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1. 发明授权

US4358610A Process for the production of methacrylic acid from isobutyraldehyde 失效
标题翻译：从异丁醛生产甲基丙烯酸的方法
公开(公告)号：US4358610A
公开(公告)日：1982-11-09
申请号：US239756
申请日：1981-03-02
申请人： S. Erik Pedersen , Louis F. Wagner , Christos Paparizos
发明人： S. Erik Pedersen , Louis F. Wagner , Christos Paparizos
IPC分类号： C07C57/00 , B01J23/887 , B01J27/00 , B01J27/198 , B01J27/199 , C07B61/00 , C07C51/00 , C07C51/235 , C07C57/05 , C07C67/00
CPC分类号： B01J23/002 , B01J23/8877 , B01J27/199 , C07C51/235 , B01J2523/00
摘要： Isobutyraldehyde is oxidized to methacrylic acid by contacting gaseous isobutyraldehyde with molecular oxygen at oxidative conditions in the presence of a catalyst of the empirical formula:Mo.sub.12 P.sub.0.1-3 Cu.sub.0.01-2 V.sub.0.01-3 M.sub.0.1-3 M'.sub.0.01-2 O.sub.xwhereM is at least one of K, Rb, Cs and Tl;M' is at least one of Be, Mg, Ca, Sr, Ba, Nb and Sb; andx is a positive number that satisfies the valence requirements of the other elements present.
摘要翻译：在氧化条件下，在经验式催化剂存在下，将气态异丁醛与分子氧接触，将异丁醛氧化成甲基丙烯酸：Mo12P0.1-3Cu0.01-2V0.01-3M0.1-3M'0.01-2Ox其中M 是K，Rb，Cs和T1中的至少一个; M'是Be，Mg，Ca，Sr，Ba，Nb和Sb中的至少一种; x是满足其它元素的化合价要求的正数。

2. 发明授权

US07348291B2 Catalyst for the manufacture of acrylonitrile 有权
标题翻译：用于制造丙烯腈的催化剂
公开(公告)号：US07348291B2
公开(公告)日：2008-03-25
申请号：US10717846
申请日：2003-11-19
申请人： Christos Paparizos , Stephen C. Jevne , Michael J. Seely
发明人： Christos Paparizos , Stephen C. Jevne , Michael J. Seely
IPC分类号： B01J23/28 , C07C253/24
CPC分类号： C07C253/26 , B01J23/002 , B01J23/8876 , B01J23/8878 , B01J27/0576 , B01J27/1853 , B01J27/192 , B01J35/023 , B01J37/0045 , B01J37/0081 , B01J2523/00 , Y02P20/52 , B01J2523/13 , B01J2523/15 , B01J2523/3712 , B01J2523/54 , B01J2523/67 , B01J2523/68 , B01J2523/842 , B01J2523/845 , B01J2523/847 , B01J2523/11 , C07C255/08
摘要： A catalyst comprising a complex of catalytic oxides comprising potassium, cesium, cerium, chromium, cobalt, nickel, iron, bismuth, molybdenum, wherein the relative ratios of these elements is represented by the following general formula AaKbCscCedCreCofNigXhFeiBijMo12Ox wherein A is Rb, Na, Li, Tl, or mixtures thereof, X is P, Sb, Te, B, Ge, W, Ca, Mg, a rare earth element, or mixtures thereof, a is 0 to about 1, b is about 0.01 to about 1, c is about 0.01 to about 1, d is about 0.01 to about 3, e is about 0.01 to about 2, f is about 0.01 to about 10, g is about 0.1 to about 10, h is 0 to about 4, i is about 0.1 to about 4, j is about 0.05 to about 4, x is a number determined by the valence requirements of the other elements present, and wherein the catalyst is substantially free of manganese and zinc. The catalyst is useful in processes for the ammoxidation of an olefin selected from the group consisting of propylene, isobutylene or mixtures thereof, to acrylonitrile, methacrylonitrile and mixtures thereof, respectively.
摘要翻译：一种催化剂，其包含包含钾，铯，铈，铬，钴，镍，铁，铋，钼的催化氧化物的络合物，其中这些元素的相对比例由以下通式表示： “In-line Formulas”end =“lead”？> A C C H＆lt;＆lt;＆lt;＆lt;＆lt;＆lt; α-in-line-formula description =“In-line Formulas”end =“tail”？>其中A是Rb，Na， Li，Tl或其混合物，X为P，Sb，Te，B，Ge，W，Ca，Mg，稀土元素或其混合物，a为0至约1，b为约0.01至约1， c为约0.01至约1，d为约0.01至约3，e为约0.01至约2，f为约0.01至约10，g为约0.1至约10，h为0至约4，i为约 0.1至约4，j为约0.05至约4，x为由存在的其它元素的化合价要求确定的数，并且其中所述催化剂基本上不含锰和锌。该催化剂可用于分别选自丙烯，异丁烯或其混合物的烯烃与丙烯腈，甲基丙烯腈及其混合物的氨氧化反应的方法。

3. 发明申请

US20070260085A1 In situ modification of molybdenum-based catalysts 有权
标题翻译：钼基催化剂的原位改性
公开(公告)号：US20070260085A1
公开(公告)日：2007-11-08
申请号：US11415565
申请日：2006-05-02
申请人： Michael Seely , Christos Paparizos
发明人： Michael Seely , Christos Paparizos
IPC分类号： C07C253/34
CPC分类号： C07C253/26 , B01J23/002 , B01J23/28 , B01J23/8876 , B01J35/0006 , B01J2523/00 , Y02P20/52 , B01J2523/11 , B01J2523/68 , B01J2523/13 , B01J2523/15 , B01J2523/14 , B01J2523/12 , C07C255/08
摘要： A process for the conversion of a hydrocarbon selected from the group consisting of propylene, isobutylene, propane, isobutane or mixtures thereof, to acrylonitrile, methacrylonitrile, or mixtures thereof, the process comprising the step of reacting in the vapor phase at an elevated temperature and pressure said hydrocarbon with a molecular oxygen-containing gas and ammonia, in the presence of a molybdenum-based ammoxidation catalyst and a catalyst modifier, wherein said catalyst modifier comprises a molybdate or a polymolybdate of at least one element M selected from the group consisting of cesium, rubidium, potassium, sodium, thallium, lithium, nickel, cobalt, iron, chromium, copper, magnesium, manganese, cerium and phosporus, and wherein the ratio of the M elements to Mo in the molybdate or polymolybdate is greater than the ratio for these M elements to Mo in the molybdenum-based catalyst. The catalyst modifier is useful in modifying the performance of molybdenum-based catalyst and inhibiting molybdenum oxide loss for such catalysts.
摘要翻译：一种将选自丙烯，异丁烯，丙烷，异丁烷或其混合物的烃转化为丙烯腈，甲基丙烯腈或其混合物的方法，该方法包括在升高的温度下在气相中反应和在钼基氨氧化催化剂和催化剂改性剂的存在下，用含分子氧的气体和氨压力所述烃，其中所述催化剂改性剂包含选自以下的至少一种元素M的钼酸盐或多钼酸盐：铯，铷，钾，钠，铊，锂，镍，钴，铁，铬，铜，镁，锰，铈和磷，并且其中钼酸盐或多钼酸盐中的M元素与Mo的比例大于对于这些M元素在钼基催化剂中的Mo。催化剂改性剂可用于改性钼基催化剂的性能并抑制这种催化剂的氧化钼损失。

4. 发明授权

US06982342B2 Ammoxidation of carboxylic acids to a mixture of nitriles 有权
公开(公告)号：US06982342B2
公开(公告)日：2006-01-03
申请号：US10438586
申请日：2003-05-15
申请人： Michael J. Seely , Sanjay P. Godbole , Christos Paparizos
发明人： Michael J. Seely , Sanjay P. Godbole , Christos Paparizos
IPC分类号： C07C253/18 , C07C253/24
CPC分类号： C07C253/26 , Y02P20/52 , C07C255/03 , C07C255/08
摘要： A process for increasing the yield of acetonitrile produced during the manufacture of acrylonitrile comprising introducing a hydrocarbon selected from the group consisting of propylene and propane, a carboxylic acid, ammonia and air into a reaction zone containing an ammoxidation catalyst, reacting the hydrocarbon, carboxylic acid, ammonia and oxygen over said catalyst at an elevated temperature to produce acrylonitrile, hydrogen cyanide and acetonitrile, and recovering the acrylonitrile, hydrogen cyanide and acetonitrile from the reactor.

5. 发明授权

US5258543A Method for ammoxidation of olefins 失效
标题翻译：烯烃的氨氧化方法
公开(公告)号：US5258543A
公开(公告)日：1993-11-02
申请号：US904611
申请日：1992-06-26
申请人： Dev D. Suresh , Michael J. Seely , Maria S. Friedrich , Christos Paparizos
发明人： Dev D. Suresh , Michael J. Seely , Maria S. Friedrich , Christos Paparizos
IPC分类号： B01J23/18 , B01J23/22 , B01J23/26 , B01J23/847 , B01J23/889 , C01C3/02 , C07B61/00 , C07C253/26 , C07C255/08
CPC分类号： B01J23/22 , B01J23/18 , B01J23/8892 , C01C3/0216 , C07C253/26 , Y02P20/52
摘要： Disclosed is a method for ammoxidizing C.sub.3 to C.sub.5 mono-olefins to .alpha.,.beta.-mono-unsaturated acyclic nitriles having 3 to 5 carbon atoms and HCN by introducing such mono-olefins molecular oxygen and ammonia into a reaction zone into vapor phase contact with a solid ammoxidation catalyst, wherein the mol ratio of introduced molecular oxygen and ammonia to said introduced mono-olefin is at least 1.5 and 1.0, respectively, wherein said catalyst contains the elements and proportions indicated by the empirical formula:V1Sb.sub.a M.sub.m N.sub.n O.sub.xwherea=0.5 to 2M=one or more of: Sn, Ti, Fe, and Gam=0.05 to 3, usually at least 0.1 and at most 1N=one or more of: W, Bi, Mo, Li, Mg, P, Zn, Mn, Te, Ge, Nb, Zr, Cr, Al, Cu, Ce, Bn=0.0 to 0.5,and wherein the preparation of the catalyst includes contacting in an aqueous dispersion a vanadium compound and an antimony compound while said vanadium is in solution.
摘要翻译：公开了一种通过将这种单烯烃分子氧和氨引入反应区中与C3- C5单烯烃氧化成具有3至5个碳原子的α，β-单不饱和非环状腈和HCN的气相接触方法固体氨氧化催化剂，其中引入的分子氧和氨与所述引入的单烯烃的摩尔比分别为至少1.5和1.0，其中所述催化剂含有以下经验式所示的元素和比例：V1SbaMmNnOx其中a = 0.5至2 M = Sn，Ti，Fe和Ga中的一种或多种：m = 0.05〜3，通常为0.1以上且1N以下= W，Bi，Mo，Li，Mg，P，Zn， Mn，Te，Ge，Nb，Zr，Cr，Al，Cu，Ce，B n = 0.0〜0.5，其中催化剂的制备包括在水分散体中使钒化合物与锑化合物接触，解。

6. 发明授权

US5012028A Process for upgrading light hydrocarbons using oxidative coupling and pyrolysis 失效
标题翻译：使用氧化偶联和热解升级轻质烃的方法
公开(公告)号：US5012028A
公开(公告)日：1991-04-30
申请号：US884474
申请日：1986-07-11
申请人： Victor Gupta , Christopher L. Bodolus , Christos Paparizos , Wilfrid G. Shaw
发明人： Victor Gupta , Christopher L. Bodolus , Christos Paparizos , Wilfrid G. Shaw
IPC分类号： B01J8/02 , B01J12/00 , B01J23/14 , C07C2/00 , C07C2/84
CPC分类号： B01J8/0242 , B01J12/005 , B01J23/14 , C07C2/00 , C07C2/84 , B01J2208/00212 , B01J2208/00504 , C07C2521/02 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2521/16 , C07C2523/02 , C07C2523/04 , C07C2523/06 , C07C2523/08 , C07C2523/10 , C07C2523/14 , C07C2523/18 , C07C2523/20 , C07C2523/30 , C07C2523/34 , C07C2523/50 , C07C2527/18 , C07C2527/224 , Y02P20/52 , Y10S585/91
摘要： A process for converting a gaseous reactant comprising methane or natural gas to higher molecular weight hydrocarbon products is disclosed which comprises: (1) contacting said gaseous reactant with an oxidative coupling catalyst at a reaction temperature in the range of about 500.degree. C. to about 1100.degree. C. for an effective period of time to form an intermediate product comprising ethane, ethylene or a mixture thereof; and (2) pyrolyzing said intermediate product at a temperature in the range of about 900.degree. C. to about 1500.degree. C. for an effective period of time to form said higher molecular weight hydrocarbon products.
摘要翻译：公开了一种将包含甲烷或天然气的气态反应物转化为较高分子量烃产物的方法，其包括：（1）将反应物与氧化偶联催化剂在约500℃至约 1100℃，有效的时间以形成包含乙烷，乙烯或其混合物的中间产物; 和（2）在约900℃至约1500℃的温度下将所述中间产物热解有效的一段时间以形成所述较高分子量的烃产物。

7. 发明授权

US4623635A Method for the preparation of high activity palladium based catalysts 失效
标题翻译：高活性钯基催化剂的制备方法
公开(公告)号：US4623635A
公开(公告)日：1986-11-18
申请号：US724535
申请日：1985-04-18
申请人： Christos Paparizos , Wilfrid G. Shaw , James L. Callahan
发明人： Christos Paparizos , Wilfrid G. Shaw , James L. Callahan
IPC分类号： B01J23/60 , B01J23/62 , B01J23/644 , B01J23/656 , B01J23/89 , B01J27/057 , C07C67/39 , B01J21/08 , B01J27/24 , B01J31/00
CPC分类号： B01J27/0576 , B01J23/60 , B01J23/622 , B01J23/644 , B01J23/656 , B01J23/89 , C07C67/39
摘要： A method for the preparation of a high activity palladium metal based catalyst having the formulaPdTe.sub.a Zn.sub.d E.sub.ewhereE is one or more metals from the group IIA, IVA, VA, IB, VIIB or VIII; anda, d and e are from about 0 to 3, with the proviso that at least d or e.noteq.0.The method comprises the step of forming an aqueous solution of a palladium compound, adding to the solution a powder of a reducing metal more electropositive than palladium and reducing the palladium to its metallic state on the surface of the reducing metal and, separating the resulting catalyst from the solution. Catalysts prepared according to this method are useful for producing esters from aldehydes and alcohols and provide greater conversions to the ester than catalysts prepared by previous processes.
摘要翻译：一种制备具有式PdTeaZnd Ee的高活性钯金属基催化剂的方法，其中E是来自IIA，IVA，VA，IB，VIIB或VIII族的一种或多种金属; 并且a，d和e为约0至3，条件是至少d或e为0。该方法包括形成钯化合物的水溶液的步骤，向溶液中加入还原金属的粉末比钯更正电，并在还原金属的表面上将钯还原成其金属状态，并将所得催化剂与溶液分离。根据该方法制备的催化剂可用于从醛和醇生产酯，并且比通过先前方法制备的催化剂提供比酯更好的转化率。

8. 发明授权

US4471061A Methods for treatment of phosphomolybdic acid based catalysts during reactor shutdown 失效
标题翻译：反应堆停堆期间处理磷钼酸催化剂的方法
公开(公告)号：US4471061A
公开(公告)日：1984-09-11
申请号：US497691
申请日：1983-05-24
申请人： Wilfrid G. Shaw , Christos Paparizos , Diane G. Farrington
发明人： Wilfrid G. Shaw , Christos Paparizos , Diane G. Farrington
IPC分类号： B01J23/92 , B01J23/94 , B01J27/28 , C07C57/055 , C07C51/25 , C07C51/377
CPC分类号： B01J23/92 , B01J23/94 , B01J27/285
摘要： The present invention relates to a method for maintaining the activity of PMA based catalysts during reactor shutdown by flushing the reactor with an oxide of nitrogen gas at a temperature of from about 150.degree. C. to about 370.degree. C. The method can be employed in the reactor by terminating the feed of hydrocarbon to the reactor and then flushing the reactor. The method can be employed to treat PMA based catalysts having the general formula Mo.sub.x P.sub.y A.sub.a B.sub.b C.sub.c D.sub.d E.sub.e O.sub.z wherein A is selected from the group consisting of ammonium, cesium, potassium, rubidium and thallium; B is selected from the group consisting of copper and vanadium; C is selected from the group consisting of antimony, arsenic, bismuth and tellurium; D is palladium; E is aluminum, barium, calcium, cerium, chromium, cobalt, iron, magnesium, manganese, nickel tantalum, titanium, tungsten, zinc, zirconium, chlorine and/or bromine; x can be 3 to 15, y can be 1 to 1.5; a can be 0.1 to 3; b can be 0.1 to 3; c can be 0 to 2; d can be 0 to 2; e can be 0 to 4 and z is a number necessary to satisfy the valence of all the other elements.
摘要翻译：本发明涉及一种在反应器关闭期间通过在约150℃至约370℃的温度下用氮氧化物冲洗反应器来维持PMA基催化剂的活性的方法。该方法可用于该反应器通过将烃的进料终止于反应器，然后冲洗反应器。该方法可用于处理具有通式MoxPyAbBCcDdEeOz的PMA基催化剂，其中A选自铵，铯，钾，铷和铊; B选自铜和钒; C选自锑，砷，铋和碲; D是钯; E是铝，钡，钙，铈，铬，钴，铁，镁，锰，镍钽，钛，钨，锌，锆，氯和/或溴; x可以是3到15，y可以是1到1.5; a可以是0.1到3; b可以为0.1〜3; c可以是0到2; d可以是0到2; e可以是0至4，并且z是满足所有其它元素的化合价所必需的数。

9. 发明授权

US06458742B1 Catalyst for the manufacture of acrylonitrile 有权
标题翻译：用于制造丙烯腈的催化剂
公开(公告)号：US06458742B1
公开(公告)日：2002-10-01
申请号：US09641380
申请日：2000-08-17
申请人： Christos Paparizos , Michael J. Seely , Maria S. Friedrich , Dev D. Suresh
发明人： Christos Paparizos , Michael J. Seely , Maria S. Friedrich , Dev D. Suresh
IPC分类号： B01J2310
CPC分类号： C07C253/26 , B01J23/8876 , Y02P20/52 , C07C255/08
摘要： A catalyst composition comprising a complex of catalytic oxides of iron, bismuth, molybdenum, cobalt, cerium, antimony, at least one of nickel or magnesium, and at least one of lithium, sodium, potassium, rubidium, or thallium, and characterized by the following empirical formula: AaBbCcFedBieCofCegSbhMomOx wherein A is at least one of Cr, P, Sn, Te, B, Ge, Zn, In, Mn, Ca, W, or mixtures thereof B is at least one of Li, Na, K, Rb, Cs, Tl, or mixtures thereof C is least one of Ni, Mg or mixtures thereof a is 0 to 4.0 b is 0.01 to 1.5 c is 1.0 to 10.0 d is 0.1 to 5.0 e is 0.1 to 2.0 f is 0.1 to 10.0 g is 0.1 to 2.0 h is 0.1 to 2.0 m is 12.0 to 18.0 and x is a number determined by the valence requirements of the other elements present. The catalyst is useful in processes for the ammoxidation of an olefin selected from the group consisting of propylene, isobutylene or mixtures thereof, to acrylonitrile, methacrylonitrile and mixtures thereof, respectively.
摘要翻译：一种催化剂组合物，其包含铁，铋，钼，钴，铈，锑，镍或镁中的至少一种和锂，钠，钾，铷或铊中的至少一种的催化氧化物的络合物，其特征在于以下经验式：其中A为Cr，P，Sn，Te，B，Ge，Zn，In，Mn，Ca，W或其混合物中的至少一种B为Li，Na，K，Rb，Cs， T1或其混合物C是Ni，Mg或其混合物中的至少一种，a为0〜4.0b为0.01〜1.5c为1.0〜10.0d，0.1〜5.0e为0.1〜2.0f，0.1〜10.0g为0.1〜2.0h 0.1至2.0μm为12.0至18.0，x为由其它元素的化合价要求确定的数。催化剂可用于将选自丙烯，异丁烯或其混合物的烯烃的氨氧化反应，丙烯腈，甲基丙烯腈及其混合物。

10. 发明授权

US06399813B1 Process for the preparation of fluid bed vinyl acetate catalyst 失效
公开(公告)号：US06399813B1
公开(公告)日：2002-06-04
申请号：US09929256
申请日：2001-08-14
申请人： Patricia Rae Blum , Larry Michael Cirjak , Marc Anthony Pepera , Christos Paparizos , George Frederick Salem , Michael James Baker
发明人： Patricia Rae Blum , Larry Michael Cirjak , Marc Anthony Pepera , Christos Paparizos , George Frederick Salem , Michael James Baker
IPC分类号： C07C67055
CPC分类号： B01J37/0045 , B01J21/08 , B01J23/44 , B01J23/52 , B01J23/56 , B01J23/58 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , C07C67/055 , C07C69/01 , C07C69/15
摘要： A process for the preparation of a fluid bed vinyl acetate (VAM) catalyst comprising impregnating a support comprising a mixture of substantially inert microspheroidal particles with a solution comprising a metal salt of Pd and M, wherein M comprises Ba, Cd, Au, La, Nb, Ce, Zn, Pb, Ca, Sr, Sb or mixtures thereof, reducing the metal salts to form a deposit of Pd and M on the support surface and impregnating the support with at least one alkali metal salt. At least 50% of the particles used for the microspheroidal support have a particle size below 105 microns.

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