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    • 1. 发明授权
    • Flame retardant thermoplastic resin composition having excellent weatherability
    • 具有优异耐候性的阻燃热塑性树脂组合物
    • US07772303B2
    • 2010-08-10
    • US11953910
    • 2007-12-11
    • Sang Hyun HongSeon Ae LeeMin Soo LeeJin Hwan Choi
    • Sang Hyun HongSeon Ae LeeMin Soo LeeJin Hwan Choi
    • C08K5/3432C08K5/5333
    • C09K21/12
    • Disclosed herein is a flame retardant thermoplastic resin composition having excellent weatherability comprising (A) about 100 parts by weight of a rubber modified aromatic vinyl resin comprising (a1) about 15 to about 100% by weight of a grafted copolymer resin prepared by graft-polymerizing about 5 to 65% by weight of a rubbery polymer, about 10 to 95% by weight of an aromatic vinyl monomer and about 0 to 40% by weight of a monomer copolymerizable with said aromatic vinyl monomer; and (a2) about 0 to 85% by weight of a copolymer resin prepared by polymerizing about 40 to 90% by weight of an aromatic vinyl monomer and about 10 to 60% by weight of a monomer copolymerizable with said aromatic vinyl monomer; (B) about 0.1 to about 10 parts by weight of a ring-shaped alkyl phosphonate ester compound; and (C) about 0.05 to about 3 parts by weight of a HALS compound.
    • 本文公开了具有优异耐候性的阻燃热塑性树脂组合物,其包含(A)约100重量份的橡胶改性芳族乙烯基树脂,其包含(a1)约15至约100重量%的通过接枝聚合制备的接枝共聚物树脂 约5至65重量%的橡胶状聚合物,约10至95重量%的芳族乙烯基单体和约0至40重量%的可与所述芳族乙烯基单体共聚的单体; 和(a2)约0至85重量%的通过聚合约40至90重量%的芳族乙烯基单体和约10至60重量%的可与所述芳族乙烯基单体共聚的单体制备的共聚物树脂; (B)约0.1至约10重量份的环状烷基膦酸酯化合物; 和(C)约0.05至约3重量份的HALS化合物。
    • 7. 发明授权
    • Chemical and impact resistant thermoplastic resin composition having improved extrudability
    • 具有改进的挤出性的耐化学和抗冲击热塑性树脂组合物
    • US08080611B2
    • 2011-12-20
    • US12797645
    • 2010-06-10
    • Jee Kwon ParkJun Myung KimJin Hwan ChoiJae Won Lee
    • Jee Kwon ParkJun Myung KimJin Hwan ChoiJae Won Lee
    • C08L33/14C08L51/04C08L67/03
    • C08L51/04C08K5/1515C08L25/12C08L25/14C08L33/062C08L33/068C08L33/20C08L35/06C08L55/02C08L67/00C08L2205/03C08L2666/02
    • The present invention provides a chemical and impact resistant thermoplastic resin composition that can have improved extrudability. In one embodiment, the thermoplastic resin composition comprises a base resin including (A) about 1 to about 98% by weight of an epoxy group-containing vinyl copolymer resin; (B) about 1 to about 98% by weight of a rubber modified styrene copolymer resin; and (C) about 1 to about 98% by weight of a polyester resin; and about 1 to about 6 parts by weight of an aromatic vinyl-vinyl cyanide copolymer resin having a weight average molecular weight of about 1,000,000 to about 5,000,000, per 100 parts by weight of the base resin comprising (A)+(B)+(C). In another embodiment, the thermoplastic resin composition comprises a base resin including (A) about 1 to about 98% by weight of an epoxy group-containing vinyl copolymer resin; (B) about 1 to about 98% by weight of a rubber modified styrene copolymer resin; and (C) about 1 to about 98% by weight of a polyester resin; and (E) about 0.01 to about 1 part by weight of an epoxy-based additive, per 100 parts by weight of the base resin comprising (A)+(B)+(C).
    • 本发明提供一种能够提高挤出性能的耐化学和耐冲击热塑性树脂组合物。 在一个实施方案中,热塑性树脂组合物包含基础树脂,其包含(A)约1至约98重量%的含环氧基的乙烯基共聚物树脂; (B)约1至约98重量%的橡胶改性苯乙烯共聚物树脂; 和(C)约1至约98重量%的聚酯树脂; 和约1至约6重量份的重均分子量为约1,000,000至约5,000,000的芳族乙烯基 - 乙烯基氰共聚物树脂,相对于每100重量份的包含(A)+(B)+( C)。 在另一个实施方案中,热塑性树脂组合物包括基础树脂,其包含(A)约1至约98重量%的含环氧基的乙烯基共聚物树脂; (B)约1至约98重量%的橡胶改性苯乙烯共聚物树脂; 和(C)约1至约98重量%的聚酯树脂; 和(E)每100重量份包含(A)+(B)+(C)的基础树脂约0.01至约1重量份的环氧基添加剂。
    • 8. 发明授权
    • Scratch-resistant flameproof thermoplastic resin composition
    • 防刮耐火热塑性树脂组合物
    • US07732515B2
    • 2010-06-08
    • US12250648
    • 2008-10-14
    • Bok Nam JangIn Chul JungJung Hwan YunJin Hwan Choi
    • Bok Nam JangIn Chul JungJung Hwan YunJin Hwan Choi
    • C08K5/523
    • C08L69/00C08K5/521C08K5/523C08L33/12C08L51/04C08L67/02C08L2201/02C08L2205/03C08L2666/02
    • Disclosed herein is a flame retardant thermoplastic resin composition that has superior scratch resistance and mechanical properties, satisfying requirements for the appearance of housing materials resulting from a recent increase in volume of electrical and electronic products, and that contains a phosphorus-based flame-retarding agent, satisfying requirements for fire safety and prevention of environmental problems. The resin composition with scratch resistance comprises a base resin comprising (A) about 30 to about 90 parts by weight of a polycarbonate resin, (B) about 15 to about 50 parts by weight of a polymethylmethacrylate resin and (C) about 5 to about 50 parts by weight of a polyethylene terephthalate-based resin, and (D) about 5 to about 30 parts by weight of a phosphorus-based flame-retarding agent based on 100 parts by weight of the base resin. The composition may further comprise about 1 to about 30 parts by weight of an impact modifier based on 100 parts by weight of the base resin.
    • 本发明公开了一种阻燃热塑性树脂组合物,其具有优异的耐擦伤性和机械性能,满足了近来电气和电子产品体积增加所引起的外壳材料外观的要求,并且含有磷系阻燃剂 满足消防安全要求,防范环境问题。 具有耐刮擦性的树脂组合物包括基础树脂,其包含(A)约30至约90重量份的聚碳酸酯树脂,(B)约15至约50重量份的聚甲基丙烯酸甲酯树脂和(C)约5至约 50重量份的聚对苯二甲酸乙二醇酯类树脂,(D)基于100重量份的基础树脂约5至约30重量份的磷系阻燃剂。 基于100重量份的基础树脂,组合物还可以包含约1至约30重量份的抗冲改性剂。
    • 9. 发明授权
    • Thermoplastic resin composition with good heat stability, light stability, and impact strength
    • 热塑性树脂组合物具有良好的热稳定性,光稳定性和冲击强度
    • US08080618B2
    • 2011-12-20
    • US12477530
    • 2009-06-03
    • Jun Myung KimJin Hwan ChoiJee Kwon ParkJae Won Lee
    • Jun Myung KimJin Hwan ChoiJee Kwon ParkJae Won Lee
    • C08L67/02C08L63/00C08L63/10C08L25/08
    • C08L25/14C08K5/1345C08K5/3462C08K5/3475C08K5/524C08L25/08C08L25/12C08L35/06C08L55/02C08L67/02C08L2666/02C08L2666/18
    • Disclosed herein is a thermoplastic resin composition with good heat stability, light stability and impact strength. In an exemplary embodiment, the thermoplastic resin composition comprises (A) about 10 to about 99 parts by weight of an epoxy group-containing styrenic resin; (B) about 1 to about 90 parts by weight of a polyester resin; (C) about 0.1 to about 10 parts by weight of a thermoplastic polyester resin comprising a cycloaliphatic diol such as cyclohexane dimethanol, per about 100 parts by weight of a base resin comprising (A)+(B); (D) about 0.05 to about 2 parts by weight of a hindered phenolic compound, per about 100 parts by weight of a base resin comprising (A)+(B); (E) about 0.05 to about 4 parts by weight of a phosphite compound, per about 100 parts by weight of a base resin comprising (A)+(B); and (F) about 0.2 to about 6 parts by weight of a compound comprising a HALS compound, benzotriazol based compound, or a combination thereof, per about 100 parts by weight of a base resin comprising (A)+(B).
    • 本文公开了具有良好的热稳定性,光稳定性和冲击强度的热塑性树脂组合物。 在一个示例性实施方案中,热塑性树脂组合物包含(A)约10至约99重量份的含环氧基的苯乙烯树脂; (B)约1至约90重量份的聚酯树脂; (C)约0.1至约10重量份的包含脂环族二醇如环己烷二甲醇的热塑性聚酯树脂,每100重量份包含(A)+(B)的基础树脂; (D)每100重量份包含(A)+(B)的基础树脂,约0.05至约2重量份的受阻酚化合物; (E)约0.05至约4重量份的亚磷酸酯化合物,每100重量份包含(A)+(B)的基础树脂; 和(F)约100至约6重量份的包含HALS化合物,苯并三唑基化合物或其组合的化合物,每100重量份包含(A)+(B)的基础树脂。