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1. 发明申请

US20110227239A1 METHOD OF MOLDING 有权
标题翻译：成型方法
公开(公告)号：US20110227239A1
公开(公告)日：2011-09-22
申请号：US13131961
申请日：2009-11-19
申请人： Shigeru Yamaki , Hideo Miyata , Nobuyuki Mitarai , Nobuaki Ishii , Katsumi Murofushi , Kunio Yoshida
发明人： Shigeru Yamaki , Hideo Miyata , Nobuyuki Mitarai , Nobuaki Ishii , Katsumi Murofushi , Kunio Yoshida
IPC分类号： B29D11/00
CPC分类号： B29C43/021 , B29C2035/0822 , B29C2035/0827 , B29C2035/0838 , B29C2043/025 , B29C2043/046 , B29C2043/3634 , B29C2043/525 , B29C2059/023 , B29D11/00365 , B29K2105/0002 , B29L2011/0016 , C08F230/08 , C08G77/20 , C08F2230/085 , C08F2222/1026
摘要： There is provided a method of molding which is capable of more highly precisely molding a molded article to be molded such as a lens than conventional technologies.A molded article such as a lens array and a mold for nanoimprinting is molded by repeating multiple times a transfer step including: a transformation step of bringing a light curable composition containing a compound having a polymerizable functional group and a polymerization initiator into contact with a transfer member 62 on which a transfer shape portion shaped equally to or reversely to an aspherical lens portion 312 is formed to transform the light curable composition to the transfer shape of the transfer member 62; a curing step of irradiating at least a transformed portion of the transformed light curable composition with light by a light irradiation unit 60 to cure the light curable composition; and a separation step of separating the cured light curable composition and the transfer member.
摘要翻译：提供了一种成型方法，其能够比传统技术更高精度地模制诸如透镜的模制品的模制品。通过重复多次转印步骤来模制诸如透镜阵列和纳米压印模具的模制品，其包括：将含有具有聚合性官能团的化合物和聚合引发剂的光固化性组合物与转印剂接触的转化步骤形成与非球面透镜部分312相等或相反形状的转印形状部分的构件62将光固化组合物转变成转印部件62的转印形状; 固化步骤，通过光照射单元60用光照射至少所述转化的可光固化组合物的转化部分以固化所述光固化组合物; 以及分离固化的光固化性组合物和转印体的分离工序。

2. 发明授权

US08840830B2 Method of molding 有权
标题翻译：成型方法
公开(公告)号：US08840830B2
公开(公告)日：2014-09-23
申请号：US13131961
申请日：2009-11-13
申请人： Shigeru Yamaki , Hideo Miyata , Nobuyuki Mitarai , Nobuaki Ishii , Katsumi Murofushi , Kunio Yoshida
发明人： Shigeru Yamaki , Hideo Miyata , Nobuyuki Mitarai , Nobuaki Ishii , Katsumi Murofushi , Kunio Yoshida
IPC分类号： B29C35/08 , B29D11/00
CPC分类号： B29C43/021 , B29C2035/0822 , B29C2035/0827 , B29C2035/0838 , B29C2043/025 , B29C2043/046 , B29C2043/3634 , B29C2043/525 , B29C2059/023 , B29D11/00365 , B29K2105/0002 , B29L2011/0016 , C08F230/08 , C08G77/20 , C08F2230/085 , C08F2222/1026
摘要： There is provided a method of molding which is capable of more highly precisely molding a molded article to be molded such as a lens than conventional technologies.A molded article such as a lens array and a mold for nanoimprinting is molded by repeating multiple times a transfer step including: a transformation step of bringing a light curable composition containing a compound having a polymerizable functional group and a polymerization initiator into contact with a transfer member 62 on which a transfer shape portion shaped equally to or reversely to an aspherical lens portion 312 is formed to transform the light curable composition to the transfer shape of the transfer member 62; a curing step of irradiating at least a transformed portion of the transformed light curable composition with light by a light irradiation unit 60 to cure the light curable composition; and a separation step of separating the cured light curable composition and the transfer member.
摘要翻译：提供了一种成型方法，其能够比传统技术更高精度地模制诸如透镜的模制品的模制品。通过重复多次转印步骤来模制诸如透镜阵列和纳米压印模具的模制品，其包括：将含有具有聚合性官能团的化合物和聚合引发剂的光固化性组合物与转印剂接触的转化步骤形成与非球面透镜部分312相等或相反形状的转印形状部分的构件62将光固化组合物转变成转印部件62的转印形状; 固化步骤，通过光照射单元60用光照射至少所述转化的可光固化组合物的转化部分以固化所述光固化组合物; 以及分离固化的光固化性组合物和转印体的分离工序。

3. 发明申请

US20110263779A1 HARDENING COMPOSITION AND HARDENED PRODUCT THEREOF 失效
标题翻译：硬化组合物及其硬化产品
公开(公告)号：US20110263779A1
公开(公告)日：2011-10-27
申请号：US13139847
申请日：2009-12-10
申请人： Katsumi Murofushi , Nobuaki Ishii , Shigeru Yamaki , Hideo Miyata , Yotaro Hattori
发明人： Katsumi Murofushi , Nobuaki Ishii , Shigeru Yamaki , Hideo Miyata , Yotaro Hattori
IPC分类号： C08L35/02 , C08L43/04 , C08K3/04 , C08L83/04 , B82Y30/00
CPC分类号： C08F2/44 , C08F220/08 , C08F222/1006 , C08F292/00 , C08L33/06 , Y10T428/2991 , Y10T428/2995 , C08L2666/04 , C08F220/18
摘要： The present invention is directed to a hardening composition comprising silica fine particles (a), a (meth)acrylate (b) having two or more ethylenically unsaturated groups and being free from cyclic structure, a (meth)acrylate (c) having an ethylenically unsaturated group and having an alicyclic structure, a polymerization initiator (d) and black inorganic fine particles (e), wherein the silica fine particles (a) are surface-treated with a silane compound (f) represented by the following general formula (1) and a silane compound (g) represented by the following general formula (2): (in the formula (1), R1 represents a hydrogen atom or a methyl group, R2 represents an alkyl group having 1 to 3 carbon atoms or a phenyl group, R3 represents a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms; q represents an integer of 1 to 6; and r represents an integer of 0 to 2, (in the formula (2), R4 is an alkyl group having 1 to 3 carbon atoms or a phenyl group which may have a substituent; R5 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms; s is an integer of 0 to 6; and t is an integer of 0 to 2.
摘要翻译：本发明涉及一种包含二氧化硅细颗粒（a），具有两个或更多个烯属不饱和基团并且不含环状结构的（甲基）丙烯酸酯（b））的硬化组合物，具有烯键式不饱和基团和具有脂环结构的聚合引发剂（d）和黑色无机细颗粒（e），其中二氧化硅微粒（a）用下述通式（1）表示的硅烷化合物（f）进行表面处理）和由以下通式（2）表示的硅烷化合物（g）：（式（1）中，R 1表示氢原子或甲基，R 2表示碳原子数1〜3的烷基或苯基基团，R 3表示氢原子或碳原子数1〜10的烃基; q表示1〜6的整数，r表示0〜2的整数，（式（2）中，R 4表示烷基具有1至3个碳原子的苯基或可具有取代基的苯基 ent R5是氢原子或碳原子数1〜10的烃基; s为0〜6的整数; t为0〜2的整数。

4. 发明申请

US20110098411A1 CURABLE COMPOSITION AND CURED PRODUCT THEREOF 审中-公开
标题翻译：可固化组合物和固化产品
公开(公告)号：US20110098411A1
公开(公告)日：2011-04-28
申请号：US13002245
申请日：2009-06-30
申请人： Shigeru Yamaki , Hideo Miyata , Nobuyuki Mitarai , Nobuaki Ishii , katsumi Kurofushi
发明人： Shigeru Yamaki , Hideo Miyata , Nobuyuki Mitarai , Nobuaki Ishii , katsumi Kurofushi
IPC分类号： C08L83/07
CPC分类号： C09C1/309 , B82Y30/00 , C01P2004/64 , C01P2006/22 , C08F2/44 , C08F220/18 , C08F222/1006 , C08F292/00 , C09C1/3081 , C08F220/10
摘要： An object of the present invention is to provide a curable composition which has excellent handling properties and which is able to form a cured product excellent in transparency, heat resistance, environment resistance and molding processability. The curable composition of the present invention comprises (a) silica fine particles, (b) a (meth)acrylate having at least two ethylenic unsaturated groups and no ring structure, (c) a (meth)acrylate having an ethylenic unsaturated group and an alicyclic structure, and (d) a polymerization initiator, said silica fine particles (a) are surface-treated with a silane compound (e) represented by the following general formula (1) and a silane compound (f) represented by the following general formula (2).
摘要翻译：本发明的目的是提供一种处理性能优异且能够形成透明性，耐热性，耐环境性和成型加工性优异的固化物的固化性组合物。本发明的固化性组合物包含（a）二氧化硅微粒，（b）具有至少两个烯键式不饱和基团且不具有环结构的（甲基）丙烯酸酯，（c）具有烯属不饱和基团的（甲基）丙烯酸酯，脂肪族结构和（d）聚合引发剂，用下述通式（1）表示的硅烷化合物（e）和下述通式（1）表示的硅烷化合物（f）对所述二氧化硅微粒（a）进行表面处理公式（2）。

5. 发明授权

US08349934B2 Hardening composition and hardened product thereof 失效
标题翻译：硬化组合物及硬化物
公开(公告)号：US08349934B2
公开(公告)日：2013-01-08
申请号：US13139847
申请日：2009-12-10
申请人： Katsumi Murofushi , Nobuaki Ishii , Shigeru Yamaki , Hideo Miyata , Yotaro Hattori
发明人： Katsumi Murofushi , Nobuaki Ishii , Shigeru Yamaki , Hideo Miyata , Yotaro Hattori
IPC分类号： C08K3/04 , C08F236/00
CPC分类号： C08F2/44 , C08F220/08 , C08F222/1006 , C08F292/00 , C08L33/06 , Y10T428/2991 , Y10T428/2995 , C08L2666/04 , C08F220/18
摘要： The present invention is directed to a hardening composition comprising silica fine particles (a), a (meth)acrylate (b) having two or more ethylenically unsaturated groups and being free from cyclic structure, a (meth)acrylate (c) having an ethylenically unsaturated group and having an alicyclic structure, a polymerization initiator (d) and black inorganic fine particles (e), wherein the silica fine particles (a) are surface-treated with a silane compound (f) represented by the following general formula (1) and a silane compound (g) represented by the following general formula (2): (in the formula (1), R1 represents a hydrogen atom or a methyl group, R2 represents an alkyl group having 1 to 3 carbon atoms or a phenyl group, R3 represents a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms; q represents an integer of 1 to 6; and r represents an integer of 0 to 2, (in the formula (2), R4 is an alkyl group having 1 to 3 carbon atoms or a phenyl group which may have a substituent; R5 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms; s is an integer of 0 to 6; and t is an integer of 0 to 2.
摘要翻译：本发明涉及一种包含二氧化硅细颗粒（a），具有两个或更多个烯属不饱和基团并且不含环状结构的（甲基）丙烯酸酯（b））的硬化组合物，具有烯键式不饱和基团和具有脂环结构的聚合引发剂（d）和黑色无机细颗粒（e），其中二氧化硅微粒（a）用下述通式（1）表示的硅烷化合物（f）进行表面处理）和由以下通式（2）表示的硅烷化合物（g）：（式（1）中，R 1表示氢原子或甲基，R 2表示碳原子数1〜3的烷基或苯基基团，R 3表示氢原子或碳原子数1〜10的烃基; q表示1〜6的整数，r表示0〜2的整数，（式（2）中，R 4表示烷基具有1至3个碳原子的苯基或可具有取代基的苯基 ent R5是氢原子或碳原子数1〜10的烃基; s为0〜6的整数; t为0〜2的整数。

6. 发明申请

US20120010361A1 CURABLE COMPOSITION AND CURED PRODUCT THEREOF 审中-公开
标题翻译：可固化组合物和固化产品
公开(公告)号：US20120010361A1
公开(公告)日：2012-01-12
申请号：US13260283
申请日：2010-03-10
申请人： Yoshifumi Urakawa , Shigeru Yamaki , Hideo Miyata , Nobuyuki Mitarai , Saori Yamaki , Nobuaki Ishii
发明人： Yoshifumi Urakawa , Shigeru Yamaki , Hideo Miyata , Nobuyuki Mitarai , Saori Yamaki , Nobuaki Ishii
IPC分类号： C08K5/5419 , C08L33/14 , C08L35/02
CPC分类号： C08F2/44 , C08F292/00 , C08K9/06 , G02B1/041 , C08L33/08 , C08L33/10 , C08F222/10 , C08L33/06
摘要： The present invention provides a curable composition having a proper viscosity and excellent handling properties, and a cured product that is obtainable by curing the curable composition and has excellent transparency, heat resistance and resistance to environment and a low Abbe's number, and further can effectively decrease chromatic aberration by the combined use with a material having a high Abbe's number.The curable composition is characterized by comprising (a) silica fine particles, (b) a (meth)acrylate compound having at least two ethylenic unsaturated groups and having no ring structure, (c) a (meth)acrylate compound having at least two ethylenic unsaturated groups and having an aromatic ring structure and (d) a polymerization initiator, wherein the silica particles (a) are surface treated by a specific silane compound (e) and a specific silane compound (f).
摘要翻译：本发明提供具有适度的粘度和优异的处理性能的固化性组合物，以及通过固化该固化性组合物而得到的固化物，具有优异的透明性，耐热性，耐环境性和低的阿贝数，进一步可以有效降低通过与具有高阿贝数的材料组合使用的色差。固化性组合物的特征在于，包含（a）二氧化硅微粒，（b）具有至少两个烯键式不饱和基团且不具有环结构的（甲基）丙烯酸酯化合物，（c）具有至少两个烯属不饱和基团并具有芳环结构，（d）聚合引发剂，其中二氧化硅颗粒（a）由特定的硅烷化合物（e）和特定的硅烷化合物（f）进行表面处理。

7. 发明申请

US20110112243A1 PAINT COMPOSITION AND PROCESS OF FORMING PAINT FILMS USING THE SAME 审中-公开
标题翻译：涂料组合物和使用其形成胶片的方法
公开(公告)号：US20110112243A1
公开(公告)日：2011-05-12
申请号：US13002251
申请日：2009-06-24
申请人： Nobuaki Ishii , Katsuro Urakawa , Nobuyuki Mitarai , Katsumi Murofushi
发明人： Nobuaki Ishii , Katsuro Urakawa , Nobuyuki Mitarai , Katsumi Murofushi
IPC分类号： C09D175/04
CPC分类号： C09D175/06 , B05D7/53 , C08F220/18 , C08F220/36 , C08G18/4277 , C08G18/44 , C08G18/664 , C08G18/771 , C08G18/8116 , C08G18/8125 , C09D133/14 , C09D175/04
摘要： The invention has an object of providing paint compositions showing excellent performances in both scratch resistance and impact resistance, and processes for forming multilayer paint films using the paint composition. The invention has another object of providing paint compositions suitably used as clear paints for finish painting automobiles and the like, and highly solidifiable paint compositions. A paint composition according to the invention includes a polyisocyanate prepolymer (A) including a monomer unit of Formula (1) below and a polyol (B), and has an average functional group equivalent weight of 160 to 400 g/eq. A process for forming multilayer paint films involves the paint composition. wherein R1 is a hydrogen atom or a methyl group; n is an integer of 0 or 1; when n=0, l=0, p=1 and m is an integer of 1 to 8; and when n=1, m=2, l=2 and p is an integer of 1 to 4.
摘要翻译：本发明的目的是提供在耐划伤性和耐冲击性方面表现出优异性能的涂料组合物，以及使用该涂料组合物形成多层涂膜的方法。本发明的另一个目的是提供适合用作涂漆汽车等的清漆的油漆组合物和高度可固化的油漆组合物。根据本发明的涂料组合物包括包含下述式（1）的单体单元和多元醇（B）的多异氰酸酯预聚物（A），其平均官能团当量为160-400g / eq。形成多层涂膜的方法涉及涂料组合物。其中R1是氢原子或甲基; n为0或1的整数; 当n = 0时，l = 0，p = 1，m为1〜8的整数。当n = 1时，m = 2，l = 2，p为1〜4的整数。

8. 发明申请

US20100087611A1 URETHANE COMPOUND, CURABLE COMPOSITION CONTAINING THE SAME, AND CURED PRODUCT THEREOF 审中-公开
标题翻译： URETHANE化合物，含有其的可固化组合物及其固化产物
公开(公告)号：US20100087611A1
公开(公告)日：2010-04-08
申请号：US12597101
申请日：2008-04-24
申请人： Yoshifumi Urakawa , Nobuaki Ishii , Nobuyuki Mitarai , Yotaro Hattori , Hiroko Oi , Katsumi Murofushi
发明人： Yoshifumi Urakawa , Nobuaki Ishii , Nobuyuki Mitarai , Yotaro Hattori , Hiroko Oi , Katsumi Murofushi
IPC分类号： C08F126/06 , C07D251/30
CPC分类号： C09D175/16 , C08G18/3853 , C08G18/8016 , C08G18/8116
摘要： It is an object of the present invention to provide a urethane compound capable of providing a cured product which is excellent in surface hardness, scratch resistance, flexibility and bending property, has reduced curling property and also has good transparency, a curable composition containing the same and a cured product thereof. The curable composition of the present invention is characterized by containing a specific urethane compound having an isocyanurate ring skeleton and a polymerization initiator.
摘要翻译：本发明的目的是提供能够提供表面硬度，耐擦伤性，柔软性和弯曲性优异的固化物的聚氨酯化合物，具有降低的卷曲性，并且还具有良好的透明性，含有该固化物的固化性组合物及其固化物。本发明的固化性组合物的特征在于含有具有异氰脲酸酯环骨架的特定的氨基甲酸酯化合物和聚合引发剂。

9. 发明申请

US20110077334A1 CURABLE COMPOSITION CONTAINING REACTIVE (METH) ACRYLATE POLYMER AND CURED PRODUCTS THEREOF 审中-公开
标题翻译：含有反应性（甲基）丙烯酸酯聚合物的固化性组合物及其固化产物
公开(公告)号：US20110077334A1
公开(公告)日：2011-03-31
申请号：US12993745
申请日：2009-05-20
申请人： Hiroko OI , Yotaro Hattori , Nobuaki Ishii , Katsumi Murofushi
发明人： Hiroko OI , Yotaro Hattori , Nobuaki Ishii , Katsumi Murofushi
IPC分类号： C09D133/12 , C08F120/10 , C08K3/34 , C08K7/18 , C09D1/00 , C09J133/12
CPC分类号： C08F220/36 , C08F2220/343 , C08G18/6229 , C08G18/6254 , C08G18/672 , C08G18/8116 , C08L75/04 , C08L2666/20 , C09D133/14 , C09J4/06 , C09J133/14 , C09J175/14 , C08F2220/346
摘要： It is an object of the present invention to provide a curable composition capable of forming a heat-resistant cured film which is excellent in surface hardness, is good in flexibility and bending properties, and has strength and flexibility that are compatible with each other, and a cured product (film) of the composition. The curable composition includes a reactive (meth)acrylate polymer (A) having a monomer unit represented by the following formula (1), a polymerization initiator (B) and a reactive monomer(C): wherein R1 is a hydrogen atom, a methyl group or an ethyl group, R2 is a hydrogen atom or a methyl group, X1 is a straight-chain or branched hydrocarbon group of 2 to 6 carbon atoms or an alcohol residue of polyethylene glycol, polypropylene glycol or caprolactone-modified both-terminal diol, n is an integer of 2 to 4, and m is an integer of 1 to 5.
摘要翻译：本发明的目的是提供一种能够形成表面硬度优异，柔软性和弯曲性好的耐热性固化膜的固化性组合物，具有彼此相容的强度和柔软性，该组合物的固化产物（膜）。可固化组合物包括具有由下式（1）表示的单体单元，聚合引发剂（B）和反应性单体（C）的反应性（甲基）丙烯酸酯聚合物（A）：其中R1是氢原子，甲基基或乙基，R 2为氢原子或甲基，X 1为2〜6个碳原子的直链或支链烃基或聚乙二醇，聚丙二醇或己内酯改性的双末端二醇的醇残基 n为2〜4的整数，m为1〜5的整数。

10. 发明申请

US20100210812A1 CURABLE COMPOSITION AND CURED PRODUCT THEREOF 审中-公开
标题翻译：可固化组合物和固化产品
公开(公告)号：US20100210812A1
公开(公告)日：2010-08-19
申请号：US12668552
申请日：2008-06-26
申请人： Yoshifumi Urakawa , Nobuaki Ishii , Miyuki Tomita , Yotaro Hattori , Haruhiko Ikeda , Katsumi Murofushi
发明人： Yoshifumi Urakawa , Nobuaki Ishii , Miyuki Tomita , Yotaro Hattori , Haruhiko Ikeda , Katsumi Murofushi
IPC分类号： C08G75/00
CPC分类号： C09D175/16 , C08F283/006 , C08G18/672 , C08G18/8116
摘要： It is an object of the present invention to provide a curable composition having excellent curability and capable of forming a cured film which is excellent in surface hardness, scratch resistance, flexibility, bending property, transparency and curling property, and a cured product thereof. The curable composition of the present invention is characterized by comprising (A) a urethane compound represented by the following general formula (1), (B) a thiol compound and (C) a polymerization initiator. wherein R1 is a straight-chain or branched divalent aliphatic group, a divalent organic group having an alicyclic group, a divalent organic group having an aromatic ring or [—(CH2)a—O—(CH2)b—]c (a and b are each independently an integer of 1 to 10, and c is an integer of 1 to 5), R2 is a straight-chain or branched divalent aliphatic group, a divalent organic group having an alicyclic group, a divalent organic group having an aromatic ring or [—(CH2)d—O—(CH2)e—]f (d and e are each independently an integer of 1 to 10, and f is an integer of 1 to 5), and R3 and R4 are each independently a hydrogen atom or a methyl group.
摘要翻译：本发明的目的是提供一种固化性优异且能够形成表面硬度，耐擦伤性，柔软性，弯曲性，透明性和卷曲性优异的固化膜的固化性组合物及其固化物。本发明的固化性组合物的特征在于，包含（A）由以下通式（1）表示的氨基甲酸酯化合物，（B）硫醇化合物和（C）聚合引发剂。其中R1是直链或支链二价脂族基团，具有脂环族基团的二价有机基团，具有芳环的二价有机基团或[ - （CH 2）a -O-（CH 2）b - ] c（a和 b各自独立地为1〜10的整数，c为1〜5的整数），R2为直链或支链的二价脂族基团，具有脂环基的二价有机基团，具有芳香族的二价有机基团环或[ - （CH 2）d -O-（CH 2）e - ] f（d和e各自独立地为1〜10的整数，f为1〜5的整数），R 3和R 4各自独立地氢原子或甲基。

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