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1. 发明授权

US4565719A Energy control window film systems and methods for manufacturing the same 失效
标题翻译：能量控制窗膜系统及其制造方法
公开(公告)号：US4565719A
公开(公告)日：1986-01-21
申请号：US433511
申请日：1982-10-08
申请人： Roger W. Phillips , Patrick K. Higgins , Peter H. Berning
发明人： Roger W. Phillips , Patrick K. Higgins , Peter H. Berning
IPC分类号： B32B9/00 , B32B15/00 , C03C17/36 , E06B3/24
CPC分类号： C03C17/3605 , C03C17/36 , C03C17/3613 , C03C17/3618 , C03C17/3644 , C03C17/366 , C03C17/3681 , C03C2217/78 , Y10T428/24975 , Y10T428/31678 , Y10T428/31681
摘要： An energy control sheet, including a highly transparent substructure having first and second surfaces, a substantially transparent, thin film metal layer formed on one surface of the substructure, and a highly transparent thin film dielectric layer formed over said metal layer. The dielectric layer comprises a mixed metal oxide layer having metal constituents of at least one lanthanide series metal (e.g. cerium oxide) and at least one transition or semiconductor metal (e.g. tin oxide). The dielectric layer is characterized by substantial water vapor impermeability so that the weatherability of the energy control sheet is substantially improved. The metal layer is either a silver layer or a silver-palladium alloy.
摘要翻译：一种能量控制片，包括具有第一和第二表面的高度透明的子结构，形成在所述子结构的一个表面上的基本上透明的薄膜金属层，以及形成在所述金属层上的高透明薄膜电介质层。电介质层包括具有至少一种镧系金属（例如氧化铈）和至少一种过渡金属或半导体金属（例如氧化锡）的金属成分的混合金属氧化物层。电介质层的特征在于显着的水蒸气不渗透性，使得能量控制片的耐候性显着提高。金属层是银层或银 - 钯合金。

2. 发明授权

US4930866A Thin film optical variable article and method having gold to green color shift for currency authentication 失效
标题翻译：薄膜光学可变制品和方法具有金色到绿色的颜色转换用于货币认证
公开(公告)号：US4930866A
公开(公告)日：1990-06-05
申请号：US204723
申请日：1988-06-10
申请人： Peter H. Berning , Roger W. Phillips
发明人： Peter H. Berning , Roger W. Phillips
IPC分类号： B42D15/00
CPC分类号： B42D25/29 , B42D2035/24 , Y10S359/90
摘要： Thin film optical variable article to be used in a reflection mode having a gold to green color shift with angle for currency authentication and adapted to be carried by a substantially opaque currency sheet which serves as a substrate. The article includes a substantially transparent, optically thick element carrying a colorant and having first and second surfaces and a multilayer interference coating carried on one of said first and second surfaces. The article is adapted to be carried by the currency sheet so that the coating faces the currency sheet and the colorant carrying element serves as a superstrate facing the incident light. The multilayer interference coating is comprised of a substantially opaque layer of aluminum nearest the substrate, followed by a layer of magnesium fluoride, and then by a layer of chromium having substantial transmission. The colorant has a yellow hue whereby at normal incidence of light the article has a coppery-gold color shifting towards a vivid green at non-normal incidence of light. The colorant operates in an essentially subtractive mode to cause a modification of the normal incidence gold color and the color shift with angle properties as seen by reflection.
摘要翻译：用于具有金色至绿色的反射模式的薄膜光学可变制品，其具有用于货币认证的角度并且适于由用作基板的基本上不透明的货币单元承载。所述制品包括携带着色剂并且具有第一和第二表面的基本上透明的光学厚的元件，以及承载在所述第一和第二表面之一上的多层干涉涂层。该物品适于由货币单据携带，使得涂层面向货币单，并且着色剂承载元件用作面对入射光的上表面。多层干涉涂层由最接近基底的基本上不透明的铝层组成，之后是一层氟化镁，然后由具有实质透射率的铬层组成。着色剂具有黄色色调，因此在正常入射光下，该物品具有以非正常入射光转向生动的绿色的铜色金色。着色剂以基本上减法的方式进行操作，以便通过反射观察到正常入射金色和颜色偏移与角度特性的变化。

3. 发明授权

US4779898A Thin film optically variable article and method having gold to green color shift for currency authentication 失效
标题翻译：用于货币认证的具有金色至绿色色彩的薄膜光学变量制品和方法
公开(公告)号：US4779898A
公开(公告)日：1988-10-25
申请号：US88144
申请日：1987-08-21
申请人： Peter H. Berning , Roger W. Phillips
发明人： Peter H. Berning , Roger W. Phillips
IPC分类号： B42D15/00
CPC分类号： B42D25/29 , B42D2035/24 , Y10S283/904
摘要： Thin film optical variable article to be used in a reflection mode having a gold to green color shift with angle for currency authentication and adapted to be carried by a substantially opaque currency sheet which serves as a substrate. The article includes a substantially transparent, optically thick element carrying a subtractive colorant and having first and second surfaces and a multilayer interference coating carried on one of said first and second surfaces. The article is adapted to be carried by the currency sheet so that the coating faces the currency sheet and the colorant carrying element serves as a superstrate facing the incident light. The multilayer interference coating is comprised of a substantially opaque layer of aluminum nearest the substrate, followed by a layer of magnesium fluoride, and then by a layer of chromium having substantial transmission. The colorant has a yellow hue. At normal incidence of light the article has a coppery-gold color shifting towards a vivid green at non-normal incidence of light. The colorant operates in an essentially subtractive mode in combination with the multilayer interference coating to provide the color shift from gold to green at two different angles of incidence and substantially no color at higher angles of incidence to cause a modification of the normal incidence gold color and the color shift with angle properties as seen by reflection.
摘要翻译：用于具有金色至绿色的反射模式的薄膜光学可变制品，其具有用于货币认证的角度并且适于由用作基板的基本上不透明的货币单元承载。所述制品包括携带减色剂并且具有第一和第二表面的基本上透明的光学厚的元件以及承载在所述第一和第二表面之一上的多层干涉涂层。该物品适于由货币单据携带，使得涂层面向货币单，并且着色剂承载元件用作面对入射光的上表面。多层干涉涂层由最接近基底的基本上不透明的铝层组成，之后是一层氟化镁，然后由具有实质透射率的铬层组成。着色剂具有黄色色调。在正常光照下，该物品在非正常发光情况下，呈铜绿色转向生动的绿色。着色剂以与多层干涉涂层组合的基本上减色模式操作，以在两个不同的入射角度提供从黄金到绿色的颜色偏移，并且在较高的入射角度基本上没有颜色，以引起正常入射的金色的变化，通过反射看到的角度属性的颜色偏移。

4. 发明授权

US4705356A Thin film optical variable article having substantial color shift with angle and method 失效
标题翻译：薄膜光学可变制品具有显着的颜色偏移角度和方法
公开(公告)号：US4705356A
公开(公告)日：1987-11-10
申请号：US630414
申请日：1984-07-13
申请人： Peter H. Berning , Roger W. Phillips
发明人： Peter H. Berning , Roger W. Phillips
IPC分类号： G02B5/22 , G02B5/28 , G06K19/06
CPC分类号： G02B5/288 , G02B5/223 , G06K19/06046 , Y10S283/902
摘要： Thin film optically variable article having substantial color shift with varying angle of light incidence and viewing and including an optically thick, substantially transparent element carrying a colorant and having first and second surfaces. A multilayer interference coating is carried on one of said first and second surfaces. The colorant serves to modify in essentially a subtractive mode the color at normal incidence and the color shift with angle of the multilayer interference coating as seen by reflection or transmission.
摘要翻译：薄膜光学可变制品具有具有变化的光入射角和观察角度的显着色移，并且包括带有着色剂并具有第一和第二表面的光学厚的基本上透明的元件。所述第一表面和第二表面中的一个上承载多层干涉涂层。着色剂用于在基本上减法模式下修改在反射或透射下观察到的多层干涉涂层在正常入射时的颜色和颜色偏移。

5. 发明授权

US4705300A Thin film optically variable article and method having gold to green color shift for currency authentication 失效
公开(公告)号：US4705300A
公开(公告)日：1987-11-10
申请号：US935065
申请日：1986-11-21
申请人： Peter H. Berning , Roger W. Phillips
发明人： Peter H. Berning , Roger W. Phillips
IPC分类号： B42D15/00
CPC分类号： B42D25/29
摘要： Thin film optical variable article to be used in a reflection mode having a gold to green color shift with angle for currency authentication and adapted to be carried by a substantially opaque currency sheet which serves as a substrate. The article includes a substantially transparent, optically thick element carrying a subtractive colorant and having first and second surfaces and a multilayer interference coating carried on one of said first and second surfaces. The article is adapted to be carried by the currency sheet so that the coating faces the currency sheet and the colorant carrying element serves as a superstrate facing the incident light. The multilayer interference coating is comprised of a substantially opaque layer of aluminum nearest the substrate, followed by a layer of magnesium fluoride, and then by a layer of chromium having substantial transmission. The colorant has a yellow hue. At normal incidence of light the article has a coppery-gold color shifting towards a vivid green at non-normal incidence of light. The colorant operates in an essentially subtractive mode in combination with the multilayer interference coating to provide the color shift from gold to green at two different angles of incidence and substantially no color at higher angles of incidence to cause a modification of the normal incidence gold color and the color shift with angle properties as seen by reflection.

6. 发明授权

US07029745B2 Security articles having diffractive surfaces and color shifting backgrounds 有权
$Security articles having diffractive surfaces and color shifting backgrounds$
公开(公告)号：US07029745B2
公开(公告)日：2006-04-18
申请号：US10706211
申请日：2003-11-12
申请人： Richard L. Bonkowski , Patrick K. Higgins , Charles T. Markantes , Roger W. Phillips
发明人： Richard L. Bonkowski , Patrick K. Higgins , Charles T. Markantes , Roger W. Phillips
IPC分类号： B32B3/00
CPC分类号： B42D25/328 , B42D25/29 , B42D25/369 , B42D25/373 , B42D2035/24 , G03H1/0011 , G03H1/02 , G03H1/0244 , G03H1/0256 , G03H2250/12 , G03H2250/42 , Y10T428/24355 , Y10T428/24479 , Y10T428/2457 , Y10T428/24802
摘要： A security article includes a light transmissive substrate having a first surface and an opposing second surface, with the first surface having an embossed region with an optical diffraction pattern or a holographic image pattern. A color shifting optical coating is formed on the substrate such as on the opposing second surface, with the optical coating providing an observable color shift as the angle of incident light or viewing angle changes. The security article can be used in a variety of applications and products to provide for enhanced security measures such as anticounterfeiting.

7. 发明授权

US5424119A Polymeric sheet having oriented multilayer interference thin film flakes therein, product using the same and method 失效
标题翻译：具有定向多层干涉薄膜薄片的聚合薄片，产品使用相同和方法
公开(公告)号：US5424119A
公开(公告)日：1995-06-13
申请号：US191992
申请日：1994-02-04
申请人： Roger W. Phillips , Paul G. Coombs , Patrick K. Higgins , Charles T. Markantes
发明人： Roger W. Phillips , Paul G. Coombs , Patrick K. Higgins , Charles T. Markantes
IPC分类号： B42D15/10 , B29C41/24 , B29C47/02 , B29C47/04 , B29C47/06 , B29C47/14 , B29C55/12 , B29C70/62 , B29D7/01 , B29L7/00 , B29L9/00 , B32B7/02 , B32B27/08 , B41M3/14 , G02B5/28 , B32B5/16 , B29C47/00 , B32B7/00 , B32B15/04 , B32B33/00
CPC分类号： B29C41/24 , B29C47/0021 , B29C47/06 , B29C47/062 , B29C55/12 , B29C70/62 , B29D7/01 , B32B27/08 , B41M3/14 , B42D25/355 , B29K2105/0032 , B29K2105/18 , B29K2995/002 , B29K2995/003 , B29K2995/0053 , Y10S428/916 , Y10T428/24124 , Y10T428/256 , Y10T428/257 , Y10T428/258 , Y10T428/259 , Y10T428/2991 , Y10T428/2993 , Y10T428/31507 , Y10T428/31786 , Y10T428/31797
摘要： A polymeric sheet comprising a layer of polymeric material having a first and second parallel surfaces. A plurality of oriented multilayer interference thin film flakes are disposed in the layer of polymeric material. The flakes have first and second parallel surfaces and a width and a thickness and have an aspect ratio of at least 2:1 for the width with respect to the thickness.
摘要翻译：包括具有第一和第二平行表面的聚合物材料层的聚合物片材。多个定向多层干涉薄膜薄片设置在聚合物材料层中。薄片具有第一和第二平行表面和宽度和厚度，并且对于相对于厚度的宽度具有至少2:1的纵横比。

8. 发明授权

US4581282A Enhanced durability solar insulating window film and assembly using the same 失效
标题翻译：增强耐用性太阳能绝缘窗膜和组装使用相同
公开(公告)号：US4581282A
公开(公告)日：1986-04-08
申请号：US567637
申请日：1984-01-03
申请人： Patrick K. Higgins , Roger W. Phillips , James K. Snyder
发明人： Patrick K. Higgins , Roger W. Phillips , James K. Snyder
IPC分类号： E06B3/66 , B32B15/08 , B32B17/10 , E06B9/24 , B32B15/04
CPC分类号： B32B17/10018 , B32B17/10055 , B32B17/10174 , Y10T428/12569 , Y10T428/12861 , Y10T428/12882 , Y10T428/1291 , Y10T428/24975 , Y10T428/31681 , Y10T428/31692
摘要： Solar insulating window film comprising a sheet of substantially transparent flexible polymer thin film plastic material having first and second surfaces. First, second and third layers are adherent to the first surface of the film. The second layer is formed of copper. The first layer is formed of a material which possesses substantially the same nobility as copper or is inert to copper. The first layer counting from the first surface is formed of a material selected from nickel and palladium and oxides and sulfides thereof. The third layer counting from the first surface is formed of a material selected from nickel, palladium and chromium and oxides and sulfides thereof.
摘要翻译：太阳能绝缘窗膜包括具有第一表面和第二表面的基本透明的柔性聚合物薄膜塑料材料片。首先，第二层和第三层附着在膜的第一表面上。第二层由铜形成。第一层由具有与铜基本相同的贵金属或对铜惰性的材料形成。从第一表面计数的第一层由选自镍和钯及其氧化物和硫化物的材料形成。从第一表面计数的第三层由选自镍，钯和铬及其氧化物和硫化物的材料形成。

9. 发明授权

US07005178B2 Security articles having diffractive surfaces and color shifting backgrounds 有权
$Security articles having diffractive surfaces and color shifting backgrounds$
标题翻译：具有衍射面和色移背景的安全用品
公开(公告)号：US07005178B2
公开(公告)日：2006-02-28
申请号：US10688357
申请日：2003-10-17
申请人： Richard L. Bonkowski , Patrick K. Higgins , Charles T. Markantes , Roger W. Phillips
发明人： Richard L. Bonkowski , Patrick K. Higgins , Charles T. Markantes , Roger W. Phillips
IPC分类号： G02B5/28
CPC分类号： B42D25/328 , B42D25/29 , B42D25/369 , B42D25/373 , B42D2035/24 , G03H1/0011 , G03H1/02 , G03H1/0244 , G03H1/0256 , G03H2250/12 , G03H2250/42 , Y10T428/24355 , Y10T428/24479 , Y10T428/2457 , Y10T428/24802
摘要： A security article includes a light transmissive substrate having a first surface and an opposing second surface, with the first surface having an embossed region with an optical diffraction pattern or a holographic image pattern. A color shifting optical coating is formed on the substrate such as on the opposing second surface, with the optical coating providing an observable color shift as the angle of incident light or viewing angle changes. The security article can be used in a variety of applications and products to provide for enhanced security measures such as anticounterfeiting.
摘要翻译：安全制品包括具有第一表面和相对的第二表面的透光基底，其中第一表面具有带有光学衍射图案或全息图像图案的压花区域。在相对的第二表面上的基板上形成色移光学涂层，随着入射光的角度或视角的变化，光学涂层提供可观察的色移。安全文章可用于各种应用和产品，以提供增强的安全措施，如防伪。

10. 发明授权

US06114018A Paired optically variable article with paired optical structures and ink, paint and foil incorporating the same and method 失效
标题翻译：具有成对光学结构和油墨的配对光学变量制品，包含相同的方法的油漆和箔
公开(公告)号：US06114018A
公开(公告)日：2000-09-05
申请号：US957852
申请日：1997-10-27
申请人： Roger W. Phillips , Charles T. Markantes , Shari Powell Fisher , Robert G. Slusser , Patrick K. Higgins , Anton F. Bleikolm
发明人： Roger W. Phillips , Charles T. Markantes , Shari Powell Fisher , Robert G. Slusser , Patrick K. Higgins , Anton F. Bleikolm
IPC分类号： G02B5/28 , B05D1/28 , B05D5/06 , B29C70/58 , B41M3/00 , B41M3/06 , B41M3/14 , B42D15/00 , B44C5/08 , B44F1/08 , B44F1/12 , C03C17/00 , C09C1/00 , C09C1/62 , C09D5/29 , C09D5/36 , C09D11/00 , F24J2/48 , G02B5/22 , B32B3/14 , B32B5/16 , B32B7/06 , B32B7/10
CPC分类号： B05D5/06 , B05D1/286 , B29C70/585 , B41M3/00 , B41M3/06 , B41M3/14 , B41M3/148 , B42D25/29 , B44F1/08 , C03C17/00 , C09C1/0015 , C09C1/0078 , C09D11/50 , C09D5/36 , F24J2/485 , G02B5/223 , G02B5/285 , B42D2035/24 , C01P2004/54 , C09C2200/24 , C09C2200/303 , C09C2220/20 , Y02E10/40 , Y10S428/915 , Y10S428/916 , Y10T428/1476 , Y10T428/1486 , Y10T428/24843 , Y10T428/24851 , Y10T428/2486 , Y10T428/24893 , Y10T428/24901 , Y10T428/2817 , Y10T428/2839 , Y10T428/2982
摘要： An optically variable article comprising of a substrate and at least one non-overlapping pair of optically variable structures on the surface of the substrate, the optically variable structures having the same color at one angle of incidence and different colors at all other angles of incidence. The optically variable structures are formed from optically variable pigments, optically variable opaque foils, or optically variable multilayer thin film interference stacks.
摘要翻译：一种光学可变制品，其包括基底和在基底表面上的至少一个不重叠的光学可变结构对，所述光学可变结构在一个入射角具有相同的颜色，在所有其它入射角处具有不同的颜色。光学可变结构由光学可变颜料，光学可变不透明箔或光学可变多层薄膜干涉叠层形成。

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