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    • 1. 发明授权
    • Semiconductor device
    • 半导体器件
    • US07221013B2
    • 2007-05-22
    • US10916645
    • 2004-08-12
    • Satoru GotoYoshihisa Nagano
    • Satoru GotoYoshihisa Nagano
    • H01L27/108H01L29/76H01L31/119H01L21/00
    • H01L28/55H01L27/10852H01L28/65H01L28/82
    • A semiconductor device includes: an insulating underlying layer of which surface portion has a concave portion; a lower electrode formed on the underlying layer along the inner face of the concave portion; a capacitor insulating film formed on the lower electrode and made of a high-dielectric or a ferroelectric subjected to thermal treatment for crystallization; and an upper electrode formed on the capacitor insulating film. The lower electrode and the upper electrode are made of a material that generates tensile stress in the thermal treatment for the capacitor insulating film, and the upper end part of the side wall and the corner part at the bottom face of the concave portion of the underlying layer are rounded.
    • 半导体器件包括:表面部分具有凹部的绝缘下层; 沿着所述凹部的内表面形成在所述下层上的下电极; 在下电极上形成的电容器绝缘膜,由用于结晶的热处理的高电介质或铁电体构成; 以及形成在电容器绝缘膜上的上电极。 下电极和上电极由在电容绝缘膜的热处理中产生拉伸应力的材料制成,并且侧壁的上端部和位于底部的凹部的底部的底面的角部 层是圆形的。
    • 9. 发明授权
    • Method of manufacturing semiconductor devices
    • 制造半导体器件的方法
    • US5840200A
    • 1998-11-24
    • US788310
    • 1997-01-24
    • Satoshi NakagawaToyoji ItoYoji BitoYoshihisa Nagano
    • Satoshi NakagawaToyoji ItoYoji BitoYoshihisa Nagano
    • H01L21/02H01L21/311H01L21/3213H01L21/302
    • H01L28/55H01L21/31122H01L21/32136
    • A device insulating film, a lower-layer platinum film, a ferroelectric film, an upper-layer platinum film, and a titanium film are sequentially formed on a semiconductor substrate in this order. On the titanium film, a photoresist mask is further formed in a desired pattern. The thickness of the titanium film is adjusted to be 1/10 or more of the total thickness of a multilayer film consisting of the upper-layer platinum film, the ferroelectric film, and the lower-layer platinum film. The titanium film is then subjected to dry etching and the photoresist film is removed by ashing process. The titanium film thus patterned is used as a mask in etching the upper-layer platinum film, the ferroelectric film, and the lower-layer platinum film by a dry-etching method using a plasma of a gas mixture of chlorine and oxygen in which the volume concentration of oxygen gas is adjusted to be 40%. During the dry-etching process, the titanium film is oxidized to provide a high etching selectivity. Subsequently, the titanium film is removed by dry etching using a plasma of chlorine gas.
    • 依次在半导体衬底上依次形成器件绝缘膜,下层铂膜,铁电体膜,上层铂膜和钛膜。 在钛膜上,以期望的图案进一步形成光致抗蚀剂掩模。 将钛膜的厚度调节为由上层铂膜,铁电体膜和下层铂膜构成的多层膜的总厚度的+ E,fra 1/10 + EE以上。 然后对钛膜进行干蚀刻,并通过灰化处理去除光致抗蚀剂膜。 通过使用氯气和氧气的混合气体的等离子体的干蚀刻方法,将如此构图的钛膜用作蚀刻上层铂膜,铁电体膜和下层铂膜的掩模,其中 氧气体积浓度调整为40%。 在干蚀刻工艺期间,钛膜被氧化以提供高蚀刻选择性。 随后,使用氯气等离子体通过干蚀刻除去钛膜。