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1. 发明授权

US07495057B2 Lpa hybride 失效
标题翻译： Lpa杂种
公开(公告)号：US07495057B2
公开(公告)日：2009-02-24
申请号：US10474440
申请日：2002-04-08
申请人： Adrianus J De Koning , Markus R Luesken , Peter Dijkink
发明人： Adrianus J De Koning , Markus R Luesken , Peter Dijkink
IPC分类号： C08G18/04 , C08L75/00
CPC分类号： C08L51/08 , C08F283/006 , C08G18/672 , C08L75/16 , C08L2666/02 , C08L29/00
摘要： The invention relates to resin compositions that contains as components: (A) a monomer with at least one ethylenic unsaturation and with an isocyanate reactive group, (B) an ethylenically unsaturated monomer that can react with component (A) by means of radical polymerization, (C) a polyisocyanate that can react with component (A) by means of a polyurethane reaction and that on average has at least 1.75 isocyanate groups, (D) a catalyst for the radical polymerization, and that also contains (E) a thermoplastic polymer with an average molecular weight of at least 10,000 Dalton. The invention also relates to a process for the preparation of moulded articles from such resin compositions, as well as the moulded articles themselves.
摘要翻译：本发明涉及含有以下组分的树脂组合物：（A）具有至少一个烯属不饱和度和异氰酸酯反应性基团的单体，（B）可通过自由基聚合与组分（A）反应的烯属不饱和单体，（C）可通过聚氨酯反应与组分（A）反应并且平均具有至少1.75个异氰酸酯基团的多异氰酸酯，（D）用于自由基聚合的催化剂，并且还含有（E）热塑性聚合物平均分子量至少为10,000道尔顿。本发明还涉及从这种树脂组合物以及模塑制品本身制备模塑制品的方法。

2. 发明授权

US4948821A Thermosetting composition 失效
标题翻译：热固性组合物
公开(公告)号：US4948821A
公开(公告)日：1990-08-14
申请号：US233437
申请日：1988-08-18
申请人： Adrianus J. De Koning , Arnold J. Voskamp
发明人： Adrianus J. De Koning , Arnold J. Voskamp
IPC分类号： C08F299/04 , C08F283/01 , C08L67/06
CPC分类号： C08L67/06
摘要： The invention relates to a thermosetting composition comprisingA: 30-65 parts by weight of unsaturated polyester with a molar mass per double bond of 142-500B: 25-55 parts by weight of ethylenically unsaturated monomerC: 3-35 parts by weight of slightly ethylenically unsaturated polyesterD: 0-750 parts by weight of filler, fibrous material and, if so desired, other usual additives, characterized in that as as slight ethylenically unsaturated polyester an unsaturated polyester is used which has a molar mass per double bond of 1200-20,000 and an acid number of 5-50, and in which between 50 and 90% of the unsaturation consists of a terminal monoester of a .alpha., .beta.-unsaturated dicarboxylic acid. The composition presents little or no shrinkage in setting.

3. 发明授权

US4766179A Bismaleimide compositions 失效
标题翻译：双马来酰亚胺组合物
公开(公告)号：US4766179A
公开(公告)日：1988-08-23
申请号：US867691
申请日：1986-05-28
申请人： Adrianus J. De Koning
发明人： Adrianus J. De Koning
IPC分类号： C08F20/00 , C08F2/44 , C08F20/26 , C08F20/34 , C08F20/52 , C08F220/28 , C08F220/34 , C08F222/40 , C08G73/12 , C08L79/08
CPC分类号： C08F222/40 , C08G73/12
摘要： The invention relates to a composition comprising(A) 64-4 parts by wt. of a bismaleimide compound, or an isomaleimide isomer thereof, a maleimide-amide compound or an isomaleimide isomer thereof and maleic anhydride compound,(B) 7-77 parts by wt. of one or more ethylenically unsaturated compounds containing 5-50 C-atoms and is characterized in that the composition further comprises(C) 3-60 parts by wt. of one or more compounds from the group of hydroxy-alkylacrylates or amino-alkylacrylates,(D) 1-20 parts by wt. of one or more terminally functional polymers as flexibilizer, with the proviso that the sum, of parts of compounds A, B, C and D amounts to 100.
摘要翻译：本发明涉及一种组合物，其包含（A）64-4重量份的双马来酰亚胺化合物或其异马来酰亚胺异构体，马来酰亚胺 - 酰胺化合物或异马来酰亚胺异构体和马来酸酐化合物，（B）7-77重量份。的一种或多种含有5-50个C原子的烯键式不饱和化合物，其特征在于该组合物还包含（C）3-60重量份的一种或多种来自丙烯酸烷基酯或氨基 - 烷基丙烯酸酯的化合物，（D）1-20重量份。的一种或多种末端官能聚合物作为增韧剂，条件是化合物A，B，C和D的部分的总和等于100。

4. 发明授权

US4684706A Compositions containing maleimide-amide compounds as well as the preparation and application thereof 失效
标题翻译：含有马来酰亚胺 - 酰胺化合物的组合物及其制备和应用
公开(公告)号：US4684706A
公开(公告)日：1987-08-04
申请号：US823576
申请日：1986-01-29
申请人： Adrianus J. de Koning , Jacobus A. Loontjens , Hubertus A. M. Mostert , Hubertus A. A. Omloo
发明人： Adrianus J. de Koning , Jacobus A. Loontjens , Hubertus A. M. Mostert , Hubertus A. A. Omloo
IPC分类号： C08F20/00 , C07D207/44 , C07D207/448 , C07D207/452 , C07D307/34 , C07D307/66 , C07D405/12 , C07D407/12 , C08F20/52 , C08F22/36 , C08F22/40 , C08F34/00 , C08F222/40 , C08G73/00 , C08G73/10 , C08G73/12 , C08F226/06
CPC分类号： C07D207/452 , C07D307/34 , C07D405/12 , C08F222/40
摘要： The invention relates to compositions containing 80-30 wt.-% of bismaleimide-compounds, 5-60 wt.-% maleimide-amide compounds and 1-10 wt.-% of a maleic an hydride derivative. The invention also relates to the preparation of such compositions as well as the homogeneous curable compositions, in a suitable solvent, comprising bismaleimide/maleimide-amide/maleic an hydride. The obtained copolymers show good chemical resistance and a high heat distortion temperature.

5. 发明授权

US5286832A Process and resin composition for the manufacture of cast, injection moulded or compression moulded pieces 失效
标题翻译：用于制造铸造，注塑或压塑件的工艺和树脂组合物
公开(公告)号：US5286832A
公开(公告)日：1994-02-15
申请号：US671620
申请日：1991-03-20
申请人： Ronald L. Verleg , Adrianus J. De Koning
发明人： Ronald L. Verleg , Adrianus J. De Koning
IPC分类号： B29C39/00 , B29C43/00 , B29C45/00 , B29K31/00 , C08F290/06 , C08G18/62 , C08G18/67 , C08G18/68 , C08J3/24 , C08G18/34 , C08F20/06
CPC分类号： C08J3/243 , C08G18/6705 , C08G18/675 , C08G18/683 , Y10S525/92
摘要： The present invention relates to a process for the manufacture of a cast, injection moulded or compression moulded articles by curing a resin composition in a desired shape using catalysts, and allowing the shaped piece to post-cure under such conditions that an HDT of at least 150.degree. C. is obtained. The resin composition comprises a polyisocyanate, an ethylenically unsaturated monomer and a vinyl ester compound, and the vinyl ester compound contains on average about two to about 6 (meth)acrylate groups and on average about two to about 6 hydroxyl groups, and has a molecular weight higher than 300. The invention also relates to a resin composition suitable for use in the process.
摘要翻译：本发明涉及一种通过使用催化剂固化所需形状的树脂组合物来制造铸造，注塑或压塑制品的方法，并且允许成形件在至少达到HDT的条件下后固化获得150摄氏度。树脂组合物包含多异氰酸酯，烯键式不饱和单体和乙烯基酯化合物，并且乙烯基酯化合物平均包含约2至约6个（甲基）丙烯酸酯基团，平均约2至约6个羟基，并且具有分子本发明还涉及适用于该方法的树脂组合物。

6. 发明授权

US5075398A Bismaleimide-styrene compound-acid compound-containing thermosetting composition 失效
标题翻译：双马来酰亚胺苯乙烯复合酸化合物热固化组合物
公开(公告)号：US5075398A
公开(公告)日：1991-12-24
申请号：US434501
申请日：1989-11-13
申请人： Adrianus J. de Koning , Jacobus Loontjens
发明人： Adrianus J. de Koning , Jacobus Loontjens
IPC分类号： C07D207/44 , C07D207/452 , C07D307/34 , C07D405/12 , C08F222/40
CPC分类号： C07D207/452 , C07D307/34 , C07D405/12 , C08F222/40
摘要： Thermosetting compositions consist of a homogeneous mixture of an ethylenically unsaturated compound, a bismaleimide compound or a bismaleimide containing composition and an acid compound, with optionally further copolymerizable compounds and usual additives. The thermosetting composition are useful as a coating resin, a laminating resin or for the manufacture of shaped articles.
摘要翻译：热固性组合物由烯属不饱和化合物，双马来酰亚胺化合物或含双马来酰亚胺组合物和酸化合物的均匀混合物，任选的其它可共聚合的化合物和通常的添加剂组成。热固性组合物可用作涂布树脂，层压树脂或用于制造成型制品。

7. 发明授权

US4582883A Compositions containing maleimide-amide compounds as well as the preparation and application thereof 失效
标题翻译：含有马来酰亚胺 - 酰胺化合物的组合物及其制备和应用
公开(公告)号：US4582883A
公开(公告)日：1986-04-15
申请号：US650080
申请日：1984-09-13
申请人： Adrianus J. de Koning , Jacobus A. Loontjens , Hubertus A. M. Mostert , Hubertus A. A. Omloo
发明人： Adrianus J. de Koning , Jacobus A. Loontjens , Hubertus A. M. Mostert , Hubertus A. A. Omloo
IPC分类号： C08F20/00 , C07D207/44 , C07D207/448 , C07D207/452 , C07D307/34 , C07D307/66 , C07D405/12 , C07D407/12 , C08F20/52 , C08F22/36 , C08F22/40 , C08F34/00 , C08F222/40 , C08G73/00 , C08G73/10 , C08G73/12 , C08F226/06
CPC分类号： C07D207/452 , C07D307/34 , C07D405/12 , C08F222/40
摘要： The invention relates to compositions containing 80-30 weight % of bismaleimide-compounds, 5-60 weight % maleimide-amide compounds and 1-10 weight % maleic anhydride derivative. The invention further relates to the preparation of such compositions and to homogeneous curable compositions comprising bismaleimide/maleimide-amide/maleic anhydride compositions according to the invention. The obtained copolymers show good chemical resistance and a high heat distortion temperature.
摘要翻译：本发明涉及含有80-30重量％双马来酰亚胺化合物，5-60重量％马来酰亚胺 - 酰胺化合物和1-10重量％马来酸酐衍生物的组合物。本发明还涉及这种组合物的制备和包含本发明的双马来酰亚胺/马来酰亚胺 - 酰胺/马来酸酐组合物的均匀的可固化组合物。所得共聚物显示出良好的耐化学性和高的热变形温度。

8. 发明授权

US5393829A Resin composition containing low-molecular weight compounds which form a polyester urethane hybrid network 失效
标题翻译：含有形成聚酯聚氨酯混合网络的低分子量化合物的树脂组合物
公开(公告)号：US5393829A
公开(公告)日：1995-02-28
申请号：US169711
申请日：1992-12-28
申请人： Ronald L. Verleg , Adrianus J. De Koning
发明人： Ronald L. Verleg , Adrianus J. De Koning
IPC分类号： C08G18/68 , B29C45/00 , C08L75/06
CPC分类号： C08G18/683 , C08G18/68 , C08G2120/00
摘要： The invention relates to a resin composition containing low-molecular compounds which form a polyester urethane hybrid network. The resin composition contains a first component consisting of a condensation product of at least one diol and at least one unsaturated dicarboxylic acid material, a second component containing an ethylenically unsaturated monomer capable of copolymerizing with the first component, and a third component consisting of a polyisocyanate. The first component substantially consists of a diester compound of 2 diol molecules and 1 molecule of a dicarboxylic acid material, which dicarboxylic acid material consists of at least 75% of .alpha.-, .beta.-unsaturated dicarboxylic acid.
摘要翻译：本发明涉及含有形成聚酯聚氨酯混合网络的低分子化合物的树脂组合物。该树脂组合物含有由至少一种二醇与至少一种不饱和二羧酸物质的缩合物构成的第一成分，含有能够与第一成分共聚的烯属不饱和单体的第二成分和由多异氰酸酯。第一组分基本上由2个二醇分子的二酯化合物和1分子的二羧酸材料组成，该二羧酸材料由至少75％的α-不饱和二羧酸组成。

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