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1. 发明授权

US06596796B1 Stabilizers for emulsion crude rubbers, synthetic latex and natural rubber latex 失效
标题翻译：乳化乳胶，合成胶乳和天然橡胶胶乳的稳定剂
公开(公告)号：US06596796B1
公开(公告)日：2003-07-22
申请号：US09688417
申请日：2000-10-16
申请人： Hans-Rudolf Meier , Gerrit Knobloch , Paul Dubs , Samuel Evans
发明人： Hans-Rudolf Meier , Gerrit Knobloch , Paul Dubs , Samuel Evans
IPC分类号： C08K5134
CPC分类号： C08K5/134 , C08L21/02
摘要： There are described compositions comprising a) an emulsion crude rubber, synthetic latex or natural rubber latex subject to oxidative, thermal, dynamic and/or light-induced degradation, and b) as stabilizer at least one compound of formula I wherein R1 is C8-C20alkyl; and optionally c) as further stabilizer at least one compound of formula II wherein R2 is C8-C12alkyl, R3 is hydrogen, C1-C12alkyl, cyclohexyl, 1-methylcyclohexyl, benzyl, &agr;-methylbenzyl, &agr;,&agr;-dimethylbenzyl or —CH2—S—R2, R4 is C1-C12alkyl, benzyl, &agr;-methylbenzyl, 60 ,&agr;-dimethylbenzyl or —CH2—S—R2, and R5 is hydrogen or methyl.
摘要翻译：描述的组合物包括：a）经受氧化，热，动态和/或光诱导降解的乳液粗橡胶，合成胶乳或天然橡胶胶乳，和b）作为稳定剂的至少一种式I化合物，其中R1是C8-C20烷基;和任选地，c）作为其它稳定剂的至少一种式II化合物，其中R2是C8-C12烷基，R3是氢，C1-C12烷基，环己基，1-甲基环己基，苄基，α-甲基苄基，α，α-二甲基苄基或-CH2-S-R2 R 4是C 1 -C 12烷基，苄基，α-甲基苄基，60，α-二甲基苄基或-CH 2 -S-R 2，R 5是氢或甲基。

2. 发明授权

US07947831B2 Sulfoxides or sulfones grafted onto polymers 失效
标题翻译：接枝到聚合物上的亚砜或砜
公开(公告)号：US07947831B2
公开(公告)日：2011-05-24
申请号：US11523441
申请日：2006-09-19
申请人： Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi , Samuel Evans , Paul Dubs , Michèle Gerster
发明人： Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi , Samuel Evans , Paul Dubs , Michèle Gerster
IPC分类号： C07C317/00 , C07C317/04 , C07C317/06 , C07C317/10 , C07C317/18 , C07C317/44
CPC分类号： C07D303/22 , C07C317/04 , C07C317/10 , C07C317/18 , C07C317/44 , C07C323/12 , C07C323/25 , C07C323/52 , C07C323/65 , C07C2601/14 , C07D303/16 , C07D405/12 , C07F7/1804 , C08C19/20 , C08C19/22 , C08K5/36
摘要： Polymers grafted with a compound of formula I, wherein the general symbols are as defined within, have outstanding stability against oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation.
摘要翻译：用式I化合物接枝的聚合物，其中通式如上所定义，具有优异的抗氧化，热，动态，光诱导和/或臭氧诱导的降解的稳定性。

3. 发明授权

US07160955B2 Sulfoxides or sulfones grafted onto polymers 失效
标题翻译：接枝到聚合物上的亚砜或砜
公开(公告)号：US07160955B2
公开(公告)日：2007-01-09
申请号：US10473848
申请日：2002-03-26
申请人： Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi , Samuel Evans , Paul Dubs , Michèle Gerster
发明人： Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi , Samuel Evans , Paul Dubs , Michèle Gerster
IPC分类号： C08F8/34
CPC分类号： C07D303/22 , C07C317/04 , C07C317/10 , C07C317/18 , C07C317/44 , C07C323/12 , C07C323/25 , C07C323/52 , C07C323/65 , C07C2601/14 , C07D303/16 , C07D405/12 , C07F7/1804 , C08C19/20 , C08C19/22 , C08K5/36
摘要： Polymers grafted with a compound of formula I, formula (I) wherein the general symbols are as defined in claim 1, have outstanding stability against oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation [R1—SOmnR—SOp—R2. (I)
摘要翻译：用式I化合物（I）接枝的聚合物，其中通式如权利要求1所定义，具有优异的抗氧化，热，动态，光诱导和/或臭氧诱导的降解的稳定性，公式描述=“在线公式”end =“lead”？> [R＆lt; 1＆lt;＆lt;＆lt;＆lt;＆gt;＆lt; img id =“PRIVATE-USE-CHARACTER-00001” =“6.77mm”wi =“8.47mm”file =“US07160955-20070109-Brketclosest.TIF”alt =“私人使用字符Brketclosest”img-content =“character”img-format =“tif”/> R 2 SO 2 -R 2。（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>

4. 发明申请

US20070015870A1 Sulfoxides or sulfones grafted onto polymers 失效
标题翻译：接枝到聚合物上的亚砜或砜
公开(公告)号：US20070015870A1
公开(公告)日：2007-01-18
申请号：US11523441
申请日：2006-09-19
申请人： Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi , Samuel Evans , Paul Dubs , Michele Gerster
发明人： Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi , Samuel Evans , Paul Dubs , Michele Gerster
IPC分类号： C08L63/00
CPC分类号： C07D303/22 , C07C317/04 , C07C317/10 , C07C317/18 , C07C317/44 , C07C323/12 , C07C323/25 , C07C323/52 , C07C323/65 , C07C2601/14 , C07D303/16 , C07D405/12 , C07F7/1804 , C08C19/20 , C08C19/22 , C08K5/36
摘要： Polymers grafted with a compound of formula I, wherein the general symbols are as defined in claim 1, have outstanding stability against oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation.
摘要翻译：用式I化合物接枝的聚合物，其中通式符号如权利要求1所定义，对氧化，热，动态，光诱导和/或臭氧诱导的降解具有突出的稳定性。

5. 发明授权

US4699939A Ortho cyclohexyl, para hydroxy aralkanoic acid esters and amide antioxidants 失效
标题翻译：邻苯环，对羟基芳烷酸酯和酰胺类抗氧化剂
公开(公告)号：US4699939A
公开(公告)日：1987-10-13
申请号：US916575
申请日：1986-10-08
申请人： Ivan Orban , Hans-Rudolf Meier , Paul Dubs , Samuel Evans , Peter Hofmann
发明人： Ivan Orban , Hans-Rudolf Meier , Paul Dubs , Samuel Evans , Peter Hofmann
IPC分类号： C07B63/04 , C07B31/00 , C07C67/00 , C07C69/732 , C07C69/734 , C07C69/90 , C07C233/18 , C07C235/34 , C07C235/46 , C07C235/48 , C07C235/50 , C07C313/00 , C07C323/12 , C07C323/14 , C07C323/41 , C07C323/42 , C08K5/06 , C08K5/103 , C08K5/13 , C08K5/16 , C08K5/20 , C08K5/37 , C08L101/00 , C09K15/08 , C09K15/14 , C09K15/24 , C09K15/28 , C09K15/30 , C07C69/94 , C07C69/616
CPC分类号： C09K15/24 , C08K5/103 , C08K5/20
摘要： Compounds of formula I ##STR1## wherein R.sub.1, R.sub.2 and A are essentially hydrocarbyl or substituted hydrocarbyl groups with at least one of R.sub.1 and R.sub.2 being cyclohexyl, n is 0, 1 or 2, m is an integer of 1 to 4 and X is oxygen or --N(R.sub.3)-- wherein R.sub.3 is hydrogen, C.sub.1 -C.sub.4 alkyl or phenyl.
摘要翻译：式I的化合物其中R 1，R 2和A基本上为具有至少一个R 1和R 2的烃基或取代的烃基，其中R 1和R 2为环己基，n为0,1或2，m为1至4的整数并且X是氧或-N（R3） - ，其中R3是氢，C1-C4烷基或苯基。

6. 发明授权

US5258433A Sulfoxides of alkylthiomethylphenols 失效
标题翻译：烷硫基甲基苯酚的亚砜
公开(公告)号：US5258433A
公开(公告)日：1993-11-02
申请号：US747569
申请日：1991-08-20
申请人： Hans-Rudolf Meier , Paul Dubs
发明人： Hans-Rudolf Meier , Paul Dubs
IPC分类号： C07C317/18 , C07C317/44 , C08K5/41 , C09K15/14 , C10M135/08 , C10N30/00 , C10N30/08 , C10N30/12 , C10N40/08
CPC分类号： C08K5/41 , C07C317/18 , C09K15/14
摘要： Sulfoxides of alkylthiomethylphenols of the formula I ##STR1## in which R.sub.1 is hydrogen, C.sub.1 -C.sub.20 alkyl, C.sub.2 -C.sub.18 alkenyl, C.sub.5 -C.sub.7 cycloalkyl, C.sub.5 -C.sub.7 cycloalkenyl, phenyl or C.sub.7 -C.sub.9 phenylalkyl, R.sub.2 is hydrogen, C.sub.1 -C.sub.20 alkyl, C.sub.2 -C.sub.18 alkenyl, C.sub.5 -C.sub.7 cycloalkyl, C.sub.5 -C.sub.7 cycloalkenyl, phenyl, C.sub.7 -C.sub.9 phenylalkyl or a radical --CH.sub.2 --SO--R.sub.5, in which R.sub.5 is C.sub.8 -C.sub.20 alkyl which may be interrupted by --O--, --S-- or --SO-- groups, mono- or dihydroxy-substituted C.sub.2 -C.sub.12 alkyl, phenyl, benzyl, --(CH.sub.2).sub.n COOR.sub.6 or --CH(CH.sub.3)COOR.sub.6, in which R.sub.6 is C.sub.1 -C.sub.20 alkyl and n is 1 or 2, R.sub.3 is hydrogen or a group --CH.sub.2 --SO--R.sub.5, in which R.sub.5 is as defined above, and R.sub.4 has the same meanings as R.sub.2 , with the proviso that only one of the radicals R.sub.2, R.sub.3 or R.sub.4 is the group --CH.sub.2 --SO--R.sub.5 and that, if R.sub.4 is --CH.sub.2 --SO--R.sub.5 and R.sub.1 and R.sub.2 are simultaneously tert-butyl or tert-amyl, R.sub.5 is not C.sub.8 -C.sub.14 alkyl, or mixtures of these compounds with the corresponding non-oxidised compounds are suitable for stabilising organic materials which are sensitive to oxidative, thermal and/or light-induced degradation.
摘要翻译：其中R 1是氢，C 1 -C 20烷基，C 2 -C 18烯基，C 5 -C 7环烷基，C 5 -C 7环烯基，苯基或C 7 -C 9苯基烷基，R 2是氢，C 1 -C 20烷基，C 2（C 1 -C 20）烷基硫代甲基苯酚 -C 18烯基，C 5 -C 7环烷基，C 5 -C 7环烯基，苯基，C 7 -C 9苯基烷基或基团-CH 2 -SO 3 -R 5，其中R 5为可被-O - ， - S-或-SO-基团间隔的C 8 -C 20烷基，单或二羟基取代的C 2 -C 12烷基，苯基，苄基， - （CH 2）n COOR 6或-CH（CH 3）COOR 6，其中R 6是C 1 -C 20烷基，n是1或2，R 3是氢或基团-CH 2 -SO-R 5，其中R 5如上定义，并且R 4具有与R 2相同的含义，条件是基团R 2，R 3或R 4中只有一个是基团-CH 2 -SO-R 5，并且如果R 4 是-CH2-SO-R5，R1和R2同时是叔丁基或叔戊基，R5不是C8-C14烷基，或这些化合物与相应的非氧化化合物的混合物适用于稳定对氧化，热和 /或光诱导的降解。

7. 发明授权

US4863982A Isocyanuric acid derivatives 失效
标题翻译：异氰脲酸衍生物
公开(公告)号：US4863982A
公开(公告)日：1989-09-05
申请号：US217100
申请日：1988-07-06
申请人： Werner Stegmann , Eduard Troxler , Peter Hofmann , Hans-Rudolf Meier , Paul Dubs
发明人： Werner Stegmann , Eduard Troxler , Peter Hofmann , Hans-Rudolf Meier , Paul Dubs
IPC分类号： C07D251/72 , C07D251/14 , C07D251/34 , C08K5/34 , C08K5/3477
CPC分类号： C07D251/34 , C08K5/3477
摘要： Compounds of the formula I ##STR1## R.sup.4 is C.sub.5 -C.sub.7 -cycloalkyl which can be substituted by C.sub.1 -C.sub.4 -alkyl, and R.sup.5 to R.sup.9 are independently of one another C.sub.1 -C.sub.18 alkyl, unsubstituted or C.sub.1 -C.sub.4 -alkyl-substituted C.sub.5 -C.sub.7 -cycloalkyl, phenyl, benzyl or allyl, are suitable for stabilizing organic material against thermal, oxidative and/or actinic degradation.
摘要翻译： R 1是C 1 -C 4 - 烷基取代的C 5 -C 7 - 环烷基，R 5至R 9彼此独立地为C 1 -C 18 烷基，未取代的或C 1 -C 4 - 烷基取代的C 5 -C 7 - 环烷基，苯基，苄基或烯丙基适于稳定有机材料以防止热，氧化和/或光化降解。

8. 发明授权

US6046263A Liquid antioxidants as stabilizers 失效
标题翻译：液体抗氧化剂作为稳定剂
公开(公告)号：US6046263A
公开(公告)日：2000-04-04
申请号：US81432
申请日：1998-05-19
申请人： Michael Rasberger , Samuel Evans , Paul Dubs , Stephan Allenbach
发明人： Michael Rasberger , Samuel Evans , Paul Dubs , Stephan Allenbach
IPC分类号： C08K5/134 , C08K5/20 , C08K5/372 , C08K5/09 , C08K15/04
CPC分类号： C08K5/1345 , C08K5/20 , C08K5/372
摘要： Products are described which are obtainable by reacting compounds of formula I with compounds of formula IIa or/and IIb and IIIa or/and IIIb and additionally, where appropriate, IV ##STR1## wherein the general symbols are as defined in claim 1, the compound of formula I being, for example, methyl 3-(3',5'-di-tert-butyl-4'-hydroxyphenyl)propionate, the compound of formula IIa being, for example, diethanolamine, the compound of formula IIIa being, for example, methyl oleate, and the compound of formula IV being, for example, sulfur. The cited products can be used as liquid antioxidants in organic materials.
摘要翻译：描述了可通过使式I化合物与式IIa或/和IIb和IIIa或/和IIIb化合物反应而得到的产物，另外在适当情况下使其中通式如权利要求1所定义，式I化合物作为例如3-（3'，5'-二叔丁基-4'-羟基苯基）丙酸甲酯，式IIa的化合物是例如二乙醇胺，式IIIa的化合物是例如，油酸甲酯，式Ⅳ化合物为例如硫。所引用的产品可用作有机材料中的液体抗氧化剂。

9. 发明授权

US5668206A Liquid antioxidants as stabilizers 失效
标题翻译：液体抗氧化剂作为稳定剂
公开(公告)号：US5668206A
公开(公告)日：1997-09-16
申请号：US466520
申请日：1995-06-06
申请人： Paul Dubs , Roger Martin , Samuel Evans
发明人： Paul Dubs , Roger Martin , Samuel Evans
IPC分类号： C07C69/28 , C07C67/62 , C07C69/30 , C07C69/732 , C07C215/08 , C07C323/12 , C08K5/00 , C08K5/134 , C08K5/3435 , C09K15/08 , C08K5/04 , C08K5/06 , C08K5/10
CPC分类号： C08K5/3435 , C07C215/08 , C07C323/12 , C07C67/62 , C07C69/732 , C08K5/005 , C08K5/134 , C09K15/08
摘要： Products are described which can be obtained by reacting components a), b) and c), where component a) is a compound of the formula I or a mixture of compounds of the formula I, component b) is a compound of the formula II or a mixture of compounds of the formula II and component c) is a compound of the formula III or a mixture of compounds of the formula III, ##STR1## in which the general symbols are as defined in claim 1, the compound of the formula I being, for example, pentaerythritol, thiodiethylene glycol, 1,4-butanediol, 1,4-propanediol, diethylene glycol, triethylene glycol, diethanolamine or glycerol, the compound of the formula II being, for example, sunflower oil or coconut fat, and the compound of the formula III being, for example, methyl 3-(3',5'-di-tert-butyl-4'-hydroxyphenyl)propionate. The abovementioned products can be used as liquid antioxidants in polymers and lubricants.
摘要翻译：描述了通过使组分a），b）和c）反应得到的产物，其中组分a）是式I化合物或式I化合物的混合物，组分b）是式II化合物或式II化合物和组分c）的化合物的混合物是式III的化合物或式III化合物，X（Y）a，（I），（II）权利要求1中，式I化合物为例如季戊四醇，硫代二甘醇，1,4-丁二醇，1,4-丙二醇，二甘醇，三甘醇，二乙醇胺或甘油，式II化合物为例如向日葵油或椰子脂肪，式III化合物为例如3-（3'，5'-二叔丁基-4'-羟基苯基）丙酸甲酯。上述产品可用作聚合物和润滑剂中的液体抗氧化剂。

10. 发明授权

US5427701A Substituted phenols as stabilizers 失效
标题翻译：取代酚作为稳定剂
公开(公告)号：US5427701A
公开(公告)日：1995-06-27
申请号：US275689
申请日：1994-07-14
申请人： Hans R. Meier , Samuel Evans , Paul Dubs
发明人： Hans R. Meier , Samuel Evans , Paul Dubs
IPC分类号： C07C323/16 , C07C323/52 , C08K5/13 , C08K5/36 , C08K5/37 , C08K5/375 , C08L75/04 , C08L101/00 , C09K15/14 , C10M135/22 , C10M135/24 , C10M135/26 , C10M135/28 , C10N30/00 , C10N30/08 , C10N30/10 , C10N40/25 , C07C321/00
CPC分类号： C10M135/28 , C07C323/00 , C08K5/375 , C09K15/14 , C10M135/24 , C10M135/26 , C10M2219/084 , C10M2219/085 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106
摘要： Novel compositions are described which comprises an elastomer or a lubricant and at least one compound of the formulae I or II ##STR1## The symbols R.sub.1, R.sub.2, R.sub.3, Z.sub.1 and Z.sub.2 are as defined in claim 1.The compounds of the formula II and some of the compounds of the formula I are novel, and they are used especially as antioxidants.
摘要翻译：描述了新的组合物，其包含弹性体或润滑剂和至少一种式I或II的化合物。（I）符号R1，R2，R3，Z1和Z2如权利要求中所定义。式II化合物和一些式I化合物是新颖的，它们特别用作抗氧化剂。

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