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1. 发明授权

US4249938A N-Phenyl-N-methyl-urea derivatives, and their production and use 失效
标题翻译： N-苯基-N-甲基脲衍生物及其制备和使用
公开(公告)号：US4249938A
公开(公告)日：1981-02-10
申请号：US919683
申请日：1978-06-27
申请人： Ichiki Takemoto , Seizo Sumida , Ryo Yoshida , Katsuzo Kamoshita
发明人： Ichiki Takemoto , Seizo Sumida , Ryo Yoshida , Katsuzo Kamoshita
IPC分类号： A01N47/30 , C07C275/34 , C07C275/64 , C07C323/44 , A01N31/08 , C07C119/20 , C07C127/19
CPC分类号： A01N47/30 , C07C275/34 , C07C275/64 , C07C323/44
摘要： An N'-phenyl-N-methyl-urea derivative of the formula: ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are each hydrogen, lower alkyl, lower alkoxy, lower alkylthio, halogen or trifluoromethyl, R.sup.4 is hydrogen or lower alkyl, A is methyl or methoxy, X is oxygen or sulfur, Y is hydrogen or halogen, Z is a straight or branched alkylene chain having not more than 8 carbon atoms which may have no less than one atom of oxygen and/or sulfur inside and/or at the end of the alkylene chain and n is an integer of 1 to 3, which shows a pronounced herbicidal activity against a wide variety of weeds in the cultivation of crop plants without any material toxicity to mammals or fish or any chemical injury to said crop plants.
摘要翻译：其中R 1，R 2和R 3各自为氢，低级烷基，低级烷氧基，低级烷硫基，卤素或三氟甲基，R 4为氢或低级烷基，A为是甲基或甲氧基，X是氧或硫，Y是氢或卤素，Z是具有不超过8个碳原子的直链或支链亚烷基链，其可以具有不少于一个氧和/或硫原子的内部和/或在亚烷基链的末端，n是1至3的整数，其显示了对作物栽培中各种杂草的显着的除草活性，对哺乳动物或鱼没有任何物质毒性或对所述作物的任何化学损伤植物。

2. 发明授权

US4309212A Herbicidal compositions and methods employing urea derivatives 失效
标题翻译：使用尿素衍生物的除草组合物和方法
公开(公告)号：US4309212A
公开(公告)日：1982-01-05
申请号：US952775
申请日：1978-10-19
申请人： Ichiki Takemoto , Seizo Sumida , Ryo Yoshida , Katsuzo Kamoshita
发明人： Ichiki Takemoto , Seizo Sumida , Ryo Yoshida , Katsuzo Kamoshita
IPC分类号： A01N47/30 , C07C275/34 , C07C275/64
CPC分类号： C07C275/64 , A01N47/30 , C07C275/34
摘要： Novel N'-phenyl-N-methylurea derivatives of the formula: ##STR1## wherein R.sub.1 is a hydrogen atom, a methyl group or a methoxy group, R.sub.2 is a hydrogen atom or a lower alkyl group, R.sub.3, which may be the same or different, is a halogen atom, a lower alkyl group, a lower alkoxy group, a lower alkylthio group or a trifluoromethyl group, n is an integer of 0 to 5, X is a hydrogen atom or a halogen atom, Y is an oxygen atom or a sulfur atom and Z is a straight or branched C.sub.1 -C.sub.8 alkylene group which may have no less than one atom of oxygen and/or sulfur at the terminal of and/or inside the carbon chain, which shows a pronounced herbicidal activity against a wide variety of weeds in the cultivation of crop plants as well as a notable fungicidal activity against a wide variety of phytopathogenic fungi causing plant diseases to crop plants without any material toxicity to mammals and fish or any chemical injury to said crop plants.
摘要翻译：新颖的下式的N-苯基-N-甲基脲衍生物：其中R1是氢原子，甲基或甲氧基，R2是氢原子或低级烷基，R3可以相同或不同的是卤素原子，低级烷基，低级烷氧基，低级烷硫基或三氟甲基，n为0〜5的整数，X为氢原子或卤素原子，Y为氧原子或硫原子，Z是在碳链末端和/或内部可以具有不少于一个氧原子和/或硫原子的直链或支链C 1 -C 8亚烷基，其显示出明显的除草活性栽培作物的各种杂草以及针对各种植物病原真菌的显着的杀真菌活性，其对植物病害造成植物病害而对哺乳动物和鱼没有任何物质毒性或对所述作物的任何化学损伤。

3. 发明授权

US4690709A Urea derivatives, and their use as herbicides 失效
标题翻译：尿素衍生物及其作为除草剂的用途
公开(公告)号：US4690709A
公开(公告)日：1987-09-01
申请号：US203485
申请日：1980-11-03
申请人： Ichiki Takemoto , Seizo Sumida , Ryo Yoshida , Katsuzo Kamoshita
发明人： Ichiki Takemoto , Seizo Sumida , Ryo Yoshida , Katsuzo Kamoshita
IPC分类号： A01N47/30 , C07C275/34 , C07C275/64 , C07C127/19 , C07C119/00
CPC分类号： C07C275/64 , A01N47/30 , C07C275/34
摘要： Novel N'-phenyl-N-methylurea derivatives of the formula: ##STR1## wherein R.sub.1 is a hydrogen atom, a methyl group or a methoxy group, R.sub.2 is a hydrogen atom or a lower alkyl group, R.sub.3, which may be the same or different, is a halogen atom, a lower alkyl group, a lower alkoxy group, a lower alkylthio group or a trifluoromethyl group, n is an integer of 0 to 5, X is a hydrogen atom or a halogen atom, Y is an oxygen atom or a sulfur atom and Z is a straight or branched C.sub.1 -C.sub.8 alkylene group which may have no less than one atom of oxygen and/or sulfur at the terminal of and/or inside the carbon chain, which shows a pronounced herbicidal activity against a wide variety of weeds in the cultivation of crop plants as well as a notable fungicidal activity agaist a wide variety of phytopathogenic fungi causing plant diseases to crop plants without any material toxicity to mammals and fish or chemical injury to said crop plants.
摘要翻译：新颖的下式的N-苯基-N-甲基脲衍生物：其中R1是氢原子，甲基或甲氧基，R2是氢原子或低级烷基，R3可以相同或不同的是卤素原子，低级烷基，低级烷氧基，低级烷硫基或三氟甲基，n为0〜5的整数，X为氢原子或卤素原子，Y为氧原子或硫原子，Z是在碳链末端和/或内部可以具有不少于一个氧原子和/或硫原子的直链或支链C 1 -C 8亚烷基，其显示出明显的除草活性种植作物的各种杂草以及显着的杀真菌活性使各种植物病原真菌引起植物病害，对作物没有任何物质毒性，对所述作物的哺乳动物和鱼类或化学损伤没有任何物质毒性。

4. 发明授权

US4378992A Urea derivatives, and their production and use 失效
标题翻译：尿素衍生物及其生产和使用
公开(公告)号：US4378992A
公开(公告)日：1983-04-05
申请号：US114746
申请日：1980-01-24
申请人： Ryo Yoshida , Ichiki Takemoto , Seizo Sumida , Katsuzo Kamoshita
发明人： Ryo Yoshida , Ichiki Takemoto , Seizo Sumida , Katsuzo Kamoshita
IPC分类号： A01N47/30 , C07C67/00 , C07C205/37 , C07C205/38 , C07C217/84 , C07C217/86 , C07C217/88 , C07C239/00 , C07C265/12 , C07C275/34 , C07C275/64 , C07C313/00 , C07C319/20 , C07C323/36 , C07C323/44 , C07C69/76 , C07C127/19
CPC分类号： A01N47/30 , C07C205/37 , C07C205/38 , C07C217/84 , C07C217/86 , C07C217/88 , C07C265/12 , C07C275/34 , C07C275/64 , C07C323/36 , C07C2101/08 , C07C2101/14 , C07C2101/16 , C07C2102/10 , C07C2102/42 , C07C2103/68 , C07C2103/74
摘要： Novel N'-phenyl-N-methylurea derivatives of the formula: ##STR1## wherein R is a C.sub.4 -C.sub.10 cycloalkyl group, a C.sub.4 -C.sub.10 cycloalkenyl group, a C.sub.4 -C.sub.10 cycloalkyl group condensed with a benzene ring or substituted with at least one C.sub.1 -C.sub.4 alkyl group or a C.sub.4 -C.sub.10 cycloalkenyl group condensed with a benzene ring or substituted with a C.sub.1 -C.sub.4 alkyl group, Z is a C.sub.1 -C.sub.4 alkylene group which may have an atom of oxygen and/or sulfur at the terminal of and/or inside the carbon chain, Y is an oxygen atom or a sulfur atom, A is a hydrogen atom, a methyl group or a methoxy group and n is an integer of 0 or 1 with the proviso that in the chain consisting of --(Z).sub.n --Y--, oxygen and/or sulfur atoms can not be present in succession, which shows a pronounced herbicidal activity against a wide variety of weeds in the cultivation of crop plants without any material toxicity to mammals and any chemical injury to said crop plants.
摘要翻译：新的N-苯基-N-甲基脲衍生物，其分子式如下：其中R是C 4 -C 10环烷基，C 4 -C 10环烯基，与苯环稠合或至少被取代的C 4 -C 10环烷基一个C1-C4烷基或与苯环缩合或被C1-C4烷基取代的C4-C10环烯基，Z是可以在末端具有氧和/或硫原子的C1-C4亚烷基的碳链和/或内部，Y是氧原子或硫原子，A是氢原子，甲基或甲氧基，n是0或1的整数，条件是在由 - （Z）nY-，氧和/或硫原子不能连续地存在，其显示了在对作物植物的栽培中对各种杂草的显着的除草活性，而对哺乳动物没有任何物质毒性和对所述的作物植物。

5. 发明授权

US4427596A N-[2-(Cyclopropyl) ethoxy] phenylanilide derivatives, and their production and use 失效
标题翻译： N- [2-（环丙基）乙氧基]苯基苯胺衍生物及其制备和用途
公开(公告)号：US4427596A
公开(公告)日：1984-01-24
申请号：US243631
申请日：1981-03-13
申请人： Ichiki Takemoto , Katsuzo Kamoshita , Ryo Yoshida , Seizo Sumida
发明人： Ichiki Takemoto , Katsuzo Kamoshita , Ryo Yoshida , Seizo Sumida
IPC分类号： A01N37/24 , A01N47/30 , A01N53/00 , C07C67/00 , C07C205/37 , C07C239/00 , C07C275/34 , C07C131/105
CPC分类号： C07C205/37 , A01N37/24 , A01N47/30 , A01N53/00
摘要： A compound of the formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3, which may be same or different, are each hydrogen or C.sub.1 -C.sub.4 alkyl, X is chlorine or bromine, Y is hydrogen, chlorine, bromine, fluorine or iodine and Z is N,N-dimethylamino, N-methoxy-N-methylamino, C.sub.1 -C.sub.4 alkyl or C.sub.3 -C.sub.6 cycloalkyl, which is useful as a herbicide.
摘要翻译：下式的化合物：其中R 1，R 2和R 3可以相同或不同，各自为氢或C 1 -C 4烷基，X为氯或溴，Y为氢，氯，溴，氟或碘， Z是N，N-二甲基氨基，N-甲氧基-N-甲基氨基，C 1 -C 4烷基或C 3 -C 6环烷基，其可用作除草剂。

6. 发明授权

US4260411A N'-phenyl-N-methylurea derivatives 失效
标题翻译： N'-苯基-N-甲基脲衍生物
公开(公告)号：US4260411A
公开(公告)日：1981-04-07
申请号：US19613
申请日：1979-03-12
申请人： Ryo Yoshida , Ichiki Takemoto , Seizo Sumida , Katsuzo Kamoshita
发明人： Ryo Yoshida , Ichiki Takemoto , Seizo Sumida , Katsuzo Kamoshita
IPC分类号： A01N47/30 , C07C67/00 , C07C239/00 , C07C275/32 , C07C275/64 , C07C313/00 , C07C319/20 , C07C323/29 , C07C323/44 , C07D317/64 , C07C127/19
CPC分类号： A01N47/30 , C07C275/32 , C07C275/64 , C07C323/29 , C07D317/64
摘要： A compound of the formula: ##STR1## wherein A is a hydrogen atom, a methyl group or a methoxy group, Rs are same or different and each a halogen atom, a lower alkyl group, a lower alkoxy group, a lower alkylthio group, a trifluoromethyl group, a cyano group or a methylenedioxy group, X is a hydrogen atom or a halogen atom, Y is an oxygen atom or a sulfur atom, Z is a lower alkylene group and n is an integer of 0 to 3, provided that the substituted ureido group being present at the m- or p-position to the substituent represented by the symbol X and at the same time at the m- or p-position to the substituent represented by the symbol Z, which shows herbicidal and/or fungicidal activities and can be prepared, for instance, by reacting the corresponding phenyl isocyanate with a reagent of the formula: ##STR2## wherein A is as defined above.
摘要翻译：下式的化合物，其中A是氢原子，甲基或甲氧基，R 5相同或不同，卤素原子，低级烷基，低级烷氧基，低级烷硫基，三氟甲基，氰基或亚甲二氧基，X为氢原子或卤素原子，Y为氧原子或硫原子，Z为低级亚烷基，n为0〜3的整数，条件是取代的脲基存在于由符号X表示的取代基的m-位或对位上，并且在与由符号Z表示的取代基表示的取代基的m-位或对位的位置同时存在，和/或杀真菌活性，并且可以例如通过使相应的苯基异氰酸酯与下式的试剂反应来制备：其中A如上所定义。

7. 发明授权

US4437880A N'-Phenyl-N-methylurea derivatives 失效
标题翻译： N'-苯基-N-甲基脲衍生物
公开(公告)号：US4437880A
公开(公告)日：1984-03-20
申请号：US269851
申请日：1981-05-28
申请人： Junya Takahashi , Ichiki Takemoto , Katsuzo Kamoshita , Ryo Yoshida , Haruhiko Katoh , Seizo Sumida
发明人： Junya Takahashi , Ichiki Takemoto , Katsuzo Kamoshita , Ryo Yoshida , Haruhiko Katoh , Seizo Sumida
IPC分类号： A01N47/30 , C07C67/00 , C07C205/06 , C07C239/00 , C07C265/12 , C07C275/28 , C07C275/36 , C07C275/64 , C07C127/19
CPC分类号： C07C265/12 , A01N47/30 , C07C205/06 , C07C275/28 , C07C275/64
摘要： A compound of the formula: ##STR1## wherein R is a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group, X is a C.sub.3 -C.sub.4 alkylene group or a C.sub.3 alkenylene group, Y is a hydrogen atom or a chlorine atom, A is a methyl group or a methoxy group and the substituted ureido group is present at the m- or p-position to the group of the formula: ##STR2## which is useful as a herbicide.
摘要翻译：下式的化合物：其中R是氢原子或C1-C4烷基，X是C3-C4亚烷基或C3亚链烯基，Y是氢原子或氯原子，A是甲基或甲氧基，并且取代的脲基存在于下式的基团的对位或对位：，其可用作除草剂。

8. 发明授权

US4334912A Urea derivatives, and their production and use 失效
标题翻译：尿素衍生物及其生产和使用
公开(公告)号：US4334912A
公开(公告)日：1982-06-15
申请号：US129980
申请日：1980-03-12
申请人： Ryo Yoshida , Haruhiko Katoh , Seizo Sumida , Ichiki Takemoto , Junya Takahashi , Katsuzo Kamoshita
发明人： Ryo Yoshida , Haruhiko Katoh , Seizo Sumida , Ichiki Takemoto , Junya Takahashi , Katsuzo Kamoshita
IPC分类号： A01N47/36 , C07D213/64 , C07D213/643 , C07D213/70 , C07D213/73 , C07D213/75 , A01N43/40 , C07D213/62
CPC分类号： C07D213/643 , A01N47/36 , C07D213/70 , C07D213/73 , C07D213/75
摘要： A compound of the formula: ##STR1## wherein A is a hydrogen atom, a methyl group or a methoxy group, X is a straight or branched C.sub.1 -C.sub.4 alkylene chain, Y is an oxygen atom or a sulfur atom, R, which may be the same or different, is a lower alkyl group, a lower alkoxy group, a trifluoromethyl group, a chlorine atom, a bromine atom or a fluorine atom, m is an integer of 0 to 5 and n is an integer of 0 or 1, provided that in case of R being a fluorine atom, m is an integer of 0 to 5 and in case of R being other than a fluorine atom, m is an integer of 0 to 3, which shows a pronounced herbicidal activity against a wide variety of weeds in the cultivation of crop plants without any material toxicity to mammals and any chemical injury to said crop plants.
摘要翻译：下式的化合物：其中A是氢原子，甲基或甲氧基，X是直链或支链C 1 -C 4亚烷基链，Y是氧原子或硫原子，R可以是相同或不同，为低级烷基，低级烷氧基，三氟甲基，氯原子，溴原子或氟原子，m为0〜5的整数，n为0或1的整数条件是，在R为氟原子的情况下，m为0〜5的整数，在R为氟原子以外的情况下，m为0〜3的整数，表示对宽的显着的除草活性对种植作物的各种杂草，对哺乳动物没有任何物质毒性，对所述作物造成任何化学损伤。

9. 发明授权

US4129436A N'-[4-(substituted phenethyloxy)phenyl]-N-methyl-N-methoxyurea 失效
标题翻译： N {40- {8 4-（取代的苯乙氧基）苯基{9-N-甲基-N-甲氧基脲
公开(公告)号：US4129436A
公开(公告)日：1978-12-12
申请号：US882383
申请日：1978-03-01
申请人： Ichiki Takemoto , Ryo Yoshida , Seizo Sumida , Katsuzo Kamoshita
发明人： Ichiki Takemoto , Ryo Yoshida , Seizo Sumida , Katsuzo Kamoshita
IPC分类号： A01N47/28 , A01N47/30 , A01P13/00 , C07C67/00 , C07C239/00 , C07C275/34 , C07C275/64 , A01N9/20 , C07C69/76
CPC分类号： A01N47/30 , C07C275/64
摘要： An N'-[4-(substituted phenethyloxy)phenyl]-N-methyl-N-methoxyurea of the formula: ##STR1## wherein X.sub.1 is a hydrogen atom or a methyl group and X.sub.2 is a C.sub.1 -C.sub.5 alkyl or a C.sub.1 -C.sub.5 alkoxy group, which shows a pronounced herbicidal activity against a wide variety of weeds in the cultivation of soybean, peanut, cotton, corn, wheat or rice plants without any material toxicity to mammals, fishes and said crop plants.
摘要翻译：具有下式的N' - [4-（取代的苯乙氧基）苯基] -N-甲基-N-甲氧基脲其中X1是氢原子或甲基，X2是C1-C5烷基或C1- C5烷氧基，其对大豆，花生，棉花，玉米，小麦或水稻植物的种植中的各种杂草显示出显着的除草活性，对哺乳动物，鱼类和所述作物没有任何物质毒性。

10. 发明授权

US4123256A N-(4-substituted benzyloxy)phenyl)-N-methyl-N-methoxyurea 失效
标题翻译： N-（4-取代苄氧基）苯基）-N-甲基-N-甲氧基脲
公开(公告)号：US4123256A
公开(公告)日：1978-10-31
申请号：US835745
申请日：1977-09-22
申请人： Ryo Yoshida , Ichiki Takemoto , Seizo Sumida , Katsuzo Kamoshita
发明人： Ryo Yoshida , Ichiki Takemoto , Seizo Sumida , Katsuzo Kamoshita
IPC分类号： A01N47/30 , A01P13/00 , C07C67/00 , C07C239/00 , C07C275/34 , C07C275/64 , C07C69/76 , A01N9/20 , C07C121/75
CPC分类号： A01N47/30 , C07C275/64
摘要： An N-[4-(substituted benzyloxy)phenyl]-N'-methyl-N'-methoxyurea of the formula: ##STR1## wherein X, which may be the same or different, is halogen, nitro, cyano, trifluoromethyl, lower alkyl or lower alkoxy and n is an integer of 1 to 5, which shows a pronounced herbicidal activity against a wide variety of weeds in the cultivation of soybean, kidney bean, peanut, cotton or rice plants without any material toxicity to mammals and said crop plants.
摘要翻译：具有下式的N- [4-（取代的苄氧基）苯基] -N'-甲基-N'-甲氧基脲其中X可以相同或不同，为卤素，硝基，氰基，三氟甲基，低级烷基或低级烷氧基，n为1至5的整数，其对大豆，芸豆，花生，棉花或水稻植物的栽培中的各种杂草显示出显着的除草活性，而对哺乳动物和所述作物没有任何物质毒性植物。

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