专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US5473086A Process for the hydrogenation of maleic acid to 1,4-butanediol 失效
标题翻译：马来酸氢化为1,4-丁二醇的方法
公开(公告)号：US5473086A
公开(公告)日：1995-12-05
申请号：US373666
申请日：1995-01-17
申请人： John R. Budge , Thomas G. Attig , S. Erik Pedersen
发明人： John R. Budge , Thomas G. Attig , S. Erik Pedersen
IPC分类号： B01J23/656 , B01J23/68 , C07B61/00 , C07C27/04 , C07C29/149 , C07C29/17 , C07C31/20 , C07D307/08 , C07D307/02
CPC分类号： C07D307/08 , B01J23/6567 , C07C29/177
摘要： Maleic acid, maleic anhydride or other hydrogenatable precursor are catalytically hydrogenated to 1,4-butanediol and tetrahydrofuran. It has been discovered that high yields of 1,4-butanediol are achieved when the hydrogenation catalyst comprises palladium, silver and rhenium on a carbon support and is prepared by the steps of(i) impregnating a carbon support with a source of palladium, silver and rhenium, wherein the source of palladium, silver and rhenium is at least one solution,(ii) after each impregnation step, drying the impregnated carbon support to remove solvent,(iii) heating the impregnated carbon support at a temperature of about 120.degree. C. to about 350.degree. C. under reducing conditions.The palladium in the catalyst is present in the form of crystallites having a particle size of less than 10 nm.
摘要翻译：将马来酸，马来酸酐或其它可氢化的前体催化氢化成1,4-丁二醇和四氢呋喃。已经发现，当氢化催化剂在碳载体上包含钯，银和铼时，实现了高收率的1,4-丁二醇，并且通过以下步骤制备：（i）用钯，银浸渍碳载体和铼，其中钯，银和铼的来源是至少一种溶液，（ii）在每个浸渍步骤之后，干燥浸渍的碳载体以除去溶剂，（iii）在约120℃的温度下加热浸渍的碳载体在还原条件下，C至约350℃。催化剂中的钯以粒径小于10nm的微晶的形式存在。

2. 发明授权

US4864057A Dehydrogenation of carboxylic acids with mixed metal phosphorus oxide catalysts 失效
标题翻译：用混合金属磷氧化物催化剂脱羧羧酸
公开(公告)号：US4864057A
公开(公告)日：1989-09-05
申请号：US408860
申请日：1982-08-17
申请人： S. Erik Pedersen , James L. Callahan , Harley F. Hardman
发明人： S. Erik Pedersen , James L. Callahan , Harley F. Hardman
IPC分类号： B01J23/89 , B01J27/185 , B01J27/186 , C07C51/377
CPC分类号： B01J27/186 , B01J23/8933 , B01J27/1853 , C07C51/377
摘要： A process is provided for the oxydehydrogenation of saturated carboxylic acids or a lower alkyl ester thereof with oxygen in the presence of iron phosphorus oxide catalysts containing promoters selected from the group Ag, Al, B, Be, Cd, Co, Cu, Ga, Ge, In, Mn, Ni, Te, Th, Ti, Tl, U, V, Zn, Zr, rare earths and mixtures thereof.
摘要翻译：提供了在含有选自Ag，Al，B，Be，Cd，Co，Cu，Ga，Ge的促进剂的铁磷氧化物催化剂存在下，将饱和羧酸或其低级烷基酯氧与氧气脱氢的方法，In，Mn，Ni，Te，Th，Ti，Tl，U，V，Zn，Zr，稀土及其混合物。

3. 发明授权

US4677238A Preparation of indenes 失效
标题翻译：茚的制备
公开(公告)号：US4677238A
公开(公告)日：1987-06-30
申请号：US906851
申请日：1986-09-12
申请人： S. Erik Pedersen , Linda L. Pfingsten
发明人： S. Erik Pedersen , Linda L. Pfingsten
IPC分类号： C07C1/24 , C07C1/20
CPC分类号： C07C1/24 , C07C2102/08 , C07C2527/173
摘要： Disclosed is the vapor phase cyclodehydration of an aldehyde or ketone over a solid catalyst which comprises phosphoric acid on a solid inorganic oxide support to make indene or a substituted indene according to the equation: ##STR1##
摘要翻译：公开了在固体催化剂上的醛或酮的气相环化醛化，其包含在固体无机氧化物载体上的磷酸以制备茚或取代的茚，其根据以下等式： + TR

4. 发明授权

US4613711A Indenes by catalytic dehydrocyclization 失效
标题翻译：茚的催化脱氢环化
公开(公告)号：US4613711A
公开(公告)日：1986-09-23
申请号：US801355
申请日：1985-11-25
申请人： S. Erik Pedersen , Wilfrid G. Shaw , Linda L. Pfingsten
发明人： S. Erik Pedersen , Wilfrid G. Shaw , Linda L. Pfingsten
IPC分类号： B01J27/04 , B01J37/20 , C07C5/373
CPC分类号： B01J37/20 , B01J27/04 , C07C5/373
摘要： Disclosed is the dehydrocyclization of certain alkylaromatics to indene or a substituted indene by contacting certain alkylaromatics in admixture with H.sub.2 O with a sulfided metal oxide catalyst.
摘要翻译：公开了通过将某些烷基芳族化合物与H 2 O的混合物与硫化金属氧化物催化剂接触来将某些烷基芳族化合物脱氢化为茚或取代的茚。

5. 发明授权

US4568783A Indenes by catalytic dehydrogenation of indanes 失效
标题翻译：茚的催化脱氢茚
公开(公告)号：US4568783A
公开(公告)日：1986-02-04
申请号：US747739
申请日：1985-06-24
申请人： S. Erik Pedersen , Diane G. Farrington
发明人： S. Erik Pedersen , Diane G. Farrington
IPC分类号： C07C5/46 , C07C5/42
CPC分类号： C07C5/46
摘要： Disclosed is the vapor phase catalytic dehydrogenation of indanes to indenes over a Co--Mo oxide on alumina catalyst and in the presence of sulfur.
摘要翻译：公开了在氧化铝催化剂上和在硫存在下，在Co-Mo氧化物上的烷烃到茚的气相催化脱氢。

6. 发明授权

US4427792A Iron-phosphorus mixed oxide catalysts and process for their preparation 失效
标题翻译：铁磷复合氧化物催化剂及其制备方法
公开(公告)号：US4427792A
公开(公告)日：1984-01-24
申请号：US291603
申请日：1981-08-10
申请人： S. Erik Pedersen , Noel J. Bremer , James L. Callahan
发明人： S. Erik Pedersen , Noel J. Bremer , James L. Callahan
IPC分类号： B01J27/185 , B01J27/186 , B01J27/18
CPC分类号： B01J27/1853 , B01J27/186
摘要： A process is provided for the preparation of iron phosphorous mixed oxide catalysts which are highly active at moderate temperatures by introducing iron and phosphorus containing compounds and promoter element containing compounds, if any, into a substantially organic liquid medium, heating, separating the resulting precursor, drying and calcining. The catalysts are useful for the dehydrogenation or oxydehydrogenation of organic compounds such as aldehydes or carboxylic acids.
摘要翻译：提供了一种通过将含铁和磷的化合物和含促进剂元素的化合物（如果有的话）引入基本上有机的液体介质中，在中等温度下高度活性的铁磷混合氧化物催化剂的制备方法，加热，分离所得的前体，干燥和煅烧。该催化剂可用于有机化合物如醛或羧酸的脱氢或氧化脱氢。

7. 发明授权

US4381411A Production of methacrolein from isobutyraldehyde utilizing promoted iron phosphorus oxide catalysts 失效
标题翻译：使用促进的铁磷氧化物催化剂从异丁醛生产异丁烯醛
公开(公告)号：US4381411A
公开(公告)日：1983-04-26
申请号：US276312
申请日：1981-06-22
申请人： S. Erik Pedersen , Louis F. Wagner
发明人： S. Erik Pedersen , Louis F. Wagner
IPC分类号： C07C45/65 , C07C45/32
CPC分类号： C07C45/65
摘要： A process is provided for the oxydehydrogenation of aldehydes such as isobutyraldehyde with oxygen in the presence of iron phosphorus oxide catalysts containing promoters selected from Ag, Al, B, Be, Cd, Co, Cr, Cu, Ga, Ge, In, Mn, Ni, Te, Th, Ti, Tl, U, V, Zn, Zr, rare earths and mixtures thereof.
摘要翻译：在含有选自Ag，Al，B，Be，Cd，Co，Cr，Cu，Ga，Ge，In，Mn中的促进剂的铁磷氧化物催化剂存在下，提供了用于氧气脱氢醛，例如异丁醛与氧的方法， Ni，Te，Th，Ti，Tl，U，V，Zn，Zr，稀土及其混合物。

8. 发明授权

US4165299A Preparation of a single phase vanadium (IV) bis (metaphosphate) oxidation catalyst with an improved surface area 失效
标题翻译：制备具有改善的表面积的单相钒（Ⅳ）双（偏磷酸盐）氧化催化剂
公开(公告)号：US4165299A
公开(公告)日：1979-08-21
申请号：US908869
申请日：1978-05-23
申请人： S. Erik Pedersen
发明人： S. Erik Pedersen
IPC分类号： B01J23/22 , B01J27/198 , C07C51/25 , B01J27/14 , B01J27/02 , C01B15/16
CPC分类号： B01J27/198 , B01J23/22 , C07C51/252
摘要： A method for the preparation of a single phase vanadium(IV)bis(metaphosphate), VO(PO.sub.3).sub.2, catalyst having an improved surface area and useful for the vapor phase oxidation of linear C.sub.4 unsaturated olefins, such as the n-butenes, to prepare maleic anhydride.
摘要翻译：制备单相钒（Ⅳ）双（偏磷酸盐），VO（PO3）2）的催化剂，其具有改善的表面积，可用于直链C 4不饱和烯烃（如正丁烯）的汽相氧化，制备马来酸酐。

9. 发明授权

US5698749A Catalysts for the hydrogenation of aqueous maleic acid to 1,4-butanediol 失效
标题翻译：用于将马来酸水溶液氢化成1,4-丁二醇的催化剂
公开(公告)号：US5698749A
公开(公告)日：1997-12-16
申请号：US524195
申请日：1995-09-06
申请人： S. Erik Pedersen , John G. Frye, Jr. , Thomas G. Attig , John R. Budge
发明人： S. Erik Pedersen , John G. Frye, Jr. , Thomas G. Attig , John R. Budge
IPC分类号： B01J23/656 , C07C29/149 , C07C29/156 , C07C29/17 , C07C31/20 , C07D307/08
CPC分类号： C07C29/177
摘要： Maleic acid, maleic anhydride or other hydrogenatable precursor are catalytically hydrogenated to 1,4-butanediol and tetrahydrofuran. It has been discovered that high yields of 1,4-butanediol are achieved when the hydrogenation catalyst comprises at least one noble metal of Group VIII of the Periodic Table and at least one of rhenium, tungsten or molybdenum on a carbon support wherein the carbon support has been contacted with an oxidizing agent prior to the deposition of the metals. This hydrogenation catalyst is prepared by the steps of (i) oxidizing the carbon support by contacting the carbon support with an oxidizing agent, (ii) impregnating in one or more impregnation steps comprising contacting the carbon support with a source of Group VIII metal and at least one metal selected from the group consisting of rhenium, tungsten and molybdenum being in at least one solution, (iii) after each impregnation step, drying at a temperature under about 150.degree. C. the impregnated carbon support to remove solvent, (iv) heating the impregnated carbon support at a temperature of about 100.degree. C. to about 350.degree. C. under reducing conditions.
摘要翻译：将马来酸，马来酸酐或其它可氢化的前体催化氢化成1,4-丁二醇和四氢呋喃。已经发现，当氢化催化剂包含至少一种元素周期表第VIII族的贵金属和碳载体上的铼，钨或钼中的至少一种时，可实现高收率的1,4-丁二醇，其中碳载体在金属沉积之前已经与氧化剂接触。该加氢催化剂是通过以下步骤制备的：（i）通过使碳载体与氧化剂接触来氧化碳载体，（ii）在一个或多个浸渍步骤中浸渍，包括使碳载体与VIII族金属源接触，选自铼，钨和钼中的至少一种金属在至少一种溶液中，（iii）在每个浸渍步骤之后，在约150℃的温度下干燥浸渍的碳载体以除去溶剂，（iv）在还原条件下，在约100℃至约350℃的温度下加热浸渍的碳载体。

10. 发明授权

US4473707A Oxidative dehydrogenation of carboxylic acids with mixed metal phosphorus oxide coated catalysts 失效
标题翻译：用混合金属磷氧化物涂覆的催化剂氧化脱氢羧酸
公开(公告)号：US4473707A
公开(公告)日：1984-09-25
申请号：US392497
申请日：1982-06-28
申请人： Harry H. I. Teng , S. Erik Pedersen
发明人： Harry H. I. Teng , S. Erik Pedersen
IPC分类号： B01J27/18 , C07C51/377 , C07C57/05
CPC分类号： B01J27/18 , C07C51/377
摘要： A process is provided for the preparation of coated iron phosphorus oxide containing catalysts useful in the oxydehydrogenation of saturated carboxylic acids, wherein the catalysts are prepared by partially wetting a carrier or support in an aqueous silica solution/suspension, contacting the partially wet carrier with a powder of the iron phosphorus oxide catalyst, drying and calcining.
摘要翻译：提供了一种制备用于饱和羧酸氧化脱氢的含有氧化磷的涂层的含氧化磷氧化物的方法，其中催化剂是通过在二氧化硅水溶液/悬浮液中部分润湿载体或载体而制备的，该部分湿载体与铁磷氧化物催化剂粉末，干燥和煅烧。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式