone
    • C08K5/22C08K5/23C09B27/00C09B29/15C09B33/147C09B33/153C09B43/32
    • C09B43/32C08K5/235C09B27/00C09B29/106C09B33/153
    • Compounds of the formula I ##STR1## in which R is a radical of the formula --OR.sub.5 or --NHR.sub.5, A is a radical of the formula II or III ##STR2## in which B is a radical of the formula ##STR3## in which n is the number 1 or 2, R.sub.1 and R.sub.3 independently of one another are --H or Cl, R.sub.2 and R.sub.4 independently of one another are --H, halogen, --NO.sub.2, --CN, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, --CF.sub.3, C.sub.2 -C.sub.5 alkoxycarbonyl, or --CONH-phenyl, --NHCO-phenyl or phenyloxy which is unsubstituted or substituted on the phenyl nucleus by one or two chlorine atoms or one or two methyl, methoxy or ethoxy groups, R.sub.5 is alkyl having at least 10 C atoms, R.sub.6 and R.sub.7 independently of one another are --H, halogen, --NO.sub.2, --CN, --CF.sub.3, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy, R.sub.8 is --H, --Cl, --Br, --CH.sub.3 or --OCH.sub.3 and X is --H, --Br, --OCH.sub.3, --CN or --NO.sub.2, are particularly suitable as pigments for coloring polyolefins.
    • 其中R为式-OR5或-NHR5基团的式I化合物(Ⅰ)化合物,A为式II或III的基团。 )其中B是式为“IMAGE”的基团,其中n为数1或2,R 1和R 3彼此独立地为-H或Cl,R 2和R 4彼此独立地为-H,卤素, - NO 2,-CN,C 1 -C 4烷基,C 1 -C 4烷氧基,-CF 3,C 2 -C 5烷氧基羰基或-CONH-苯基,-NHCO-苯基或苯氧基,其在苯基上被未取代或取代一个或两个氯原子或一个或 两个甲基,甲氧基或乙氧基,R5是具有至少10个C原子的烷基,R 6和R 7彼此独立地是-H,卤素,-NO 2,-CN,-CF 3,C 1 -C 4烷基或C 1 -C 4烷氧基,R 8是 -H,-Cl,-Br,-CH 3或-OCH 3,X为-H,-Br,-OCH 3,-CN或-NO 2,特别适合作为着色聚烯烃的颜料。
    • 8. 发明授权
    • Novel compositions based on tetrachloroisoindolinone pigments
    • 基于四氯异吲哚啉酮颜料的新型组合物
    • US4892899A
    • 1990-01-09
    • US130245
    • 1987-12-08
    • Edward E. JaffeJost von der CroneBernhard Medinger
    • Edward E. JaffeJost von der CroneBernhard Medinger
    • C07D209/50C09B57/04C09B67/20C09B67/22
    • C09B67/0034C09B57/04
    • Composition of matter containing(a) a compound of the formula I ##STR1## in which A is one of the groups of the formulae ##STR2## in which B is --O--, --S--, --SO.sub.2 --, --N.dbd.N--, --CH.sub.2 --, --CH.dbd.CH--, ##STR3## --CONH--, --NHCONH--, or --CONHNHCO--, Q is --O-- or --NH-- and Z is --O-- or --S-- and R and R' are independently of each other hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or phenoxy, and(b) a compound of the formula II ##STR4## in which A' is as defined above for A, D is hydrogen, amino or a group of the formula III ##STR5## E is --O-- or --S--, T.sub.1, T.sub.2 and T.sub.3 independently of one another are chlorine or a group --ET', T' is a group of the formulae ##STR6## X.sup..sym. is H.sup..sym. or a group of the formulae M.sup.n.sym. /n or N.sup..beta. (R.sub.1)(R.sub.2)(R.sub.3)(R.sub.4), Mhu n.sym. is an n-valent metal cation, n is 1, 2 or 3, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently of one another hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.5 -C.sub.6 -cycloalkyl, unsubstituted or C.sub.1 -C.sub.18 -alkyl-substituted phenyl or R.sub.3 and R.sub.4 together with the N atom form a pyrrolidine, imidazolidine, piperidine, piperazine or morpholine radical, or R.sub.2, R.sub.3 and R.sub.4 together with the N atom form a pyrrole, pyridine, picoline, pyrazine, quinoline or isoquinoline radical and Y is hydrogen, halogen, methyl, methoxy or amino.Pigment mixtures of this type, in particular when used in paints, are distinguished in particular by increased tinctorial strength and high luster and especially by improved rheology.
    • 含有(a)式I化合物的物质组成(IMA)>其中A是下列各组之一: > + TR 其中B为-O - , - S - , - SO 2 - , - N = N-,-CH 2 - , - CH = CH-, - , - CONH - , - NHCONH-或 -CONHNHCO-,Q是-O-或-NH-,Z是-O-或-S-,R和R'彼此独立地是氢,卤素,C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基或苯氧基 ,和(b)式II的化合物(II)其中A'如上对A所定义,D是氢,氨基或式III的基团,其中E是-O - 或-S-,T1,T2和T3彼此独立地是氯或基团-ET',T'是下式的基团:X(+)是H(+)或式 Mn(+)/ n或Nβ(R1)(R2)(R3)(R4),Mhu n(+)为n价金属阳离子,n为1,2或3,R1,R2,R3和R4 独立地为氢,C 1 -C 18 - 烷基,C 5 -C 6 - 环烷基,未取代的或C 1 -C 18烷基取代的苯基或R 3和R 4至 吡咯,吡啶,吡嗪,喹啉或异喹啉基,Y为氢,卤素,吡啶,吡啶,吡啶,吡啶,吡啶, 甲基,甲氧基或氨基。 特别是当用于油漆时,特别是通过增加着色强度和高光泽特别是通过改进的流变学来区分这种颜料混合物。
    • 9. 发明授权
    • Bis-isoindoline pigments
    • 双异吲哚啉颜料
    • US4259488A
    • 1981-03-31
    • US46289
    • 1979-06-07
    • Jost von der Crone
    • Jost von der Crone
    • C09B57/04
    • C09B57/04
    • Isoindoline pigments of the formula ##STR1## or of a formula which is a tautomer thereof, wherein R represents a direct bond or an aliphatic, cycloaliphatic, aliphatic-cycloaliphatic, araliphatic or aromatic radical, R.sub.1 represents a hydrogen atom or an alkyl group of 1 to 4 carbon atoms, or, if R represents an ethylene group, both R.sub.1 s together also represent an ethylene group, R.sub.2 and R.sub.3 represent hydrogen atoms, alkyl groups of 1 to 4 carbon atoms or phenyl groups which are unsubstituted or substituted by methyl groups or halogen atoms, X represents an oxygen atom or a NH group, and Y represents an oxygen or a sulfur atom or a NH group dye plastics in fast yellow or brown shades.
    • 式[IMAGE]或其互变异构体的式的异吲哚啉颜料,其中R表示直接键或脂族,脂环族,脂族 - 脂环族,芳脂族或芳族基团,R1表示氢原子或1 至4个碳原子,或者如果R表示亚乙基,则两个R 1一起也表示亚乙基,R 2和R 3表示氢原子,1至4个碳原子的烷基或未被取代或被甲基取代的苯基或 卤素原子,X表示氧原子或NH基团,Y表示氧或硫原子,或NH基染料塑料为快黄色或棕色色调。