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1. 发明授权

US5824414A Preparation of spherical polyphenol particles 失效
标题翻译：制备球形多酚颗粒
公开(公告)号：US5824414A
公开(公告)日：1998-10-20
申请号：US633378
申请日：1996-04-17
申请人： Shiro Kobayashi , Hiroshi Uyama , Sunao Maeda , Shinichirou Tawaki
发明人： Shiro Kobayashi , Hiroshi Uyama , Sunao Maeda , Shinichirou Tawaki
IPC分类号： C08G61/10 , C12P7/22 , C12P1/00
CPC分类号： C12P7/22 , C08G61/10 , Y10T428/2982
摘要： Phenols are reacted with hydrogen peroxide in a solution comprising an organic solvent compatible with water, water, a peroxidase and a dispersing agent to obtain spherical polyphenol particles.
摘要翻译：苯酚与含有与水，水，过氧化物酶和分散剂相容的有机溶剂的溶液中的过氧化氢反应，得到球状多酚颗粒。

2. 发明授权

US5204428A Copolymer and method of producing the same 失效
标题翻译：共聚物及其制造方法
公开(公告)号：US5204428A
公开(公告)日：1993-04-20
申请号：US809224
申请日：1991-12-16
申请人： Shiro Kobayashi , Yoshihiro Taguchi , Hiroshi Uyama
发明人： Shiro Kobayashi , Yoshihiro Taguchi , Hiroshi Uyama
IPC分类号： C08F216/14 , C08F220/10 , C08F246/00 , C09K11/02 , H01G4/18 , H05B33/20
CPC分类号： H01G4/18 , C08F216/14 , C08F220/10 , C08F246/00 , C09K11/02 , H05B33/20
摘要： A copolymer of the present invention is produced by copolymerization of an electron-donating monomer having an electron-accepting group and an electron-accepting monomer having an electron-accepting group. The copolymer thus exhibits a high dielectric constant, a low level of hygroscopicity and good adhesion.
摘要翻译：本发明的共聚物是通过具有电子接受基团的给电子性单体和具有电子接受基团的电子接受性单体的共聚来制造的。因此共聚物表现出高介电常数，低吸湿性和良好的粘合性。

3. 发明授权

US06344516B1 Resin composition and process for producing the same 失效
标题翻译：树脂组合物及其制造方法
公开(公告)号：US06344516B1
公开(公告)日：2002-02-05
申请号：US09763969
申请日：2001-02-28
申请人： Ryohei Ikeda , Shiro Kobayashi , Hiroshi Uyama
发明人： Ryohei Ikeda , Shiro Kobayashi , Hiroshi Uyama
IPC分类号： C08K516
CPC分类号： C08G61/10
摘要： A curable resin composition, which comprises a resin formed, in the presence of a transition metal complex, by polymerizing an oxidative-polymerizable compound that contains a phenol-compound-containing vegetable oil. A method for producing a curable resin composition comprising a resin formed, in the presence of a catalyst, by polymerizing an oxidative-polymerizable compound that contains a phenol-compound-containing vegetable oil, wherein the catalyst is a transition metal complex. The curable resin composition is useful as a raw material for a urushi-like coating, a friction material, a brake lining material, a brake pad material, a material for forming a coating film, a compound for a recording material, a raw material for an ink, a raw material for a coating,.a raw material for a adhesive, a raw material for an epoxy resin, a raw material for a photoresist or antioxidant, and a starting material for a functional polymer.
摘要翻译：一种可固化树脂组合物，其包含在过渡金属配合物的存在下形成的树脂，通过聚合含有含苯酚化合物的植物油的可氧化聚合化合物。一种固化性树脂组合物的制造方法，其特征在于，在催化剂存在下，通过聚合含有含苯酚化合物的植物油的氧化聚合性化合物而形成的树脂，其中，所述催化剂为过渡金属络合物。固化性树脂组合物可用作尿素状涂层的原料，摩擦材料，制动衬片材料，制动衬块材料，用于形成涂膜的材料，用于记录材料的化合物，用于记录材料的原料油墨，涂料用原料，粘合剂用原料，环氧树脂用原料，光致抗蚀剂或抗氧化剂用原料，功能性聚合物原料等。

4. 发明授权

US5864050A Curable resin compound, method for producing the same, and cured-resin material 失效
标题翻译：可固化树脂化合物，其制备方法和固化树脂材料
公开(公告)号：US5864050A
公开(公告)日：1999-01-26
申请号：US743997
申请日：1996-11-04
申请人： Yoshihiro Taguchi , Shiro Kobayashi , Hiroshi Uyama , Atsushi Nakamura
发明人： Yoshihiro Taguchi , Shiro Kobayashi , Hiroshi Uyama , Atsushi Nakamura
IPC分类号： C07C45/68 , C07C45/71 , C07C49/84 , C08F290/06 , C08F299/04 , C08G65/40 , C08G65/48 , C08F138/00 , C07C49/796
CPC分类号： C08G65/48 , C07C45/68 , C07C45/71 , C07C49/84 , C08G65/4012 , C08G2650/20 , C08G2650/60 , C08L2312/00
摘要： The present invention provides a curable resin compound which is soluble in organic solvents and easy to use, and a method for producing the same. The curable resin compound comprises a structure and crosslinkable groups which end-cap the structure, the structure comprising three or four non-substituted benzene rings each of which is joined with each adjacent benzene ring by an ether or ketone linkage so that both types of linkages are present in the structure. Though the curable resin compound exhibits satisfactory solubilities in organic solvents, a composition comprising the compound can be cured by a crosslinking reaction to be insoluble in the organic solvents while being provided with improved solvent resistance and chemical resistance. Accordingly, the present invention also provides a cured-resin material derived from the aforementioned curable resin compound, the cured-resin material being excellent in solvent resistance, chemical resistance and thermal resistance.
摘要翻译：本发明提供一种可溶于有机溶剂且易于使用的可固化树脂化合物及其制备方法。可固化树脂化合物包括结构和端基结构的可交联基团，其结构包含三个或四个未取代的苯环，每个苯环通过醚或酮键与每个相邻的苯环连接，使得两种类型的键存在于结构中。尽管可固化树脂化合物在有机溶剂中表现出令人满意的溶解性，但是包含该化合物的组合物可以通过交联反应固化而不溶于有机溶剂，同时具有改进的耐溶剂性和耐化学性。因此，本发明还提供了由上述固化性树脂化合物衍生的固化树脂材料，其耐溶剂性，耐化学性和耐热性优异的固化树脂材料。

5. 发明授权

US5164477A Polyfunctional polymerization initiator 失效
标题翻译：多官能聚合引发剂
公开(公告)号：US5164477A
公开(公告)日：1992-11-17
申请号：US739539
申请日：1991-08-02
申请人： Shiro Kobayashi , Hiroshi Uyama
发明人： Shiro Kobayashi , Hiroshi Uyama
IPC分类号： C08G73/02
CPC分类号： C08G73/0233
摘要： A polyfunctional polymerization initiator suitable to cationic ring-opening polymerization of heterocyclic monomers, having at least one carbon atom bonded directly to a carbon-carbon double bond in a linear or cyclic organic group and, further, having at least two following groups containing the above said carbon atoms and represented by the general formula:--CH.sub.2 Xwhere X represents an electron attracting group such as I, Br, Cl, F, --OSO.sub.2 R, --SOR, --OCOR, --OPO(OR).sub.2 and --OP(OR)R and R is optionally selected from (substituted) alkyl groups or (substituted) aryl groups.Various types of telechelic polymer, block copolymer, comb-like polymer and star-like polymer having controlled molecular weight and narrow molecular weight distribution can be produced efficiently from the heterocyclic monomer as the starting material.
摘要翻译：适用于杂环单体的阳离子开环聚合的多官能聚合引发剂，其具有至少一个与直链或环状有机基团中的碳 - 碳双键直接键合的碳原子，并且还具有至少两个含有上述基团的以下基团所述碳原子由通式-CH 2 X表示，其中X表示吸电子基团，例如I，Br，Cl，F，-OSO 2 R，-SOR，-OCOR，-OPO（OR）2和-OP（OR） R和R可以选自（取代的）烷基或（取代的）芳基。作为起始原料，可以从杂环单体有效地制备各种类型的遥爪聚合物，嵌段共聚物，梳状聚合物和具有受控分子量和窄分子量分布的星状聚合物。

6. 发明授权

US5449743A Method for ring opening polymerization using a hydrolase catalyst 失效
标题翻译：使用水解酶催化剂的开环聚合方法
公开(公告)号：US5449743A
公开(公告)日：1995-09-12
申请号：US184912
申请日：1994-01-24
申请人： Shiro Kobayashi , Hiroshi Uyama
发明人： Shiro Kobayashi , Hiroshi Uyama
IPC分类号： C08G69/16 , C08G63/08 , C08G63/78 , C08G63/82 , C08G64/20 , C08G69/20 , C08G85/00 , C12N9/20 , C12P7/62 , C12P13/02 , C08G63/123
CPC分类号： C08G63/08 , C08G63/823 , C12N9/20 , C12P7/62 , C12P7/625
摘要： In a method for ring opening polymerization in which the polymerization proceeds with the ring opening of a cyclic compound as a monomer, a hydrolase is used as a catalyst.
摘要翻译：在作为单体的环状化合物的开环进行聚合的开环聚合方法中，使用水解酶作为催化剂。

7. 发明授权

US08642694B2 Bio-based coating composition and its coated article 有权
标题翻译：生物基涂料组合物及其涂层制品
公开(公告)号：US08642694B2
公开(公告)日：2014-02-04
申请号：US12713569
申请日：2010-02-26
申请人： Koji Morita , Hirofumi Yamashita , Hitomi Ohara , Shiro Kobayashi , Masahiko Ishii
发明人： Koji Morita , Hirofumi Yamashita , Hitomi Ohara , Shiro Kobayashi , Masahiko Ishii
IPC分类号： C08L67/04 , C08G63/08 , C08G63/02 , C08G63/06
CPC分类号： C08L67/04 , C08F220/06 , C08F220/14 , C08F220/18 , C08F2220/1825 , C08F2220/281 , C08L33/066 , C08L33/068 , C08L2666/04 , C08L2666/02
摘要： There are provided: a bio-based coating composition which is a bio-based ingredient coating composition in consideration of environment and does not need any expensive ingredient and is also excellent in hydrolysis resistance; and an article coated with the coating composition. The bio-based coating composition is characterized by comprising the following film-forming ingredients: a lactic acid polymer (A) which contains a polyfunctional compound having a hydroxyl group and/or a carboxyl group in a functionality of not less than 3 and lactic acid as essential monomer ingredients and has a specific SP value; and a resin (B) which contains a hydroxyl group and/or a carboxyl group and has a specific SP value; wherein the difference (ΔSP) between the SP values of the lactic acid polymer (A) and the resin (B) is in the range of 0.2 to 4.0. The coated article is characterized by being obtained by being coated with the aforementioned coating composition.
摘要翻译：提供：生物基涂料组合物，考虑到环境是生物基成分涂料组合物，不需要任何昂贵的成分，并且耐水解性也优异; 和涂覆有涂料组合物的制品。生物基涂料组合物的特征在于包含以下成膜成分：含有官能度不低于3的具有羟基和/或羧基的多官能化合物的乳酸聚合物（A）和乳酸作为必需单体成分，具有特定的SP值; 和含有羟基和/或羧基并具有特定SP值的树脂（B）; 其中，乳酸聚合物（A）和树脂（B）的SP值之差（DeltaSP）在0.2〜4.0的范围内。涂层制品的特征在于通过涂覆上述涂料组合物获得。

8. 发明申请

US20090083687A1 PRINTED CIRCUIT BOARD DESIGN SUPPORT METHOD AND APPARATUS 有权
标题翻译：印刷电路板设计支持方法和设备
公开(公告)号：US20090083687A1
公开(公告)日：2009-03-26
申请号：US12238895
申请日：2008-09-26
申请人： Toshisato Sadamatsu , Shinichi Hama , Shiro Kobayashi
发明人： Toshisato Sadamatsu , Shinichi Hama , Shiro Kobayashi
IPC分类号： G06F17/50
CPC分类号： G06F17/5068
摘要： A method used for supporting designing of a printed circuit board including a plurality of conductive layers having conductive areas to which a constant potential is applied, includes specifying conductive areas having a predetermined wiring from the conductive areas for each of the plurality of conductive layers, extracting areas that overlap each other in a planar view from the specified conductive areas, specifying an interlayer connection member that electrically connects at least two of the plurality of conductive layers in the extracted area, and clearly specifying an area within a predetermined distance from a center of the specified interlayer connection member and in the extracted area.
摘要翻译：一种用于支持包括具有施加恒定电位的导电区域的多个导电层的印刷电路板的设计的方法包括从多个导电层中的每一个的导电区域指定具有预定布线的导电区域，提取指定从提取区域中电连接多个导电层中的至少两个的层间连接构件，并且明确地指定距离所述提取区域中的多个导电层的中心的预定距离内的区域指定的层间连接构件和提取区域。

9. 发明授权

US06841650B2 Crystallizable poly (2,5-di-substituted-1,4-phenylene oxide) and a method of preparing the same 有权
标题翻译：可结晶的聚（2,5-二取代-1,4-亚苯基氧化物）及其制备方法
公开(公告)号：US06841650B2
公开(公告)日：2005-01-11
申请号：US10157862
申请日：2002-05-31
申请人： Hideyuki Higashimura , Kiyoshi Fujisawa , Yoshihiko Moro-Oka , Shiro Kobayashi
发明人： Hideyuki Higashimura , Kiyoshi Fujisawa , Yoshihiko Moro-Oka , Shiro Kobayashi
IPC分类号： C08G65/44 , C08G59/50
CPC分类号： C08G65/44
摘要： There is disclosed a crystallizable poly(2,5-di-substituted-1,4-phenylene oxide), which exhibits an exothermic peak for crystallization of not less than 5 J/g at 150° C. or over when cooled after melting, and/or an endothermic peak, at the time of melting of crystals thereof, of not less than 5 J/g at 150° C. or over when re-heated after cooling of the melt, and which comprises a recurring unit of the following formula (I), and a method of preparing the same by polymerization of a 2,5-di-substituted-phenol of the following formula (II) by use of a copper complex catalyst made of a tridentate ligand of which nitrogen atoms coordinate to a copper atom in coexistence with oxygen: wherein R1's independently represent a hydrocarbon group or a substituted hydrocarbon group, and they may be the same or different. The crystallizable poly(2,5-di-substituted-1,4-phenylene oxide) is able to provide a melt molding which has a reduced degree of coloration and good heat resistance.
摘要翻译：公开了一种可结晶的聚（2,5-二取代-1,4-亚苯基氧化物），其在熔化后冷却时在150℃或更高温度下表现出不低于5J / g的结晶放热峰，和/或其结晶时的吸热峰在熔融物冷却后再加热时在150℃以上不低于5J / g，并且其包含以下的重复单元式（I）的方法和通过使用由氮原子配位的三齿配体构成的铜络合物催化剂聚合下述式（II）的2,5-二取代苯酚而制备的方法与氧共存的铜原子：其中R 1独立地表示烃基或取代的烃基，它们可以相同或不同。可结晶的聚（2,5-二取代-1,4-亚苯基氧化物）能够提供具有降低的着色程度和良好的耐热性的熔融模塑。

10. 发明授权

US06576800B2 Oxidation polymer of a substituted phenol 失效
标题翻译：取代苯酚的氧化聚合物
公开(公告)号：US06576800B2
公开(公告)日：2003-06-10
申请号：US09905978
申请日：2001-07-17
申请人： Hideyuki Higashimura , Shiro Kobayashi
发明人： Hideyuki Higashimura , Shiro Kobayashi
IPC分类号： C07C4100
CPC分类号： C08G65/44
摘要： An oxidation polymer of a substituted phenol, obtained by oxidative polymerization of at least one compound selected from the group consisting of a compound of formula (Ia) and a compound of formula (Ib), in which the oxidation polymer has a number-average polymerization degree of 3 or more: wherein R1 to R4 each represent a hydrogen atom and the like; provided that at least one of R1 to R4 represents a substituted or unsubstituted, saturated hydrocarbon group having 10 or more carbon atoms, and R1 and/or R4 represent a hydrogen atom; wherein R11 represents a substituted or unsubstituted, saturated hydrocarbon group having 15 or more carbon atoms, and R12 is the same as R11, or when R12 is different from R11, R12 represents a substituted or unsubstituted hydrocarbon group and the like.
摘要翻译：通过氧化聚合至少一种选自式（Ia）化合物和式（Ib）化合物的化合物的化合物获得的取代苯酚的氧化聚合物，其中氧化聚合物具有数均聚合 3以上：其中，R1〜R4各自表示氢原子等; 条件是R 1至R 4中的至少一个表示具有10个或更多个碳原子的取代或未取代的饱和烃基，R 1和/或R 4表示氢原子;其中R 11表示取代或未取代的饱和烃基，其具有15或更多的碳原子，R 12与R 11相同，或者当R 12与R 11不同时，R 12表示取代或未取代的烃基等。

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