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1. 发明授权

US08722801B2 Process for producing hydrolyzable silyl group-containing fluoropolymer, and composition containing hydrolyzable silyl group-containing fluoropolymer 失效
标题翻译：含有水解性甲硅烷基的含氟聚合物的制造方法以及含有可水解甲硅烷基的含氟聚合物的组合物
公开(公告)号：US08722801B2
公开(公告)日：2014-05-13
申请号：US13463886
申请日：2012-05-04
申请人： Shun Saito , Sho Masuda , Hiroshi Nishio
发明人： Shun Saito , Sho Masuda , Hiroshi Nishio
IPC分类号： C08F8/00
CPC分类号： C09D127/12 , C08F8/42 , C08F214/247 , C08F2800/20 , C08F2810/50 , C08G18/222 , C08G18/246 , C08G18/6279 , C08G18/718 , C08J3/09 , C08J2327/22 , C09D127/22 , C08F214/18 , C08F214/245 , C08F214/24 , C08F216/1416 , C08F224/00
摘要： The present invention has an object to provide a process for producing a hydrolyzable silyl group-containing fluoropolymer which is excellent in storage stability and has a sufficient pot life. At the time of producing a hydrolyzable silyl group-containing fluoropolymer by reacting an isocyanate group of an isocyanate group-containing alkoxysilane to a hydroxy group of a hydroxy group-containing fluoropolymer, the reaction is carried out in the presence a compound containing a specific metal atom at a certain concentration.
摘要翻译：本发明的目的是提供一种储存稳定性优异并且具有足够的使用期的含有水解性甲硅烷基的含氟聚合物的制造方法。通过使含异氰酸酯基的烷氧基硅烷的异氰酸酯基与含羟基的含氟聚合物的羟基反应来制造含有水解性甲硅烷基的含氟聚合物时，在含有特定金属的化合物存在下进行反应一定浓度的原子

2. 发明授权

US09856340B2 Photocurable fluorinated polymer composition 有权
公开(公告)号：US09856340B2
公开(公告)日：2018-01-02
申请号：US13399223
申请日：2012-02-17
申请人： Shun Saito , Hiroshi Nishio , Sho Masuda
发明人： Shun Saito , Hiroshi Nishio , Sho Masuda
IPC分类号： C08F214/18 , C08K5/00 , C08F214/26 , C08L27/12 , C08L29/10 , C08F216/14 , C08L63/00
CPC分类号： C08F214/186 , C08F214/262 , C08F214/265 , C08F214/267 , C08F216/1416 , C08K5/0025 , C08L27/12 , C08L29/10 , C08L63/00 , C08L2666/14
摘要： To provide a photocurable fluorinated polymer composition which has a high curing rate, shows little shrinkage before and after photocuring and requires no post treatment such as heat treatment after photocuring and whereby it is possible to obtain a cured resin excellent in heat resistance and weather resistance. According to the photocurable fluorinated polymer composition comprising a fluorinated polymer (A) containing polymerized units derived from a fluoroolefin and polymerized units derived from an unsaturated monomer having an oxetanyl group or a substituted oxetanyl group, and a photoreaction initiator (B), of the present invention, it is possible to provide a photocurable fluorinated polymer composition which has a high curing rate, shows little shrinkage before and after photocuring and requires no post treatment such as heat treatment after photocuring and whereby it is possible to obtain a cured resin excellent in heat resistance and weather resistance.

3. 发明申请

US20120149798A1 PHOTOCURABLE FLUORINATED POLYMER COMPOSITION 有权
标题翻译：可光化氟化聚合物组合物
公开(公告)号：US20120149798A1
公开(公告)日：2012-06-14
申请号：US13399223
申请日：2012-02-17
申请人： Shun SAITO , Hiroshi Nishio , Sho Masuda
发明人： Shun SAITO , Hiroshi Nishio , Sho Masuda
IPC分类号： C08F224/00 , C08F2/46
CPC分类号： C08F214/186 , C08F214/262 , C08F214/265 , C08F214/267 , C08F216/1416 , C08K5/0025 , C08L27/12 , C08L29/10 , C08L63/00 , C08L2666/14
摘要： To provide a photocurable fluorinated polymer composition which has a high curing rate, shows little shrinkage before and after photocuring and requires no post treatment such as heat treatment after photocuring and whereby it is possible to obtain a cured resin excellent in heat resistance and weather resistance. According to the photocurable fluorinated polymer composition comprising a fluorinated polymer (A) containing polymerized units derived from a fluoroolefin and polymerized units derived from an unsaturated monomer having an oxetanyl group or a substituted oxetanyl group, and a photoreaction initiator (B), of the present invention, it is possible to provide a photocurable fluorinated polymer composition which has a high curing rate, shows little shrinkage before and after photocuring and requires no post treatment such as heat treatment after photocuring and whereby it is possible to obtain a cured resin excellent in heat resistance and weather resistance.
摘要翻译：为了提供固化速度高的光固化性氟化聚合物组合物，在光固化前后收缩少，不需要后固化，例如光固化后的热处理，可以得到耐热性和耐候性优异的固化树脂。根据含有含有衍生自氟代烯烃的聚合单元的氟化聚合物（A）和衍生自具有氧杂环丁烷基或取代的氧杂环丁烷基的不饱和单体的聚合单元和光反应引发剂（B）的光固化氟化聚合物组合物，本发明中，可以提供固化速度快，光固化前后收缩少的光固化性氟代聚合物组合物，光固化后不进行热处理等后处理，能够得到热稳定性优异的固化树脂耐候性和耐候性。

4. 发明申请

US20100331482A1 COMPOSITION FOR COATING AGENT 有权
标题翻译：涂料代理组合物
公开(公告)号：US20100331482A1
公开(公告)日：2010-12-30
申请号：US12878064
申请日：2010-09-09
申请人： Shun SAITO , Satoshi Fujita , Koichi Sasaki , Sho Masuda
发明人： Shun SAITO , Satoshi Fujita , Koichi Sasaki , Sho Masuda
IPC分类号： C08L83/06
CPC分类号： C09D127/22 , C08G18/6275 , C08G18/718 , C08K5/5403 , C09D175/04 , C09D183/08
摘要： To provide a composition for a coating agent capable of forming a coating film excellent in the weather resistance, having high uniformity and having favorable gloss on the surface.A composition for a coating agent, which comprises a fluoropolymer (component A) containing units (A2) having a compound represented by the following formula (1) reacted with units based on a hydroxy group-containing monomer and units (A1) based on a fluoroolefin, and component B represented by the following formula (2), wherein the proportion of the component A is from 10 to 90 mass % to the total content of the component A and the component B: OCN(CH2)mSiXnR3-n (1) wherein R is a hydrogen atom or a monovalent hydrocarbon group, X is an alkoxy group, n is an integer of from 1 to 3, and m is an integer of from 1 to 5, (R1)4-aSi(OR2)a (2) wherein each of R1 and R2 which are independent of each other, is a monovalent hydrocarbon group, and “a” is an integer of from 1 to 4.
摘要翻译：提供能够形成耐候性优异，均匀性好，表面光泽好的涂膜的涂布剂组合物。包含含有含有由下式（1）表示的化合物的单元（A2））的含氟聚合物（A组分）的涂料组合物与基于含羟基的单体和基于单体（A1）的单元反应，基于氟代烯烃和由下式（2）表示的组分B，其中组分A的比例为组分A和组分B的总含量为10至90质量％：OCN（CH 2）m SiX n R 3-n（1 ）其中R为氢原子或一价烃基，X为烷氧基，n为1〜3的整数，m为1〜5的整数，（R1）4-aSi（OR2）a （2）其中R1和R2彼此独立的是一价烃基，“a”是1至4的整数。

5. 发明授权

US08778499B2 Coating composition for solar heat-collecting reflector, and solar heat-collecting reflector and process for its production 失效
标题翻译：用于太阳能集热反射器的涂料组合物和太阳能集热反射器及其生产方法
公开(公告)号：US08778499B2
公开(公告)日：2014-07-15
申请号：US13568256
申请日：2012-08-07
申请人： Shun Saito , Masataka Aikawa , Takashi Takayanagi , Sho Masuda
发明人： Shun Saito , Masataka Aikawa , Takashi Takayanagi , Sho Masuda
IPC分类号： B05D3/02 , B32B15/08 , F24J2/46 , C09D175/04 , C08G18/62 , C08G18/71 , C08G18/79 , F24J2/10 , G02B5/08 , C09D127/12
CPC分类号： C09D127/12 , C08G18/6279 , C08G18/718 , C08G18/792 , C09D175/04 , F24S23/82 , F24S40/40 , F24S2023/86 , G02B5/0808 , Y02E10/40 , Y10T428/3154 , Y10T428/31678
摘要： To provide a coating composition for back coating, by which, in a solar heat-collecting reflector, a cured coating film layer excellent in durability such as heat resistance or water resistance and excellent in weather resistance, scratch resistance and impact resistance, can be formed, and a solar heat-collecting reflector having such a cured coating film layer. A coating composition for back coating to be used for the production of a solar heat-collecting reflector, which comprises a fluoropolymer (A) having units (A1) derived from a fluoroolefin and units (A2) having a crosslinkable group. A solar heat-collecting reflector having a cured coating film layer formed by the coating composition.
摘要翻译：提供一种背涂用涂料组合物，其可以在太阳能集热反射体中形成耐热性，耐水性等耐久性优异，耐刮擦性，耐冲击性优异的固化涂膜层和具有这种固化涂膜层的太阳能集热反射器。一种用于生产太阳能集热反射器的背涂涂料组合物，其包含具有衍生自氟代烯烃的单元（A1）的氟聚合物（A）和具有可交联基团的单元（A2）。一种具有由涂料组合物形成的固化涂膜层的太阳能集热反射器。

6. 发明申请

US20120247457A1 COATING COMPOSITION FOR SOLAR HEAT-COLLECTING REFLECTIVE PLATE, AND SOLAR HEAT-COLLECTING REFLECTIVE PLATE AND PROCESS FOR ITS PRODUCTION 审中-公开
标题翻译：太阳能热收集板和太阳能热收集板的涂料组合物及其生产工艺
公开(公告)号：US20120247457A1
公开(公告)日：2012-10-04
申请号：US13495032
申请日：2012-06-13
申请人： Shun SAITO , Masataka Aikawa , Takashi Takayanagi , Sho Masuda
发明人： Shun SAITO , Masataka Aikawa , Takashi Takayanagi , Sho Masuda
IPC分类号： F24J2/10 , C09D127/18 , C09D127/20 , C09D127/16 , C09D127/14 , B05D5/06 , C09D127/12
CPC分类号： G02B1/14 , C08K5/0025 , C09D127/12 , F24S23/82 , F24S2023/86 , G02B1/105 , G02B5/0808 , Y02E10/40
摘要： The present invention is to provide a coating composition for surface coating capable of forming a cured coating film layer that protects a reflective substrate of a solar heat-collecting reflective plate and that is excellent in the impact resistance and the weather resistance such as the heat resistance and the water resistance, as well as a solar heat-collecting reflective plate having such a cured coating film layer, and a process for its production. A coating composition for surface coating to be used for the production of a solar heat-collecting reflective plate having a reflective substrate made of metal, which comprises a fluoropolymer (A) having units (A1) derived from a fluoroolefin and units (A2) having a crosslinkable group. Further, a solar heat-collecting reflective plate having a cured coating film layer formed from the coating composition for surface coating, and a process for its production.
摘要翻译：本发明提供一种能够形成保护太阳能集热反射板的反射基板的固化涂膜层的表面涂层用涂料组合物，其耐冲击性和耐候性如耐热性优异和耐水性，以及具有这种固化涂膜层的太阳能集热反射板及其制造方法。一种用于生产具有由金属制成的反射基板的太阳能集热反射板的表面涂层用涂料组合物，其包含具有由氟烯烃衍生的单元（A1）的含氟聚合物（A）和具有可交联基团。此外，具有由表面被覆用涂料组合物形成的固化涂膜层的太阳能集热反射板及其制造方法。

7. 发明授权

US08436123B2 Composition for coating agent 有权
标题翻译：涂层剂组成
公开(公告)号：US08436123B2
公开(公告)日：2013-05-07
申请号：US12878064
申请日：2010-09-09
申请人： Shun Saito , Satoshi Fujita , Koichi Sasaki , Sho Masuda
发明人： Shun Saito , Satoshi Fujita , Koichi Sasaki , Sho Masuda
IPC分类号： C08G77/24
CPC分类号： C09D127/22 , C08G18/6275 , C08G18/718 , C08K5/5403 , C09D175/04 , C09D183/08
摘要： A composition for a coating agent including a component A and a component B, wherein the proportion of component A is 10-90 mass % to the total content of component A and component B, wherein component A is a fluoropolymer containing units (A1) based on a fluoroolefin and units (A2) having a compound of formula (1) reacted with units based on a hydroxy group-containing monomer: OCN(CH2)mSiXnR3-n (1) (wherein R is a hydrogen atom or a C1-10 monovalent hydrocarbon group, X is a C1-5 alkoxy group, n is an integer of 1 to 3, and m is an integer of 1 to 5), wherein component B is a compound of formula (2) and/or a partially hydrolyzed condensate of the compound of formula (2): (R1)4-aSi(OR2)a (2) (wherein each of R1 and R2 are independently a C1-10 monovalent hydrocarbon group, and a is an integer of 1 to 4).
摘要翻译：用于包含A成分和B成分的涂布剂组合物，其中A成分与A成分和B成分的总成分相比为10〜90质量％，其中，成分A为含氟单体（A1）系的含氟聚合物在具有式（1）的化合物的单元（A2）与基于含羟基的单体的基团OCN（CH 2）m SiX n R 3-n（1）（其中R是氢原子或C1-10 一价烃基，X为C 1-5烷氧基，n为1〜3的整数，m为1〜5的整数），其中，B为式（2）的化合物和/或部分水解的式（2）化合物的缩合物：（R1）4-aSi（OR2）a（2）（其中R1和R2各自独立地为C1-10一价烃基，a为1〜4的整数）。

8. 发明申请

US20120301728A1 COATING COMPOSITION FOR SOLAR HEAT-COLLECTING REFLECTOR, AND SOLAR HEAT-COLLECTING REFLECTOR AND PROCESS FOR ITS PRODUCTION 失效
标题翻译：太阳能热收集反射器的涂料组合物和太阳能热收集反应器及其生产工艺
公开(公告)号：US20120301728A1
公开(公告)日：2012-11-29
申请号：US13568256
申请日：2012-08-07
申请人： Shun Saito , Masataka Aikawa , Takashi Takayanagi , Sho Masuda
发明人： Shun Saito , Masataka Aikawa , Takashi Takayanagi , Sho Masuda
IPC分类号： C09D127/12 , C08K3/22 , B32B27/06 , B05D5/06
CPC分类号： C09D127/12 , C08G18/6279 , C08G18/718 , C08G18/792 , C09D175/04 , F24S23/82 , F24S40/40 , F24S2023/86 , G02B5/0808 , Y02E10/40 , Y10T428/3154 , Y10T428/31678
摘要： To provide a coating composition for back coating, by which, in a solar heat-collecting reflector, a cured coating film layer excellent in durability such as heat resistance or water resistance and excellent in weather resistance, scratch resistance and impact resistance, can be formed, and a solar heat-collecting reflector having such a cured coating film layer. A coating composition for back coating to be used for the production of a solar heat-collecting reflector, which comprises a fluoropolymer (A) having units (A1) derived from a fluoroolefin and units (A2) having a crosslinkable group. A solar heat-collecting reflector having a cured coating film layer formed by the coating composition.
摘要翻译：提供一种背涂用涂料组合物，其可以在太阳能集热反射体中形成耐热性，耐水性等耐久性优异，耐刮擦性，耐冲击性优异的固化涂膜层和具有这种固化涂膜层的太阳能集热反射器。一种用于生产太阳能集热反射器的背涂涂料组合物，其包含具有衍生自氟代烯烃的单元（A1）的氟聚合物（A）和具有可交联基团的单元（A2）。一种具有由涂料组合物形成的固化涂膜层的太阳能集热反射器。

9. 发明授权

US07652110B2 Powder coating composition 有权
标题翻译：粉末涂料组合物
公开(公告)号：US07652110B2
公开(公告)日：2010-01-26
申请号：US12248923
申请日：2008-10-10
申请人： Sho Masuda , Yuji Hara , Kouichi Sasaki
发明人： Sho Masuda , Yuji Hara , Kouichi Sasaki
IPC分类号： C08F12/20
CPC分类号： C09D127/12 , C08G18/6279 , C08G2150/20 , C08K5/0025 , C08K5/29 , C09D5/03 , C09D175/04
摘要： The claimed invention relates to a powder coating composition containing a fluorinated copolymer (X) having a glass transition point of at least 50° C. and a number average molecular weight of from 10,000 to 22,000, and a curing agent (Y), wherein the fluorinated copolymer (X) is a copolymer obtained by polymerization of a monomer mixture containing (A) from 45 to 55 mol % of chlorotrifluoroethylene and/or tetrafluoroethylene, (B) from 2 to 40 mol % of a vinyl ether which has a C4 or 5 alkyl group containing a tertiary carbon atom, (C) from 5 to 20 mol % of a vinyl ether having a crosslinkable functional group, and (E) from 1 to 32 mol % of a vinyl ester which has a C3-5 alkyl group containing a tertiary or higher carbon atom, wherein the total content of (B) and (E) is from 30 to 50 mol %, and the curing agent (Y) is reactive with the crosslinkable functional group.
摘要翻译：所要求保护的发明涉及含有玻璃化转变温度为至少50℃，数均分子量为10,000〜22,000的氟化共聚物（X）和固化剂（Y）的粉末涂料组合物，其中，含氟共聚物（X）是通过聚合含有（A）45〜55摩尔％的三氟氯乙烯和/或四氟乙烯的单体混合物，（B）的2-40摩尔％的具有C4或 5个含有叔碳原子的烷基，（C）5〜20摩尔％的具有交联性官能团的乙烯基醚，（E）1〜32摩尔％的具有C3-5烷基的乙烯基酯（B）和（E）的总含量为30〜50摩尔％，固化剂（Y）与交联性官能团反应。

10. 发明授权

US08173557B2 Laminated sheet 有权
标题翻译：复合板
公开(公告)号：US08173557B2
公开(公告)日：2012-05-08
申请号：US12538901
申请日：2009-08-11
申请人： Yoshiaki Higuchi , Takuya Nakao , Sho Masuda
发明人： Yoshiaki Higuchi , Takuya Nakao , Sho Masuda
IPC分类号： B32B27/12
CPC分类号： A01G9/1438 , B32B5/022 , B32B5/024 , B32B17/02 , B32B27/12 , B32B27/304 , B32B27/32 , B32B27/322 , B32B2260/021 , B32B2260/046 , B32B2262/101 , B32B2307/412 , B32B2307/54 , B32B2307/712 , B32B2307/7265 , B32B2410/00 , B32B2419/06 , B32B2607/00 , C08K7/14 , Y02A40/252 , Y10T442/2213 , Y10T442/2221 , Y10T442/30 , Y10T442/3854 , Y10T442/3878 , Y10T442/60 , Y10T442/674 , Y10T442/677 , C08L27/12
摘要： A laminated sheet comprising a woven or nonwoven fabric comprising glass fibers fixed by a binder, and a fluororesin film laminated on each other, wherein the binder contains a copolymer (A) having repeating units (a1) based on at least one fluoromonomer selected from the group consisting of tetrafluoroethylene, chlorotrifluoroethylene and hexafluoropropylene, and repeating units (a2) based on at least one non-fluoromonomer selected from the group consisting of a vinyl ether, a vinyl ester, an isopropenyl ether, an isopropenyl ester, an allyl ether and an allyl ester.
摘要翻译：一种层压片材，其包含由粘合剂固定的玻璃纤维的织造或无纺织物和彼此层压的氟树脂膜，其中所述粘合剂含有基于至少一种选自以下的含氟单体的重复单元（a1）的共聚物（A）由四氟乙烯，三氟氯乙烯和六氟丙烯组成的组，以及基于至少一种选自乙烯基醚，乙烯基酯，异丙烯基醚，异丙烯基酯，烯丙基醚的非氟单体的重复单元（a2）和烯丙酯。

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