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1. 发明授权

US6110862A Catalytic material having improved conversion performance 失效
标题翻译：催化材料具有改进的转化性能
公开(公告)号：US6110862A
公开(公告)日：2000-08-29
申请号：US74239
申请日：1998-05-07
申请人： Shau-Lin F. Chen , Harold N. Rabinowitz , Chong Kim
发明人： Shau-Lin F. Chen , Harold N. Rabinowitz , Chong Kim
IPC分类号： B01D53/94 , B01D53/86 , B01J23/40 , B01J32/00 , B01J35/10
CPC分类号： B01D53/865 , B01J23/40 , B01J35/1042 , B01J35/108 , Y02C20/10
摘要： A novel catalytic material is prepared by dispersing a catalytically active species, e.g., one or more platinum group metals, on a support phase that contains a high porosity, meso-pores high surface area (HPMPHSA) material. The HPMPHSA material has a porosity, measured in milliliters per gram of material, that is typically at least about 30 percent greater than that of a corresponding conventional material, preferably at least 50 percent greater. In a particular embodiment, the support phase of the catalytic material contains a HPMPHSA alumina having a porosity of about 0.9 ml/g, whereas a conventional alumina typically has a porosity of about 0.45 ml/g. The surface area is above 90, preferably above 100, more preferably equal or above 150 to 160 m.sup.2 /g. The support phase may be wholly composed of the HPMPHSA material or it may be composed of a mixture of the HPMPHSA material and a conventional material. Such a mixture preferably contains at least about 20 percent HPMPHSA material, by weight, e.g., 20 to 50 percent by weight.
摘要翻译：通过将催化活性物质，例如一种或多种铂族金属分散在含有高孔隙率，中孔高表面积（HPMPHSA）材料的载体相上来制备新的催化材料。 HPMPHSA材料具有以毫克/克材料测量的孔隙率，其通常比相应的常规材料的孔隙率至少大约30％，优选地至少大于50％。在一个具体实施方案中，催化材料的载体相含有孔隙率为约0.9ml / g的HPMPHSA氧化铝，而常规氧化铝通常具有约0.45ml / g的孔隙率。表面积大于90，优选大于100，更优选等于或高于150至160m2 / g。支撑相可以完全由HPMPHSA材料组成，或者它可以由HPMPHSA材料和常规材料的混合物组成。这种混合物优选含有至少约20％重量的HPMPHSA材料，例如20至50％重量。

2. 发明授权

US07276212B2 Exhaust articles for internal combustion engines 有权
标题翻译：内燃机用排气制品
公开(公告)号：US07276212B2
公开(公告)日：2007-10-02
申请号：US09968192
申请日：2001-10-01
申请人： Zhicheng Hu , Patrick L. Burk , Shau-Lin F. Chen , Harold N. Rabinowitz , Christopher M. Minnella , Aaron N. Israel
发明人： Zhicheng Hu , Patrick L. Burk , Shau-Lin F. Chen , Harold N. Rabinowitz , Christopher M. Minnella , Aaron N. Israel
IPC分类号： B01D53/34 , F01N3/10
CPC分类号： B01D53/9454 , B01J23/63 , B01J23/8946 , B01J37/0244 , F01N3/2803 , F01N2510/06 , Y02T10/22
摘要： Provided is a base metal undercoat containing catalyst and an exhaust article containing the catalyst. The catalyst contains a base metal undercoat with an oxygen storage component, and at least one catalytic layer. Also provided are methods for preparing the catalyst and methods for monitoring the oxygen storage capacity of an exhaust article containing the catalyst.
摘要翻译：提供含有催化剂的贱金属底涂层和含有该催化剂的排气制品。催化剂含有具有储氧成分的贱金属底涂层和至少一个催化剂层。还提供了制备催化剂的方法和用于监测含有催化剂的排气制品的储氧能力的方法。

3. 发明申请

US20090042722A1 Manufacture of Exhaust Articles for Internal Combustion Engines 有权
标题翻译：内燃机尾气制造
公开(公告)号：US20090042722A1
公开(公告)日：2009-02-12
申请号：US12183365
申请日：2008-07-31
申请人： Zhicheng Hu , Patrick L. Burk , Shau-Lin F. Chen , Harold N. Rabinowitz , Christopher M. Minnella , Aaron N. Israel
发明人： Zhicheng Hu , Patrick L. Burk , Shau-Lin F. Chen , Harold N. Rabinowitz , Christopher M. Minnella , Aaron N. Israel
IPC分类号： B01J23/10
CPC分类号： B01D53/9454 , B01J23/63 , B01J23/8946 , B01J37/0244 , F01N3/2803 , F01N2510/06 , Y02T10/22
摘要： Provided are methods for manufacturing a base metal undercoat containing catalyst and an exhaust article containing the catalyst. The catalyst contains a base metal undercoat with an oxygen storage component, substantially free of platinum group metal components, and at least one catalytic layer.
摘要翻译：提供了制备含有催化剂的贱金属底涂层和含有该催化剂的排气制品的方法。催化剂含有基本不含铂族金属组分的氧储存组分的基底金属底涂层和至少一种催化剂层。

4. 发明授权

US07811962B2 Manufacture of exhaust articles for internal combustion engines 有权
标题翻译：制造内燃机排气制品
公开(公告)号：US07811962B2
公开(公告)日：2010-10-12
申请号：US12183365
申请日：2008-07-31
申请人： Zhicheng Hu , Patrick L. Burk , Shau-Lin F. Chen , Harold N. Rabinowitz , Christopher M. Minnella , Aaron N. Israel
发明人： Zhicheng Hu , Patrick L. Burk , Shau-Lin F. Chen , Harold N. Rabinowitz , Christopher M. Minnella , Aaron N. Israel
IPC分类号： B01J23/10
CPC分类号： B01D53/9454 , B01J23/63 , B01J23/8946 , B01J37/0244 , F01N3/2803 , F01N2510/06 , Y02T10/22
摘要： Provided are methods for manufacturing a base metal undercoat containing catalyst and an exhaust article containing the catalyst. The catalyst contains a base metal undercoat with an oxygen storage component, substantially free of platinum group metal components, and at least one catalytic layer.
摘要翻译：提供了制备含有催化剂的贱金属底涂层和含有该催化剂的排气制品的方法。催化剂含有基本不含铂族金属组分的氧储存组分的基底金属底涂层和至少一种催化剂层。

5. 发明授权

US07189376B2 Multi-zoned catalyst and trap 有权
标题翻译：多区域催化剂和捕集阱
公开(公告)号：US07189376B2
公开(公告)日：2007-03-13
申请号：US10366096
申请日：2003-02-13
申请人： Sanath V. Kumar , Harold N. Rabinowitz
发明人： Sanath V. Kumar , Harold N. Rabinowitz
IPC分类号： B01D50/00
CPC分类号： F01N3/0842 , B01D53/945 , B01J23/44 , B01J35/04 , F01N3/0814 , F01N3/28 , F01N13/0097 , F01N2570/16
摘要： Provided are coated, multi-zoned catalyst substrates that trap and combust hydrocarbon and nitrogen oxides pollutants in a single monolith substrate. In some embodiments, the multi-zoned catalysts contain both radial and axial zones. The zones can be formed by deposition of segregated coating compositions (or washcoats) containing platinum group metals and pollutant adsorbent materials to form layers along the length and radius of the honeycomb substrate. The invention also relates to exhaust gas treating systems that incorporate the multi-zoned catalysts.
摘要翻译：提供了在单个整体衬底中捕获和燃烧烃和氮氧化物污染物的涂覆的多区域催化剂衬底。在一些实施方案中，多区域催化剂包含径向和轴向区域。这些区域可以通过沉积包含铂族金属和污染物吸附剂材料的分离的涂料组合物（或洗面漆）形成，以沿蜂窝基材的长度和半径形成层。本发明还涉及掺入多区域催化剂的废气处理系统。

6. 发明授权

US07524465B2 Multi-zone catalytic converter 有权
标题翻译：多区催化转化器
公开(公告)号：US07524465B2
公开(公告)日：2009-04-28
申请号：US11482651
申请日：2006-07-07
申请人： Sanath V. Kumar , Harold N. Rabinowitz , John J. Steger
发明人： Sanath V. Kumar , Harold N. Rabinowitz , John J. Steger
IPC分类号： B01D50/00
CPC分类号： F01N3/0842 , B01D53/945 , B01J23/44 , B01J35/04 , F01N3/0814 , F01N3/28 , F01N13/0097 , F01N2570/16
摘要： Provided is an exhaust article (catalyst) coated on a single substrate, such as a monolithic honeycomb having a plurality of channels along the axial length of the catalyst. Different washcoat compositions are deposited along the length the channel walls of the substrate beginning from either the inlet or outlet axial end of the substrate to form inlet and outlet catalyst layers, respectively. In the coating process, the channel walls are coated with catalyst washcoat compositions to lengths that are less than the substrates' axial length. The architecture of the resulting catalyst layers defines a plurality of zones along the length of the substrate. The properties of each zone of the catalyst can be optimized to address specific catalyst functions by manipulation of both the coating lengths and the catalyst washcoat compositions.
摘要翻译：提供了涂覆在单个基板上的排气制品（催化剂），例如沿着催化剂的轴向长度具有多个通道的整体式蜂窝体。不同的修补基面涂层组合物沿着衬底的通道壁的长度沉积，从衬底的入口或出口轴向端开始分别形成入口和出口催化剂层。在涂覆过程中，通道壁涂覆有催化剂修补基面涂层组合物，其长度小于基材的轴向长度。所得到的催化剂层的结构限定了沿衬底长度的多个区域。催化剂的每个区域的性质可以通过操纵涂层长度和催化剂修补基面涂料组合物来优化以满足具体的催化剂功能。

7. 发明申请

US20080044330A1 Layered catalyst composite 审中-公开
标题翻译：层状催化剂复合材料
公开(公告)号：US20080044330A1
公开(公告)日：2008-02-21
申请号：US11507340
申请日：2006-08-21
申请人： Shau-Lin Franklin Chen , Harold N. Rabinowitz , Jin Sakakibara , Tian Luo
发明人： Shau-Lin Franklin Chen , Harold N. Rabinowitz , Jin Sakakibara , Tian Luo
IPC分类号： B01D53/94
CPC分类号： B01D53/945 , B01D2255/1023 , B01D2255/1025 , B01D2255/204 , B01D2255/206 , B01D2255/9025 , B01D2255/908 , B01J23/40 , B01J23/464 , B01J23/63 , B01J37/0244 , B01J37/0248 , Y02T10/22
摘要： A layered, three-way conversion catalyst having the capability of simultaneously catalyzing the oxidation of hydrocarbons and carbon monoxide and the reduction of nitrogen oxides is disclosed. In one or more embodiments, the catalyst comprises three layers in conjunction with a carrier: a first layer deposited on the carrier and comprising palladium deposited on a refractory metal oxide and an oxygen storage component; a second layer deposited on the first layer and comprising rhodium deposited on a refractory metal oxide and an oxygen storage component; and a third layer deposited on the second layer and comprising palladium deposited on a refractory metal oxide.
摘要翻译：公开了具有同时催化烃和一氧化碳氧化和氮氧化物还原的能力的层状三元转化催化剂。在一个或多个实施方案中，催化剂包括与载体结合的三层：沉积在载体上并包含沉积在难熔金属氧化物上的钯和储氧组分的第一层; 沉积在第一层上并包含沉积在难熔金属氧化物上的铑和储氧组分的第二层; 以及沉积在第二层上并包含沉积在难熔金属氧化物上的钯的第三层。

8. 发明授权

US07022644B2 Hydrogen sulfide-suppressing catalyst compositions 有权
公开(公告)号：US07022644B2
公开(公告)日：2006-04-04
申请号：US10079450
申请日：2002-02-20
申请人： John S. Foong , Harold N. Rabinowitz
发明人： John S. Foong , Harold N. Rabinowitz
IPC分类号： B01J23/02
CPC分类号： B01D53/945 , B01J23/58 , B01J23/63 , B01J37/0244 , B01J37/0248 , F01N3/2803 , Y02T10/22
摘要： Hydrogen sulfide formation is suppressed by a three-way conversion catalyst having an underlayer and a topcoat overlying the under layer. The under layer is prepared by dispersing a Group IIa metal oxide such as an oxide of magnesium, calcium, barium or strontium on a carrier such as a refractory metal oxide monolith. A topcoat overlying the undercoat is comprised of a three-way conversion catalyst material such as a platinum-group metal catalytic component, e.g., platinum, palladium, rhodium or mixtures thereof.

9. 发明授权

US06764665B2 Layered catalyst composite 有权
标题翻译：层状催化剂复合材料
公开(公告)号：US06764665B2
公开(公告)日：2004-07-20
申请号：US10003663
申请日：2001-10-26
申请人： Michel Deeba , John J. Steger , Harold N. Rabinowitz , John S. Foong
发明人： Michel Deeba , John J. Steger , Harold N. Rabinowitz , John S. Foong
IPC分类号： B01D5356
CPC分类号： B01D53/945 , B01D53/865 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/902 , B01D2255/9025 , B01D2255/908 , B01D2255/9207 , B01J23/63 , B01J37/0244 , Y02T10/22
摘要： The present invention relates to a layered catalyst composite of the type generally referred to as a three-way conversion catalyst having the capability of simultaneously catalyzing the oxidation of hydrocarbons and carbon monoxide and the reduction of nitrogen oxides. The structure of the layered catalyst composite of the present invention is designed wherein there are three layers in conjunction with a carrier: a first layer deposited on the carrier and comprising a high surface area refractory metal oxide; a second layer deposited on the first layer and comprising palladium and/or platinum deposited on a high surface area refractory metal oxide, and having substantially no oxygen storage components; and a third layer deposited on the second layer and comprising platinum and/or rhodium as well as an oxygen storage component, deposited on a high surface area refractory metal oxide.
摘要翻译：本发明涉及一种具有同时催化烃和一氧化碳的氧化和还原氮氧化物的能力的通常称为三元转化催化剂的层状催化剂复合物。设计本发明的层状催化剂复合材料的结构，其中有三层结合载体：沉积在载体上并包含高表面积的难熔金属氧化物的第一层; 沉积在第一层上并包含沉积在高表面积难熔金属氧化物上的钯和/或铂，并且基本上没有储氧组分的第二层; 以及沉积在第二层上并且包含铂和/或铑以及沉积在高表面积难熔金属氧化物上的储氧组分的第三层。

10. 发明授权

US6044644A Close coupled catalyst 失效
标题翻译：闭合催化剂
公开(公告)号：US6044644A
公开(公告)日：2000-04-04
申请号：US350297
申请日：1994-12-06
申请人： Zhicheng Hu , Ronald M. Heck , Harold N. Rabinowitz
发明人： Zhicheng Hu , Ronald M. Heck , Harold N. Rabinowitz
IPC分类号： B01D53/94 , B01J23/58 , B01J23/63 , F01N3/28 , F01N13/02 , F02B1/04 , F01N3/20 , F01N3/24
CPC分类号： B01D53/945 , B01J23/58 , F01N13/009 , F01N13/0093 , F01N13/0097 , B01D2255/908 , F01N2370/00 , F01N3/0864 , F01N3/2828 , F02B1/04 , Y02T10/22
摘要： A stable, close-coupled catalyst, an article comprising the close-coupled catalyst and a related method of operation. The close-coupled catalyst comprises a catalyst support and a palladium catalytic component. Preferably and optionally, there are stabilizers including alkaline metal oxide, and rare earth metal components selected from the neodymium and lanthanum components. The close-coupled catalyst composition includes substantially no additional oxygen storage component such as praseodymium or cerium compounds. There is preferably a catalyst such as a three-way catalyst downstream of the close-coupled catalyst. The downstream catalyst preferably includes an oxygen storage component such as cerium oxide or praseodymium oxide.
摘要翻译：稳定的紧密耦合的催化剂，包含紧密耦合催化剂的物品和相关的操作方法。紧密耦合的催化剂包括催化剂载体和钯催化组分。优选和任选地，存在稳定剂，包括碱金属氧化物和选自钕和镧组分的稀土金属组分。紧密耦合的催化剂组合物基本上不含另外的储氧组分如镨或铈化合物。优选催化剂，例如紧密耦合的催化剂下游的三元催化剂。下游催化剂优选包括氧存储组分如氧化铈或氧化镨。

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