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1. 发明授权

US08445738B2 Process for producing cumene 有权
标题翻译：异丙苯生产工艺
公开(公告)号：US08445738B2
公开(公告)日：2013-05-21
申请号：US13119781
申请日：2009-09-23
申请人： Shyh-Yuan Hwang , Dana E. Johnson , Joseph C. Peters , Chung-Ming Chi , Kevin J. Fallon , Francis A. Demers
发明人： Shyh-Yuan Hwang , Dana E. Johnson , Joseph C. Peters , Chung-Ming Chi , Kevin J. Fallon , Francis A. Demers
IPC分类号： C07C2/86 , C07C37/08
CPC分类号： C07C2/864 , C07C29/145 , C07C37/08 , C07C2529/70 , Y02P20/52 , C07C15/085 , C07C31/10 , C07C39/04
摘要： A process is described for producing cumene comprising contacting a feed stream comprising benzene and a further feed stream comprising isopropanol or a mixture of isopropanol and propylene in the presence of an alkylation catalyst comprising at least a molecular sieve of the MCM-22, family in an alkylation zone under alkylation conditions of at least partial liquid phase and with a water concentration in the liquid phase of at least 50 ppm to react at least part of said isopropanol and benzene to produce an effluent stream containing cumene.
摘要翻译：描述了一种用于生产异丙基苯的方法，包括在包含至少分子筛MCM-22族的烷基化催化剂的烷基化催化剂存在下，使包含苯的进料流和包含异丙醇或异丙醇和丙烯的混合物的另外的进料流接触在至少部分液相的烷基化条件下，在液相中的水浓度为至少50ppm以使至少部分所述异丙醇和苯反应以产生含有枯烯的流出物流。

2. 发明申请

US20110201858A1 PROCESS FOR PRODUCING CUMENE 审中-公开
标题翻译：生产过程的方法
公开(公告)号：US20110201858A1
公开(公告)日：2011-08-18
申请号：US13119789
申请日：2009-09-23
申请人： Shyh-Yuan Henry Hwang , Dana E. Johnson , Joseph C. Peters , Chung-Ming Chi , Kevin J. Fallon , Francis A. Demers
发明人： Shyh-Yuan Henry Hwang , Dana E. Johnson , Joseph C. Peters , Chung-Ming Chi , Kevin J. Fallon , Francis A. Demers
IPC分类号： C07C2/00
CPC分类号： C07C409/10 , C07C2/66 , C07C2/864 , C07C29/145 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/65 , C07C2529/70 , C07C15/085 , C07C31/10 , C07C49/08 , C07C39/04
摘要： In a process for producing cumene from acetone and benzene, a feed stream comprising acetone is contacted with hydrogen in the presence of a hydrogenation catalyst in a first reaction zone under hydrogenation conditions sufficient to convert at least part of the acetone to isopropanol and produce a first liquid effluent stream rich in isopropanol and a first vapor stream rich in unreacted hydrogen. Benzene is then added to at least part of the first liquid effluent stream, without intermediate purification of the first liquid effluent stream, and optionally to at least part of the first vapor stream, to form a second feed stream. The second feed stream is then contacted with an alkylation catalyst in a second reaction zone separate from the first reaction zone under alkylation conditions sufficient to maintain at least part of the second feed stream in the liquid phase and to cause at least part of the isopropanol in the second feed stream to react with the benzene to form cumene and water and produce a second effluent stream comprising at least cumene, water and unreacted benzene. Hydrogen is separated from the first vapor stream and/or the second effluent stream. At least part of the hydrogen is recycled to the first reaction zone and/or purged from the system.
摘要翻译：在从丙酮和苯生产异丙基苯的方法中，在氢化条件下，在氢化催化剂存在下，将含丙酮的进料流与氢气接触，在氢化条件下，将至少部分丙酮转化成异丙醇，并产生第一富含异丙醇的液体流出物流和富含未反应氢的第一蒸气流。然后将苯添加到至少部分第一液体流出物流中，而不用第一液体流出物流的中间纯化，以及任选地至少部分第一蒸气流，形成第二进料流。然后在足以将至少部分第二进料流保持在液相中并使至少部分异丙醇在烷基化条件下与第一反应区分离的第二反应区中的第二进料流与烷基化催化剂接触所述第二进料流与苯反应以形成异丙基苯和水，并产生包含至少异丙基苯，水和未反应的苯的第二流出物流。氢气与第一蒸气流和/或第二流出物流分离。至少部分氢被再循环到第一反应区和/或从系统中清除。

3. 发明申请

US20110178342A1 PROCESS FOR PRODUCING CUMENE 有权
标题翻译：生产过程的方法
公开(公告)号：US20110178342A1
公开(公告)日：2011-07-21
申请号：US13119781
申请日：2009-09-23
申请人： Shyh-Yuan Henry Hwang , Dana E. Johnson , Joseph C. Peters , Chung-Ming Chi , Kevin J. Fallon , Francis A. Demers
发明人： Shyh-Yuan Henry Hwang , Dana E. Johnson , Joseph C. Peters , Chung-Ming Chi , Kevin J. Fallon , Francis A. Demers
IPC分类号： C07C37/60 , C07C2/64
CPC分类号： C07C2/864 , C07C29/145 , C07C37/08 , C07C2529/70 , Y02P20/52 , C07C15/085 , C07C31/10 , C07C39/04
摘要： A process is described for producing cumene comprising contacting a feed stream comprising benzene and a further feed stream comprising isopropanol or a mixture of isopropanol and propylene in the presence of an alkylation catalyst comprising at least a molecular sieve of the MCM-22 family in an alkylation zone under alkylation conditions of at least partial liquid phase and with a water concentration in the liquid phase of at least 50 ppm to react at least part of said isopropanol and benzene to produce an effluent stream containing cumene.
摘要翻译：描述了一种用于生产异丙基苯的方法，包括在包含至少分子筛MCM-22族的烷基化催化剂的烷基化催化剂存在下，使包含苯的进料流和包含异丙醇或异丙醇和丙烯的混合物的另外的进料流接触，在至少部分液相的烷基化条件下，在液相中的水浓度为至少50ppm以使至少部分所述异丙醇和苯反应以产生含有枯烯的流出物流。

4. 发明授权

US5739071A Method and apparatus for regeneratinig and stabilizing dehydrogenation catalysts 失效
标题翻译：再生和稳定脱氢催化剂的方法和装置
公开(公告)号：US5739071A
公开(公告)日：1998-04-14
申请号：US617965
申请日：1996-03-18
申请人： Shiou-Shan Chen , Shyh-Yuan Hwang , Slawomir A. Oleksy , Sanjeev Ram , Joseph C. Peters
发明人： Shiou-Shan Chen , Shyh-Yuan Hwang , Slawomir A. Oleksy , Sanjeev Ram , Joseph C. Peters
IPC分类号： B01J23/94 , B01J38/06 , C07C5/333 , B01J20/34
CPC分类号： B01J38/06 , B01J23/94 , C07C5/3332 , C07C2523/04 , C07C2523/745 , C07C2523/78 , Y02P20/584
摘要： A method and apparatus are disclosed for regenerating and/or stabilizing the activity of a dehydrogenation catalyst used in dehydrogenating an alkylaromatic hydrocarbon to obtain an alkenylaromatic hydrocarbon, the method comprising the steps of continuously or intermittently adding to a reactant stream an effective amount of an alkali metal or alkali metal compound without interrupting the dehydrogenation reaction.
摘要翻译：公开了用于再生和/或稳定用于脱氢烷基芳族烃的脱氢催化剂的活性以获得链烯基芳烃的方法和装置，所述方法包括以下步骤：连续或间歇地向反应物流中加入有效量的碱金属或碱金属化合物，而不会中断脱氢反应。

5. 发明授权

US07745676B2 Alkylaromatics production 有权
标题翻译：烷基芳烃生产
公开(公告)号：US07745676B2
公开(公告)日：2010-06-29
申请号：US11881921
申请日：2007-07-30
申请人： Michael C. Clark , Vijay Nanda , Maruti Bhandarkar , Joseph C. Peters , Chung-Ming Chi , Brian Maerz
发明人： Michael C. Clark , Vijay Nanda , Maruti Bhandarkar , Joseph C. Peters , Chung-Ming Chi , Brian Maerz
IPC分类号： C07C2/66
CPC分类号： C07C2/66 , C07C15/073 , C07C15/02
摘要： A process is described for producing an alkylaromatic compound, in which a first feed comprising an alkylatable aromatic compound and a second feed comprising an alkene are introduced into a first alkylation reaction zone comprising a first alkylation catalyst. The first alkylation reaction zone is operated under conditions effective to cause alkylation of the alkylatable aromatic compound by the alkene to produce said alkylaromatic compound, the conditions being such that the alkylatable aromatic compound is at least predominantly in the vapor phase. A first effluent comprising the alkylaromatic compound and unreacted alkylatable aromatic compound is withdrawn from the first alkylation reaction zone and at least part of the unreacted alkylatable aromatic compound is treated to remove catalyst poisons therefrom and produce a treated unreacted alkylatable aromatic stream. At least part of the unreacted alkylatable aromatic compound and a third feed comprising said alkene is introduced into a second alkylation reaction zone comprising a second alkylation catalyst. The second alkylation reaction zone is operated under conditions effective to cause alkylation of the unreacted alkylatable aromatic compound by the alkene to produce said alkylaromatic compound, the conditions being such that the alkylatable aromatic compound is at least predominantly in the liquid phase. A second effluent comprising said alkylaromatic compound is withdrawn from the second alkylation reaction zone.
摘要翻译：描述了用于生产烷基芳族化合物的方法，其中将包含可烷基化芳族化合物的第一种进料和包含烯烃的第二种进料引入到包含第一烷基化催化剂的第一烷基化反应区中。第一烷基化反应区在有效使烷基化芳族化合物被烯烃烷基化以产生所述烷基芳族化合物的条件下运行，条件是使可烷基化芳族化合物至少主要在气相中。包含烷基芳族化合物和未反应的可烷基化芳族化合物的第一流出物从第一烷基化反应区取出，并且处理至少部分未反应的可烷基化芳族化合物以除去其中的催化剂毒物并产生经处理的未反应的可烷基化芳族物流。将至少部分未反应的可烷基化芳族化合物和包含所述烯烃的第三进料引入到包含第二烷基化催化剂的第二烷基化反应区中。第二烷基化反应区在有效使得未反应的可烷基化芳族化合物被烯烃烷基化以产生所述烷基芳族化合物的条件下运行，条件是使可烷基化芳族化合物至少主要在液相中。从第二烷基化反应区取出包含所述烷基芳族化合物的第二流出物。

6. 发明申请

US20090036722A1 Alkylaromatics production 有权
标题翻译：烷基芳烃生产
公开(公告)号：US20090036722A1
公开(公告)日：2009-02-05
申请号：US11881921
申请日：2007-07-30
申请人： Michael C. Clark , Vijay Nanda , Maruti Bhandarkar , Joseph C. Peters , Chung-Ming Chi , Brian Maerz
发明人： Michael C. Clark , Vijay Nanda , Maruti Bhandarkar , Joseph C. Peters , Chung-Ming Chi , Brian Maerz
IPC分类号： C07C2/68
CPC分类号： C07C2/66 , C07C15/073 , C07C15/02
摘要： A process is described for producing an alkylaromatic compound, in which a first feed comprising an alkylatable aromatic compound and a second feed comprising an alkene are introduced into a first alkylation reaction zone comprising a first alkylation catalyst. The first alkylation reaction zone is operated under conditions effective to cause alkylation of the alkylatable aromatic compound by the alkene to produce said alkylaromatic compound, the conditions being such that the alkylatable aromatic compound is at least predominantly in the vapor phase. A first effluent comprising the alkylaromatic compound and unreacted alkylatable aromatic compound is withdrawn from the first alkylation reaction zone and at least part of the unreacted alkylatable aromatic compound is treated to remove catalyst poisons therefrom and produce a treated unreacted alkylatable aromatic stream. At least part of the unreacted alkylatable aromatic compound and a third feed comprising said alkene is introduced into a second alkylation reaction zone comprising a second alkylation catalyst. The second alkylation reaction zone is operated under conditions effective to cause alkylation of the unreacted alkylatable aromatic compound by the alkene to produce said alkylaromatic compound, the conditions being such that the alkylatable aromatic compound is at least predominantly in the liquid phase. A second effluent comprising said alkylaromatic compound is withdrawn from the second alkylation reaction zone.
摘要翻译：描述了用于生产烷基芳族化合物的方法，其中将包含可烷基化芳族化合物的第一种进料和包含烯烃的第二种进料引入到包含第一烷基化催化剂的第一烷基化反应区中。第一烷基化反应区在有效使烷基化芳族化合物被烯烃烷基化以产生所述烷基芳族化合物的条件下运行，条件是使可烷基化芳族化合物至少主要在气相中。包含烷基芳族化合物和未反应的可烷基化芳族化合物的第一流出物从第一烷基化反应区取出，并且处理至少部分未反应的可烷基化芳族化合物以除去其中的催化剂毒物并产生经处理的未反应的可烷基化芳族物流。将至少部分未反应的可烷基化芳族化合物和包含所述烯烃的第三进料引入到包含第二烷基化催化剂的第二烷基化反应区中。第二烷基化反应区在有效使得未反应的可烷基化芳族化合物被烯烃烷基化以产生所述烷基芳族化合物的条件下运行，条件是使可烷基化芳族化合物至少主要在液相中。从第二烷基化反应区取出包含所述烷基芳族化合物的第二流出物。

7. 发明申请

US20130331626A1 PROCESS FOR REDUCING THE BENZENE CONTENT OF GASOLINE 有权
标题翻译：减少汽油的苯含量的方法
公开(公告)号：US20130331626A1
公开(公告)日：2013-12-12
申请号：US13982944
申请日：2011-11-30
申请人： Shyh-Yuan H. Hwang , Ronald Birkhoff , Richard F. Guarino , J. Erik Moy , Joseph C. Peters
发明人： Shyh-Yuan H. Hwang , Ronald Birkhoff , Richard F. Guarino , J. Erik Moy , Joseph C. Peters
IPC分类号： C10G49/08
CPC分类号： C10G49/08 , C10G29/205
摘要： In a process for alkylating benzene contained in a benzene-containing refinery gasoline stream, the benzene-containing refinery gasoline stream is contacted with an alkylating agent selected from one or more C2 to C5 olefins in at least one alkylation reaction zone under alkylation conditions to produce an alkylated effluent which has reduced benzene content as compared with said refinery gasoline stream and is essentially free of said alkylating agent. An aliquot of the alkylated effluent is then recycled to the one at least one alkylation reaction zone such that the molar ratio of alkylatable aromatic compounds to said alkylating agent in the combined refinery gasoline and recycle streams introduced into the at least one alkylation reaction zone is at least 1.0:1.
摘要翻译：在含苯精炼汽油流中含苯的烷基化方法中，在烷基化条件下，在含至少一个烷基化反应区的含苯精炼汽油流与选自一种或多种C 2至C 5烯烃的烷基化剂接触以产生烷基化流出物与所述精炼汽油流相比具有降低的苯含量，并且基本上不含所述烷化剂。然后将烷基化流出物的等分试样再循环到一个至少一个烷基化反应区，使得引入到至少一个烷基化反应区的组合炼油厂汽油和再循环料流中的可烷基化芳族化合物与所述烷基化剂的摩尔比在至少1.0：1。

8. 发明授权

US5434325A Process for the production of tertiary butylethylbenzene 失效
标题翻译：生产叔丁基乙基苯的方法
公开(公告)号：US5434325A
公开(公告)日：1995-07-18
申请号：US277787
申请日：1994-07-20
申请人： Shiou-Shan Chen , Joseph C. Peters
发明人： Shiou-Shan Chen , Joseph C. Peters
IPC分类号： C07C2/66
CPC分类号： C07C2/66 , C07C2529/70 , Y02P20/582
摘要： The present invention provides an alkylation process which is highly selective towards the production of para-tertiarybutylethylbenzene in high yield and in high para isomer content, while minimizing the development of unwanted by-products and impurities during the alkylation reaction. In accordance with the process, a feed stream mixture comprising the olefin alkylating agent and a molar excess of an aromatic hydrocarbon substrate is introduced into the inlet of a reactor zone and through a bed of active zeolite alkylation catalyst under alkylation conditions such that substantially all of the olefin reacts with the aromatic substrate to produce a mixture comprising the alkylated product and unreacted aromatic compound. This mixture is continuously withdrawn from the reactor zone as reactor effluent, after which the effluent is split into a product stream and recycle stream. The recycle stream is continuously recirculated back into the inlet of said reactor zone, preferably after being first combined with fresh feed stream mixture, in an amount such that the quantity of said aromatic compound and said olefin present in said reaction zone prior to contact with said catalyst is maintained at a preferred mole ratio greater than 10 to 1.
摘要翻译：本发明提供了一种烷基化方法，其以高产率和高对位异构体含量生产对 - 叔丁基苯是高选择性的，同时最小化烷基化反应期间不期望的副产物和杂质的发展。根据该方法，将包含烯烃烷基化剂和摩尔过量的芳烃底物的进料流混合物在烷基化条件下引入反应器区的入口并通过活性沸石烷基化催化剂床，使得基本上全部烯烃与芳族底物反应产生包含烷基化产物和未反应的芳族化合物的混合物。将该混合物作为反应器流出物从反应器区域连续取出，然后将流出物分成产物流和再循环流。再循环流连续再循环回所述反应器区的入口，优选在与新鲜进料流混合物首次混合之后，其量使得所述芳族化合物和所述烯烃在与所述反应区接触之前存在于所述反应区中的量催化剂保持在大于10比1的优选摩尔比。

9. 发明授权

US09200215B2 Process for reducing the benzene content of gasoline 有权
标题翻译：降低汽油苯含量的方法
公开(公告)号：US09200215B2
公开(公告)日：2015-12-01
申请号：US13982944
申请日：2011-11-30
申请人： Shyh-Yuan H. Hwang , Ronald Birkhoff , Richard F. Guarino , J. Erik Moy , Joseph C. Peters
发明人： Shyh-Yuan H. Hwang , Ronald Birkhoff , Richard F. Guarino , J. Erik Moy , Joseph C. Peters
IPC分类号： C07C2/66 , C10G49/08 , C10G29/20
CPC分类号： C10G49/08 , C10G29/205
摘要： In a process for alkylating benzene contained in a benzene-containing refinery gasoline stream, the benzene-containing refinery gasoline stream is contacted with an alkylating agent selected from one or more C2 to C5 olefins in at least one alkylation reaction zone under alkylation conditions to produce an alkylated effluent which has reduced benzene content as compared with said refinery gasoline stream and is essentially free of said alkylating agent. An aliquot of the alkylated effluent is then recycled to the one at least one alkylation reaction zone such that the molar ratio of alkylatable aromatic compounds to said alkylating agent in the combined refinery gasoline and recycle streams introduced into the at least one alkylation reaction zone is at least 1.0:1.
摘要翻译：在含苯精炼汽油流中含苯的烷基化方法中，在烷基化条件下，在含至少一个烷基化反应区的含苯精炼汽油流与选自一种或多种C 2至C 5烯烃的烷基化剂接触以产生烷基化流出物与所述精炼汽油流相比具有降低的苯含量，并且基本上不含所述烷化剂。然后将烷基化流出物的等分试样再循环到一个至少一个烷基化反应区，使得引入到至少一个烷基化反应区的组合炼油厂汽油和再循环料流中的可烷基化芳族化合物与所述烷基化剂的摩尔比在至少1.0：1。

10. 发明授权

US09199891B2 Process for reducing the benzene content of gasoline 有权
标题翻译：降低汽油苯含量的方法
公开(公告)号：US09199891B2
公开(公告)日：2015-12-01
申请号：US13982964
申请日：2011-11-30
申请人： Shyh-Yuan H. Hwang , Ronald Birkhoff , Richard F. Guarino , J. Erik Moy , Joseph C. Peters
发明人： Shyh-Yuan H. Hwang , Ronald Birkhoff , Richard F. Guarino , J. Erik Moy , Joseph C. Peters
IPC分类号： C07C2/66 , C07C2/64
CPC分类号： C07C2/64 , C10G29/205 , C10G53/02 , C10G2300/104 , C10G2400/02
摘要： A process is disclosed for alkylating benzene contained in a benzene-containing refinery gasoline stream also comprising at least 0.1 wt % of at least one C6 to C8 olefin. In the process, the refinery gasoline stream is contacted under alkylation conditions with an alkylating agent selected from one or more C2 to C5 olefins in at least a first alkylation reaction zone and a second alkylation reaction zone connected in series to produce an alkylated effluent, which has reduced benzene content as compared with said refinery gasoline stream. All of the refinery gasoline stream is introduced into the first alkylation reaction stage, whereas an aliquot of the alkylated effluent is recycled and introduced to the second, but not the first, alkylation reaction zone.
摘要翻译：公开了一种方法，其用于烷基化还含有至少0.1wt％的至少一种C 6至C 8烯烃的含苯精炼汽油流中的苯。在该过程中，炼油厂汽油流在烷基化条件下与在至少第一烷基化反应区和第二烷基化反应区中串联选择一种或多种C 2至C 5烯烃的烷基化剂接触以产生烷基化流出物，其中与所述精炼汽油流相比，苯含量降低。将所有炼油厂汽油流引入第一烷基化反应阶段，而将烷基化流出液的等分试样循环并引入第二烷基化反应区而不是第一烷基化反应区。

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