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1. 发明授权

US4886551A Method for improving the scratch resistance and increasing the sliding ability of coated surfaces and improved coating materials 失效
标题翻译：提高耐刮擦性和提高涂层表面和改进涂料的滑动能力的方法
公开(公告)号：US4886551A
公开(公告)日：1989-12-12
申请号：US106560
申请日：1987-10-06
申请人： Hans-Ferdi Fink , Roland Berger , Wernfried Heilen , Peter Muss
发明人： Hans-Ferdi Fink , Roland Berger , Wernfried Heilen , Peter Muss
IPC分类号： C09D7/12
CPC分类号： C09D7/125 , C08L83/12
摘要： Compounds of the general formula ##STR1## wherein R.sup.1 is alkyl with 1 to 8 carbon atoms,R.sup.2 is --O-- or --(CH.sub.2).sub.p O--, in which p=2, 3 or 4,R.sup.3 is hydrogen, alkyl with 1 to 4 carbon atoms or acyl,n is 40 to 60m is 0 to 3,x and y being selected so that the molecular weight of the polyoxyalkylene block is 1400 to 3000 and the molar ratio of x:y is 0.8 to 2.2, are added to coating compositions, such as paint, varnish or lacquer, in amounts of 0.001 to 0.5% by weight, based on the coating composition. This improves the scratch resistance and the sliding ability of the cured coatings.
摘要翻译：其中R1是具有1-8个碳原子的烷基，R2是-O-或 - （CH2）pO-，其中p = 2,3或4，R3是氢具有1至4个碳原子的烷基或酰基，n为40至60μm为0至3，选择x和y，使得聚氧化烯嵌段的分子量为1400至3000，x：y的摩尔比为0.8 至2.2，以涂料组合物计，其量为0.001至0.5重量％，添加到涂料组合物中，如油漆，清漆或漆。这提高了耐擦伤性和固化涂层的滑动能力。

2. 发明授权

US4804737A Siloxanes, their synthesis and use as deaerating agents for curable resins of plastisols 失效
标题翻译：硅氧烷，它们的合成和用作增塑溶胶的可固化树脂的脱气剂
公开(公告)号：US4804737A
公开(公告)日：1989-02-14
申请号：US72880
申请日：1987-07-14
申请人： Roland Berger , Hans-Ferdi Fink , Otto Klocker
发明人： Roland Berger , Hans-Ferdi Fink , Otto Klocker
IPC分类号： B01D19/04 , C08G77/38 , C08L101/00 , C08G77/04
CPC分类号： C08G77/38 , B01D19/0409 , C08L101/00 , Y10S516/06
摘要： Alkoxysiloxanes of the general formula ##STR1## are disclosed wherein R.sup.1 is methyl or ##STR2## and/or ##STR3## the sum of the units a being 0 to 100, the sum of the units b being 0 to 15, with the proviso that the ratio of methyl to alkoxy groups in R.sup.1 is less than 50:1, and that b.gtoreq.1 when a=0 and a.gtoreq.5 when b=0.The compounds may be synthesized by known methods from halogen- or alkoxysiloxanes, the alkoxy group of which has 1 to 4 carbon atoms. The compounds are effective deaerating agents for curable resins and plastisols. The invention is also directed to compositions containing the novel deaerating compounds as well as to methods for deaerating coating systems.
摘要翻译：公开了通式为“IMAGE”的烷氧基硅氧烷，其中R1是甲基或/或<或者<或者>单位a的总和为0至100，单元b的总和为0至15，条件是 R1中的甲基与烷氧基的比例小于50:1，当b = 0时，当a = 0且a> 5时，b> / = 1。化合物可以通过已知的方法由卤代或烷氧基硅氧烷合成，其烷氧基具有1至4个碳原子。这些化合物是可固化树脂和增塑溶胶的有效脱气剂。本发明还涉及含有新型脱气化合物的组合物以及用于脱气涂料体系的方法。

3. 发明授权

US4621521A Apparatus for determining foam formation of crude petroleum 失效
标题翻译：用于测定原油的泡沫形成的装置
公开(公告)号：US4621521A
公开(公告)日：1986-11-11
申请号：US704372
申请日：1985-02-22
申请人： Horst Lattek , Hans-Ferdi Fink , Gotz Koerner
发明人： Horst Lattek , Hans-Ferdi Fink , Gotz Koerner
IPC分类号： G01N7/14 , G01N13/00 , G01N13/02 , G01N33/28
CPC分类号： G01N7/14 , G01N13/00 , G01N2013/025
摘要： An apparatus for simulating the actual conditions of foam formation during crude oil production includes a transparent cylindrical measuring vessel having a circumferential flange formed at its open top. A ring-shaped member is seated on the flange and defines a chamber in communication with the measuring vessel. The ring-shaped member and the measuring vessel are connected in a gas-tight manner. A supply line for the liquid to be dissolved or distributed in the crude oil sample and a discharge line for the liquid evaporating under measurement conditions open into the chamber. The supply line is connected to a supply reservoir via a metering valve for the liquid. A stop valve is provided in the discharge line.
摘要翻译：用于模拟原油生产期间泡沫形成的实际条件的装置包括透明圆柱形测量容器，其具有在其开口顶部形成的圆周凸缘。环形构件位于凸缘上并且限定与测量容器连通的腔室。环形构件和测量容器以气密方式连接。用于溶解或分布在原油样品中的液体的供应管线和用于在测量条件下蒸发的液体的排出管线进入室中。供应管线通过用于液体的计量阀连接到供应储存器。排气管中设有截止阀。

4. 发明授权

US4380503A Process for preparing oil-in-water emulsion 失效
标题翻译：水包油乳液的制备方法
公开(公告)号：US4380503A
公开(公告)日：1983-04-19
申请号：US269844
申请日：1981-06-03
申请人： Gotz Koerner , Gerd Sanger , Hans-Ferdi Fink , Friedhelm Grassmann
发明人： Gotz Koerner , Gerd Sanger , Hans-Ferdi Fink , Friedhelm Grassmann
IPC分类号： B01F3/08 , B01F5/06 , B01F13/10 , B01F17/00 , C10L1/32 , B01J13/00
CPC分类号： B01F17/0028 , B01F3/0811 , B01F3/0853 , B01F5/0682 , B01F5/0688 , C10L1/328 , B01F2013/1052 , Y10S516/926
摘要： The invention relates to a process for the preparation of fine-particulate, stable emulsions of the oil-in-water type, in which the quantity of emulsifier required to achieve a stable emulsion is distributed in about 0.5 to 3 times the amount of water by weight, based upon the weight of the emulsifier, the emulsifying amount of the oleic phase is introduced into the foregoing dispersion, homogenization is performed under the effect of high shear stresses until a uniform gel is obtained, the gel so obtained is forced through a slotted disk comprising a plurality of holes less than 10 mm in diameter and into the residual amount of water, and the emulsion so generated is stirred while avoiding high shear stresses until the gel particles are completely dissolved. The process makes it possible to obtain fine-particulate, storage-stable and dilutable oil-in-water emulsions using only very small quantities of emulsifier.
摘要翻译：本发明涉及一种制备水包油型细颗粒稳定乳液的方法，其中达到稳定乳液所需的乳化剂的量分布在水的约0.5至3倍的水中重量，基于乳化剂的重量，将油相的乳化量引入到上述分散体中，在高剪切应力的作用下进行均化，直到获得均匀的凝胶，所得到的凝胶被迫穿过开槽圆盘包括直径小于10mm的多个孔和剩余量的水，并且如此产生的乳液在避免高剪切应力的同时被搅拌，直到凝胶颗粒完全溶解。该方法使得仅使用非常少量的乳化剂可以获得细颗粒，储存稳定和可稀释的水包油乳液。

5. 发明授权

US4028218A Defoaming composition and method of defoaming aqueous solutions or dispersions 失效
标题翻译：消泡组合物和消泡水溶液或分散体的方法
公开(公告)号：US4028218A
公开(公告)日：1977-06-07
申请号：US515847
申请日：1974-10-18
申请人： Hans-Ferdi Fink , Herwig Fritsch , Gotz Koerner , Gerd Rossmy , Gunter Schmidt
发明人： Hans-Ferdi Fink , Herwig Fritsch , Gotz Koerner , Gerd Rossmy , Gunter Schmidt
IPC分类号： B01D19/04 , C08K3/22 , C08K3/36 , C08L83/12 , C12M1/21 , D01F2/08
CPC分类号： C08L83/12 , B01D19/0409 , C08K3/22 , C08K3/36 , D06L3/085 , D06P1/5292 , Y10S8/01
摘要： In the disclosed method of preventing the formation of foam and destroying existing foam in an aqueous solution or dispersion, an effective amount of a composition comprising about 0.2 to 7.5 percent by weight of highly disperse silica or alumina with the balance being methylpolysiloxanepolyoxyalkylene mixed block polymer consisting essentially ofA. about 10-60 percent by weight of methylpolysiloxane;B. with the balance polyoxyalkylene, > 80-100 percent by weight of the polyoxyalkylene block consisting of oxypropylene units,Is added to the solution or dispersion.The application also discloses defoaming preparations or compositions of finely disperse silica or alumina and methylpolysiloxane-polyoxyalkylene mixed block polymer which may be diluted in oily substances. The preparation may optionally comprise non-ionogenic emulsifier of an HLB value of 8 to 14.
摘要翻译：在所公开的防止泡沫形成和破坏现有泡沫在水溶液或分散体中的方法中，有效量的组合物包括约0.2-7.5重量％的高分散二氧化硅或氧化铝，余量为甲基聚硅氧烷聚氧化烯混合嵌段聚合物，基本上是A.约10-60％甲基纤维素的重量百分比; B.以平衡阳离子聚氧乙烯计，聚丙烯单体聚氧乙烯嵌段的重量百分比> 80-100％，加入到溶液或分散液中。

6. 发明授权

US4692267A Use of polymers of alkylvinyl ethers to prevent or eliminate foam on aqueous media 失效
标题翻译：使用烷基乙烯基醚的聚合物来防止或消除含水介质上的泡沫
公开(公告)号：US4692267A
公开(公告)日：1987-09-08
申请号：US797637
申请日：1985-11-13
申请人： Jurgen Fock , Eberhard Esselborn , Hans-Ferdi Fink , Wernfried Heilen
发明人： Jurgen Fock , Eberhard Esselborn , Hans-Ferdi Fink , Wernfried Heilen
IPC分类号： B01D19/04 , C09K3/00
CPC分类号： B01D19/0404
摘要： Method of using polymers of alkylvinyl ethers whose alkyl radical has 2 to 18 carbon atoms with a weight average molecular weight M.sub.w of 400 to 10,000 in amounts of 1 to 200 ppm for preventing or eliminating foam on aqueous media.
摘要翻译：使用烷基乙烯基醚的聚合物的方法，其烷基乙烯基醚的烷基具有2至18个碳原子，重均分子量＆Upbar＆Mw为400至10,000，其量为1至200ppm，用于防止或消除含水介质上的泡沫。

7. 发明授权

US4564665A Oil gas separation 失效
标题翻译：油气分离
公开(公告)号：US4564665A
公开(公告)日：1986-01-14
申请号：US482202
申请日：1983-04-05
申请人： Ian C. Callaghan , Hans-Ferdi Fink , Clive M. Gould , Gotz Koerner , Hans-Jurgen Patzke , Christian Weitemeyer
发明人： Ian C. Callaghan , Hans-Ferdi Fink , Clive M. Gould , Gotz Koerner , Hans-Jurgen Patzke , Christian Weitemeyer
IPC分类号： B01D19/00 , B01D19/04 , C08G77/00 , C08G77/04 , C10G29/20 , C08G77/06
CPC分类号： B01D19/0005 , B01D19/0409
摘要： Polysiloxanes of specified molecular weight and molecular weight distribution are effective anti-foam agents for reducing foaming in crude oil/gas separators. They are particularly useful in breaking microgas dispersions.The polysiloxanes, preferably polydimethyl siloxane, contain not more than 10% by weight of components of molecular weight 50,000 and lower, at least 15% by weight of components of molecular weight 200,000 and higher and not more than 6% by weight of components of molecular weight 370,000 and higher, molecular weights being expressed as polystyrene equivalent molecular weights.
摘要翻译：具有特定分子量和分子量分布的聚硅氧烷是有效的消泡剂，用于减少原油/气体分离器中的起泡。它们特别适用于破碎微气体分散体。聚硅氧烷（优选聚二甲基硅氧烷）含有不超过10重量％的分子量为50,000以下的组分，至少15重量％的分子量为20万分率以上且不超过6重量％的分子组分重量370,000和更高，分子量表示为聚苯乙烯当量分子量。

8. 发明授权

US4447498A Use of organopolysiloxanes in the manufacture of paper-coated plaster boards 失效
标题翻译：使用有机聚硅氧烷制造纸质石膏板
公开(公告)号：US4447498A
公开(公告)日：1984-05-08
申请号：US445682
申请日：1982-12-01
申请人： Hans-Ferdi Fink , Gotz Koerner , Edmund Luksch
发明人： Hans-Ferdi Fink , Gotz Koerner , Edmund Luksch
IPC分类号： B32B13/08 , C08G77/26 , D21H17/59 , B32B15/12 , B32B31/12
CPC分类号： C08G77/26 , B32B13/08 , D21H17/59 , Y10T428/31663 , Y10T428/31996
摘要： Use of an organopolysiloxane having the formula ##STR1## in which R.sup.1 is an alkyl or aryl radical, at least 80% of the R.sup.1 radicals being alkyl radicals,R.sup.2 is an alkyl radical or the R.sup.4 Z radical, at least 2/3 of the R.sup.2 radicals being R.sup.4 Z radicals, in whichR.sup.4 is a difunctional hydrocarbon radical,Z is --NH.sub.2, --NH(CH.sub.2).sub.c --NH.sub.2, --NH(CH.sub.2).sub.c NH(CH.sub.2).sub.c NH.sub.2, in which c is 2, 3, --NHCONH.sub.2 radical, --SH, --S.sub.4 --R.sup.4 --Si(OR.sup.3).sub.3, --P(C.sub.6 H.sub.5).sub.2 or ##STR2## R.sup.3 is an alkyl radical with 1 to 4 carbon atoms, or a hydrogen radical,a is not less than 4,b/a is not less than 0.001, but not greater than 0.5, andx is not less than 0.1, but not greater than 2,as a material for decreasing the water absorption of paper which is intended to be used for coating plaster paste in the manufacture of paper-laminated plaster boards. The organosilicon compounds cure without the use of special catalysts. Their aqueous preparations exhibit high stability at use concentrations and are independent of the pH of the paper. The water absorption of papers which are free of aluminum sulfate can also be reduced.
摘要翻译：使用具有式“IMAGE”的有机聚硅氧烷，其中R 1是烷基或芳基，至少80％的R 1基团是烷基，R 2是烷基或R 4 Z基，R 2的至少2/3 基团是R4Z基团，其中R4是双官能烃基，Z是-NH2，-NH（CH2）c-NH2，-NH（CH2）cNH（CH2）cNH2，其中c是2,3，-NHCONH2基团，-SH，-S4-R4-Si（OR3）3，-P（C6H5）2或R3是具有1至4个碳原子的烷基或氢原子，a不小于4，b / a不小于0.001，但不大于0.5，x不小于0.1，但不大于2，作为用于降低纸浆吸水性的材料，用于在纸层压石膏板的制造。有机硅化合物固化而不使用特殊的催化剂。它们的水性制剂在使用浓度下表现出高稳定性，并且与纸的pH无关。也可以减少不含硫酸铝的纸的吸水性。

9. 发明授权

US4626378A Use of fluorinated norbornylsiloxanes for defoaming freshly extracted degassing crude oil 失效
标题翻译：氟化降冰片基硅氧烷用于消泡新萃取脱气原油
公开(公告)号：US4626378A
公开(公告)日：1986-12-02
申请号：US748727
申请日：1985-06-25
申请人： Roland Berger , Hans-Ferdi Fink , Gotz Koerner , Jaroslav Langner , Christian Weitemeyer
发明人： Roland Berger , Hans-Ferdi Fink , Gotz Koerner , Jaroslav Langner , Christian Weitemeyer
IPC分类号： B01D19/04 , E21B43/34 , C07F7/04 , B01D17/05
CPC分类号： E21B43/34 , B01D19/0409
摘要： The use of fluorinated norbornylsiloxanes of the general formula ##STR1## in which R is a hydrocarbon radical with 1 to 6 carbon atoms or a phenyl radical;R.sup.1, R.sup.2, R.sup.3, R.sup.4 are the same or different and represent hydrogen or methyl radicals;R.sup.5, R.sup.6, R.sup.7, R.sup.8 are the same or different and represent hydrogen, fluorine radicals, hydrocarbon radicals with 1 to 8 carbon atoms, or fluorinated hydrocarbon radicals with 1 to 20 carbon atoms, in which at least one of the R.sup.5, R.sup.6, R.sup.7, R.sup.8 radicals must be a fluorine or a fluorinated hydrocarbon radical,Y is an organosiloxanyl radical,A is a divalent hydrocarbon radical or an oxygen radical, anda is 0, 1 or 2for defoaming freshly extracted degassing crude oil. The compounds are highly effective and show a broader area of application for defoaming degassing crude oils of different origins.
摘要翻译：使用通式为“IMAGE”的氟化降冰片基硅氧烷，其中R为具有1至6个碳原子的烃基或苯基; R1，R2，R3，R4相同或不同，代表氢或甲基; R5，R6，R7，R8相同或不同，表示氢，氟原子，碳原子数为1〜8的烃基或碳原子数1〜20的氟化烃基，其中，R5，R6， R7，R8自由基必须是氟或氟化烃基，Y是有机硅氧烷基，A是二价烃基或氧自由基，a是0,1或2，用于消泡新萃取的脱气原油。这些化合物是非常有效的，并且具有更广泛的应用于不同来源的脱泡脱气原油。

10. 发明授权

US4406738A Use of an organopolysiloxane preparation for the treatment of paper for the production of plaster boards 失效
标题翻译：使用有机聚硅氧烷制剂来处理生产石膏板的纸张
公开(公告)号：US4406738A
公开(公告)日：1983-09-27
申请号：US342202
申请日：1982-01-25
申请人： Hans-Ferdi Fink , Gotz Koerner , Edmund Luksch
发明人： Hans-Ferdi Fink , Gotz Koerner , Edmund Luksch
IPC分类号： B32B13/08 , C08G77/26 , D21H17/59 , D21F11/00
CPC分类号： C08G77/26 , B32B13/08 , D21H17/59 , Y10T428/31663 , Y10T428/31996
摘要： An organopolysiloxane suitable for use in treating paper to be used in plaster boards. The organopolysiloxane is obtained by reacting a polysiloxanol of the formula ##STR1## in which R.sup.1 is a methyl or a phenyl radical, at least 90% of the R.sup.1 radicals however being methyl radicals, andn=20 to 250,with a silane having the formulaH.sub.2 N--R.sup.3 --Si(OR.sup.2).sub.3in whichR.sup.2 is a lower alkyl radical with 1 to 4 carbon atoms,R.sup.3 is a bivalent alkyl radical with 1 to 6 carbon atoms or the --(CH.sub.2).sub.x R.sup.4 (CH.sub.2).sub.y --NH.sub.2 radical, in whichR.sup.4 is oxygen, sulfur or the --NH-- or --NH--CH.sub.2 CH.sub.2 --NH-- radical andx.ltoreq.3, andy.ltoreq.2,in such amounts that 1 SiOH group of the polysiloxanol corresponds to more than 1 and up to 3 OR.sup.2 groups of the silane. Method for preparation of paper and cardboard for use in plaster boards as well as plaster boards made by using the present invention are disclosed.
摘要翻译：适用于处理石膏板用纸的有机聚硅氧烷。有机聚硅氧烷是通过使式（IMAGE）的聚硅氧烷醇（其中R 1是甲基或苯基）反应得到的，至少90％的R 1基团是甲基，n = 20至250，硅烷具有式（II）其中R 2是具有1至4个碳原子的低级烷基，R 3是具有1至6个碳原子的二价烷基或 - （CH 2）x R 4（CH 2）y -NH 2 基团，其中R 4是氧，硫或-NH-或-NH-CH 2 CH 2 -NH-基和x 3和y 2，其量使得聚硅氧烷醇的1个SiOH基团对应于更多比1个和多达3个OR2组的硅烷。公开了用于石膏板以及通过使用本发明制成的石膏板的纸和纸板的制备方法。

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