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1. 发明申请

US20120010361A1 CURABLE COMPOSITION AND CURED PRODUCT THEREOF 审中-公开
标题翻译：可固化组合物和固化产品
公开(公告)号：US20120010361A1
公开(公告)日：2012-01-12
申请号：US13260283
申请日：2010-03-10
申请人： Yoshifumi Urakawa , Shigeru Yamaki , Hideo Miyata , Nobuyuki Mitarai , Saori Yamaki , Nobuaki Ishii
发明人： Yoshifumi Urakawa , Shigeru Yamaki , Hideo Miyata , Nobuyuki Mitarai , Saori Yamaki , Nobuaki Ishii
IPC分类号： C08K5/5419 , C08L33/14 , C08L35/02
CPC分类号： C08F2/44 , C08F292/00 , C08K9/06 , G02B1/041 , C08L33/08 , C08L33/10 , C08F222/10 , C08L33/06
摘要： The present invention provides a curable composition having a proper viscosity and excellent handling properties, and a cured product that is obtainable by curing the curable composition and has excellent transparency, heat resistance and resistance to environment and a low Abbe's number, and further can effectively decrease chromatic aberration by the combined use with a material having a high Abbe's number.The curable composition is characterized by comprising (a) silica fine particles, (b) a (meth)acrylate compound having at least two ethylenic unsaturated groups and having no ring structure, (c) a (meth)acrylate compound having at least two ethylenic unsaturated groups and having an aromatic ring structure and (d) a polymerization initiator, wherein the silica particles (a) are surface treated by a specific silane compound (e) and a specific silane compound (f).
摘要翻译：本发明提供具有适度的粘度和优异的处理性能的固化性组合物，以及通过固化该固化性组合物而得到的固化物，具有优异的透明性，耐热性，耐环境性和低的阿贝数，进一步可以有效降低通过与具有高阿贝数的材料组合使用的色差。固化性组合物的特征在于，包含（a）二氧化硅微粒，（b）具有至少两个烯键式不饱和基团且不具有环结构的（甲基）丙烯酸酯化合物，（c）具有至少两个烯属不饱和基团并具有芳环结构，（d）聚合引发剂，其中二氧化硅颗粒（a）由特定的硅烷化合物（e）和特定的硅烷化合物（f）进行表面处理。

2. 发明申请

US20110227239A1 METHOD OF MOLDING 有权
标题翻译：成型方法
公开(公告)号：US20110227239A1
公开(公告)日：2011-09-22
申请号：US13131961
申请日：2009-11-19
申请人： Shigeru Yamaki , Hideo Miyata , Nobuyuki Mitarai , Nobuaki Ishii , Katsumi Murofushi , Kunio Yoshida
发明人： Shigeru Yamaki , Hideo Miyata , Nobuyuki Mitarai , Nobuaki Ishii , Katsumi Murofushi , Kunio Yoshida
IPC分类号： B29D11/00
CPC分类号： B29C43/021 , B29C2035/0822 , B29C2035/0827 , B29C2035/0838 , B29C2043/025 , B29C2043/046 , B29C2043/3634 , B29C2043/525 , B29C2059/023 , B29D11/00365 , B29K2105/0002 , B29L2011/0016 , C08F230/08 , C08G77/20 , C08F2230/085 , C08F2222/1026
摘要： There is provided a method of molding which is capable of more highly precisely molding a molded article to be molded such as a lens than conventional technologies.A molded article such as a lens array and a mold for nanoimprinting is molded by repeating multiple times a transfer step including: a transformation step of bringing a light curable composition containing a compound having a polymerizable functional group and a polymerization initiator into contact with a transfer member 62 on which a transfer shape portion shaped equally to or reversely to an aspherical lens portion 312 is formed to transform the light curable composition to the transfer shape of the transfer member 62; a curing step of irradiating at least a transformed portion of the transformed light curable composition with light by a light irradiation unit 60 to cure the light curable composition; and a separation step of separating the cured light curable composition and the transfer member.
摘要翻译：提供了一种成型方法，其能够比传统技术更高精度地模制诸如透镜的模制品的模制品。通过重复多次转印步骤来模制诸如透镜阵列和纳米压印模具的模制品，其包括：将含有具有聚合性官能团的化合物和聚合引发剂的光固化性组合物与转印剂接触的转化步骤形成与非球面透镜部分312相等或相反形状的转印形状部分的构件62将光固化组合物转变成转印部件62的转印形状; 固化步骤，通过光照射单元60用光照射至少所述转化的可光固化组合物的转化部分以固化所述光固化组合物; 以及分离固化的光固化性组合物和转印体的分离工序。

3. 发明申请

US20110098411A1 CURABLE COMPOSITION AND CURED PRODUCT THEREOF 审中-公开
标题翻译：可固化组合物和固化产品
公开(公告)号：US20110098411A1
公开(公告)日：2011-04-28
申请号：US13002245
申请日：2009-06-30
申请人： Shigeru Yamaki , Hideo Miyata , Nobuyuki Mitarai , Nobuaki Ishii , katsumi Kurofushi
发明人： Shigeru Yamaki , Hideo Miyata , Nobuyuki Mitarai , Nobuaki Ishii , katsumi Kurofushi
IPC分类号： C08L83/07
CPC分类号： C09C1/309 , B82Y30/00 , C01P2004/64 , C01P2006/22 , C08F2/44 , C08F220/18 , C08F222/1006 , C08F292/00 , C09C1/3081 , C08F220/10
摘要： An object of the present invention is to provide a curable composition which has excellent handling properties and which is able to form a cured product excellent in transparency, heat resistance, environment resistance and molding processability. The curable composition of the present invention comprises (a) silica fine particles, (b) a (meth)acrylate having at least two ethylenic unsaturated groups and no ring structure, (c) a (meth)acrylate having an ethylenic unsaturated group and an alicyclic structure, and (d) a polymerization initiator, said silica fine particles (a) are surface-treated with a silane compound (e) represented by the following general formula (1) and a silane compound (f) represented by the following general formula (2).
摘要翻译：本发明的目的是提供一种处理性能优异且能够形成透明性，耐热性，耐环境性和成型加工性优异的固化物的固化性组合物。本发明的固化性组合物包含（a）二氧化硅微粒，（b）具有至少两个烯键式不饱和基团且不具有环结构的（甲基）丙烯酸酯，（c）具有烯属不饱和基团的（甲基）丙烯酸酯，脂肪族结构和（d）聚合引发剂，用下述通式（1）表示的硅烷化合物（e）和下述通式（1）表示的硅烷化合物（f）对所述二氧化硅微粒（a）进行表面处理公式（2）。

4. 发明授权

US08840830B2 Method of molding 有权
标题翻译：成型方法
公开(公告)号：US08840830B2
公开(公告)日：2014-09-23
申请号：US13131961
申请日：2009-11-13
申请人： Shigeru Yamaki , Hideo Miyata , Nobuyuki Mitarai , Nobuaki Ishii , Katsumi Murofushi , Kunio Yoshida
发明人： Shigeru Yamaki , Hideo Miyata , Nobuyuki Mitarai , Nobuaki Ishii , Katsumi Murofushi , Kunio Yoshida
IPC分类号： B29C35/08 , B29D11/00
CPC分类号： B29C43/021 , B29C2035/0822 , B29C2035/0827 , B29C2035/0838 , B29C2043/025 , B29C2043/046 , B29C2043/3634 , B29C2043/525 , B29C2059/023 , B29D11/00365 , B29K2105/0002 , B29L2011/0016 , C08F230/08 , C08G77/20 , C08F2230/085 , C08F2222/1026
摘要： There is provided a method of molding which is capable of more highly precisely molding a molded article to be molded such as a lens than conventional technologies.A molded article such as a lens array and a mold for nanoimprinting is molded by repeating multiple times a transfer step including: a transformation step of bringing a light curable composition containing a compound having a polymerizable functional group and a polymerization initiator into contact with a transfer member 62 on which a transfer shape portion shaped equally to or reversely to an aspherical lens portion 312 is formed to transform the light curable composition to the transfer shape of the transfer member 62; a curing step of irradiating at least a transformed portion of the transformed light curable composition with light by a light irradiation unit 60 to cure the light curable composition; and a separation step of separating the cured light curable composition and the transfer member.
摘要翻译：提供了一种成型方法，其能够比传统技术更高精度地模制诸如透镜的模制品的模制品。通过重复多次转印步骤来模制诸如透镜阵列和纳米压印模具的模制品，其包括：将含有具有聚合性官能团的化合物和聚合引发剂的光固化性组合物与转印剂接触的转化步骤形成与非球面透镜部分312相等或相反形状的转印形状部分的构件62将光固化组合物转变成转印部件62的转印形状; 固化步骤，通过光照射单元60用光照射至少所述转化的可光固化组合物的转化部分以固化所述光固化组合物; 以及分离固化的光固化性组合物和转印体的分离工序。

5. 发明申请

US20130310516A1 CURABLE COMPOSITION AND CURED MATERIAL OF THE SAME 审中-公开
标题翻译：可固化组合物和固化材料
公开(公告)号：US20130310516A1
公开(公告)日：2013-11-21
申请号：US13982134
申请日：2012-02-17
申请人： Yoshifumi Urakawa , Shigeru Yamaki , Nobuaki Ishii
发明人： Yoshifumi Urakawa , Shigeru Yamaki , Nobuaki Ishii
IPC分类号： C08K5/5425
CPC分类号： C08K5/5425 , C08F2/44 , C08F292/00 , G02B1/041 , C08L33/08 , C08L33/10
摘要： The present invention provides a curable composition, wherein a cured material obtainable by curing the curable composition has excellent transparency, thermal durability and surface hardness and has a small Abbe number. In particular, the present invention provides a curable composition containing (a) silica fine particles; (b) a (meth)acrylate compound having two or more ethylenically unsaturated groups; (c) a (meth)allyl compound having two or more ethylenically unsaturated groups and having an aromatic ring structure; and (d) a polymerization initiator; wherein the surface of the silica fine particles (a) has been treated with a specified silane compound (e) and a specified silane compound (f).
摘要翻译：本发明提供一种可固化组合物，其中通过固化可固化组合物获得的固化材料具有优异的透明性，耐热性和表面硬度，并且具有小的阿贝数。特别地，本发明提供了含有（a）二氧化硅微粒的固化性组合物，（b）具有两个以上烯属不饱和基团的（甲基）丙烯酸酯化合物; （c）具有两个以上烯键式不饱和基团并具有芳环结构的（甲基）烯丙基化合物; 和（d）聚合引发剂; 其中二氧化硅微粒（a）的表面已用特定的硅烷化合物（e）和特定的硅烷化合物（f）进行处理。

6. 发明申请

US20110294948A1 AROMATIC GROUP-CONTAINING (METH) ACRYLATE COMPOUND 审中-公开
标题翻译：含芳族基团（甲基）丙烯酸酯化合物
公开(公告)号：US20110294948A1
公开(公告)日：2011-12-01
申请号：US13201387
申请日：2010-02-09
申请人： Yoshifumi Urakawa , Shigeru Yamaki , Nobuaki Ishii , Yoshihiko Maeda
发明人： Yoshifumi Urakawa , Shigeru Yamaki , Nobuaki Ishii , Yoshihiko Maeda
IPC分类号： C09D147/00 , C08F136/20 , C08F236/20 , C07C69/602
CPC分类号： C07C69/76 , C08F20/30 , C09D4/00 , C09D5/18 , C09D175/16 , G02B1/04 , C08L33/10
摘要： Disclosed is a (meth)acrylate compound which can provide a cured article having a high refractive index and excellent transparency and heat resistance, and which has superior handling characteristics; further disclosed are a curable composition containing the (meth)acrylate compound, and a cured article thereof. The (meth)acrylate compound contains an aromatic group represented by the following general formula (1), the curable composition comprising the aromatic-group containing (meth)acrylate compound, and the cured article thereof. (In the formula, R1, R2, R3 and R4 are each independently a hydrogen atom or a methyl group; X is an organic group having an aromatic group and 6 to 30 carbon atoms; and a and b are each independently an integer of 0 to 3.)
摘要翻译：公开了一种（甲基）丙烯酸酯化合物，其可以提供具有高折射率和优异的透明性和耐热性的固化物，并且具有优异的处理特性; 进一步公开了含有（甲基）丙烯酸酯化合物的固化性组合物及其固化物。（甲基）丙烯酸酯化合物包含由以下通式（1）表示的芳族基团，所述含有芳香族基团的（甲基）丙烯酸酯化合物的固化性组合物及其固化物。（式中，R 1，R 2，R 3，R 4各自独立地为氢原子或甲基，X为具有芳基和碳原子数为6〜30的有机基团，a和b各自独立地为0以下的整数）至3.）

7. 发明申请

US20110263779A1 HARDENING COMPOSITION AND HARDENED PRODUCT THEREOF 失效
标题翻译：硬化组合物及其硬化产品
公开(公告)号：US20110263779A1
公开(公告)日：2011-10-27
申请号：US13139847
申请日：2009-12-10
申请人： Katsumi Murofushi , Nobuaki Ishii , Shigeru Yamaki , Hideo Miyata , Yotaro Hattori
发明人： Katsumi Murofushi , Nobuaki Ishii , Shigeru Yamaki , Hideo Miyata , Yotaro Hattori
IPC分类号： C08L35/02 , C08L43/04 , C08K3/04 , C08L83/04 , B82Y30/00
CPC分类号： C08F2/44 , C08F220/08 , C08F222/1006 , C08F292/00 , C08L33/06 , Y10T428/2991 , Y10T428/2995 , C08L2666/04 , C08F220/18
摘要： The present invention is directed to a hardening composition comprising silica fine particles (a), a (meth)acrylate (b) having two or more ethylenically unsaturated groups and being free from cyclic structure, a (meth)acrylate (c) having an ethylenically unsaturated group and having an alicyclic structure, a polymerization initiator (d) and black inorganic fine particles (e), wherein the silica fine particles (a) are surface-treated with a silane compound (f) represented by the following general formula (1) and a silane compound (g) represented by the following general formula (2): (in the formula (1), R1 represents a hydrogen atom or a methyl group, R2 represents an alkyl group having 1 to 3 carbon atoms or a phenyl group, R3 represents a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms; q represents an integer of 1 to 6; and r represents an integer of 0 to 2, (in the formula (2), R4 is an alkyl group having 1 to 3 carbon atoms or a phenyl group which may have a substituent; R5 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms; s is an integer of 0 to 6; and t is an integer of 0 to 2.
摘要翻译：本发明涉及一种包含二氧化硅细颗粒（a），具有两个或更多个烯属不饱和基团并且不含环状结构的（甲基）丙烯酸酯（b））的硬化组合物，具有烯键式不饱和基团和具有脂环结构的聚合引发剂（d）和黑色无机细颗粒（e），其中二氧化硅微粒（a）用下述通式（1）表示的硅烷化合物（f）进行表面处理）和由以下通式（2）表示的硅烷化合物（g）：（式（1）中，R 1表示氢原子或甲基，R 2表示碳原子数1〜3的烷基或苯基基团，R 3表示氢原子或碳原子数1〜10的烃基; q表示1〜6的整数，r表示0〜2的整数，（式（2）中，R 4表示烷基具有1至3个碳原子的苯基或可具有取代基的苯基 ent R5是氢原子或碳原子数1〜10的烃基; s为0〜6的整数; t为0〜2的整数。

8. 发明授权

US08349934B2 Hardening composition and hardened product thereof 失效
标题翻译：硬化组合物及硬化物
公开(公告)号：US08349934B2
公开(公告)日：2013-01-08
申请号：US13139847
申请日：2009-12-10
申请人： Katsumi Murofushi , Nobuaki Ishii , Shigeru Yamaki , Hideo Miyata , Yotaro Hattori
发明人： Katsumi Murofushi , Nobuaki Ishii , Shigeru Yamaki , Hideo Miyata , Yotaro Hattori
IPC分类号： C08K3/04 , C08F236/00
CPC分类号： C08F2/44 , C08F220/08 , C08F222/1006 , C08F292/00 , C08L33/06 , Y10T428/2991 , Y10T428/2995 , C08L2666/04 , C08F220/18
摘要： The present invention is directed to a hardening composition comprising silica fine particles (a), a (meth)acrylate (b) having two or more ethylenically unsaturated groups and being free from cyclic structure, a (meth)acrylate (c) having an ethylenically unsaturated group and having an alicyclic structure, a polymerization initiator (d) and black inorganic fine particles (e), wherein the silica fine particles (a) are surface-treated with a silane compound (f) represented by the following general formula (1) and a silane compound (g) represented by the following general formula (2): (in the formula (1), R1 represents a hydrogen atom or a methyl group, R2 represents an alkyl group having 1 to 3 carbon atoms or a phenyl group, R3 represents a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms; q represents an integer of 1 to 6; and r represents an integer of 0 to 2, (in the formula (2), R4 is an alkyl group having 1 to 3 carbon atoms or a phenyl group which may have a substituent; R5 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms; s is an integer of 0 to 6; and t is an integer of 0 to 2.
摘要翻译：本发明涉及一种包含二氧化硅细颗粒（a），具有两个或更多个烯属不饱和基团并且不含环状结构的（甲基）丙烯酸酯（b））的硬化组合物，具有烯键式不饱和基团和具有脂环结构的聚合引发剂（d）和黑色无机细颗粒（e），其中二氧化硅微粒（a）用下述通式（1）表示的硅烷化合物（f）进行表面处理）和由以下通式（2）表示的硅烷化合物（g）：（式（1）中，R 1表示氢原子或甲基，R 2表示碳原子数1〜3的烷基或苯基基团，R 3表示氢原子或碳原子数1〜10的烃基; q表示1〜6的整数，r表示0〜2的整数，（式（2）中，R 4表示烷基具有1至3个碳原子的苯基或可具有取代基的苯基 ent R5是氢原子或碳原子数1〜10的烃基; s为0〜6的整数; t为0〜2的整数。

9. 发明授权

US5630638A Seat lift mechanism for an automotive vehicle 失效
标题翻译：机动车辆的座椅升降机构
公开(公告)号：US5630638A
公开(公告)日：1997-05-20
申请号：US698183
申请日：1996-08-15
申请人： Kazuhiro Hirasawa , Shigeru Yamaki
发明人： Kazuhiro Hirasawa , Shigeru Yamaki
IPC分类号： B60N2/24 , B60N2/14
CPC分类号： B60N2/245
摘要： A seat lift mechanism in an automotive vehicle incorporates a swivel base mounted on a stationary base secured to a compartment floor of the vehicle for rotation about a vertical axis so as to be moved between a forward-facing position where the front side of the swivel base is oriented to the front of the vehicle, and a sideways position where the front side of the swivel base is opposed to a side door opening of the vehicle. A frame is supported on the swivel base for rotation therewith and a lift rack provided thereon with a passenger seat is mounted on the frame. The lift rack is connected to the frame by means of a link mechanism in such a manner that when the swivel base is retained in the sideways position, the lift rack and seat are movable from a first position on the frame to a second position close to the ground where the seating surface of the seat is maintained at an inclined angle. An actuator is combined with the link mechanism to reciprocate the lift rack and seat between the first and second positions. With the seat lift mechanism, the seat can be moved out of the door opening and lowered to the position adjacent to the ground. Thus, an aged or handicapped person can easily sit on the seat or stand up therefrom, and get in or out of the vehicle without any difficulty.
摘要翻译：机动车辆中的座椅提升机构包括安装在固定在车辆车厢底板上的固定基座上的旋转座，用于围绕垂直轴线旋转，以便在向前的位置之间移动，在前向位置，旋转底座定向到车辆的前部，以及侧面位置，其中旋转底座的前侧与车辆的侧门开口相对。框架支撑在旋转底座上以与其一起旋转，并且在其上设置有乘客座椅的提升架安装在框架上。提升架通过连杆机构连接到框架，使得当旋转底座保持在侧面位置时，提升架和座椅可从框架上的第一位置移动到接近于第二位置的第二位置座椅的座面保持倾斜的地面。致动器与连杆机构相结合，使提升架和座椅在第一和第二位置之间往复运动。通过座椅提升机构，座椅可以从门开口移出并降低到与地面相邻的位置。因此，老年人或残疾人可以容易地坐在座位上或站起来，而不会困难地进出车辆。

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