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1. 发明授权

US4220563A Heat-curable and solvent-soluble ester group-containing polymer compositions and process for their preparation 失效
标题翻译：可热固化和溶剂可溶的含酯基聚合物组合物及其制备方法
公开(公告)号：US4220563A
公开(公告)日：1980-09-02
申请号：US847580
申请日：1977-11-01
申请人： Shigeyoshi Hara , Takeyoshi Yamada
发明人： Shigeyoshi Hara , Takeyoshi Yamada
IPC分类号： C08G73/16 , C08J11/18 , C08L67/00 , C09D5/25 , C08L67/02
CPC分类号： C08J11/18 , C08G73/16 , C08L67/00 , C08J2367/02 , Y02W30/706
摘要： A heat-curable and solvent-soluble ester group-containing polymer composition is prepared by the steps of:(1) either (i) reacting a highly polymerized linear aromatic polyester with a diaryl carbonate to depolymerize it to a solvent-soluble low-molecular-weight polyester (component A) containing terminal aryl carboxylate groups, or (ii) effecting the above depolymerization in the presence of a compound containing at least two specified functional groups thereby to form a modified solvent-soluble low-molecular-weight polyester (component A') containing terminal aryl carboxylate groups; and(2) either (i) mixing the resulting component A or A' with a monomeric or solvent-soluble polymeric, polyfunctional compound (component B) containing at least two hydroxyl and/or primary or secondary amino groups or (ii) partially reacting the resulting component A or A' with the component B. The composition has superior workability in molding and curing, and gives cured molded products of high utilitarian value. It is especially suitable for use in wire enamelling varnishes.
摘要翻译：通过以下步骤制备可热固化和溶剂可溶的含酯基聚合物组合物：（1）（i）使高度聚合的线性芳族聚酯与碳酸二芳基酯反应以将其解聚成溶剂可溶的低分子量含有末端芳基羧酸酯基的重量份聚酯（A成分），或者（ii）在含有至少两个特定官能团的化合物的存在下进行上述解聚，从而形成改性溶剂可溶性低分子量聚酯 A'），其包含末端芳基羧酸酯基团; （2）（i）将所得组分A或A'与含有至少两个羟基和/或伯或仲氨基的单体或溶剂可溶的聚合多官能化合物（组分B）混合，或（ii）部分反应所得到的组分A或A'与组分B组合。该组合物在成型和固化中具有优异的可加工性，并且具有高功利价值的固化模制产品。它特别适用于电线搪瓷清漆。

2. 发明授权

US5061521A Process for producing modified molded polymer articles 失效
标题翻译：改性聚合物制品的制造方法
公开(公告)号：US5061521A
公开(公告)日：1991-10-29
申请号：US451892
申请日：1989-12-18
申请人： Zen-ichiro Endo , Shigeyoshi Hara , Umewaka Nakatani
发明人： Zen-ichiro Endo , Shigeyoshi Hara , Umewaka Nakatani
IPC分类号： C08G61/08 , C08J7/12 , C08L65/00
CPC分类号： C08J7/126 , C08G61/08 , C08J7/12 , C08L65/00 , C08J2365/00
摘要： A method for improving the properties of a metathesis polymerized cycloolefin article by treating with molecular halogen in an organic solvent. Degree of treatment can be regulated according to the swelling power of the solvent for the polymer. Improved properties include improved flame retardance, oxidation resistance and surface properties.
摘要翻译：一种通过在有机溶剂中用分子卤素处理来改善易位聚合的环烯烃制品的性质的方法。可以根据溶剂对聚合物的溶胀力来调节处理程度。改进的性能包括改进的阻燃性，抗氧化性和表面性能。

3. 发明授权

US4902740A Polyamideimides containing 3,4'-diamino-diphenylether as diamine component, with plasticizer 失效
标题翻译：含有3,4'-二氨基 - 二苯基醚作为二胺组分的聚酰胺酰亚胺与增塑剂
公开(公告)号：US4902740A
公开(公告)日：1990-02-20
申请号：US268479
申请日：1988-11-08
申请人： Shigeyoshi Hara , Hiroo Inata , Shunichi Matsumura
发明人： Shigeyoshi Hara , Hiroo Inata , Shunichi Matsumura
IPC分类号： C08G73/10 , C08G73/14 , C08K5/41 , C08L79/08 , H05K1/03 , H05K3/38
CPC分类号： C08L79/08 , C08G73/105 , C08G73/1071 , C08G73/14 , C08K5/41 , H05K1/0346 , H05K3/386
摘要： A polyamideimide having an inherent viscosity of above 0.48 which comprises a unit of the following formula (II) ##STR1## and a unit of the following formula (IV) ##STR2## as main units forming the molecular chains of the polyamideimide, and an intimate mixture of the polyamideimide and a plasticizing material for the polyamideimide.
摘要翻译：具有特性粘度高于0.48的聚酰胺酰亚胺，其包含下式（II）的单元：（II）和下式（IV）的单元作为形成分子链的主要单元聚酰胺酰亚胺和聚酰胺酰亚胺与聚酰胺酰亚胺的增塑材料的紧密混合物。

4. 发明授权

US4069206A Novel aromatic imine polymers and process for the preparation thereof 失效
标题翻译：新型芳香族亚胺聚合物及其制备方法
公开(公告)号：US4069206A
公开(公告)日：1978-01-17
申请号：US550738
申请日：1975-02-18
申请人： Shigeyoshi Hara , Masao Senoo , Koh Mori , Yutaka Taketani
发明人： Shigeyoshi Hara , Masao Senoo , Koh Mori , Yutaka Taketani
IPC分类号： C08G73/00 , C08G65/00 , C08G65/40 , C08G69/00 , C08G73/02 , C08G75/23
CPC分类号： C08G69/00 , C08G73/02 , C08G73/024 , C08G73/0253 , C08G73/028
摘要： Novel aromatic imine polymers containing as at least a part of its entire recurring units an aromatic imino group ##STR1## wherein .phi. is an aromatic ring group having a valence of at least two and has at least one electron-attracting group with respect to the group ##STR2## and R.sub.1 is a hydrogen atom or a non-aromatic hydrocarbon residue having a valence of at least 1. These polymers find a wide variety of applications by utilizing their thermal stability and various other desirable properties such as reducibility or photosensitivity. The polymers are prepared by reacting specific aromatic dihalogen compound with specific difunctional amino-containing compounds in an inert organic solvent in the presence of an acid acceptor. Copolymers can be obtained by carrying out the reaction using specific difunctional comonomers.
摘要翻译：含有至少一部分其全部重复单元的芳族亚胺聚合物是芳香族亚氨基，其中phi是具有至少两个化合价的芳环基团，并且相对于该基团具有至少一个吸电子基团 R1是氢原子或至少为1价的非芳族烃残基。这些聚合物通过利用它们的热稳定性和各种其它所需的性质如还原性或光敏性，可以找到各种应用。通过在酸性受体的存在下，在惰性有机溶剂中使特定芳族二卤化物与特定的双官能含氨基化合物反应来制备聚合物。可以通过使用特定的双官能共聚单体进行反应来获得共聚物。

5. 发明授权

US5045362A Process for producing modified molded polymer article 失效
标题翻译：改性聚合物制品的制造方法
公开(公告)号：US5045362A
公开(公告)日：1991-09-03
申请号：US451703
申请日：1989-12-18
申请人： Shigeyoshi Hara , Umewaka Nakatani
发明人： Shigeyoshi Hara , Umewaka Nakatani
IPC分类号： C08G61/08 , C08J7/12 , C08L65/00
CPC分类号： C08J7/126 , C08G61/08 , C08J7/12 , C08L65/00 , C08J2365/00
摘要： A metathesis polymerized cycloolefin article may be improved by treating with halogen halide in an organic solvent. Degree of treatment can be regulated according to the swelling power of the solvent for the polymer. Improved properties include improved flame retardance, oxidation resistance and surface properties.
摘要翻译：复分解聚合的环烯烃制品可以通过用卤代卤化物在有机溶剂中处理来改进。可以根据溶剂对聚合物的溶胀力来调节处理程度。改进的性能包括改进的阻燃性，抗氧化性和表面性能。

6. 发明授权

US5019620A Elastic crosslinked metathesis polymer composition 失效
标题翻译：弹性交联复分解聚合物组成
公开(公告)号：US5019620A
公开(公告)日：1991-05-28
申请号：US589292
申请日：1990-09-27
申请人： Zenichiro Endo , Shigeyoshi Hara
发明人： Zenichiro Endo , Shigeyoshi Hara
IPC分类号： C08G61/06 , C08G61/08
CPC分类号： C08G61/08
摘要： An elastic crosslinked metathesis polymer composition is disclosed comprised of a copolymer of a norbornene-type compound which metathesis polymerizes to a linear polymer and a norbornene-type compound having a second double bond of similar reactivity which forms a crosslinked polymer, and a hydrocarbon-based extending oil. Norbornene and dicyclopentadiene are typical comonomers. Polymerization is carried out by a RIM or resin injection molding process.

7. 发明授权

US4353802A Semipermeable composite membrane 失效
标题翻译：半透膜复合膜
公开(公告)号：US4353802A
公开(公告)日：1982-10-12
申请号：US86192
申请日：1979-10-18
申请人： Shigeyoshi Hara , Yuzuru Hayashi , Takeyuki Kawaguchi , Noriaki Sasaki , Yutaka Taketani , Hiroyoshi Minematsu
发明人： Shigeyoshi Hara , Yuzuru Hayashi , Takeyuki Kawaguchi , Noriaki Sasaki , Yutaka Taketani , Hiroyoshi Minematsu
IPC分类号： B01D61/08 , B01D69/12 , B01D71/40 , B01D71/44 , B01D71/48 , B01D71/52 , B01D71/60 , B01D71/66 , B01D71/82 , B01D13/00
CPC分类号： B01D71/60 , B01D69/125 , B01D71/44
摘要： A semipermeable composite membrane comprising a thin semipermeable film of a polymeric material deposited on one side of a microporous substrate, the polymeric material being prepared by crosslinking a soluble polymer containing at least 30 mole % of a recurring unit of the formula ##STR1## wherein all symbols are as defined herein, and having at least 0.5 milliequivalent, per gram of said polymer, of an amino group containing 1 or 2 active hydrogen atoms, with a polyfunctional compound containing at least two functional groups capable of reacting with the amino group having 1 or 2 active hydrogen atoms; and a process for preparing the same. The semipermeable composite membrane of this invention is especially useful for desalination of saline or brackish water by reverse osmosis.
摘要翻译：一种半透性复合膜，其包含沉积在微孔基材的一侧上的聚合材料的薄的半透膜，所述聚合物材料通过交联含有至少30摩尔％的式（IMAGE）的重复单元的可溶性聚合物制备，其中所有符号如本文所定义，并且每克所述聚合物具有至少0.5毫当量的含有1或2个活性氢原子的氨基，和具有至少两个能够与具有1个氨基的氨基反应的官能团的多官能化合物或2个活性氢原子; 及其制备方法。本发明的半透膜复合膜特别适用于通过反渗透脱盐盐水或微咸水。

8. 发明授权

US3951920A Permselective polymeric membrane prepared from polybenzimidazoles 失效
标题翻译：由聚苯并咪唑制备的选择性聚合物膜
公开(公告)号：US3951920A
公开(公告)日：1976-04-20
申请号：US288389
申请日：1972-09-12
申请人： Masao Senoo , Shigeyoshi Hara , Shuji Ozawa
发明人： Masao Senoo , Shigeyoshi Hara , Shuji Ozawa
IPC分类号： B01D71/62 , C08G73/18 , C08G33/02 , C08G33/04
CPC分类号： C08G73/18 , B01D71/62 , Y10S524/909
摘要： This invention provides a novel permselective polymeric membrane excellent in permselectivity which allows permeation of water in an aqueous solution at a high rate but is highly preventive of permeation of solutes, and a process for the preparation of such permselective membrane, said polymeric membrane consisting essentially of a linear polymer containing N-aryl-substituted-benzimidazole units as the main-chain-constituting units.
摘要翻译：本发明提供了一种选择性优异的新型选择性选择性聚合物膜，其允许水以高速率渗透水溶液，但是高度防止溶质渗透，以及制备这种选择性渗透膜的方法，所述聚合物膜基本上由含有N-芳基取代的苯并咪唑单元作为主链构成单元的线性聚合物。

9. 发明授权

US5096644A Process for making a filled metathesis polymer article 失效
标题翻译：制备填充复分解聚合物制品的方法
公开(公告)号：US5096644A
公开(公告)日：1992-03-17
申请号：US370532
申请日：1989-06-23
申请人： Zenichiro Endo , Shigeyoshi Hara , Paul A. Silver , Hikoichiro Yamada
发明人： Zenichiro Endo , Shigeyoshi Hara , Paul A. Silver , Hikoichiro Yamada
IPC分类号： C08G61/08 , C08K9/06 , B29C45/14 , B29C45/16 , B32B31/00
CPC分类号： C08G61/08 , C08K9/06
摘要： A molded article is produced by metathesis polymerization of a mixture containing at least one metathesis polymerizable monomer, a metathesis polymerization catalyst and an organic or inorganic filler material which has been treated with a vinyl-substituted silane coupler having at least one hydrolyzable group in addition to the vinyl group.
摘要翻译：通过使含有至少一种易位可聚合单体，易位聚合催化剂和有机或无机填充材料的混合物的复分解聚合制备模制品，所述填充材料除了具有至少一个可水解基团的乙烯基取代的硅烷偶联剂乙烯基。

10. 发明授权

US5055499A Molded polymer article filled with inorganic material and production of said article 失效
标题翻译：填充无机材料的成型聚合物制品和所述制品的生产
公开(公告)号：US5055499A
公开(公告)日：1991-10-08
申请号：US461559
申请日：1990-01-05
申请人： Zenichiro Endo , Shigeyoshi Hara , Paul A. Silver , Hikoichiro Yamada
发明人： Zenichiro Endo , Shigeyoshi Hara , Paul A. Silver , Hikoichiro Yamada
IPC分类号： C08L65/00 , C08G61/08 , C08K9/06
CPC分类号： C08G61/08 , C08K9/06
摘要： A method is disclosed for preparing filled shaped articles of metathesis polymerized poly(cycloolefins) wherein an inorganic filler material is treated with a norbornene-substituted silane coupling agent. The norbornene moiety copolymerizes with the metathesis polymerizable monomer and the silane moiety creates a bond with the filler. Products are characterized by improved physical properties.
摘要翻译：公开了一种用于制备复分解聚合的聚（环烯烃）的填充成型制品的方法，其中用降冰片烯取代的硅烷偶联剂处理无机填料。降冰片烯部分与易位可聚合单体共聚，硅烷部分与填料形成结合。产品的特征在于物理性能的改善。

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