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    • 6. 发明授权
    • Process for producing norbornene derivative having organosilyl group
    • 制备具有有机甲硅烷基的降冰片烯衍生物的方法
    • US06777570B2
    • 2004-08-17
    • US10670515
    • 2003-09-26
    • Hiroko TakahashiTakako TakahashiTaketoshi NaitoShuji Ichikawa
    • Hiroko TakahashiTakako TakahashiTaketoshi NaitoShuji Ichikawa
    • C07F708
    • C07F7/0827
    • A process for producing a norbornene derivative having an organosilyl group suitable as a synthetic intermediate for pesticides and medicaments and for production of polyolefin polymers, particularly polyolefin polymers having a good adhesiveness with metals or insulating inorganic materials in high yields with a satisfactory purity. A process for producing a norbornene derivative having an organosilyl group represented by the general formula (3): wherein R each represents an alkyl group or an aryl group, R′ represents an alkyl group or an aryl group, n represents an integer of 0 to 2 and m represents an integer of 0 or more, which comprises reacting a compound represented by the general formula (1): wherein R, n and m have the same meanings as above, and X represents a halogen atom, with a Grignard agent represented by the general formula (2): R′MgCl  (2) wherein R′ has the same meaning as above.
    • 具有适合作为农药和药物的合成中间体的有机甲硅烷基的降冰片烯衍生物的制造方法以及用于生产聚烯烃聚合物的方法,特别是具有与金属或绝缘无机材料的良好粘合性的聚烯烃聚合物,其产率高,具有令人满意的纯度。 一种具有由通式(3)表示的有机甲硅烷基的降冰片烯衍生物的方法:其中R各自表示烷基或芳基,R'表示烷基或芳基,n表示0〜 2和m表示0或更大的整数,其包括使通式(1)表示的化合物:其中R,n和m具有与上述相同的含义,X表示卤素原子,表示为格列酮 由通式(2)表示:其中R'具有与上述相同的含义。