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    • 1. 发明授权
    • Method for defoaming aqueous dispersions of polymeric organic substances
by addition of polyoxyalkylene-polysiloxane block copolymers
    • 通过加入聚氧化烯 - 聚硅氧烷嵌段共聚物来消泡聚合有机物的水分散体的方法
    • US5032662A
    • 1991-07-16
    • US309314
    • 1989-02-10
    • Roland BergerHans-Ferdi FinkOtto KlockerRoland Sucker
    • Roland BergerHans-Ferdi FinkOtto KlockerRoland Sucker
    • B01D19/04C08G77/46C09D5/02C09D7/12
    • C09D5/024B01D19/0409C08G77/46
    • Polyoxyalkylene-polysiloxane block copolymers are disclosed which exhibit an outstanding defoaming action and have the special advantage of not causing wetting defects when dispersions defoamed therewith are applied on a 2-dimensional substrate. Dispersions of polymeric organic substances, especially dispersions of vehicles, coating agents and adhesives are defoamed by the addition of 0.01 to 2.0% by weight, based on the dispersion to be defoamed, of a polyoxyalkylene-polysiloxane block copolymer of the formula,R.sup.1 O--A--[B--A--].sub.m R.sup.1whereinA is a polyoxyalkylene block with the average formula C.sub.n H.sub.2n O--)y, in which n has a value of 2.8 to 4.0 and y a value of 15 to 100,B is a polysiloxane block of the average formula, ##STR1## wherein the R.sup.2 groups are the same or different and represent an alkyl group with 1 to 4 carbon atoms or a phenyl group, with the proviso that at least 90% of the R.sup.2 groups are methyl groups and x has a value of 10 to 100,R.sup.1 groups are the same or different and represent a hydrogen atom or an alkyl group with 1 to 4 carbon atoms andm has a value of 4 to 20.
    • 公开了具有优异的消泡作用的聚氧化烯 - 聚硅氧烷嵌段共聚物,并且具有在将其消泡的分散体施加在二维基材上时不会引起润湿缺陷的特殊优点。 聚合有机物质,特别是车辆分散体,涂层剂和粘合剂的分散体通过加入基于待消泡的分散体的0.01-2.0重量%的下式的聚氧化烯 - 聚硅氧烷嵌段共聚物,即R1O-A - [BA-] mR1其中A是平均式C n H 2n O - )y的聚氧化烯嵌段,其中n的值为2.8〜4.0,ya为15〜100,B为平均式的聚硅氧烷嵌段, IMAGE>其中R2基团相同或不同并且表示具有1至4个碳原子的烷基或苯基,条件是至少90%的R 2基团是甲基,x的值为10至 100,R 1相同或不同,表示氢原子或碳原子数为1〜4的烷基,m为4〜20的数。