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    • 10. 发明授权
    • Fire-resistant polycarbonate resin composition
    • 耐火聚碳酸酯树脂组合物
    • US06602938B1
    • 2003-08-05
    • US09958630
    • 2001-10-11
    • Masatoshi IjiShin SerizawaSatoshi UmeyamaTadashi ShinomiyaIchiro Sato
    • Masatoshi IjiShin SerizawaSatoshi UmeyamaTadashi ShinomiyaIchiro Sato
    • C08L6900
    • C08L69/00C08L27/12C08L27/18C08L83/04C08L2666/02C08L83/00
    • This invention is a flame resistant polycarbonate resin composition characterized by blending 0.01-2 weight parts of a silicone compound (B)) wherein a main chain has a branch structure and having an aromatic group in an organic substituent, 0.01-2 weight parts of an alkali metal salt of an aromatic sulfonic acid (C) represented by the following general formula 1 (hereafter, referred to as general formula 1), and 0.05-5 weight parts of a fiber-forming fluorine-containing polymer (D), relative to 100 parts of a polycarbonate resin (A): General formula 1: Am—R—(SO3M)n (wherein, R is a phenyl group, naphthyl group, or a phenyl group or naphthyl group substituted by A, where A is at least one type of substituent chosen from a group comprising a halogen atom, alkyl group, aryl group, vinyl group, alkoxy group, amino group, methyl ester group and ethyl ester group, and M is an alkali metal. Also, when R is phenyl, m and n are respectively the integers 0-5 and 1-2 (m+n≦6), and when R is naphthyl, m and n are respectively the integers 0-7 and 1-2 (m+n≦8). The polycarbonate resin composition of this invention possesses superior flame resistance without losing shock resistance and moldability, and as it does not contain halogen fire retardants manufactured from chlorine and bromine compounds, there is no concern about generation of gases containing halogen from the fire retardant during combustion.
    • 本发明是一种阻燃聚碳酸酯树脂组合物,其特征在于将0.01-2重量份的有机化合物(B)的主链与有机取代基中具有芳基的主链相配合,将0.01-2重量份的 由以下通式1表示的芳香族磺​​酸(C)的碱金属盐(以下称为通式1),相对于纤维形成性含氟聚合物(D)为0.05〜5重量份 100份聚碳酸酯树脂(A):通式1:Am-R-(SO 3 M)n(其中,R为苯基,萘基或被A取代的苯基或萘基,其中A至少为 选自由卤素原子,烷基,芳基,乙烯基,烷氧基,氨基,甲基酯基和乙酯基组成的组中的一种取代基,M是碱金属,当R是苯基时, m和n分别为0-5和1-2的整数(m + n <= 6),当R为萘时 甲基,m和n分别为0-7和1-2的整数(m + n <= 8)。 本发明的聚碳酸酯树脂组合物具有优异的阻燃性,而不会失去抗冲击性和成型性,并且由于不含有由氯和溴化合物制成的卤素阻燃剂,所以不关心在燃烧期间来自阻燃剂的含卤素气体 。