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1. 发明授权

US5496958A Preparation of 5-vinylpyrrolidones 失效
标题翻译： 5-乙烯基吡咯烷酮的制备
公开(公告)号：US5496958A
公开(公告)日：1996-03-05
申请号：US266141
申请日：1994-06-27
申请人： Rolf Fischer , Werner Hoffmann , Ernst Langguth , Hardo Siegel
发明人： Rolf Fischer , Werner Hoffmann , Ernst Langguth , Hardo Siegel
IPC分类号： C07D207/26 , C07D207/267
CPC分类号： C07D207/267
摘要： A process for the preparation of a 5-vinylpyrrolidone of the formula ##STR1## wherein each of R.sup.1 and R.sup.2 is hydrogen or alkyl and R.sup.3 is preferably hydrogen but may further represent alkyl, cycloalkyl, aryl, alkylaryl, arylalkyl or a 5- to 6-membered aromatic or non-aromatic heterocyclic group containing 1 to 3 nitrogen atoms and/or an oxygen or sulfur atom, the process being carried out in two steps, first to react a 3-formylpropionic acid ester of the formula ##STR2## where each of R.sup.1 and R.sup.2 is hydrogen or C.sub.1 -C.sub.8 -alkyl, and R.sup.4 is hydrogen, alkyl, cycloalkyl, aryl, alkylaryl or arylalkyl, with a vinylymagnesium halide of the formulaCH.sub.2 .dbd.CH--Mg--X V,where X is chlorine, bromine or iodine, at a temperature of from -30.degree. to 100.degree. C., under a pressure from 0.001 to 10 bar and in a molar ratio of V:IV of from 0.3:1 to 3:1 to obtain as an intermediate product a gamma-vinylbutyrolactone of the formula ##STR3## where R.sup.1 and R.sup.2 have the abovementioned meaning; and then reacting said intermediate of the formula II with ammonia or a primary amine of the formulaR.sup.3 --NH.sub.2 III,where R.sup.3 has the abovementioned meaning, at a temperature of from 150.degree. to 350.degree. C. and under a pressure of from 0.1 to 200 bar.
摘要翻译：制备式I的5-乙烯基吡咯烷酮的方法，其中R1和R2各自为氢或烷基，R3优选为氢，但可进一步代表烷基，环烷基，芳基，烷基芳基，芳基烷基或5-至含有1至3个氮原子和/或氧或硫原子的6元芳族或非芳族杂环基，该方法分两个步骤进行，首先使式（IV）的3-甲酰基丙酸酯与式其中R1和R2各自为氢或C1-C8-烷基，R4为氢，烷基，环烷基，芳基，烷基芳基或芳基烷基，与式CH2 = CH-Mg-XV的卤化镁，其中X为氯，溴或碘，在-30℃至100℃的温度下，在0.001至10巴的压力下，V:IV的摩尔比为0.3:1至3:1，以获得中间体产生式为“IMAGE”II的γ-乙烯基丁内酯，其中R1和R2具有上述含义; 然后使式II的中间体与式（III-NH2）III的氨或伯胺反应，其中R 3具有上述含义，在150℃至350℃的温度和0.1至 200吧。

2. 发明授权

US5536854A Preparation of 2-methyl-1,4-butanediol and 3-methyltetrahydrofuran 失效
标题翻译：制备2-甲基-1,4-丁二醇和3-甲基四氢呋喃
公开(公告)号：US5536854A
公开(公告)日：1996-07-16
申请号：US380134
申请日：1995-01-26
申请人： Hans-Juergen Weyer , Rolf Fischer , Franz Merger , Juergen Frank , Jochem Henkelmann , Hardo Siegel , Thomas Ruehl
发明人： Hans-Juergen Weyer , Rolf Fischer , Franz Merger , Juergen Frank , Jochem Henkelmann , Hardo Siegel , Thomas Ruehl
IPC分类号： C07C29/141 , C07C29/149 , C07C29/17 , C07D307/06 , C07D307/08
CPC分类号： C07D307/06 , C07C29/141 , C07C29/149 , C07C29/177
摘要： 2-Methyl-1,4-butanediol and 3-methyltetrahydrofuran are prepared by reacting a compound of the general formula I or II ##STR1## where R.sup.1 and R.sup.2 are each hydrogen or C.sub.1 -C.sub.8 -alkyl and the formyl group of II may also be present as acetal with a C.sub.1 -C.sub.8 -alkanol, is reacted with hydrogen in the presence of copper or of a metal of groups 7 to 10 of the Periodical Table of elements or of a compound of these metals.
摘要翻译： 2-甲基-1,4-丁二醇和3-甲基四氢呋喃通过使通式I或II的化合物（其中R 1和R 2各自为氢或C 1 -C 8 - 烷基）和甲酰基 II族基团也可以与C 1 -C 8 - 链烷醇一起作为缩醛存在，在铜或金属元素周期表第7至10族的金属或这些金属的化合物的存在下与氢反应。

3. 发明授权

US4513150A Preparation of but-2-ene-1,4-diones substituted in the 1,4-positions 失效
标题翻译：在1,4-位上取代的丁-2-烯-1,4-二酮的制备
公开(公告)号：US4513150A
公开(公告)日：1985-04-23
申请号：US592908
申请日：1984-03-23
申请人： Rolf Fischer , Hans-Martin Weitz , Hardo Siegel
发明人： Rolf Fischer , Hans-Martin Weitz , Hardo Siegel
IPC分类号： C07C45/59
CPC分类号： C07C45/59
摘要： But-2-ene-1,4-diones substituted in the 1,4-positions, of the formula ##STR1## where R.sup.1 and R.sup.2 are each an aliphatic hydrocarbon radical of 1 to 17 carbon atoms, are prepared by a process in which a 2,5-disubstituted furan of the formula ##STR2## where R.sup.1 and R.sup.2 have the above meaning, is oxidized with a percarboxylic acid in the presence of a carboxylic acid.
摘要翻译：其中R1和R2各自为1至17个碳原子的脂族烃基的1,4-取代的1,4-取代的1,4-二酮，其通式为：其中R 1和R 2各自为1至17个碳原子的脂族烃基，其中R1和R2具有上述含义的式IIA的2,5-二取代的呋喃在羧酸的存在下被过羧酸氧化。

4. 发明授权

US06462220B1 Method for simultaneous preparation of 6-aminocapronitrile and hexamethylene diamine 有权
标题翻译：同时制备6-氨基己腈和六亚甲基二胺的方法
公开(公告)号：US06462220B1
公开(公告)日：2002-10-08
申请号：US09763710
申请日：2001-02-26
申请人： Hermann Luyken , Frank Ohlbach , Andreas Ansmann , Peter Bassler , Rolf Fischer , Johann-Peter Melder , Martin Merger , Alwin Rehfinger , Guido Voit , Günther Achhammer
发明人： Hermann Luyken , Frank Ohlbach , Andreas Ansmann , Peter Bassler , Rolf Fischer , Johann-Peter Melder , Martin Merger , Alwin Rehfinger , Guido Voit , Günther Achhammer
IPC分类号： C07C25525
CPC分类号： C07C253/30 , C07C209/48
摘要： A process for the coproduction of 6-aminocapronitrile and hexamethylenediamine starting from adiponitrile by a) hydrogenating adiponitrile in the presence of a catalyst comprising an element of the eighth transition group as catalytically active component, to obtain a mixture comprising 6-aminocapronitrile, hexamethylenediamine, adiponitrile and high boilers, b) distillatively removing hexamethylenediamine from the mixture comprising 6-aminocapronitrile, hexamethylenediamine, adiponitrile and high boilers, and either cl) distillatively removing 6-aminocapronitrile, and then d1) distillatively removing adiponitrile, or c2) simultaneously distillatively removing 6-aminocapronitrile and adiponitrile into separate fractions is characterized by base of column temperatures below 185° C. in steps d1) or c2).
摘要翻译：一种从己二腈开始共生产6-氨基己腈和六亚甲基二胺的方法，其中a）在包含第八过渡基团的元素的催化剂作为催化活性组分的存在下氢化己二腈，得到包含6-氨基己腈，己二胺，己二腈和高锅炉，b）从包含6-氨基己腈，己二胺，己二腈和高沸点的混合物中蒸馏除去六亚甲基二胺，并且将蒸馏除去6-氨基己腈，然后d1）蒸馏除去己二腈，或同时蒸馏除去6-氨基己腈和己二腈分离的馏分以步骤d1）或c2）中塔温度低于185℃的碱为特征。

5. 发明授权

US06429339B1 Method for producing cyclopentanone 失效
标题翻译：环戊酮生产方法
公开(公告)号：US06429339B1
公开(公告)日：2002-08-06
申请号：US09700365
申请日：2000-11-15
申请人： Shelue Liang , Rolf Fischer , Frank Stein , Joachim Wulff-Döring
发明人： Shelue Liang , Rolf Fischer , Frank Stein , Joachim Wulff-Döring
IPC分类号： C07C4500
CPC分类号： B01J23/10 , C07C45/48 , C07C49/395
摘要： A process for preparing cyclopentanone by reacting adipic esters of the formula R1OOC—(CH2)4—COOR2 I where R1 and R2 are each alkyl having from 1 to 12 carbon atoms, cycloalkyl having 5 or 6 carbon atoms, aralkyl or aryl and R2 may additionally be hydrogen, in the presence of oxidic catalysts comprises reacting adipic esters of the formula I having less than 5% by weight of by-products other than adipic esters in the gas phase in the presence of water, a carrier gas and a) from 0.01 to 10% by weight of at least one metal oxide selected from the first or second main group of the periodic table or from the group of the rare earth metals on titanium dioxide or zirconium dioxide as catalyst support, or b) from 0.01 to 50% by weight of at least one metal oxide selected from the second main group of the periodic table on zink oxide as catalyst support.
摘要翻译：通过使式R 1和R 2的己二酸酯反应制备环戊酮的方法各自是在氧化催化剂存在的情况下，可以另外为氢，其中R 1和R 2各自为具有1至12个碳原子的烷基，具有5或6个碳原子的环烷基或芳基，包括使式I的己二酸酯在水，载气的存在下，在气相中具有小于5重量％的除己二酸酯之外的副产物，和（ii）0.01至10重量％的至少一种金属氧化物，其选自周期表的第一或第二主族，或者来自稀土金属的二氧化钛或二氧化锆的组，作为催化剂载体，orb）为0.01至50重量％的至少一种选自氧化锌作为催化剂载体的周期表第二主要组。

6. 发明授权

US06362332B1 Coproduction of a cyclic lactam and a cyclic amine 失效
标题翻译：环内酰胺和环胺的共同生产
公开(公告)号：US06362332B1
公开(公告)日：2002-03-26
申请号：US09786914
申请日：2001-03-12
申请人： Martin Merger , Rolf Fischer , Andreas Ansmann
发明人： Martin Merger , Rolf Fischer , Andreas Ansmann
IPC分类号： C07D22310
CPC分类号： C07D201/02 , C07D295/023
摘要： A cyclic lactam and a cyclic amine are coproduced by reacting an aliphatic alpha, omega-diamine with water in the gas phase in the presence of a heterogeneous catalyst.
摘要翻译：在非均相催化剂存在下，通过在气相中使脂族α，ω-二胺与水反应来共同制备环状内酰胺和环胺。

7. 发明授权

US06297394B1 Iron-based catalyst for hydrogenating alpha-, omega-dinitriles 有权
标题翻译：用于氢化α-，ω-二腈的铁基催化剂
公开(公告)号：US06297394B1
公开(公告)日：2001-10-02
申请号：US09622773
申请日：2000-08-23
申请人： Guido Voit , Rolf Fischer , Peter Bassler , Andreas Ansmann , Hermann Luyken , Martin Merger , Frank Ohlbach , Alwin Rehfinger
发明人： Guido Voit , Rolf Fischer , Peter Bassler , Andreas Ansmann , Hermann Luyken , Martin Merger , Frank Ohlbach , Alwin Rehfinger
IPC分类号： C07C20922
CPC分类号： C07C253/30 , B01J23/8892 , C07C209/48 , C07C211/12 , C07C255/24
摘要： A material useful as catalyst for the hydrogenation of alpha, Omega-dinitriles comprises a) iron or a compound based on iron or mixtures thereof, (b) from 0.001 to 0.3% by weight based on (a) of a promoter based on 2, 3, 4 or 5 elements selected from the group consisting of aluminum, silicon, zirconium, titanium and vanadium, (c) from 0 to 0.3% by weight based on (a) of a compound based on an alkali and/or alkaline earth metal, and also (d) from 0.001 to 1% by weight based on (a) of manganese.
摘要翻译：可用作α，ω-二腈的氢化催化剂的材料包括a）铁或基于铁或其混合物的化合物，（b）基于（a）基于2,3的启动子的0.001至0.3重量％，选自铝，硅，锆，钛和钒的4或5种元素，（c）基于（a）基于碱金属和/或碱土金属的化合物，0至0.3重量％以及（d）基于（a）锰的0.001至1重量％。

8. 发明授权

US06222059B1 Process for the manufacture of aliphatic alpha, omega amino nitriles 有权
标题翻译：用于制造脂肪族α，ω-氨基腈的方法
公开(公告)号：US06222059B1
公开(公告)日：2001-04-24
申请号：US09254570
申请日：1999-03-10
申请人： Klaus Ebel , Rolf Fischer , Klemens Flick , Martin Merger , Guido Voit
发明人： Klaus Ebel , Rolf Fischer , Klemens Flick , Martin Merger , Guido Voit
IPC分类号： C07C25504
CPC分类号： C07C255/24 , C07C209/48 , C07C211/12 , C07C253/30
摘要： A process for preparing aliphatic alpha,omega-amino nitrites by partial hydrogenation of aliphatic alpha,omega-dinitriles in the presence of a catalyst, wherein the catalyst used for the partial hydrogenation comprises (a) iron or a compound based on iron or mixtures thereof and (b) from 0.01 to 5% by weight, based on (a), of a promoter based on 2,3,4 or 5 elements selected from the group consisting of aluminum, silicon, zirconium, titanium and vanadium and (c) from 0 to 5% by weight, based on (a), of a compound based on an alkali metal or alkaline earth metal.
摘要翻译：在催化剂存在下通过部分氢化脂族α，ω-二腈制备脂族α，ω-氨基亚硝酸盐的方法，其中用于部分氢化的催化剂包括（a）铁或基于铁或其混合物的化合物和（b）基于（a）0.01至5重量％的基于2,3,4或5个选自铝，硅，锆，钛和钒的元素的促进剂，和（c）基于（a）的0至5重量％的基于碱金属或碱土金属的化合物。

9. 发明授权

US6111147A Process for preparing polytetrahydrofuran and derivatives thereof 失效
标题翻译：制备聚四氢呋喃及其衍生物的方法
公开(公告)号：US6111147A
公开(公告)日：2000-08-29
申请号：US269210
申请日：1999-04-01
申请人： Christoph Sigwart , Karsten Eller , Rainer Becker , Klaus-Dieter Plitzko , Rolf Fischer , Frank Stein , Ulrich Mueller , Michael Hesse
发明人： Christoph Sigwart , Karsten Eller , Rainer Becker , Klaus-Dieter Plitzko , Rolf Fischer , Frank Stein , Ulrich Mueller , Michael Hesse
IPC分类号： C08G65/10 , C08G18/48 , C08G65/20 , C08G65/28 , C07C43/10 , C07C43/11 , C07C67/24 , C07C69/76
CPC分类号： C08G65/20 , C08G18/4854
摘要： Polytetrahydrofuran, copolymers of tetrahydrofuran and 2-butyne-1,4-diol, diesters of these polymers with C.sub.2 -C.sub.20 -monocarboxylic acids or monoesters of these polymers with C.sub.1 -C.sub.10 -monocarboxylic acids are prepared by polymerization of tetrahydrofuran in the presence of one of the telogens water, 1,4-butanediol, 2-butyne-1,4-diol, polytetrahydrofuran having a molecular weight of from 200 to 700 Dalton, a C.sub.1 -C.sub.10 -monocarboxylic acid or an anhydride of a C.sub.2 -C.sub.20 -monocarboxylic acid or a mixture of these telogens over a heterogeneous supported catalyst which comprises a catalytically active amount of an oxygen-containing molybdenum and/or tungsten compound on an oxidic support material and which has been calcined at from 5OO.degree. C. to 1OOO.degree. C. after application of the precursor compounds of the oxygen-containing molybdenum and/or tungsten compounds onto the support material precursor, wherein the catalyst is activated by treatment with a reducing agent before it is used as a polymerization catalyst.
摘要翻译： PCT No.PCT / EP97 / 05204 Sec。 371日期1999年4月1日 102（e）1999年4月1日PCT PCT 1997年9月23日PCT公布。第WO98 / 15589号公报日期：1998年4月16日四氢呋喃，四氢呋喃和2-丁炔-1,4-二醇的共聚物，这些聚合物与C2-C20-一元羧酸的二酯或这些聚合物与C1-C10-一元羧酸的单酯通过四氢呋喃在其中一种使用水，1,4-丁二醇，2-丁炔-1,4-二醇，分子量为200-700道尔顿的聚四氢呋喃，C1-C10-一元羧酸或 C2-C20-一元羧酸或这些方法的混合物在非均相载体催化剂上的混合物，其包含在氧化载体材料上的催化活性量的含氧钼和/或钨化合物，并且已经在500℃煅烧将含氧钼和/或钨化合物的前体化合物施加到载体材料前体上之后，至1000℃，其中催化剂在用作还原剂之前通过用还原剂进行活化聚合催化剂。

10. 发明授权

US5977417A Preparation of 1,4-butanediol 失效
公开(公告)号：US5977417A
公开(公告)日：1999-11-02
申请号：US192484
申请日：1998-11-17
申请人： Rolf Fischer , Christoph Sigwart
发明人： Rolf Fischer , Christoph Sigwart
IPC分类号： B01J23/04 , B01J23/06 , B01J23/28 , B01J23/32 , B01J23/38 , B01J23/46 , B01J23/656 , B01J23/70 , B01J23/72 , B01J23/88 , B01J25/00 , B01J25/02 , B01J27/16 , C07B61/00 , C07C29/132 , C07C31/20 , C07C27/00
CPC分类号： C07C29/132 , C07C31/20
摘要： 1,4-Butanediol is prepared by a process which comprises converting 1,3-butadiene diepoxide in the presence of hydrogen over a hydrogenation catalyst whose active component is not elemental Pd and/or Pt. The hydrogenation catalyst preferably contains at least one element from the group Ib, VIIb or VIIIb of the Periodic Table of Elements.

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