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    • 10. 发明授权
    • Use of complex metal oxides in the autothermal generation of hydrogen
    • 在自发生成氢气中使用复合金属氧化物
    • US07438889B2
    • 2008-10-21
    • US11165720
    • 2005-06-24
    • Guido Peter PezBaolong ZhangHans-Conrad zur Loye
    • Guido Peter PezBaolong ZhangHans-Conrad zur Loye
    • C01B3/26
    • C01B3/38C01B3/56C01B2203/0244C01B2203/0425C01B2203/0475
    • A process for producing hydrogen comprising reacting at least one hydrocarbon and steam in the presence of a complex metal oxide and a steam-hydrocarbon reforming catalyst in a production step under reaction conditions sufficient to form hydrogen and a spent complex metal oxide, wherein the complex metal oxide is represented by the formula (A′xCax′Mgx″)x(B′yMny′Fey″)yOn where A′ represents at least one element selected from the group consisting of Sr, Ba, a Group 1 element, and an element of the Lanthanide series according to the IUPAC Periodic Table of the Elements; B′ represents at least one element selected from the group consisting of Cu, Ni, Co, Cr, and V; 0≦x≦1, 0≦x′≦1, 0≦x″≦1 wherein x+x′+x″=x; 0≦y≦1, 0≦y′≦1, 0≦y″≦1 wherein y+y′+y″=y; 1≦x≦10; 1≦y≦10; and n represents a value such that the complex metal oxide is rendered electrically neutral.
    • 一种生产氢的方法,包括在复合金属氧化物和蒸汽 - 烃重整催化剂存在下,在足以形成氢的复合金属氧化物的反应条件下,在制备步骤中使至少一种烃和蒸汽反应,其中复合金属 氧化物由公式<?in-line-formula description =“In-line Formulas”end =“lead”?>(A' Ca x' x“x”x“”“”“”“Y”“”“”“” &lt;&lt;&lt;&lt; /&gt;&lt;&lt;&lt;&lt;&lt;&lt; 来自由Sr,Ba,第1族元素组成的组和根据元素IUPAC周期表的镧系元素的元素; B'表示选自Cu,Ni,Co,Cr和V中的至少一种元素; 0 <= x <= 1,0 <= x'<= 1,0 <= x“<= 1其中x + x'+ x”= x; 0 <= y <= 1,0 <= y'<= 1,0 <= y“<= 1其中y + y'+ y”= y; 1 <= x <= 10; 1 <= y <= 10; n表示使复合金属氧化物呈电中性的值。