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1. 发明授权

US5153339A Process for separation of naphthoquinone and phthalic acid 失效
标题翻译：分离萘醌和邻苯二甲酸的方法
公开(公告)号：US5153339A
公开(公告)日：1992-10-06
申请号：US392156
申请日：1982-06-25
申请人： Ryo Matsuura , Tatsuyoshi Komatsu , Kenji Usui , Toru Sato
发明人： Ryo Matsuura , Tatsuyoshi Komatsu , Kenji Usui , Toru Sato
IPC分类号： C07C27/26 , C07C27/00 , C07C45/00 , C07C46/10 , C07C50/12 , C07C51/00 , C07C51/48 , C07C63/16 , C07C67/00
CPC分类号： C07C46/10 , C07C51/48
摘要： Naphthoquinone having a purity of higher than 95% is separated from an aqueous slurry of naphthoquinone and phthalic acid prepared by contacting, with an aqueous medium, a reaction mixture gas containing naphthoquinone and phthalic anhydride formed by a catalytic vapor phase oxidation of naphthalene. An extraction of naphthoquinone is carried out with a chain or cyclic saturated hydrocarbon at 60.degree. to 110.degree. C. under the condition adjusting pH to 1.2 to 5 and substantially dissolving phthalic acid in the aqueous phase and leaving resinous materials as a bottom.
摘要翻译：通过使含有萘醌的反应混合物气体和通过萘的催化气相氧化形成的邻苯二甲酸酐与水性介质接触而制备的萘醌和邻苯二甲酸的水性浆液分离纯度高于95％的萘醌。在调节pH为1.2〜5，将邻苯二甲酸基本溶解在水相中并留下树脂状物质作为底部的状态下，用链状或环状的饱和烃在60〜110℃下进行萘醌的萃取。

2. 发明授权

US4202828A Process for separation of naphthoquinone and phthalic acid 失效
标题翻译：分离萘醌和邻苯二甲酸的方法
公开(公告)号：US4202828A
公开(公告)日：1980-05-13
申请号：US868349
申请日：1978-01-10
申请人： Ryo Matsuura , Tatsuyoshi Komatsu , Yukio Nomiyama , Kenji Usui
发明人： Ryo Matsuura , Tatsuyoshi Komatsu , Yukio Nomiyama , Kenji Usui
IPC分类号： C07C46/04 , C07C46/10 , C07C51/487 , C07C45/24 , C07C49/66 , C07C51/48 , C07C63/16
CPC分类号： C07C46/10 , C07C46/04 , C07C51/487
摘要： In a process for separation of naphthoquinone and phthalic acid from an aqueous slurry prepared by contacting a reaction mixture gas formed by a catalytic vapor phase oxidation of naphthalene with an aqueous medium, the decomposition of naphthoquinone is prevented and phthalic acid is substantially separated by adding a base to the aqueous slurry so as to neutralize only sulfuric acid component and maleic acid component without substantially neutralizing phthalic acid component and heating the aqueous slurry to dissolve phthalic acid to form a slurry of naphthoquinone in an aqueous solution of phthalic acid and extracting naphthoquinone with a solvent while preventing a crystallization of phthalic acid.A pH of the aqueous slurry is adjusted in a range of 1.2 to 2.5 before the heat dissolution of phthalic acid and the extraction of naphthoquinone.An aqueous phase obtained after the extraction of naphthoquinone is cooled to crystallize phthalic acid and then the filtrate separating from the resulting slurry is used as an aqueous medium for contacting with the reaction mixture gas, optionally after adjusting pH in a range of 1.2 to 2.5.
摘要翻译：在通过将通过萘的催化气相氧化形成的反应混合物气体与水性介质接触而制备的水性浆液分离萘醌和邻苯二甲酸的方法中，萘醌的分解被防止，邻苯二甲酸通过加入以仅中和硫酸成分和马来酸成分，而基本不中和邻苯二甲酸成分，加热含水浆料溶解邻苯二甲酸，形成萘醌在邻苯二甲酸水溶液中的浆液，并用萘磺酸提取萘醌溶剂，同时防止邻苯二甲酸的结晶。在邻苯二甲酸的热溶解和萘醌的萃取之前，将水性浆液的pH调节在1.2〜2.5的范围内。冷却萃取萘醌后得到的水相，使邻苯二甲酸结晶，然后将所得浆液分离出的滤液用作与反应混合物气体接触的水性介质，任选在将pH调节在1.2〜2.5的范围内后，

3. 发明授权

US4369140A Process for producing hydroanthraquinones 失效
标题翻译：生产氢蒽醌的方法
公开(公告)号：US4369140A
公开(公告)日：1983-01-18
申请号：US214784
申请日：1980-12-09
申请人： Tatsuyoshi Komatsu , Kenji Usui , Shigeaki Numata
发明人： Tatsuyoshi Komatsu , Kenji Usui , Shigeaki Numata
IPC分类号： C07C49/683 , C07C27/00 , C07C37/14 , C07C37/86 , C07C39/17 , C07C45/00 , C07C45/69 , C07C46/04 , C07C67/00 , C07C49/68
CPC分类号： C07C45/69 , C07C46/04
摘要： A hydroanthraquinone is produced from a reaction mixture obtained by the Diels-Alder reaction of naphthoquinone with a conjugated diolefin in an inert organic solvent. The reaction mixture in an inert organic solvent is oxidized with an oxidizing agent to decompose quinhydrone or quinhydrone derivative produced by said Diels-Alder reaction and the crystallized hydroanthraquinones are separated from said inert organic solvent.
摘要翻译：由在惰性有机溶剂中萘醌与共轭二烯烃的狄尔斯 - 阿尔德反应获得的反应混合物制备氢蒽醌。将惰性有机溶剂中的反应混合物用氧化剂氧化以分解由所述Diels-Alder反应产生的醌氢醌或醌氢醌衍生物，并将结晶的氢醌与所述惰性有机溶剂分离。

4. 发明授权

US4412954A Process for producing 1,4,4a,9a-tetrahydroanthraquinone compound 失效
标题翻译：制备1,4,4a，9a-四氢蒽醌化合物的方法
公开(公告)号：US4412954A
公开(公告)日：1983-11-01
申请号：US283174
申请日：1981-07-14
申请人： Tatsuyoshi Komatsu , Kenji Usui
发明人： Tatsuyoshi Komatsu , Kenji Usui
IPC分类号： C07C45/69 , C07C50/10
CPC分类号： C07C45/69
摘要： 1,4,4a,9a-Tetrahydroanthraquinone compounds are produced by Diels-Alder reaction of 1,4-naphthoquinone with a conjugated diolefin in the 1,4,4a,9a-tetrahydroanthraquinone compound as a reaction medium.
摘要翻译： 1,4,4a，9a-四氢蒽醌化合物通过在1,4,4a，9a-四氢蒽醌化合物中作为反应介质的1,4-萘醌与共轭二烯烃的Diels-Alder反应制备。

5. 发明授权

US4530745A Method for electrolyzing cerous sulfate 失效
标题翻译：电解硫酸铈的方法
公开(公告)号：US4530745A
公开(公告)日：1985-07-23
申请号：US620095
申请日：1984-06-13
申请人： Tatsuyoshi Komatsu , Shigeaki Numata , Katsuhiko Hioki , Toshihiko Sumino
发明人： Tatsuyoshi Komatsu , Shigeaki Numata , Katsuhiko Hioki , Toshihiko Sumino
IPC分类号： C07C45/28 , C07C46/04 , C25B1/00
CPC分类号： C07C45/28 , C07C46/04 , C25B1/00
摘要： A method for electrolyzing cerous sulfate in the electrolytic oxidation of cerous sulfate to ceric sulfate in an aqueous sulfuric acid solution, characterized in that the concentration of the cerous sulfate in the electrolyte to be supplied to the electrolytic cell is maintained, by the presence of ceric sulfate, at a level of at least the saturated concentration of cerous sulfate in the aqueous sulfuric acid solution (exclusive of the cerous sulfate and ceric sulfate) at the initial sulfuric acid concentration and at the temperature of electrolysis, and at most the saturated concentration of cerous sulfate in the presence of the ceric sulfate in the aqueous sulfuric acid solution at the initial sulfuric acid concentration and at the temperature of electrolysis, and the concentration of the ceric sulfate in the electrolyte is maintained at a level of at most the saturated concentration of ceric sulfate in the aqueous sulfuric acid solution at the initial sulfuric acid concentration and at the temperature of electrolysis.
摘要翻译：在硫酸水溶液中将硫酸铈电解氧化成硫酸铈的硫酸铈电解方法，其特征在于，通过存在铈离子保持供给到电解槽的电解质中的硫酸铈浓度硫酸盐，在初始硫酸浓度和电解温度下，至少在硫酸水溶液（不包括硫酸铈和硫酸铈）中的硫酸铈饱和浓度至少达到饱和浓度硫酸铈在硫酸水溶液存在下，在初始硫酸浓度和电解温度下，电解液中硫酸铈的浓度保持在最高饱和浓度硫酸铈在硫酸水溶液中的初始硫酸浓度和在电解温度下。

6. 发明授权

US4632782A Oxidizing an organic compound 失效
标题翻译：氧化有机化合物
公开(公告)号：US4632782A
公开(公告)日：1986-12-30
申请号：US603790
申请日：1984-04-25
申请人： Tatsuyoshi Komatsu , Shigeaki Numata , Katsuhiko Hioki , Toshihiko Sumino
发明人： Tatsuyoshi Komatsu , Shigeaki Numata , Katsuhiko Hioki , Toshihiko Sumino
IPC分类号： C07C50/12 , C07B31/00 , C07B33/00 , C07B41/06 , C07C45/00 , C07C45/28 , C07C45/29 , C07C46/04 , C07C50/08 , C07C67/00
CPC分类号： C07C46/04 , C07C50/12
摘要： A process for oxidizing an organic compound by ceric sulfate dissolved in an aqueous sulfuric acid solution, wherein the organic compound is oxidized (1) by means of a ceric sulfate-aqueous sulfuric acid solution or a cerous sulfate-containing ceric sulfate-aqueous sulfuric acid solution in which the molar concentration (mol/liter) of ceric sulfate is at least the molar concentration of cerium (ions) contained in the molecules of cerous sulfate at the maximum solubility of cerous sulfate in an aqueous sulfuric acid solution at the final sulfuric acid concentration (exclusive of ceric sulfate and cerous sulfate) and at the temperature under the oxidation reaction conditions and at most the saturated molar concentration of ceric sulfate in said aqueous sulfuric acid solution, (2) under a condition such that at the end of the oxidation reaction, the concentration of ceric sulfate is maintained at a level capable of dissolving cerous sulfate which is present at a concentration of at least the maximum solubility of cerous sulfate in said aqueous sulfuric acid solution.
摘要翻译：溶解在硫酸水溶液中的硫酸铈氧化有机化合物的方法，其中有机化合物通过硫酸铈 - 硫酸水溶液或含硫酸铈的硫酸铈 - 硫酸水溶液氧化（1）其中硫酸铈的摩尔浓度（mol / l）至少为硫酸铈分子中硫酸铈分子的最大溶解度在最终硫酸的硫酸水溶液中的摩尔浓度（摩尔/升）浓度（不包括硫酸铈和硫酸铈），并且在氧化反应条件下的温度和至多在所述硫酸水溶液中的硫酸铈的饱和摩尔浓度，（2）在氧化结束的条件下反应中，将硫酸铈的浓度维持在能够溶解至少浓度的硫酸铈的水平硫酸铈在所述硫酸水溶液中的最大溶解度。

7. 发明授权

US4450111A Process for the purification of anthraquinone 失效
标题翻译：净化蒽醌的方法
公开(公告)号：US4450111A
公开(公告)日：1984-05-22
申请号：US373106
申请日：1982-04-29
申请人： Tatsuyoshi Komatsu , Shigeaki Numata , Kazuhiro Maruyama
发明人： Tatsuyoshi Komatsu , Shigeaki Numata , Kazuhiro Maruyama
IPC分类号： C07C50/18 , C07C45/00 , C07C45/69 , C07C46/02 , C07C46/04 , C07C46/10 , C07C67/00 , C07C49/68
CPC分类号： C07C46/10 , C07C45/69 , C07C46/02 , C07C46/04
摘要： In a process for purifying crude anthraquinone obtained by the oxidation, by molecular oxygen in an aqueous alkali metal hydroxide solution, of an adduct obtained by the Diels-Alder reaction of butadiene with 1,4-naphthoquinone obtained by a catalytic vapor phase oxidation reaction of naphthalene, an improvement characterized in that said crude anthraquinone is subjected to oxidation treatment in an aqueous medium in the presence of a hypochlorite.
摘要翻译：在通过氧化获得的粗品蒽醌的纯化方法中，通过碱金属氢氧化物水溶液中的分子氧，通过丁二烯的Diels-Alder反应获得的加合物与通过催化气相氧化反应得到的1,4-萘醌萘，其特征在于所述粗制蒽醌在次氯酸盐存在下在水性介质中进行氧化处理。

8. 发明授权

US4536337A Process for the preparation of quinones 失效
标题翻译：醌类制备方法
公开(公告)号：US4536337A
公开(公告)日：1985-08-20
申请号：US596695
申请日：1984-04-04
申请人： Tatsuyoshi Komatsu , Shigeaki Numata , Toshihiko Sumino , Katsumi Matsuzaki , Masao Narita , Katsuhiko Hioki
发明人： Tatsuyoshi Komatsu , Shigeaki Numata , Toshihiko Sumino , Katsumi Matsuzaki , Masao Narita , Katsuhiko Hioki
IPC分类号： C07C46/04 , C07C51/16 , C07C50/02 , C07C50/10 , C07C50/16 , C07C50/22
CPC分类号： C07C46/04 , C07C51/16
摘要： A process for preparing a quinone, which comprises reacting a polynuclear aromatic hydrocarbon and a ceric salt in an aqueous acid solution in the presence of an organic solvent selected from the group consisting of chlorobenzene and an alkylbenzene represented by the general formula: ##STR1## where each of R.sub.1, R.sub.2 and R.sub.3 is an alkyl group and the total carbon number of the alkyl groups is from 3 to 6.
摘要翻译：一种制备醌的方法，其包括在选自氯苯和由以下通式表示的烷基苯的有机溶剂存在下，在酸性水溶液中使多核芳烃和铈盐反应： I），其中R1，R2和R3各自为烷基，烷基的总碳数为3至6。

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