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1. 发明申请

US20070269657A1 Method for the Production of an Isotropic Polymeric Network 审中-公开
标题翻译：各向同性聚合物网络生产方法
公开(公告)号：US20070269657A1
公开(公告)日：2007-11-22
申请号：US10552472
申请日：2004-04-14
申请人： Roelof Marissen , Ronald Lange , Betty Coussens , Jozef Put , Joachim Dijk Van , Jacobus Loontjens
发明人： Roelof Marissen , Ronald Lange , Betty Coussens , Jozef Put , Joachim Dijk Van , Jacobus Loontjens
IPC分类号： B29C47/78 , B32B9/04
CPC分类号： C08G77/54 , C08G61/02 , C08G61/12 , C08G83/00 , Y10T428/31504
摘要： The present invention relates to a method for the production of an isotropic polymeric network comprising multifunctional molecules with a functionality of at least 5 by reacting in a solvent the multifunctional molecules with a coupling agent, wherein the coupling agent is present in an amount which is sufficient to couple the multifunctional molecules to at least 5 other multifunctional molecules and wherein the sum, ρ, of the amounts of the multifunctional molecules and coupling agent per unit of volume, in kg/m3, is at least equal to the value as given by expression (I) in which a=0.2 d=the diameter of the multifunctional molecule, including the length of the bonds to the middle of atoms of the coupling agent to which it is attached. L=the length of the coupling agent, measured between the middle of the atoms that are connected to the multifunctional molecule. m1=the molecular mass of the multifunctional molecule as present in the isotropic 20 polymeric network m2=the molecular mass of the coupling agent as present in the isotropic polymeric network n=the functionality of the multifunctional molecule (n≧5). The invention furthermore relates to an isotropic polymeric network with a density lower than 1000 kg/m3 and a specific Young's modulus of at least 0.01 GPa.m3/kg, shaped articles hereof and the use of the isotropic polymeric network as construction material.
摘要翻译：本发明涉及通过在溶剂中使多官能分子与偶联剂反应而制备各向同性聚合物网络的方法，其中官能度至少为5的多官能分子，其中偶联剂的存在量足够将多功能分子连接至至少5个其他多功能分子，其中以kg / m 3为单位的单位体积的多功能分子和偶联剂的量的总和至少为等于由表达式（I）给出的值，其中a = 0.2d =多功能分子的直径，包括连接到其所连接的偶联剂的原子中间的键的长度。 L =耦合剂的长度，在连接到多功能分子的原子的中间测量。 m 1 =各向同性20聚合物网络中存在的多官能分子的分子量m 2 =存在于各向同性聚合物网络中的偶联剂的分子质量n =多功能分子的功能（n> = 5）。本发明还涉及密度低于1000kg / m 3的各向同性聚合物网络，并且具有至少0.01GPa.m 3 / kg的特定杨氏模量，成形文章和各向同性聚合物网络的使用作为建筑材料。

2. 发明授权

US5075398A Bismaleimide-styrene compound-acid compound-containing thermosetting composition 失效
标题翻译：双马来酰亚胺苯乙烯复合酸化合物热固化组合物
公开(公告)号：US5075398A
公开(公告)日：1991-12-24
申请号：US434501
申请日：1989-11-13
申请人： Adrianus J. de Koning , Jacobus Loontjens
发明人： Adrianus J. de Koning , Jacobus Loontjens
IPC分类号： C07D207/44 , C07D207/452 , C07D307/34 , C07D405/12 , C08F222/40
CPC分类号： C07D207/452 , C07D307/34 , C07D405/12 , C08F222/40
摘要： Thermosetting compositions consist of a homogeneous mixture of an ethylenically unsaturated compound, a bismaleimide compound or a bismaleimide containing composition and an acid compound, with optionally further copolymerizable compounds and usual additives. The thermosetting composition are useful as a coating resin, a laminating resin or for the manufacture of shaped articles.
摘要翻译：热固性组合物由烯属不饱和化合物，双马来酰亚胺化合物或含双马来酰亚胺组合物和酸化合物的均匀混合物，任选的其它可共聚合的化合物和通常的添加剂组成。热固性组合物可用作涂布树脂，层压树脂或用于制造成型制品。

3. 发明申请

US20070161773A1 Process for preparing a high molecular polycondensate 审中-公开
标题翻译：制备高分子缩聚物的方法
公开(公告)号：US20070161773A1
公开(公告)日：2007-07-12
申请号：US10584863
申请日：2004-12-29
申请人： Jacobus Loontjens
发明人： Jacobus Loontjens
IPC分类号： C08G64/00 , C08G63/02
CPC分类号： C08G69/04 , C08G63/91 , C08G64/42 , C08G69/28 , C08G69/44 , C08G69/48
摘要： The invention relates to a process for preparing a high-molecular polycondensate, i.e. a polyester, a polyamide, a polyester-amide, a polycarbonate, a polyether or a block copolymer by melt-mixing a polyester, a polyamide, a polycarbonate, a polyether or a mixture of at least two of these said polycondensates with a carbonyl bislactam according to formula (I) in which formula n is an integer of between 3 and 15, and a diepoxide. Preferably said diepoxide is a compound containing epoxy radicals of formula (II), which radicals are linked direct to carbon, oxygen, nitrogen or sulfur atoms, wherein R1 and R3 are both hydrogen, R2 is hydrogen or methyl, and m=0, or wherein R1 and R3, taken together, are —CH2—CH2— or —CH2—CH2—CH2—, in which case R2 is hydrogen and m=0 or 1. The present invention results in a more stable process for the production of a polycondensate with a high molecular mass. Furthermore the polycondensate obtained with the process according to the invention has, even under extreme process conditions such as high temperature, less discoloration. With the process according to the invention a permanent increase in the molecular weight of a polycondensate is obtained in an even faster way than with processes according to the state of the art.
摘要翻译：本发明涉及通过熔融混合聚酯，聚酰胺，聚碳酸酯，聚醚等制备高分子缩聚物，即聚酯，聚酰胺，聚酯 - 酰胺，聚碳酸酯，聚醚或嵌段共聚物的方法或这些所述缩聚物中的至少两种与根据式（I）的羰基双内酰胺的混合物，其中式n为3至15的整数，和二环氧化物。优选地，所述双环氧化物是含有式（II）的环氧基的化合物，该基团直接连接到碳，氧，氮或硫原子上，其中R 1和R 3，都是氢，R 2是氢或甲基，m = 0，或者其中R 1和R 3均一起是 - CH 2 -CH 2 - 或-CH 2 -CH 2 -CH 2 - / SUB > - ，其中R 2是氢，m = 0或1.本发明导致制备具有高分子量的缩聚物的更稳定的方法。此外，通过本发明的方法获得的缩聚物即使在极端的工艺条件下，例如高温，较少变色。通过根据本发明的方法，以比根据现有技术的方法更快的方式获得缩聚物的分子量的永久增加。

4. 发明申请

US20070010603A1 Process for the preparation of a polymer composition 失效
标题翻译：制备聚合物组合物的方法
公开(公告)号：US20070010603A1
公开(公告)日：2007-01-11
申请号：US10572371
申请日：2004-09-17
申请人： Jacobus Loontjens
发明人： Jacobus Loontjens
IPC分类号： C08K5/35
CPC分类号： C08G63/91
摘要： The invention relates to a process for the preparation of a polymer composition, the process comprising a step of contacting a polymer that comprises carboxyl groups with a cyclic imino ether compound characterized in that the cyclic imino ether compound is a phenylene oxazine according to formula (I), in which formula R=an oxazine group according to formula (II) n=0, 1, 2, 3, 4 or 5 and that the polymer is contacted with said oxazine in an extruder at a temperature above 100° C.
摘要翻译：本发明涉及一种制备聚合物组合物的方法，该方法包括使包含羧基的聚合物与环状亚氨基醚化合物接触的步骤，其特征在于环状亚氨基醚化合物是式（I ），其中R =式（II）的恶嗪基n = 0,1,2,3,4或5，并且聚合物在挤出机中在高于100℃的温度下与所述恶嗪接触。

5. 发明申请

US20050222407A1 Method for the preparation of ethylenically unsaturated compounds with lactam-blocked isocyanate groups 审中-公开
标题翻译：用内酰胺封端异氰酸酯基团制备烯属不饱和化合物的方法
公开(公告)号：US20050222407A1
公开(公告)日：2005-10-06
申请号：US10505325
申请日：2003-02-20
申请人： Jacobus Loontjens
发明人： Jacobus Loontjens
IPC分类号： C07D223/10 , C08F20/36 , C08G18/67 , C08G18/80 , C08G18/81 , C08F8/30
CPC分类号： C08G18/672 , C07D223/10 , C08G18/8074 , C08G18/8116
摘要： The invention relates to a method for the preparation of ethylenically unsaturated lactam-blocked isocyanate compounds, by reacting an unsaturated amine-functional or hydroxy-functional compound with carbonylbislactam. These compounds can be polymerised and are subsequently cured by the built-in crosslinker to form thermosetting polymers which can be applied for instance in powder coatings.
摘要翻译：本发明涉及通过使不饱和胺官能化或羟基官能化合物与羰基双内酰胺反应来制备烯键式不饱和内酰胺封端异氰酸酯化合物的方法。这些化合物可以被聚合并随后通过内置的交联剂固化以形成可用于例如粉末涂料中的热固性聚合物。

6. 发明授权

US5013701A Catalyst system for high-temperature (co) polymerization of ethylene 失效
标题翻译：用于乙烯高温（共）聚合的催化剂体系
公开(公告)号：US5013701A
公开(公告)日：1991-05-07
申请号：US336608
申请日：1989-04-10
申请人： Luc M. C. Coosmans , Johannes Blenkers , Jacobus Loontjens
发明人： Luc M. C. Coosmans , Johannes Blenkers , Jacobus Loontjens
IPC分类号： C08F4/64 , C08F4/60 , C08F4/62 , C08F4/685 , C08F10/02
CPC分类号： C08F10/02
摘要： Catalyst system, suitable for the (co)polymerization of ethylene and optionally minor amounts of 1-alkenes and/or dienes at a temperature of at least 180.degree. C., to be prepared by combining at least two components A and B, which components comprise:A: one or more titanium compounds, one or more vanadium compounds, one or more aluminium compounds, one or more magnesium compounds and optionally one or more halogen compounds, in such amounts that the atomic ratio of magnesium to the sum of titanium and vanadium is between 0 and 10, the atomic ratio of aluminium to the sum of titanium and vanadium is at least 3, the atomic ratio of aluminium to magnesium is at least 1, and the atomic ratio of halogen to magnesium is at least 2,B: one or more organoaluminium compounds, which two components are, separately or in combination, supplied direct to the polymerization vessel.

7. 发明申请

US20050158560A1 Process for the preparation of a functionalized polymer intermediate products, compositions and shaped parts 失效
标题翻译：制备官能化聚合物中间产物，组合物和成型部件的方法
公开(公告)号：US20050158560A1
公开(公告)日：2005-07-21
申请号：US10505323
申请日：2003-02-20
申请人： Jacobus Loontjens , Bartholomeus Johannes Plum , Albert Geenen, Van , Weihua Ming
发明人： Jacobus Loontjens , Bartholomeus Johannes Plum , Albert Geenen, Van , Weihua Ming
IPC分类号： C08C19/30 , C08F8/30 , C08G85/00 , B32B27/00 , C08F283/04 , C08G18/81
CPC分类号： C08C19/30 , C08F8/30 , C08G85/004 , Y10T428/31551
摘要： Process for the preparation of a functionalized polymer containing an additive, in which process there is formed a compound that contains, besides at least one blocked isocyanate group, a free amino, hydroxy or carboxy group; this compound is linked to an additive via the free amino, hydroxy or carboxy group in the additive; this additive linked to the compound mentioned is contacted with a polymer that contains at least one free amino or hydroxyl group, at a temperature above the polymer's melting point and at least above (150)° C., such that the blocked isocyanate group reacts with the free amino or hydroxy group of the polymer to form the functionalized polymer. The invention also relates to the intermediate products formed in the process and in the preparation thereof. Lasdy, the invention relates to functionalized polymers and polymer compositions containing the functionalized polymer.
摘要翻译：制备含有添加剂的官能化聚合物的方法，其中形成除了至少一个封端异氰酸酯基团外还含有游离氨基，羟基或羧基的化合物; 该化合物通过添加剂中的游离氨基，羟基或羧基与添加剂连接; 将与所述化合物连接的该添加剂在高于聚合物熔点和至少高于（150）℃的温度下与含有至少一个游离氨基或羟基的聚合物接触，使得封端异氰酸酯基团与聚合物的游离氨基或羟基以形成官能化聚合物。本发明还涉及在该方法和其制备过程中形成的中间产物。 Lasdy，本发明涉及含官能化聚合物的官能化聚合物和聚合物组合物。

8. 发明申请

US20050143548A1 Process for preparing a high-molecular polyamide, polyester, copolyester, copolyamide or polyester-amide block copolymer 审中-公开
标题翻译：制备高分子量聚酰胺，聚酯，共聚酯，共聚酰胺或聚酯 - 酰胺嵌段共聚物的方法
公开(公告)号：US20050143548A1
公开(公告)日：2005-06-30
申请号：US10505155
申请日：2003-02-20
申请人： Jacobus Loontjens , Bartholomeus Johannes Plum
发明人： Jacobus Loontjens , Bartholomeus Johannes Plum
IPC分类号： C08G18/08 , C08G18/42 , C08G18/60 , C08G18/80 , C08G63/91 , C08G69/48 , C08G18/00 , C08G63/02
CPC分类号： C08G18/0895 , C08G18/4213 , C08G18/603 , C08G18/8074 , C08G63/916 , C08G69/48
摘要： The invention relates to a process for preparing a high-molecular polyamide or polyester or copolyester by melt-mixing polyamide or polyester or copolyester having a lower molecular weight with a blocked diisocyanate having the following formula. wherein R=linear, branched or cyclo aliphatic C2-C20 or aromatic C6-C20 and B1, B2=Caprolactam, Imidazole, dimethyl-pyrazole, triazole, oxim, malonic acid ester, ethylacetylacetonate, phenol, cresol, aliphatic alcohol, secundary amine, hydroxy benzoic acid methyl ester. With the process according to the invention a permanent increase in the molecular weight of a polyamide is obtained within 2 minutes, whereas this takes at least 10 minutes under comparable conditions using a blocked isocyanate according to the state of the art.
摘要翻译：本发明涉及通过将具有较低分子量的聚酰胺或聚酯或共聚酯与具有下式的封端二异氰酸酯熔融混合来制备高分子量聚酰胺或聚酯或共聚酯的方法。其中R =直链，支链或环脂族C 2 -C 20或芳族C 6 -C 20和其中C B 1，B 2 =己内酰胺，咪唑，二甲基 - 吡唑，三唑，肟，丙二酸酯，乙基乙酰丙酮化物，苯酚，甲酚，脂族醇，仲胺，羟基苯甲酸酸甲酯。根据本发明的方法，在2分钟内获得聚酰胺的分子量的永久增加，而根据现有技术，使用封端异氰酸酯在相当的条件下至少需要10分钟。

9. 发明申请

US20120171271A1 ANTIMICROBIAL MATERIAL FOR WATER STERILIZATION 审中-公开
标题翻译：用于水灭菌的抗微生物材料
公开(公告)号：US20120171271A1
公开(公告)日：2012-07-05
申请号：US13375274
申请日：2010-07-13
申请人： Jacobus Loontjens , Alexander Peter Marie Vrinzen
发明人： Jacobus Loontjens , Alexander Peter Marie Vrinzen
IPC分类号： A01N25/12 , B29B9/02 , A01N59/16 , A01P1/00 , B82Y40/00 , B82Y5/00
CPC分类号： C02F1/688 , A01N59/16 , C02F1/50 , Y02W10/37 , A01N25/10 , A01N25/12 , A01N25/34 , A01N2300/00
摘要： The present invention relates to an antimicrobial material consisting of particles comprising an antimicrobial agent (A) and a carrier (B), wherein: the antimicrobial material is a granular material; at least 90% w/w of the particles have a particle size in the range of from 1.0 mm up to and including 8.0 mm measured according to the method DIN 66165-1/-2; at least 90% w/w of the particles have an aspect ratio R, equal to or lower than 8; the antimicrobial agent (A) comprises elemental silver nanoparticles; the antimicrobial agent (A) is present in an amount in the range of from 0.001% w/w up to and including 2% w/w on antimicrobial material; the carrier (B) is a polymer comprising a polyamide; the carrier (B) is present in an amount in the range of from 98% w/w up to and including 99.999% w/w on antimicrobial material. The invention further relates to an article comprising the granular antimicrobial material, a device comprising the granular antimicrobial material or the article. The invention also relates to a process for preparing the granular antimicrobial material and use of the granular antimicrobial material or an article or a device comprising the granular antimicrobial material in water treatment systems/appliances, water filters, swimming pools, whirlpools, water supply containers, water storage and for treatment of drinking water.
摘要翻译：本发明涉及由包含抗微生物剂（A）和载体（B）的颗粒组成的抗微生物材料，其中：抗微生物材料是颗粒材料; 至少90％w / w的颗粒具有根据DIN 66165-1 / -2的方法测量的尺寸在1.0mm至8.0mm范围内的粒度; 至少90％w / w的颗粒具有等于或低于8的纵横比R; 抗微生物剂（A）包含元素银纳米颗粒; 抗微生物剂（A）以抗微生物材料的0.001％w / w至2％w / w的量存在; 载体（B）是包含聚酰胺的聚合物; 载体（B）的存在量为抗菌材料的98％w / w至99.999％w / w的范围。本发明还涉及包含颗粒抗微生物材料的制品，包含颗粒状抗微生物材料或制品的装置。本发明还涉及一种制备颗粒抗微生物材料的方法以及在水处理系统/设备，水过滤器，游泳池，旋流器，给水容器中的粒状抗微生物材料或包含颗粒状抗微生物材料的制品或装置的使用，储水和饮用水处理。

10. 发明申请

US20060122367A1 Process for preparing biocompatible polyurea 审中-公开
标题翻译：制备生物相容性聚脲的方法
公开(公告)号：US20060122367A1
公开(公告)日：2006-06-08
申请号：US10525953
申请日：2003-08-07
申请人： Rolf Mulhaupt , Jacobus Loontjens , Steffen Maier , Jorg Zimmermann
发明人： Rolf Mulhaupt , Jacobus Loontjens , Steffen Maier , Jorg Zimmermann
IPC分类号： C08G73/00
CPC分类号： C08G71/02
摘要： A process is provided for preparing urea-containing polymers by contacting a hydroxy-functional organic compound having a functionality of two or more, with a coupling agent in the presence of a strong base, wherein the coupling agent is a carbonylbislactam compound having the general formula (I): wherein n is an integer from 3 to 15, and that the contacting is conducted at a temperature between 0° C. and 80° C. The polymers thus obtained are believed to be new and are useful e.g. in tissue engineering and coatings applications.
摘要翻译：提供了一种制备含尿素聚合物的方法，其通过使具有两个或多个官能度的羟基官能的有机化合物与强碱的存在下与偶联剂接触，其中偶联剂是具有通式的羰基双内酰胺化合物（I）：其中n为3至15的整数，并且接触在0℃至80℃之间的温度下进行。由此获得的聚合物被认为是新的，可用于例如在组织工程和涂料应用中。

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